CN103304724A - Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion - Google Patents
Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion Download PDFInfo
- Publication number
- CN103304724A CN103304724A CN2012100585834A CN201210058583A CN103304724A CN 103304724 A CN103304724 A CN 103304724A CN 2012100585834 A CN2012100585834 A CN 2012100585834A CN 201210058583 A CN201210058583 A CN 201210058583A CN 103304724 A CN103304724 A CN 103304724A
- Authority
- CN
- China
- Prior art keywords
- polymerization reaction
- reaction kettle
- parts
- vinyl acetate
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention relates to a vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion. The copolymerized emulsion is characterized by using the vinyl chloride, the acrylic acid ester, the vinyl acetate, the acrylic acid, sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, polyoxyethylene octyl phenyl ether, alkylphenol polyoxyethylene (4) ether, polyvinyl pyrrolidone, an ammonium persulfate solution and deionized water as raw materials, preparing emulsified monomers, mixing, polymerizing, performing vacuum-pumping recovery and filtering. The vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion is wide in using range, and can be used as base materials for producing aqueous industrial coatings or aqueous ink.
Description
Technical field
The present invention relates to the base-material of a kind of aqueous industrial coating or water color ink.Specifically, be vinyl chloride-acrylate-vinyl acetate between to for plastic of producing aqueous industrial coating or water color ink-acrylate copolymer emulsion.
Background technology
At present, the base-material that is used for producing aqueous industrial coating or water color ink all is pure the third copolymer emulsion, styrene-acrylic emulsion or polyaminoester emulsion, and the force of cohesion of pure the third copolymer emulsion, styrene-acrylic emulsion or polyaminoester emulsion is all less, so that the aqueous industrial coating of making or water color ink water resistance, moisture resistance properties and salt spray resistance are all poor.Therefore, the use range of above-mentioned pure the third copolymer emulsion, styrene-acrylic emulsion or polyaminoester emulsion is restricted.
Summary of the invention
The problem to be solved in the present invention provides a kind of vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.This vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion, use range is unrestricted.
For addressing the above problem, take following technical scheme:
Vinyl chloride-acrylate-vinyl acetate between to for plastic of the present invention-acrylate copolymer emulsion characteristics are to be made by the raw material of following parts by weight:
40～80 parts in vinylchlorid;
10～40 parts of acrylate;
5～15 parts of vinyl acetate between to for plastics;
0.5～3 part in vinylformic acid;
0.7～1.3 part of Sodium dodecylbenzene sulfonate;
0.7～1.3 part of sodium lauryl sulphate;
1.1～1.3 parts of Triton X-100s;
0.07～0.7 part in alkylphenol-polyethenoxy (4) ether;
0.3～0.7 part of Polyvinylpyrolidone (PVP);
17～17.2 parts of ammonium persulfate solutions;
25～30 parts of deionized waters.
Wherein, described ammonium persulfate solution be with ammonium persulphate and water according to ammonium persulphate: the part by weight of water=1: 42 mixes.
The method for preparing vinyl chloride-acrylate-vinyl acetate between to for plastic of the present invention-acrylate copolymer emulsion is as follows:
First vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid and alkylphenol-polyethenoxy (4) ether is dropped in the pre-emulsification reactor, stirred 50～70 minutes, mix, obtain the pre-emulsification monomer;
Add in the polymerization reaction kettle after again deionized water, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100 and Polyvinylpyrolidone (PVP) being dissolved together;
Afterwards, successively 1/4 of 1/4 and ammonium persulfate solution of above-mentioned emulsified monomer dropped in the polymerization reaction kettle, stir and heat to 71.5～72.5 ℃ after 30～60 minutes, carry out polyreaction; After pressure in polymerization reaction kettle reduces 0.2MPa by original pressure, in 6～8 hours, remaining 3/4 emulsified monomer and 3/4 ammonium persulfate solution are added in the polymerization reaction kettle; Afterwards, the temperature in the polymerization reaction kettle is risen to 74～75 ℃, and the pressure that remains to polymerization reaction kettle under this temperature is brought down below 0.1MPa;
Afterwards, the material in the polymerization reaction kettle is lowered the temperature, after temperature is down to 38～42 ℃, polymerization reaction kettle is vacuumized, reclaim unreacted vinylchlorid;
At last, with 300 eye mesh screens the material in the polymerization reaction kettle is filtered, obtain vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.
Take such scheme, have the following advantages:
Can be found out by such scheme, because the present invention contains vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100, alkylphenol-polyethenoxy (4) ether, Polyvinylpyrolidone (PVP), ammonium persulfate solution and deionized water, vinylchlorid wherein has very high water resistance, moisture resistance properties and salt spray resistance, thereby greatly improved the water resistance of vinyl chloride-acrylate-vinyl acetate between to for plastic of the present invention-acrylate copolymer emulsion, moisture resistance properties and salt spray resistance, so that being used in water, the aqueous industrial coating of making take the present invention as base-material or water color ink contact, relatively moist and the occasion of salt fog often occurs, thus vast use range.
Embodiment
Embodiment one
Choose first 40 parts vinylchlorid, 40 parts acrylate, 15 parts acetic acid second, 0.5 part vinylformic acid, 0.7 Sodium dodecylbenzene sulfonate, 0.7 part sodium lauryl sulphate, 1.1 parts Triton X-100, part alkylphenol-polyethenoxy (4) ether of 0.07,0.3 part Polyvinylpyrolidone (PVP), 17 parts ammonium persulfate solution and 25 parts deionized water.Wherein, described ammonium persulfate solution be with ammonium persulphate and water according to ammonium persulphate: the part by weight of water=1: 42 mixes.
Again vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid and alkylphenol-polyethenoxy (4) ether is dropped in the pre-emulsification reactor, stirred 50 minutes, mix, obtain the pre-emulsification monomer.
Again deionized water, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100 and Polyvinylpyrolidone (PVP) are dissolved in the rear adding polymerization reaction kettle together.
Afterwards, successively 1/4 of 1/4 and ammonium persulfate solution of above-mentioned emulsified monomer dropped in the polymerization reaction kettle, stir and heat to 71.5 ℃ after 30 minutes, carry out polyreaction.Pressure in polymerization reaction kettle adds remaining 3/4 emulsified monomer and 3/4 ammonium persulfate solution in the polymerization reaction kettle in 6 hours after reducing 0.2Mpa by original pressure.Afterwards, the temperature in the polymerization reaction kettle is risen to 74 ℃, and the pressure that remains to polymerization reaction kettle under this temperature is brought down below 0.1Mpa.
Afterwards, with water coolant the material in the polymerization reaction kettle is lowered the temperature.After temperature is down to 38 ℃, polymerization reaction kettle is vacuumized, reclaim unreacted vinylchlorid.
At last, with 300 eye mesh screens the material in the polymerization reaction kettle is filtered, obtain vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.
Embodiment two
Choose first 60 vinylchlorid, 25 acrylate, 10 acetic acid second, 1.75 parts vinylformic acid, 1.0 Sodium dodecylbenzene sulfonate, 1.0 parts sodium lauryl sulphate, 1.2 parts Triton X-100, part alkylphenol-polyethenoxy (4) ether of 0.37,0.5 part Polyvinylpyrolidone (PVP), 17.1 parts ammonium persulfate solution and 28 parts deionized water.Wherein, described ammonium persulfate solution be with ammonium persulphate and water according to ammonium persulphate: the part by weight of water=1: 42 mixes.
Again vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid and alkylphenol-polyethenoxy (4) ether is dropped in the pre-emulsification reactor, stirred 60 minutes, mix, obtain the pre-emulsification monomer.
Again deionized water, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100 and Polyvinylpyrolidone (PVP) are dissolved in the rear adding polymerization reaction kettle together.
Afterwards, successively 1/4 of 1/4 and ammonium persulfate solution of above-mentioned emulsified monomer dropped in the polymerization reaction kettle, stir and heat to 72 ℃ after 45 minutes, carry out polyreaction.Pressure in polymerization reaction kettle adds remaining 3/4 emulsified monomer and 3/4 ammonium persulfate solution in the polymerization reaction kettle in 7 hours after reducing 0.2MPa by original pressure.Afterwards, the temperature in the polymerization reaction kettle is risen to 75 ℃, and the pressure that remains to polymerization reaction kettle under this temperature is brought down below 0.1Mpa.
Afterwards, with water coolant the material in the polymerization reaction kettle is lowered the temperature.After temperature is down to 40 ℃, polymerization reaction kettle is vacuumized, reclaim unreacted vinylchlorid.
At last, with 300 eye mesh screens the material in the polymerization reaction kettle is filtered, obtain vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.
Embodiment three
Choose first 80 vinylchlorid, 10 acrylate, 5 acetic acid second, 3 parts vinylformic acid, 1.3 Sodium dodecylbenzene sulfonate, 1.3 parts sodium lauryl sulphate, 1.3 parts Triton X-100, part alkylphenol-polyethenoxy (4) ether of 0.7,0.7 part Polyvinylpyrolidone (PVP), 17.2 parts ammonium persulfate solution and 30 parts deionized water.Wherein, described ammonium persulfate solution be with ammonium persulphate and water according to ammonium persulphate: the part by weight of water=1: 42 mixes.
Again vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid and alkylphenol-polyethenoxy (4) ether is dropped in the pre-emulsification reactor, stirred 70 minutes, mix, obtain the pre-emulsification monomer.
Again deionized water, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100 and Polyvinylpyrolidone (PVP) are dissolved in the rear adding polymerization reaction kettle together.
Afterwards, successively 1/4 of 1/4 and ammonium persulfate solution of above-mentioned emulsified monomer dropped in the polymerization reaction kettle, stir and heat to 72.5 ℃ after 60 minutes, carry out polyreaction.Pressure in polymerization reaction kettle adds remaining 3/4 emulsified monomer and 3/4 ammonium persulfate solution in the polymerization reaction kettle in 8 hours after reducing 0.2MPa by original pressure.Afterwards, the temperature in the polymerization reaction kettle is risen to 76 ℃, and the pressure that remains to polymerization reaction kettle under this temperature is brought down below 0.1Mpa.
Afterwards, with water coolant the material in the polymerization reaction kettle is lowered the temperature.After temperature is down to 42 ℃, polymerization reaction kettle is vacuumized, reclaim unreacted vinylchlorid.
At last, with 300 eye mesh screens the material in the polymerization reaction kettle is filtered, obtain vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.
Claims (1)
1. vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion is characterized in that being made by the raw material of following parts by weight:
40～80 parts in vinylchlorid;
10～40 parts of acrylate;
5～15 parts of vinyl acetate between to for plastics;
0.5～3 part in vinylformic acid;
0.7～1.3 part of Sodium dodecylbenzene sulfonate;
0.7～1.3 part of sodium lauryl sulphate;
1.1～1.3 parts of Triton X-100s;
0.07～0.7 part in alkylphenol-polyethenoxy (4) ether;
0.3～0.7 part of Polyvinylpyrolidone (PVP);
17～17.2 parts of ammonium persulfate solutions;
25～30 parts of deionized waters;
Wherein, described ammonium persulfate solution be with ammonium persulphate and water according to ammonium persulphate: the part by weight of water=1: 42 mixes;
First vinylchlorid, acrylate, vinyl acetate between to for plastic, vinylformic acid and alkylphenol-polyethenoxy (4) ether is dropped in the pre-emulsification reactor, stirred 50～70 minutes, mix, obtain the pre-emulsification monomer;
Add in the polymerization reaction kettle after again deionized water, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, Triton X-100 and Polyvinylpyrolidone (PVP) being dissolved together;
Afterwards, successively 1/4 of 1/4 and ammonium persulfate solution of above-mentioned emulsified monomer dropped in the polymerization reaction kettle, stir and heat to 71.5～72.5 ℃ after 30～60 minutes, carry out polyreaction; After pressure in polymerization reaction kettle reduces 0.2MPa by original pressure, in 6～8 hours, remaining 3/4 emulsified monomer and 3/4 ammonium persulfate solution are added in the polymerization reaction kettle; Afterwards, the temperature in the polymerization reaction kettle is risen to 74～75 ℃, and the pressure that remains to polymerization reaction kettle under this temperature is brought down below 0.1MPa;
Afterwards, the material in the polymerization reaction kettle is lowered the temperature, after temperature is down to 38～42 ℃, polymerization reaction kettle is vacuumized, reclaim unreacted vinylchlorid;
At last, with 300 eye mesh screens the material in the polymerization reaction kettle is filtered, obtain vinyl chloride-acrylate-vinyl acetate between to for plastic-acrylate copolymer emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100585834A CN103304724A (en) | 2012-03-08 | 2012-03-08 | Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100585834A CN103304724A (en) | 2012-03-08 | 2012-03-08 | Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103304724A true CN103304724A (en) | 2013-09-18 |
Family
ID=49130476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012100585834A Pending CN103304724A (en) | 2012-03-08 | 2012-03-08 | Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103304724A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015067818A (en) * | 2013-10-01 | 2015-04-13 | 東洋インキＳｃホールディングス株式会社 | Aqueous gravure printing ink composition for laminate |
| CN105368241A (en) * | 2015-10-12 | 2016-03-02 | 江苏科技大学 | Anticorrosive paint composition containing self-emulsifying curing agent and preparation method of anticorrosive paint |
| CN105985479A (en) * | 2015-02-02 | 2016-10-05 | 北京化工大学 | Preparation of acrylate modified vinyl chloride-vinyl acetate copolymerized resin through microsuspension polymerization |
| CN108424486A (en) * | 2018-02-10 | 2018-08-21 | 无锡洪汇新材料科技股份有限公司 | Vinyl chloride-vinyl acetate-butylacrylate-acrylic acid hexafluoro butyl ester copolymer emulsion and preparation method thereof |
| CN109233476A (en) * | 2018-08-27 | 2019-01-18 | 深圳市南硕明泰科技有限公司 | A kind of Side fascia heat insulation coating and preparation method thereof |
| CN109627371A (en) * | 2018-12-06 | 2019-04-16 | 无锡洪汇新材料科技股份有限公司 | A kind of special-purpose aqueous lotion of pack adhesive for alfoils and preparation method thereof |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102850A (en) * | 1972-04-10 | 1973-12-24 | ||
| JPS49112990A (en) * | 1973-03-01 | 1974-10-28 | ||
| JPH08102850A (en) * | 1994-09-30 | 1996-04-16 | Nec Corp | Picture processor |
| JPH09112990A (en) * | 1995-10-18 | 1997-05-02 | Noritz Corp | Ceiling mounted fan apparatus |
| CN1844270A (en) * | 2006-05-17 | 2006-10-11 | 河北科技大学 | Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor |
| CN101402701A (en) * | 2008-10-22 | 2009-04-08 | 无锡市洪汇化工有限公司 | Method for preparing chloroethylene-vinyl acetate-maleic acid copolymerized resin |
| CN101724116A (en) * | 2009-12-08 | 2010-06-09 | 南京工业大学 | Polymer emulsion and preparation method thereof |
-
2012
- 2012-03-08 CN CN2012100585834A patent/CN103304724A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102850A (en) * | 1972-04-10 | 1973-12-24 | ||
| JPS49112990A (en) * | 1973-03-01 | 1974-10-28 | ||
| JPH08102850A (en) * | 1994-09-30 | 1996-04-16 | Nec Corp | Picture processor |
| JPH09112990A (en) * | 1995-10-18 | 1997-05-02 | Noritz Corp | Ceiling mounted fan apparatus |
| CN1844270A (en) * | 2006-05-17 | 2006-10-11 | 河北科技大学 | Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor |
| CN101402701A (en) * | 2008-10-22 | 2009-04-08 | 无锡市洪汇化工有限公司 | Method for preparing chloroethylene-vinyl acetate-maleic acid copolymerized resin |
| CN101724116A (en) * | 2009-12-08 | 2010-06-09 | 南京工业大学 | Polymer emulsion and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015067818A (en) * | 2013-10-01 | 2015-04-13 | 東洋インキＳｃホールディングス株式会社 | Aqueous gravure printing ink composition for laminate |
| CN105985479A (en) * | 2015-02-02 | 2016-10-05 | 北京化工大学 | Preparation of acrylate modified vinyl chloride-vinyl acetate copolymerized resin through microsuspension polymerization |
| CN105368241A (en) * | 2015-10-12 | 2016-03-02 | 江苏科技大学 | Anticorrosive paint composition containing self-emulsifying curing agent and preparation method of anticorrosive paint |
| CN105368241B (en) * | 2015-10-12 | 2017-10-27 | 江苏科技大学 | A kind of anticorrosive paint composition containing self-emulsifying curing agent and preparation method thereof |
| CN108424486A (en) * | 2018-02-10 | 2018-08-21 | 无锡洪汇新材料科技股份有限公司 | Vinyl chloride-vinyl acetate-butylacrylate-acrylic acid hexafluoro butyl ester copolymer emulsion and preparation method thereof |
| CN109233476A (en) * | 2018-08-27 | 2019-01-18 | 深圳市南硕明泰科技有限公司 | A kind of Side fascia heat insulation coating and preparation method thereof |
| CN109627371A (en) * | 2018-12-06 | 2019-04-16 | 无锡洪汇新材料科技股份有限公司 | A kind of special-purpose aqueous lotion of pack adhesive for alfoils and preparation method thereof |
| CN109627371B (en) * | 2018-12-06 | 2021-02-26 | 无锡洪汇新材料科技股份有限公司 | Special water-based emulsion for medicine package aluminum foil adhesive and preparation method thereof |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN110951004B (en) * | 2019-12-04 | 2021-12-17 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103304724A (en) | Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion | |
| CN103391975B (en) | Polymer encapsulated titanium dioxide particles | |
| CN101367898B (en) | PVDC copolymerization emulsion, preparation and uses thereof | |
| CN101525399A (en) | Polyacrylate emulsion with high water resistance and preparation method thereof | |
| CN105315413A (en) | Novel modified acrylate emulsion adhesive and preparation method thereof | |
| US20160376459A1 (en) | Aqueous organic silicon fluoro-containing polymer dispersion and method for manufacturing the same | |
| CN104761673B (en) | A kind of carbomer and preparation method thereof | |
| CN104861116B (en) | Preparation method of fluorine-containing soap-free emulsion repellent | |
| CN101775105B (en) | Preparation method of high-impact polyacrylate grafting vinyl chloride emulsion copolymer resin | |
| CN104877056B (en) | Polyvinyl chloride resin preparing method capable of reducing membranes of surfaces of particles and improving porosity | |
| CN103342781B (en) | Vinyl chloride-butyl acrylate-epoxy resin copolymerization emulsion and preparation method thereof | |
| CN103232566B (en) | Preparation method of high-solid-content low-viscosity acrylate emulsion for sealing gum | |
| CN104892821A (en) | Preparation method of vinyl acetate-vinyl versatate copolymer emulsion | |
| CN103360536A (en) | Polyvinyl chloride production method adding chain extender to match with later-stage heating process | |
| CN101787102A (en) | Method for preparing white latex by utilizing polystyrene waste | |
| CN102311515A (en) | Method for feeding materials and controlling temperature in process for producing copolymerization resin by suspension method | |
| CN102504089B (en) | Preparation method of water-resistant acrylic ester core-shell emulsion | |
| CN105367701A (en) | Vinyl chloride-styrene-butyl acrylate copolymer emulsion and preparation method thereof | |
| CN104804144A (en) | Preparation method of impact-resistant PVC (polyvinyl chloride) | |
| CN104448092A (en) | Impact-resistant chloroethylene copolymer resin and preparation method thereof | |
| CN112778461B (en) | Preparation method of aqueous PVDF resin dispersion emulsion | |
| CN103665253A (en) | High-performance water-based acrylate pressure-sensitive adhesive and manufacturing process thereof | |
| CN105801728A (en) | PVC resin oil-soluble terminator and preparation method thereof | |
| CN108912261B (en) | Flame-retardant acrylate miniemulsion and preparation method thereof | |
| CN103435749A (en) | Preparation of low-salinity and low-viscosity polyacrylamide water-in-water dispersion liquid by employing seed swelling method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130918 |