CN103276361B - 一种在镁基复合材料表面制备Ti/TiO2或TiN生物相容性膜层的方法 - Google Patents
一种在镁基复合材料表面制备Ti/TiO2或TiN生物相容性膜层的方法 Download PDFInfo
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- CN103276361B CN103276361B CN201310169315.4A CN201310169315A CN103276361B CN 103276361 B CN103276361 B CN 103276361B CN 201310169315 A CN201310169315 A CN 201310169315A CN 103276361 B CN103276361 B CN 103276361B
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 128
- 239000011777 magnesium Substances 0.000 title claims abstract description 116
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 115
- 239000002131 composite material Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 36
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title description 3
- 239000010936 titanium Substances 0.000 claims abstract description 54
- 239000011159 matrix material Substances 0.000 claims abstract description 40
- 238000000151 deposition Methods 0.000 claims abstract description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- 238000010891 electric arc Methods 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 18
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 17
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 16
- 239000001506 calcium phosphate Substances 0.000 claims description 15
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 15
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 15
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 15
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 13
- 239000004137 magnesium phosphate Substances 0.000 claims description 13
- 229960002261 magnesium phosphate Drugs 0.000 claims description 13
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 13
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 13
- 230000008021 deposition Effects 0.000 claims description 11
- 238000005516 engineering process Methods 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000007733 ion plating Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 230000003019 stabilising effect Effects 0.000 claims description 7
- 238000010301 surface-oxidation reaction Methods 0.000 claims description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 7
- 244000137852 Petrea volubilis Species 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 229910052774 Proactinium Inorganic materials 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000005240 physical vapour deposition Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 23
- 238000005260 corrosion Methods 0.000 abstract description 13
- 238000006243 chemical reaction Methods 0.000 abstract description 12
- 230000007797 corrosion Effects 0.000 abstract description 12
- 210000001124 body fluid Anatomy 0.000 abstract description 7
- 239000010839 body fluid Substances 0.000 abstract description 7
- 239000012530 fluid Substances 0.000 abstract description 6
- 238000002513 implantation Methods 0.000 abstract description 5
- 238000007599 discharging Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 38
- 238000002474 experimental method Methods 0.000 description 18
- 229910000861 Mg alloy Inorganic materials 0.000 description 14
- 210000001519 tissue Anatomy 0.000 description 12
- 241001465754 Metazoa Species 0.000 description 11
- 239000000758 substrate Substances 0.000 description 10
- 241000283973 Oryctolagus cuniculus Species 0.000 description 8
- 230000007170 pathology Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 230000007541 cellular toxicity Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- -1 poly(lactic acid) Polymers 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000007943 implant Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012620 biological material Substances 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 210000003734 kidney Anatomy 0.000 description 2
- 210000004185 liver Anatomy 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 210000003205 muscle Anatomy 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910007991 Si-N Inorganic materials 0.000 description 1
- 229910006294 Si—N Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 239000013060 biological fluid Substances 0.000 description 1
- 239000003519 biomedical and dental material Substances 0.000 description 1
- 230000008468 bone growth Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 210000004409 osteocyte Anatomy 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000008467 tissue growth Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- Physical Vapour Deposition (AREA)
- Materials For Medical Uses (AREA)
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CN107723680B (zh) * | 2017-08-28 | 2019-10-29 | 南昌大学 | 一种耐蚀性可调控的镁合金表面多级纳米涂层的制备方法 |
CN109731134A (zh) * | 2018-12-26 | 2019-05-10 | 中南大学湘雅二医院 | 一种表面改性镁合金骨植入材料及制备方法 |
CN111378942A (zh) * | 2018-12-28 | 2020-07-07 | 芜湖美的厨卫电器制造有限公司 | 金属表面的防腐蚀处理工艺、金属工件、电加热管及电热水器 |
CN114807839B (zh) * | 2022-04-25 | 2023-03-14 | 南昌大学 | 一种牙科用阶梯降解镁合金屏障膜及其制备方法 |
CN115006601A (zh) * | 2022-06-13 | 2022-09-06 | 上海锐畅医疗科技有限公司 | 一种抗菌纳米复合涂层及其制备方法 |
CN115478274A (zh) * | 2022-10-10 | 2022-12-16 | 西安工业大学 | 避免钛合金与异种金属电偶腐蚀的防护方法及防护涂层 |
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Title |
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AZ91C镁合金表面Ti-TiN复合镀层的阴极多弧离子镀法制备与表征;王成龙等;《腐蚀与防护》;20080430;第29卷(第4期);第182-184页 * |
镁合金电弧离子镀镀金属氮化物薄膜的研究;熊光连;《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》;20120715(第7期);第B022-187页 * |
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Effective date of registration: 20240522 Address after: Room 140, Building 1, R&D Headquarters, Central South University Science and Technology Park, Yingzuo Road, Yuelu Street, Yuelu District, Changsha City, Hunan Province, 410006 Patentee after: Changsha magnesium New Material Technology Co.,Ltd. Country or region after: China Address before: Yuelu District City, Hunan province 410083 Changsha Lushan Road No. 932 Patentee before: CENTRAL SOUTH University Country or region before: China |