CN103289019A - Modified butyl rubber - Google Patents
Modified butyl rubber Download PDFInfo
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- CN103289019A CN103289019A CN2013102586588A CN201310258658A CN103289019A CN 103289019 A CN103289019 A CN 103289019A CN 2013102586588 A CN2013102586588 A CN 2013102586588A CN 201310258658 A CN201310258658 A CN 201310258658A CN 103289019 A CN103289019 A CN 103289019A
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- butyl rubber
- modified butyl
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- isoprene
- vulcanizing agent
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Abstract
The invention discloses modified butyl rubber. The modified butyl rubber comprises the following components in parts by weight: 15-40 parts of butyl rubber, 8-15 parts of maleic anhydride, 5-10 parts of sulfonyl chloride, 7-10 parts of plasticizer, 0.5-2 parts of vulcanizing agent, 0.5-1 part of antioxidant, and 20-30 parts of inorganic filler. The modified butyl rubber disclosed by the invention is added with the plasticizer, so that the guarant viscosity is lowered; at the room temperature, the modified butyl rubber has high elasticity and high strength of the common vulcanized rubber; the added vulcanizing agent is produced in a vulcanizing manner, so that the holding power of a product is improved, and the peel strength is better.
Description
Technical field
The present invention relates to a kind of modified butyl rubber, belong to the high performance material field.
Background technology
Isoprene-isobutylene rubber is carried out the halogenation modification become a kind of comparatively ripe isoprene-isobutylene rubber modification technology.Its main products has chlorinated butyl rubber and brominated butyl rubber.Chlorinated butyl rubber has kept that conventional butyl rubbers is low ventilative, outside damping, anti-ozone and the chemical mediator-resitant property, also increased the characteristic that conventional butyl rubbers does not have,, good heat resistance fast as vulcanization rate.
But since the polarity of chlorinated butyl rubber still a little less than, cause the consistency of itself and polar polymer relatively poor.Therefore, need provide a kind of new technical scheme to solve the problems referred to above.
Summary of the invention
The modified butyl rubber that the purpose of this invention is to provide a kind of excellent performance.
For achieving the above object, the technical solution used in the present invention is:
A kind of modified butyl rubber, this modified butyl rubber is formed by following weight part:
Isoprene-isobutylene rubber 15-40 part;
MALEIC ANHYDRIDE 8-15 part;
SULPHURYL CHLORIDE 5-10 part;
Softening agent 7-10 part;
Vulcanizing agent 0.5-2 part;
Oxidation inhibitor 0.5-1 part;
Inorganic filler 20-30 part.
Described isoprene-isobutylene rubber is the rubbery copolymer of iso-butylene and isoprene.
Described softening agent is one or more the combination in Vaseline, phthalate compound, the synthetic polyisoprene.
Described vulcanizing agent is sulphur or zinc oxide.
Described inorganic filler is one or more the combination in clay, talcum powder, calcium carbonate, the silicon-dioxide.
Described oxidation inhibitor is sulfenyl phenolate.
Advantage of the present invention: adding among the present invention has softening agent, reduces system viscosity, and when room temperature, it has elastomerics and the high strength of common vulcanized rubber, adds vulcanizing agent and makes with vulcanization production, improves the viscosity of holding of product, and stripping strength is preferably arranged.
Embodiment
Following examples are intended to illustrate the present invention rather than to the bright further restriction of we.
Embodiment 1
A kind of modified butyl rubber, the composition of this modified butyl rubber:
Isoprene-isobutylene rubber 15 ㎏;
MALEIC ANHYDRIDE 8 ㎏;
SULPHURYL CHLORIDE 5 ㎏;
Softening agent 7 ㎏;
Vulcanizing agent 0.5 ㎏;
Oxidation inhibitor 0.5 ㎏;
Inorganic filler 20 ㎏.
Isoprene-isobutylene rubber is the rubbery copolymer of iso-butylene and isoprene, and softening agent is Vaseline, and vulcanizing agent is sulphur, and inorganic filler is clay, and oxidation inhibitor is sulfenyl phenolate.
Embodiment 2
A kind of modified butyl rubber, the composition of this modified butyl rubber:
Isoprene-isobutylene rubber 25 ㎏;
MALEIC ANHYDRIDE 12 ㎏;
SULPHURYL CHLORIDE 7 ㎏;
Softening agent 8 ㎏;
Vulcanizing agent 1 ㎏;
Oxidation inhibitor 0.8 ㎏;
Inorganic filler 25 ㎏.
Isoprene-isobutylene rubber is the rubbery copolymer of iso-butylene and isoprene, and softening agent is phthalate compound, and vulcanizing agent is zinc oxide, and inorganic filler is talcum powder, and oxidation inhibitor is sulfenyl phenolate.
Embodiment 3
A kind of modified butyl rubber, the composition of this modified butyl rubber:
Isoprene-isobutylene rubber 40 ㎏;
MALEIC ANHYDRIDE 15 ㎏;
SULPHURYL CHLORIDE 10 ㎏;
Softening agent 10 ㎏;
Vulcanizing agent 2 ㎏;
Oxidation inhibitor 1 ㎏;
Inorganic filler 30 ㎏.
Isoprene-isobutylene rubber is the rubbery copolymer of iso-butylene and isoprene, and softening agent is synthetic polyisoprene, and vulcanizing agent is sulphur, and inorganic filler is calcium carbonate, and oxidation inhibitor is sulfenyl phenolate.
Above-mentioned softening agent can also be several combination in Vaseline, phthalate compound, the synthetic polyisoprene, and inorganic filler is silicon-dioxide, can also be several combination in clay, talcum powder, calcium carbonate, the silicon-dioxide.
Adding among the present invention has softening agent, reduces system viscosity, and when room temperature, it has elastomerics and the high strength of common vulcanized rubber, adds vulcanizing agent and makes with vulcanization production, improves the viscosity of holding of product, and stripping strength is preferably arranged.
Claims (6)
1. a modified butyl rubber is characterized in that, this modified butyl rubber is formed by following weight part:
Isoprene-isobutylene rubber 15-40 part;
MALEIC ANHYDRIDE 8-15 part;
SULPHURYL CHLORIDE 5-10 part;
Softening agent 7-10 part;
Vulcanizing agent 0.5-2 part;
Oxidation inhibitor 0.5-1 part;
Inorganic filler 20-30 part.
2. a kind of modified butyl rubber according to claim 1, it is characterized in that: described isoprene-isobutylene rubber is the rubbery copolymer of iso-butylene and isoprene.
3. a kind of modified butyl rubber according to claim 1 is characterized in that: described softening agent is one or more the combination in Vaseline, phthalate compound, the synthetic polyisoprene.
4. a kind of modified butyl rubber according to claim 1, it is characterized in that: described vulcanizing agent is sulphur or zinc oxide.
5. a kind of modified butyl rubber according to claim 1 is characterized in that: described inorganic filler is one or more the combination in clay, talcum powder, calcium carbonate, the silicon-dioxide.
6. a kind of modified butyl rubber according to claim 1, it is characterized in that: described oxidation inhibitor is sulfenyl phenolate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102586588A CN103289019A (en) | 2013-06-26 | 2013-06-26 | Modified butyl rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102586588A CN103289019A (en) | 2013-06-26 | 2013-06-26 | Modified butyl rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103289019A true CN103289019A (en) | 2013-09-11 |
Family
ID=49090592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102586588A Pending CN103289019A (en) | 2013-06-26 | 2013-06-26 | Modified butyl rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289019A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107213878A (en) * | 2017-05-31 | 2017-09-29 | 江苏精盾节能科技有限公司 | A kind of modified adsorbent and preparation method thereof |
| CN109810416A (en) * | 2018-12-27 | 2019-05-28 | 江苏金轮橡胶有限公司 | Modified butyl rubber |
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| CN1654526A (en) * | 2005-01-14 | 2005-08-17 | 四川大学 | Butyl rubber/poly(meth)acrylate blend composite damping material and process for preparing same |
| CN1834142A (en) * | 2006-03-03 | 2006-09-20 | 四川大学 | Blend sulfurized compound damping material of butyl rubber/chlorinated polyethylene olefin and prepn. process |
| CN101805426A (en) * | 2010-04-23 | 2010-08-18 | 华东理工大学 | Modified butyl rubber |
| CN101824288A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Butyl rubber composition and method for producing butyl rubber adhesive tape by using same |
| CN102174152A (en) * | 2011-02-11 | 2011-09-07 | 福建师范大学 | Method for preparing reinforcing anti-aging co-crosslinked elastomer |
| CN102212233A (en) * | 2011-04-22 | 2011-10-12 | 西安汉华橡胶科技有限公司 | R134a refrigerant-resistant rubber material and preparation method thereof |
| CN102432952A (en) * | 2010-09-29 | 2012-05-02 | 中国石油化工股份有限公司 | Quickly vulcanized butyl rubber and preparation method and application thereof |
| CN103087430A (en) * | 2013-01-29 | 2013-05-08 | 南京理工大学 | Brominated butyl/chlorinated butyl rubber composition and preparation method thereof |
-
2013
- 2013-06-26 CN CN2013102586588A patent/CN103289019A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1654526A (en) * | 2005-01-14 | 2005-08-17 | 四川大学 | Butyl rubber/poly(meth)acrylate blend composite damping material and process for preparing same |
| CN1834142A (en) * | 2006-03-03 | 2006-09-20 | 四川大学 | Blend sulfurized compound damping material of butyl rubber/chlorinated polyethylene olefin and prepn. process |
| CN101805426A (en) * | 2010-04-23 | 2010-08-18 | 华东理工大学 | Modified butyl rubber |
| CN101824288A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Butyl rubber composition and method for producing butyl rubber adhesive tape by using same |
| CN102432952A (en) * | 2010-09-29 | 2012-05-02 | 中国石油化工股份有限公司 | Quickly vulcanized butyl rubber and preparation method and application thereof |
| CN102174152A (en) * | 2011-02-11 | 2011-09-07 | 福建师范大学 | Method for preparing reinforcing anti-aging co-crosslinked elastomer |
| CN102212233A (en) * | 2011-04-22 | 2011-10-12 | 西安汉华橡胶科技有限公司 | R134a refrigerant-resistant rubber material and preparation method thereof |
| CN103087430A (en) * | 2013-01-29 | 2013-05-08 | 南京理工大学 | Brominated butyl/chlorinated butyl rubber composition and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107213878A (en) * | 2017-05-31 | 2017-09-29 | 江苏精盾节能科技有限公司 | A kind of modified adsorbent and preparation method thereof |
| CN109810416A (en) * | 2018-12-27 | 2019-05-28 | 江苏金轮橡胶有限公司 | Modified butyl rubber |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130911 |