CN103275769A - High-cleanness environment-friendly alcohol ether fuel for car - Google Patents
High-cleanness environment-friendly alcohol ether fuel for car Download PDFInfo
- Publication number
- CN103275769A CN103275769A CN2013102025278A CN201310202527A CN103275769A CN 103275769 A CN103275769 A CN 103275769A CN 2013102025278 A CN2013102025278 A CN 2013102025278A CN 201310202527 A CN201310202527 A CN 201310202527A CN 103275769 A CN103275769 A CN 103275769A
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- inhibitor
- ether
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- 239000000446 fuel Substances 0.000 title claims abstract description 256
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 147
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims abstract description 126
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 175
- 239000003112 inhibitor Substances 0.000 claims abstract description 174
- 230000007797 corrosion Effects 0.000 claims abstract description 88
- 238000005260 corrosion Methods 0.000 claims abstract description 88
- 229910052751 metal Inorganic materials 0.000 claims abstract description 85
- 239000002184 metal Substances 0.000 claims abstract description 85
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 68
- 229920001971 elastomer Polymers 0.000 claims abstract description 42
- 239000005060 rubber Substances 0.000 claims abstract description 42
- 239000004033 plastic Substances 0.000 claims abstract description 40
- 230000008961 swelling Effects 0.000 claims abstract description 40
- 239000002270 dispersing agent Substances 0.000 claims abstract description 34
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 22
- -1 amido phenol Chemical compound 0.000 claims description 65
- 230000003068 static effect Effects 0.000 claims description 63
- 239000000654 additive Substances 0.000 claims description 57
- 239000002904 solvent Substances 0.000 claims description 46
- 230000000996 additive effect Effects 0.000 claims description 43
- 229910052757 nitrogen Inorganic materials 0.000 claims description 38
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 36
- 238000005299 abrasion Methods 0.000 claims description 33
- 230000003064 anti-oxidating effect Effects 0.000 claims description 33
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 32
- 238000006555 catalytic reaction Methods 0.000 claims description 30
- 239000003921 oil Substances 0.000 claims description 28
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 22
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims description 22
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 20
- 230000004048 modification Effects 0.000 claims description 20
- 238000012986 modification Methods 0.000 claims description 20
- MOFINMJRLYEONQ-UHFFFAOYSA-N [N].C=1C=CNC=1 Chemical class [N].C=1C=CNC=1 MOFINMJRLYEONQ-UHFFFAOYSA-N 0.000 claims description 18
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 18
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 17
- 125000005605 benzo group Chemical group 0.000 claims description 17
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 claims description 16
- 241001062009 Indigofera Species 0.000 claims description 16
- 240000000203 Salix gracilistyla Species 0.000 claims description 16
- 230000007613 environmental effect Effects 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 16
- 229960002317 succinimide Drugs 0.000 claims description 16
- 229920002367 Polyisobutene Polymers 0.000 claims description 15
- 229910002651 NO3 Inorganic materials 0.000 claims description 14
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 11
- CIRMGZKUSBCWRL-LHLOQNFPSA-N (e)-10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)C(\C=C\CCCCCCCC(O)=O)C1CCCCCC CIRMGZKUSBCWRL-LHLOQNFPSA-N 0.000 claims description 10
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical group COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 claims description 8
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 8
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 7
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 7
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 6
- JTTMYKSFKOOQLP-UHFFFAOYSA-N 4-hydroxydiphenylamine Chemical compound C1=CC(O)=CC=C1NC1=CC=CC=C1 JTTMYKSFKOOQLP-UHFFFAOYSA-N 0.000 claims description 6
- CDXVUROVRIFQMV-UHFFFAOYSA-N oxo(diphenoxy)phosphanium Chemical compound C=1C=CC=CC=1O[P+](=O)OC1=CC=CC=C1 CDXVUROVRIFQMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000012286 potassium permanganate Substances 0.000 claims description 6
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 6
- 229910001488 sodium perchlorate Inorganic materials 0.000 claims description 6
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 5
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 5
- HVZJRWJGKQPSFL-UHFFFAOYSA-N tert-Amyl methyl ether Chemical compound CCC(C)(C)OC HVZJRWJGKQPSFL-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 4
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims description 4
- PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 claims description 4
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 4
- NTHGIYFSMNNHSC-UHFFFAOYSA-N 3-methylbutyl nitrate Chemical compound CC(C)CCO[N+]([O-])=O NTHGIYFSMNNHSC-UHFFFAOYSA-N 0.000 claims description 4
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- HSNWZBCBUUSSQD-UHFFFAOYSA-N amyl nitrate Chemical compound CCCCCO[N+]([O-])=O HSNWZBCBUUSSQD-UHFFFAOYSA-N 0.000 claims description 4
- HCUOPEBHVAVNIE-UHFFFAOYSA-N bis(3-methylbutyl) oxalate Chemical compound CC(C)CCOC(=O)C(=O)OCCC(C)C HCUOPEBHVAVNIE-UHFFFAOYSA-N 0.000 claims description 4
- GPKQLHLOONCFDY-UHFFFAOYSA-N bis(6-methylheptyl) phenyl phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OC1=CC=CC=C1 GPKQLHLOONCFDY-UHFFFAOYSA-N 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- HLYOOCIMLHNMOG-UHFFFAOYSA-N cyclohexyl nitrate Chemical compound [O-][N+](=O)OC1CCCCC1 HLYOOCIMLHNMOG-UHFFFAOYSA-N 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 4
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 4
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 4
- VNKYTQGIUYNRMY-UHFFFAOYSA-N methoxypropane Chemical compound CCCOC VNKYTQGIUYNRMY-UHFFFAOYSA-N 0.000 claims description 4
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- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 4
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 4
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- 239000012847 fine chemical Substances 0.000 claims description 3
- MPCADCULRRWDOX-UHFFFAOYSA-N 1,1'-biphenyl;phosphorous acid Chemical compound OP(O)O.C1=CC=CC=C1C1=CC=CC=C1 MPCADCULRRWDOX-UHFFFAOYSA-N 0.000 claims description 2
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 claims description 2
- GYVYGTTZKLHDON-UHFFFAOYSA-N 2-anilinophenol Chemical compound OC1=CC=CC=C1NC1=CC=CC=C1 GYVYGTTZKLHDON-UHFFFAOYSA-N 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
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- VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical compound [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- IDNUEBSJWINEMI-UHFFFAOYSA-N ethyl nitrate Chemical compound CCO[N+]([O-])=O IDNUEBSJWINEMI-UHFFFAOYSA-N 0.000 description 1
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- 239000002360 explosive Substances 0.000 description 1
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- 239000002816 fuel additive Substances 0.000 description 1
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
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- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 1
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Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a high-cleanliness environment-friendly alcohol ether fuel for a car. The fuel provided by the invention consists of the following raw materials: 600-800 parts of methanol, ethanol or a mixture of methanol and ethanol, 100-350 parts of an ether stabilizer, 1-6 parts of an anti-oxygen and anti-gum inhibitor, 2-5 parts of a metal deactivator, 1-3 parts of a corrosion inhibitor, 1-40 parts of a catalytic combustion improver, 2-4 parts of an antistatic agent, 10-100 parts of an antiknock stabilizer, 1-6 parts pf a purification dispersant, 1-6 parts of an anti-wear repair agent, 1-6 parts of a metal corrosion inhibitor, 2-6 parts of a rubber and plastic part corrosion and swelling inhibitor, 10-50 parts of a modified alcohol cosolvent, 0.2-0.8 part of a bactericide and 0.04-0.1 part of a recognition agent. The fuel provided by the invention has the advantages of stable performance, strong power, sufficient combustion, good seismic performance, good acceleration, easiness for starting up, no air lock, no separated layer, reduced fuel consumption, cleaner tail gas emission and no need of changing the structure of a spark ignition engine in the prior art and can be separately used, used instead of regular gasoline or used together with regular gasoline by co-combustion.
Description
Technical field
The present invention relates to a kind of fuel liquid for automobile, particularly a kind of is the automobile-used high definition environmental protection alcohol ether fuel of main raw material with methyl alcohol, ethanol or first and second alcohol mixtures.
Background technology
The world today, the energy and environment are the principal elements that influences the global economy social sustainable development, and the energy is the basic substance of human survival and Economic development.Yet along with world economy continues, the development of high speed, problems such as energy shortage, environmental pollution, ecological degeneration are more and more outstanding.According to scholarly forecast, by present consumption, oil, Sweet natural gas can only be kept less than half a century at most, and coal also can only be kept 100 or two hundred years, so no matter be any conventional energy resources structure, the energy dilemma that the mankind face all is on the rise.
As everyone knows, the national conditions of China are oil starvation, weak breath, relative rich coal, and the most important condition of substitute energy must possess two big factors: the one, and reserves are abundant, and the 2nd, burning is clean.Yet but there are the abundant coal-seam gas of abundant high sulphur coal and reserves and the byproduct coke(oven)gas of coking charcoal in China, therefore can utilize them to make the derivative product of fuel such as methyl alcohol, dme and many methyl alcohol.
Just propose in Chinese Academy of Geological Sciences's " Mineral resources and Chinese Economy Development " report: the existing reserves of Chinese hydrocarbon resources are with the consumption in 30 years of less than, and ultimate recoverable reserves can be kept consumption in 50 years reluctantly; To the year two thousand twenty, the import volume of CNPC will be above 500,000,000 tons, the Sweet natural gas import will be above 1000 billion cubic meters, both external interdependencies will reach 70% and 50% respectively, this seriously injures the national energy security of China, in case international situation is unstable or the outburst war, and the destroyed or cut-out of energy import channel, national economy high-speed cruising system will be subjected to very big impact and the big area paralysis occur, and its consequence is with hardly imaginable.
In the reserves that China's energy is verified, coal is that main body accounts for 94%, and oil accounts for 5.4%, Sweet natural gas station 0.6%.Though coal in China output accounts for 36.5% of Gross World Product, coal reserves only accounts for 13% of world saving, and under China's existence conditions, the limit of coal annual production is 2,000,000,000 tons, and the coal year consumption of China has surpassed 1,300,000,000 tons, approaches the limit, and is within sight.
According to statistics, present China motor vehicle is possessed total amount and has been reached 2.25 hundred million, and the annual annual growth that is all keeping more than 20%, becomes the national economy new growth point, has important strategic position in national economy.
Draw two conclusions from above-mentioned data: the one, energy shortage is moved towards the energy gradually and is exhausted; The 2nd, present employed main energy sources has severe contamination for the environment of human survival.So the energy dilemma forward mankind attack, various countries to the contention of the energy, will be the major cause of following whole world conflict.
The energy strategy of China also is " save preferentially, base on our country, coal is basis, multiple development ".Thereby for solid basis has been established in the further expansion production of the development of methanol fuel and carbinol derivatives product, output.Though for many years in the research of methanol fuel with use and all obtained interim achievement, but because being subjected to the restriction of the peculiar property of alcohol ether class A fuel A, cause in the research to the high density Aalcohols fuel, basically be by existing spark ignition engine being transformed or methanol fuel special engine and reach the requirement that adapts to the high density Aalcohols fuel, and the advantage of performance Aalcohols fuel.
Methyl alcohol and ethanol are a kind of good polar organic solvent, their many character are all more approaching with steam oil ratio (SOR), though their calorific value is all much lower than gasoline, but the propellant combination of which kind of ratio no matter, the calorific value of theoretical mixture gas (MJ/Kg) all is not less than gasoline and is approximately higher than gasoline (methyl alcohol 3.08, ethanol 3.00, gasoline about 2.92), susceptibility is then little than gasoline simultaneously, and octane value RON or MON are but a little more than gasoline.Therefore, Aalcohols fuel can be used for the engine of higher compression ratios and unlikely generation pinking, and can improve the efficient of engine.Tendency to detonate was also very little when particularly pure fuel was worked under the rich mixture condition.As when using methyl alcohol or ethanol as the host fuel of engine, owing to contain more oxygen in first, the ethanol, pure fuel content is more high in addition, the fuel octane number increase rate is more big, and the combustion limits of Aalcohols fuel are very wide, particularly the burning concentration upper limit is more much higher than gasoline, therefore can obtain high-level efficiency and very strong driving force on the engine that adapts to high compression ratio.The Aalcohols fuel of high density is compared the utilization ratio height with general-utility car fuel, pollutes and lacks, and ozone forms less, and is easy to store and carry, and the fuel that therefore is commonly used for racing car and high-power Der Gelaendewagen uses.
But methyl alcohol, ethanol also have many defective parts during as vehicle fuel.As the latent heat of vaporization of first, ethanol respectively than the high 2-4 of gasoline doubly and 1-1.4 doubly, though can reduce inlet air temperature, improve charging efficiency, brought difficulty to cold start-up, cause carburettor icing, problems such as fuel consumption increase.
And for example the boiling point of methyl alcohol and ethanol exceeds respectively about 30 ℃ and 43 ℃ than the initial boiling point of gasoline, but the final boiling point than gasoline is much lower, therefore, when the methyl alcohol that uses high density or alcohol fuel, in engine working process, methyl alcohol and ethanol can both evaporate fully, form gas mixture relatively uniformly with air.But the vapo(u)rability of alcohols is very poor at low temperatures, and vaporization heat is big in addition, further reduces inlet temperature during evaporation, causes cold start difficulty or warming up time to lengthen, and oil consumption increases.In addition, methyl alcohol has certain electroconductibility, and in a single day liquid methanol enters cylinder, and sticking being attached in the plug ignition gap causes loss of ignition easily.Have resource to show, help under the condition of the measure of lighting a fire not taking, high concentration methanol or alcohol fuel in the minimum start-up temperature of engine respectively at 0-16 ℃ and about 15-20 ℃.
For another example, the saturation steam pressure ratio gasoline of methyl alcohol and ethanol is much lower, but the saturated vapor pressure of propellant combination is not the relation that is simple decline with the increase of pure content, increases and the saturated vapor pressure of methanol gasoline or ethanol petrol is increase with methyl alcohol or ethanol content.Roughly methanol content be 15% and ethanol content be to reach maximum value at 12% o'clock, increase with methyl alcohol or ethanol content afterwards and reduce.When methanol content is lower than certain value, also wanting greatly of the saturation steam pressure ratio gasoline of methanol gasoline, the reason that this phenomenon occurs be since methyl alcohol can with gasoline in lighting end form the cause of the low azeotrope that boils, this phenomenon makes the vaporization losses of low ratio methanol gasoline in storage increase, and is easy to generate vapour lock when using under the high temperature.The saturated vapor pressure of ethanol petrol propellant combination and contain similar relation is arranged between the oxygen.
In addition, methyl alcohol and ethanol all are corrosive to many metals of engine fuel system, and they can corrode copper, iron, aluminium, lead, zinc, magnesium and their many alloys.Also make the corrodibility of fuel strengthen greatly even propellant combination contains 3% alcohol, pure content more highly corrosive is more big.The Basic Ways that prevents pure fuel corrosion engine metal has two, the one, change the engine metal material, use corrosion resistant metal to make engine, but this method cost height, the 2nd, in fuel, add anticorrosive additive, and method is feasible, easy, cost is low, effective, facts have proved, in pure fuel, add a spot of sanitas and just can effectively prevent metallic corrosion.
Alcohol fuel also has the burn into swelling action to rubber and plastic components except metal is corrosive.The engine fuel system mass part all is that rubber, plastic or other material are made, and understands swelling in pure fuel, becomes sticky or chap; Oil fuel pump barrier film and fuel hose are rubber items, phenomenons such as swelling, hardening also can taking place in pure fuel, become fragile or soften; The fiber mat sector-meeting is softening and cause leakage of oil gradually.So, in pure fuel, add some additive and also can reach or alleviate pure fuel to the corrodibility of rubber, plastic component and swelling, aging restraining effect.
The additive and the alcohol-ether fuel that mainly comprise alcohol-ether fuel at present at the patent application of alcohol-ether fuel:
1, application number 200510026519.8 discloses a kind of additive of novel alcohol-ether fuel, and the weight percent of its component is: ester compound: methyl-formiate, methyl methacrylate, trimethyl phosphite, methylcarbonate or diethyl carbonate 10～50%; Ether compound: dme, isopropyl ether, positive propyl ether or ether 15～40%; Aliphatic alcohols compound: primary isoamyl alcohol, isopropylcarbinol or iso-heptanol 15～50%; Aminated compounds: thanomin, diethanolamine, triethylamine, cetylamine, octadecane amine, oleic acid amine or N-methyl-p-nitroaniline 0.5～5%; Imidazole derivative: benzotriazole 0.1～1%.Utilize novel alcohol ether fuel additive of the present invention can make methyl alcohol and ethanol content in the alcohol-ether fuel reach 80%, and technological process need not emulsification, the no three wastes produce, and energy consumption is low, yield is high, system is stable.
But the weak point of this additive is: 1. preferred ether compound isopropyl ether raw material is limited in the component, has the big problem of breach as using in enormous quantities separately, and this raw material poor effect in low temperature or cold district engine cold-start; 2. the iso-heptanol cost height in the component, solubilization-aid effect is undesirable, and consumption is big, and output is limited; 3. selected imidazole derivative benzotriazole solubility property in polar solvent is good, to metal particularly non-ferrous metal corrosion inhibition effect is preferably arranged, but solubility property is relatively poor in non-polar solvent, and is undesirable to other corrosion of metal inhibition.
2, application number 200710049698.6 discloses a kind of high content environmental protection alcohol ether fuel for vehicle, count by weight, it is compounded into 75～87 parts methyl alcohol or ethanol or first by the additive of forming with inferior 37 kinds of raw materials, make in the second alcohol mixture: methyl alcohol 0.06～0.2, ethanol 0.1～0.4, Virahol 0.1～2, primary isoamyl alcohol 0～2, isopropylcarbinol 0.6～3, ethylene glycol 0～0.02, dimethyl ketone 0.02～1.5, Skellysolve A 0.02～0.5, dipropyl 0.02～0.4, pentamethylene 0.02～0.4,2,2,4-trimethylpentane 0.02～0.4, Nitromethane 99Min. 0.02～0.4, dimethylbenzene 0～2, turps 0.1～5.5, cyclopentadiene 0.02～0.03, polyisobutene 0.02～0.03, propylene diamine 0.04～0.06, methyl-formiate 0～1.5, methylcarbonate 0～2, condensate oil 0～3, varsol oil 0.12～10, petroleum naphtha 0.1～7.3, diisopropyl ether 0～3, Methylal(dimethoxymethane) 0～3, sherwood oil 0～3, tert amyl methyl ether(TAME) 0～3, methyl tertiary butyl ether 0～3, dodecyl phenol polyethenoxy ether 0～0.05, methyl benzo three (nitrogen) azoles 0～0.02, two alkylphosphonic acid carboxylic acids 0～0.01, benzo three (nitrogen) azoles 0～0.06, static inhibitor SN 0～0.02, Oleum Cocois alkyl oxalamide 0～0.1,2,2-dimethyl propylene acid anhydrides 0～0.02, C1-1406 metal corrosion inhibitor 0～0.06, BR-7064 rubber and plastic spare swelling inhibitor 0～0.06, antioxidant NS-Q1 0～0.03.This vehicle alcohol ether fuel uses separately on spark ignition engine or uses by any ratio back that is mixed with gasoline, all make the performance of fuel more stable, and anti-seismic performance is good, and dynamic property is strong, sufficient combustion, easily start, vapour lock is not stratified, and oil consumption is low, clean environment firendly has solved the versatility of spark ignition engine on multipropellant uses.
But the petroleum products raw material that relies in this alcohol-ether fuel is more, development to long-term alternative fuel has resistance, because the continuity meeting in time of petroleum products raw material is fewer and feweri, simultaneously, this fuel engine starting time when cold district-30 ℃ is longer, oil consumption increases, and can not reach best peace and quiet discharging in exhaust emissions, wear-resistant to engine, repair, lubricated aspect effect is not fine.
Summary of the invention
The object of the present invention is to provide a kind of performance more stable, need not to change the automobile-used high definition environmental protection alcohol ether fuel of existing spark ignition engine structure.This fuel can use separately, or uses with the regular gasoline exchange, mixes to burn and use, but best with independent result of use.Alcohol-ether fuel of the present invention is because stable performance, powerful, sufficient combustion, anti-seismic performance is good, acceleration is good, easily startup, vapour lock, not stratified, oil consumption reduction, exhaust emissions more do not clean, fuel oil consumption is more saved, thereby reduced existing spark ignition engine significantly to the undue dependency of gasoline, improved the emergency guarantee degree of country on the energy strategy problem.
The objective of the invention is to realize by following technical proposals:
Automobile-used high definition environmental protection alcohol ether fuel is characterized in that: the preparation of raw material by following weight parts forms:
Methyl alcohol or ethanol or first and second alcohol mixture 600-800 parts, Aalcohols fuel ether stablizer 100-350 part, antioxidizing and antigum agent 1-6 part, metal passivator 2-5 part, inhibiter 1-3 part, catalysis burning-rate accelerator 1-40 part, static inhibitor 2-4 part, antiknock stablizer 10-100 part, detergent-dispersant additive 1-6 part, agent for repairing abrasion resistance 1-6 part, Aalcohols fuel metal corrosion inhibitor 1-6 part, rubber and plastic spare corrosion swelling inhibitor 2-6 part, pure modification solubility promoter 10-50 part, Aalcohols fuel sterilant 0.2-0.8 part, Aalcohols fuel identifier 0.04-0.1 part.
Described first and second alcohol mixtures refer to that methyl alcohol and ethanol are with the combination of any weight ratio.
Described Aalcohols fuel ether stablizer is one or more combinations with any weight ratio in dimethyl ether, Anaesthetie Ether, propyl ether, Di Iso Propyl Ether, methyl tertiary butyl ether, tert amyl methyl ether(TAME), methyl-propyl ether, the Ethyl Tertisry Butyl Ether.
Described antioxidizing and antigum agent is 2,6-ditertbutylparacresol, 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butyl phenol, p-hydroxydiphenylamine, N-normal-butyl are to amido phenol, N, N-di-isopropyl Ursol D, N, one or more among N '-di-sec-butyl-p-phenyl enediamine are with the combination of any weight ratio.
Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine and N, one or more combinations with any weight ratio in the inferior bigcatkin willow-1 of N '-two.
Described inhibiter is one or more combinations with any weight ratio in trialkylphosphate, dioctylphosphoric acid ester, triphenylphosphate, tributyl phosphate, Phosphorous acid diisooctyl phenyl ester, the different monooctyl ester of phosphorous acid phenylbenzene, phosphorous acid phenylbenzene isodecyl ester, phosphorous acid diphenyl ester, triphenyl phosphite, diethanolamine, trolamine, the Yi Bingchunan.
Described catalysis burning-rate accelerator is a kind of several combinations with any weight ratio in cyclohexyl nitrate, isooctyl ester nitrate, isoamyl nitrate, nitric acid n-pentyl ester, 2-methyl nitric acid n-pentyl ester, the positive butyl ester of oxalic acid, diisopentyl oxalate, methylcarbonate, diethyl carbonate, the fatty acid methyl ester.
Described static inhibitor is one or more combinations with any weight ratio among ethylene glycol monomethyl ether, ethylene glycol ethyl ether, static inhibitor T1501, the static inhibitor T1502.
Described static inhibitor T1501 is produced by Lanzhou refinery head factory, is the commercially available prod.
Described static inhibitor T1502 is produced by Oil Materials Inst., Air Force, P.L.A., is the commercially available prod.
Described antiknock stablizer is dimethyl malonate, diethyl malonate, C1-C8 fuel-grade alcohol mixture, aromatic hydrocarbon solvent oil S100A, 2,2-dimethyl propylene acid anhydrides, N, one or more in accelerine, methylphenylamine, the isobutyl acetate are with the combination of any weight ratio.
Described aromatic hydrocarbon solvent oil S100A is produced by Taizhou city gold orange refinement worker company limited, is the commercially available prod.
Described detergent-dispersant additive is one or more combinations with any weight ratio in polyisobutenyl succinimide, polyisobutene succinimide, polyisobutenyl amine, polyetheramine, the polyene amine.
Described agent for repairing abrasion resistance is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine, 2, one or both combinations with any weight ratio in the 6-di-t-butyl mixed phenol.
Described Aalcohols fuel metal corrosion inhibitor is one or more combinations with any weight ratio among alkylphosphonic acid carboxylic acid amine salt, benzo three (nitrogen) azoles, linoleic acid dimer, 2.6-ditertbutylparacresol, Aalcohols fuel metal corrosion inhibitor C1-1406, the Aalcohols fuel metal corrosion inhibitor KT-7062.
Described Aalcohols fuel metal corrosion inhibitor C1-1406 is produced by Beijing petrochemical complex academy of sciences, is the commercially available prod.
Described Aalcohols fuel metal corrosion inhibitor KT-7062 is produced by Jinzhou Kangtai Lube Additive Co., Ltd., is the commercially available prod.
Described rubber and plastic spare corrosion swelling inhibitor is selected from the HFA-4902 inhibitor that the auspicious sunlight bio tech ltd in Beijing is produced, or the B that is produced by Beijing phenyl ring fine chemical product company limited
R-7064 inhibitor, or the two is with the combination of any weight ratio.
Described pure modification solubility promoter is one or more combinations with any weight ratio in isopropylcarbinol, primary isoamyl alcohol, propyl carbinol, Methylal(dimethoxymethane), sodium perchlorate, the potassium permanganate.
Described Aalcohols fuel sterilant is Rokafenol F 1.
Described Aalcohols fuel identifier is that solvent blue, disperse brilliant blue, pure molten sun-proof indigo plant are with the combination of any weight ratio.
The compound method of automobile-used high definition environmental protection alcohol ether fuel of the present invention is:
At normal temperatures and pressures, by weight ratio with methyl alcohol or ethanol or first and second alcohol mixtures, and Aalcohols fuel ether stablizer, antioxidizing and antigum agent, metal passivator, inhibiter, the catalysis burning-rate accelerator selected for use, static inhibitor, antiknock stablizer, detergent-dispersant additive, agent for repairing abrasion resistance, Aalcohols fuel metal corrosion inhibitor, rubber and plastic spare corrosion swelling inhibitor, pure modification solubility promoter, Aalcohols fuel sterilant, Aalcohols fuel identifier, after entering blend tank and be mixed by pipeline by each hold-up vessel, enter the hold-up vessel static reaction at last and namely got product in 8-24 hour.
The present invention is to be main raw material with methyl alcohol or ethanol or first and second alcohol mixtures, by being equipped with 14 kinds of multipurpose additives, efficiently solve many defectives that high-content, the high density first and second pure fuel bring because of its intrinsic characteristic when existing spark ignition engine is used, be embodied in the following aspects:
1, methanol fuel or alcohol fuel are low because of calorific value, the latent heat of vaporization is again respectively than the high 2-4 of gasoline times and 1-1.4 times, though can reduce inlet air temperature, improve charging efficiency, but it is very poor because of the vapo(u)rability of Aalcohols fuel at low temperatures, further reduce inlet temperature during evaporation, cause cold start difficulty or warming up time to lengthen, oil consumption increases.The present invention has realized approaching of this fuel value and gasoline heat value by after adding raw materials such as an amount of ethers, hydro carbons, lipid.
As being example with the dimethyl ether in the Aalcohols fuel ether stablizer, its advantage is:
1. dme liquefaction back is as vehicle fuel, can overcome the shortcoming of methanol fuel or alcohol fuel low-temperature startup and accelerating ability difference to a certain extent, after adding dme, make methanol fuel or alcohol fuel have good ignition properties, and delay period of ignition is short, engine mildness is difficult for producing the rough running phenomenon, and work noise is little.
2. dme is oxygenated fuel, and burning is complete, and the discharging of its CO and HC is more a lot of than vapour, diesel oil cleaning, almost can realize smokeless combustion.As long as the fuel oxygen level reaches 34% when above, engine does not all generate soot under any operating mode.Because fuel band oxygen itself, make oxygen molecule distribution uniform in the whole combustion chamber, particularly the dme vaporization heat is big, also can reduce the combustion chamber top temperature, thereby especially effectively reduced the discharging of NOx, when adopting the recycling of engine exhaust exhaust secondary, the discharging of soot will be zero, and the discharging of NOx also obtains further reducing significantly.
Though 3. the low heat value of methyl alcohol, dme is all low than vapour, diesel oil, but the calorific value of its theoretical mixture gas and gasoline, diesel oil approach or slightly high (methyl alcohol 2656KJ/Kg, dme 3067KJ/Kg, gasoline 2786KJ/Kg, diesel oil 2911KJ/Kg), after the two allotment, the theoretical mixture gas calorific value of alcohol-ether fuel and gasoline theoretical mixture gas calorific value remain basically stable or are slightly high.The dme combustionvelocity is fast in addition, the thermo-efficiency height, and burning is complete, so dynamic property is poor unlike vapour, diesel oil.In fact, because dme contains oxygen, air-fuel ratio required during burning is little, under the identical situation of air inlet amount, can be for the more fuel of Give, and therefore, taller when the dynamic property ratio uses gasoline and diesel oil during dimethyl ether fuel.
Simultaneously, the present invention has not only played catalytic combustion-supporting effect preferably to Aalcohols fuel, and has also had tangible auxiliaring effect at aspects such as cold-startings by add carbonyl carboxylate and the nitro carboxylate of 1-40 part in alcohol-ether fuel.Carbonyl carboxylate chemical property is active, particularly contain multiple functional groups such as carbonyl, hydroxyl, methoxyl group and methyl simultaneously, can with alcohols generation methylation reaction and carbonylation reaction, generate multiple derivative, thereby reduced the latent heat of vaporization of methanol fuel, improved energy transformation ratio.Experimental data shows that in the some amount scope, the usage quantity of carbonyl carboxylate whenever surpasses at 1% o'clock, and the latent heat of vaporization of methanol fuel can reduce more than 30%, and oil consumption can reduce 2-5%, and dynamic performance is significantly improved, but combustionvelocity has decline approximately.The carbonyl carboxylate also is slip additive preferably in addition, in the alcohol ether comburant (-rent), add an amount of carbonyl carboxylate, can effectively change the lubricity of alcohol-ether fuel, further reduce frictional coefficient and the degree of wear of engine, thereby reduced power loss, improved energy transformation ratio.
In addition, by adding the nitro carboxylate simultaneously, the Catalytic Combustion Effect of alcohol-ether fuel becomes more obvious, thereby certain effect has all been played in the minimizing of combustionproperty, exhaust emissions, CO and the HC of alcohol-ether fuel.
2, Aalcohols fuel is on the low side because of boiling point, occurs vapour lock easily when hot operation or engine move for a long time, causes the smooth or fuel cut-off of fuel feeding.The present invention is by after adding the higher and wideer raw materials such as ethers, mixed alcohols, carbonyl ester class and nitro ester of an amount of boiling range scope, make the whole combustion processes of alcohol-ether fuel all reach the whole trouble-free burning operating requirement of spark ignition engine, solved the vapour lock problem.
Because add the nitro carboxylate, the effect of the hydrocarbyl portion of nitric ether is to be decomposed into alkoxyl group (RO) easily, and the NO in the molecule
2Part is easy to react with alkyl, thereby the combustionproperty of alcohol-ether fuel is further improved, and delay period shortens, and rate of combustion improves.In addition again because of the adding of carbonyl carboxylate, be example with the methylcarbonate, it has good solubility property, not only the intermiscibility with other solvents is good, not stratified, also have characteristics such as higher vaporization temperature and velocity of evaporation be fast, and the oxygen level in the molecule also there is the function that improves octane value up to 53%.Methylcarbonate is owing to contain multiple functional group in its molecule, can carry out carbonylation in multiple field, methylates, esterification, carbonyl methoxylation and transesterify, and chemical reactions such as hydrolysis can take place, and generates the fine chemicals of multiple important high added value.Particularly carbonyl wherein and methyl, when the carbonyl carbon of methylcarbonate was subjected to nucleophillic attack, acyl group-oxygen bond rupture formed carbonyl compound; When its methyl carbon was subjected to nucleophillic attack, basic alkyl-oxygen bond rupture caused methylate to generate.Be raw material and dimethyl carbonate with various alcohol, can make various asymmetric methyl ethers.And as solvent, its fusing point, boiling spread is narrow, surface tension is big, viscosity is low, the medium specific inductivity is little, can obtain anti-static effect preferably, and vaporization heat is low, and owing to relative velocity of evaporation has rapid-drying properties soon, solubility parameter SP value and acetone approach, and good with the intermiscibility of gasoline, with other solvent phase ratio, methylcarbonate also has the flash-point height, steam forces down, characteristics such as Lower Explosive Limit height in the air, storing, safe in the use, its toxicity data is better than other solvent, and is little to the harm of human body, still slip additive preferably of carbonyl carboxylate simultaneously, the carbonyl carboxylate that adds some amount in alcohol-ether fuel can change the oilness of fuel, reduces wearing and tearing and the friction of engine, and avoid not vaporizing partial methanol or ethanol inflow casing wall, thereby the reduction power loss improves energy transformation ratio.
3, methyl alcohol and ethanol are a kind of good polar organic solvents, have stronger chemically reactive.The formic acid that produces in combustion processes or acetic acid can make metal materials such as copper, aluminium, manganese produce corrosion, and these materials are typical materials of Fuel Petroleum automobile.Simultaneously, the formic acid that produces in the combustion processes or acetic acid also produce softening or be full of cracks effect to automobile sealed rubber and other synthetic non-metallic material, and make these materials aging in advance.Inhibition and the corrosion swelling of rubber, the plastic component raw material that suppress of the present invention by in alcohol-ether fuel, adding an amount of metal cleaning, inhibition, metallic corrosion, make alcohol-ether fuel of the present invention all drop to very low scope to the corrosion degree of swelling of corrosion of metal degree and rubber and plastic spare, make the problems referred to above obtain fine solution.
4, because of the very easily water absorption character of Aalcohols fuel, thereby reduce or after lighter hydrocarbons solvent oil and other auxiliary agent surpass certain index because of moisture content, be prone to liquid phase separation, thereby cause influencing the normal use of fuel when temperature.Alcohol-ether fuel of the present invention is by adding an amount of ethers, mixed alcohols, solubility promoter and bipolarity or multiple polar group raw material, improved the anti-phase separation of fuel greatly, and the highest temperature of dissolving each other can be reduced to below-30 ℃, thereby fully ensured the burning result of use of alcohol-ether fuel of the present invention.
5, the formed complete skill scheme of specific components of the present invention and proportion raw material, by the interaction of each raw material,
The octane value of having realized alcohol-ether fuel is higher than the GB gasoline octane rating with a label 3-5 unit, is particularly useful for the engine of high compression ratio, has good stability, dynamic property enhancing, the technique effect that oil consumption reduces.Compare energy-conservation 3-8% with regular gasoline, and use after in regular gasoline, mixing the alcohol-ether fuel that burns more than 15%, then can reduce rate of fuel consumption more than 10%.Simultaneously, the present invention also can reduce the discharging of CO and HC in the tail gas greatly, and noise reduces, and carbon distribution and the throw out of firing system had good scavenging(action), has prolonged the work-ing life of engine.
Simultaneously, owing to do not contain many objectionable impuritiess in the alcohol-ether fuel of the present invention, as lead, sulphur, benzene, alkene, manganese etc., thereby more be conducive to the standing storage of fuel, also provide guarantee for transportation for a long time, sale.
Obviously, according to foregoing of the present invention, according to ordinary skill and the customary means of this area, under the prerequisite that does not break away from the above-mentioned basic fundamental thought of the present invention, can also make modification, replacement or the change of other various ways.
The embodiment of form is described in further detail foregoing of the present invention again by the following examples.But this should be interpreted as that the scope of the above-mentioned theme of the present invention only limits to following example, all technology that realizes based on foregoing of the present invention all belong to scope of the present invention.
Embodiment
Embodiment 1
600 parts of methyl alcohol, 300 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 2.4 parts of metal passivators, 2 parts of inhibiter, 30 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 31 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2 mixed preparing by dimethyl ether and Di Iso Propyl Ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol, 2,4,6-tri-tert-butyl phenol and N, and N-di-isopropyl Ursol D forms with weight ratio 5:2:3 mixed preparing; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:4:3 mixed preparing by trialkylphosphate, phosphorous acid diphenyl ester and trolamine; Described catalysis burning-rate accelerator is formed with weight ratio 2:2:6 mixed preparing by cyclohexyl nitrate, isooctyl ester nitrate and methylcarbonate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by N, and accelerine and aromatic hydrocarbon solvent oil S100A form with weight ratio 1:1 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutenyl succinimide and polyetheramine; Described agent for repairing abrasion resistance is N, the inferior water bigcatkin willow of N '-two-2-cyclohexanediamine; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 2:5:3 mixed preparing by alkylphosphonic acid carboxylic acid amine salt, 2,6 ditertiary butyl p cresol and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 3:1 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Embodiment 2
700 parts of methyl alcohol, 200 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 28 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 32 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 35:1 mixed preparing by dimethyl ether and Anaesthetie Ether; Described antioxidizing and antigum agent is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and p-hydroxydiphenylamine; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:3:4 mixed preparing by tributyl phosphate, dibutyl phosphite and Yi Bingchunan; Described catalysis burning-rate accelerator is formed with weight ratio 2:5 mixed preparing by isooctyl ester nitrate and methylcarbonate; Described static inhibitor is formed than mixed preparing with weight ratio 1:1 by ethylene glycol monomethyl ether and ethylene glycol ethyl ether; Described antiknock stablizer is by N, and accelerine, isobutyl acetate and methylphenylamine form with weight 2:2:1 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and N-two inferior bigcatkin willow-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight 3:3:4 mixed preparing by benzo three (nitrogen) azoles, linoleic acid dimer and 2,6 ditertiary butyl p cresol; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 5:2:3 mixed preparing by isopropylcarbinol, primary isoamyl alcohol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Embodiment 3
800 parts of methyl alcohol, 150 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 2 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 10 parts of antiknock stablizers, 3 parts of detergent-dispersant additives, 2 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 8 parts of pure modified additive solvents, 0.53 part in Aalcohols fuel sterilant, 0.07 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 5:2:3 mixed preparing by dimethyl ether, Anaesthetie Ether, tert amyl methyl ether(TAME); Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol, N, and N-di-isopropyl Ursol D and N-normal-butyl form with weight ratio 5:2:3 mixed preparing anilino phenol; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:5:2 mixed preparing by dioctylphosphoric acid ester, phosphorous acid diphenyl ester and diethanolamine; Described catalysis burning-rate accelerator is formed with weight ratio 4:2:1 mixed preparing by diethyl carbonate, isooctyl ester nitrate and fatty acid methyl ester; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by dimethyl malonate, N, and accelerine and C1-C8 fuel-grade alcohol mixture forms with weight ratio 3:4:3 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutene imide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior water bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:1 mixed preparing by benzo three (nitrogen) azoles and linoleic acid dimer; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 3:2 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Embodiment 4
400 parts of methyl alcohol, 350 parts of ethanol, 200 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 2 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 2 parts in static inhibitor, 10.4 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3 parts of swelling inhibitor of rubber and plastic spare corrosion, 7 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2 mixed preparing by dimethyl ether and Anaesthetie Ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol and N, and N-di-isopropyl Ursol D forms with weight ratio 1:1 mixed preparing; Described metal passivator is by N, N '-two inferior bigcatkin willow-1, and 2-propylene diamine and N, the inferior bigcatkin willow-1 of N '-two forms with weight ratio 1:1 mixed preparing; Described catalysis burning-rate accelerator is formed with weight ratio 5:3:2 mixed preparing by methylcarbonate, diethyl carbonate and isooctyl ester nitrate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by dimethyl malonate, N, and accelerine and aromatic hydrocarbon solvent oil S100A form with weight 3:4:3 mixed preparing; Described detergent-dispersant additive is formed with weight 2:1 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:1 mixed preparing by linoleic acid dimer and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by B
R-7064 inhibitor and HFA-4902 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 4:1:2 mixed preparing by isopropylcarbinol, sodium perchlorate and potassium permanganate; Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Embodiment 5
750 parts of ethanol, 200 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 2 parts in static inhibitor, 10.4 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 2 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3 parts of swelling inhibitor of rubber and plastic spare corrosion, 7 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 2:4 mixed preparing by Anaesthetie Ether, dimethyl ether; Described antioxidizing and antigum agent is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and p-hydroxydiphenylamine; Described metal passivator is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine; Described catalysis burning-rate accelerator is formed with weight ratio 3:1 mixed preparing by methylcarbonate and isooctyl ester nitrate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is formed with anharmonic ratio amount 3:2 mixed preparing by aromatic hydrocarbon solvent oil S100A and C1-C8 fuel-grade alcohol mixture; Described detergent-dispersant additive is formed with weight ratio 2:1 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 2:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:2 mixed preparing by benzo three (nitrogen) azoles and Aalcohols fuel metal corrosion inhibitor C1-1476; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 2:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 2:1 mixed preparing by isopropylcarbinol and primary isoamyl alcohol; Described Aalcohols fuel sterilant is by Rokafenol F 1; Described Aalcohols fuel identifier is that solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant form with weight ratio 4:2:4 mixed preparing.
Embodiment 6
200 parts of methyl alcohol, 400 parts of ethanol, 300 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 2.4 parts of Aalcohols fuel metal passivators, 2 parts of inhibiter, 30 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 32 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4 parts of swelling inhibitor of rubber and plastic spare corrosion, 11 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:1:1 mixed preparing by dimethyl ether, propyl ether, methyl tertiary butyl ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol and N, and the N-di-sec-butyl-p-phenyl enediamine forms with weight ratio 5:2 mixed preparing; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 1:1:1 mixed preparing by dioctylphosphoric acid ester, Phosphorous acid diisooctyl phenyl ester and triphenyl phosphite; Described catalysis burning-rate accelerator is formed with weight ratio 0.5:0.5:3:6 mixed preparing by isoamyl nitrate, 2-methyl nitric acid n-pentyl ester, nitric acid n-pentyl ester and methylcarbonate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is formed with weight ratio 2:1 mixed preparing by diethyl malonate and 2,2-dimethyl propylene acid anhydrides; Described detergent-dispersant additive is formed with weight ratio 1:2 mixed preparing by polyetheramine and polyisobutene succinimide; Described agent for repairing abrasion resistance is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by B
R-7064 inhibitor and HFA-4902 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 2:1 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Embodiment 7
350 parts of methyl alcohol, 300 parts of ethanol, 250 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 30 parts of catalytic combustion-supportings, 3 parts in static inhibitor, 30 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of metal corrosion inhibitors, 4.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier.
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2:1 mixed preparing by dimethyl ether, Ethyl Tertisry Butyl Ether, methyl-propyl ether; Described antioxidizing and antigum agent is formed with weight 2:1 mixed preparing phenol by 2,6 ditertiary butyl p cresol and 2,6-di-t-butyl; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 1:1 mixed preparing by triphenylphosphate and phosphorous acid hexichol isodecyl ester; Described catalysis burning-rate accelerator is formed with weight ratio 4:1:1:1 mixed preparing by the positive butyl ester of methylcarbonate, diisopentyl oxalate, isooctyl ester nitrate and oxalic acid; Described static inhibitor is formed with weight ratio 1:2 mixed preparing by ethylene glycol ethyl ether and static inhibitor T1502; Described antiknock stablizer is formed with weight ratio 1:2 mixed preparing by dimethyl malonate and aromatic hydrocarbon solvent S100A; Described detergent-dispersant additive is formed with weight ratio 2:1 mixed preparing by polyisobutene succinimide and polyetheramine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described metal corrosion inhibitor is formed with weight ratio 2:1 mixed preparing by linoleic acid dimer and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 4:1:2 mixed preparing by isopropylcarbinol, sodium perchlorate and potassium permanganate; Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
Experimental example
The alcohol-ether fuel of embodiment 1-7 is used at same new car separately respectively, and its related experiment data are as follows:
Above experimental data further specifies: the present invention has well solved many defectives that first, alcohol fuel brings because of its intrinsic characteristic when existing spark ignition engine is used, and this fuel performance is stable, concentration content reaches the alcohol-ether fuel of 85-97% content, reach the multi-functional combined additive of 3-15% by adding content, make its alcohol-ether fuel and the practical oil consumption ratio of regular gasoline reach 1:1 or better, and the discharging of CO, HC tail gas all is significantly less than national standard, even has met or exceeded the newest standards of Europe IV standard and California, USA.Simultaneously, assay shows that also leading indicators such as octane value, boiling range, hydro carbons, residual quantity, benzene, sulphur, alkene, manganese also all are better than standard and the international standard of Europe IV standard and California, USA.
Claims (10)
1. automobile-used high definition environmental protection alcohol ether fuel, it is characterized in that: the preparation of raw material by following weight parts forms:
Methyl alcohol or ethanol or first and second alcohol mixture 600-800 parts, Aalcohols fuel ether stablizer 100-350 part, antioxidizing and antigum agent 1-6 part, metal passivator 2-5 part, inhibiter 1-3 part, catalysis burning-rate accelerator 1-40 part, static inhibitor 2-4 part, antiknock stablizer 10-100 part, detergent-dispersant additive 1-6 part, agent for repairing abrasion resistance 1-6 part, Aalcohols fuel metal corrosion inhibitor 1-6 part, rubber and plastic spare corrosion swelling inhibitor 2-6 part, pure modification solubility promoter 10-50 part, Aalcohols fuel sterilant 0.2-0.8 part, Aalcohols fuel identifier 0.04-0.1 part.
2. automobile-used high definition environmental protection alcohol ether fuel according to claim 1 is characterized in that: described first and second alcohol mixtures refer to that methyl alcohol and ethanol are with the combination of any weight ratio.
3. automobile-used high definition environmental protection alcohol ether fuel according to claim 1, it is characterized in that: described Aalcohols fuel ether stablizer is one or more combinations with any weight ratio in dimethyl ether, Anaesthetie Ether, propyl ether, Di Iso Propyl Ether, methyl tertiary butyl ether, tert amyl methyl ether(TAME), methyl-propyl ether, the Ethyl Tertisry Butyl Ether;
Described antioxidizing and antigum agent is 2,6-ditertbutylparacresol, 2,6-di-tert-butylphenol, 2,4,6-tri-tert-butyl phenol, p-hydroxydiphenylamine, N-normal-butyl are to amido phenol, N, N-di-isopropyl Ursol D, N, one or more among N '-di-sec-butyl-p-phenyl enediamine are with the combination of any weight ratio;
Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine and N, one or more combinations with any weight ratio in the inferior bigcatkin willow-1 of N '-two;
Described inhibiter is one or more combinations with any weight ratio in trialkylphosphate, dioctylphosphoric acid ester, triphenylphosphate, tributyl phosphate, Phosphorous acid diisooctyl phenyl ester, the different monooctyl ester of phosphorous acid phenylbenzene, phosphorous acid phenylbenzene isodecyl ester, phosphorous acid diphenyl ester, triphenyl phosphite, diethanolamine, trolamine, the Yi Bingchunan;
Described catalysis burning-rate accelerator is a kind of several combinations with any weight ratio in cyclohexyl nitrate, isooctyl ester nitrate, isoamyl nitrate, nitric acid n-pentyl ester, 2-methyl nitric acid n-pentyl ester, the positive butyl ester of oxalic acid, diisopentyl oxalate, methylcarbonate, diethyl carbonate, the fatty acid methyl ester;
Described static inhibitor is one or more combinations with any weight ratio among ethylene glycol monomethyl ether, ethylene glycol ethyl ether, static inhibitor T1501, the static inhibitor T1502;
Described antiknock stablizer is dimethyl malonate, diethyl malonate, C1-C8 fuel-grade alcohol mixture, aromatic hydrocarbon solvent oil S100A, 2,2-dimethyl propylene acid anhydrides, N, one or more in accelerine, methylphenylamine, the isobutyl acetate are with the combination of any weight ratio;
Described detergent-dispersant additive is one or more combinations with any weight ratio in polyisobutenyl succinimide, polyisobutene succinimide, polyisobutenyl amine, polyetheramine, the polyene amine;
Described agent for repairing abrasion resistance is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine, 2, one or both combinations with any weight ratio in the 6-di-t-butyl mixed phenol;
Described Aalcohols fuel metal corrosion inhibitor is one or more combinations with any weight ratio among alkylphosphonic acid carboxylic acid amine salt, benzo three (nitrogen) azoles, linoleic acid dimer, 2.6-ditertbutylparacresol, Aalcohols fuel metal corrosion inhibitor C1-1406, the Aalcohols fuel metal corrosion inhibitor KT-7062;
Described rubber and plastic spare corrosion swelling inhibitor is selected from the HFA-4902 inhibitor that the auspicious sunlight bio tech ltd in Beijing is produced, or the B that is produced by Beijing phenyl ring fine chemical product company limited
R-7064 inhibitor, or the two is with the combination of any weight ratio;
Described pure modification solubility promoter is one or more combinations with any weight ratio in isopropylcarbinol, primary isoamyl alcohol, propyl carbinol, Methylal(dimethoxymethane), sodium perchlorate, the potassium permanganate;
Described Aalcohols fuel sterilant is Rokafenol F 1;
Described Aalcohols fuel identifier is that solvent blue, disperse brilliant blue, pure molten sun-proof indigo plant are with the combination of any weight ratio.
4. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
600 parts of methyl alcohol, 300 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 2.4 parts of metal passivators, 2 parts of inhibiter, 30 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 31 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2 mixed preparing by dimethyl ether and Di Iso Propyl Ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol, 2,4,6-tri-tert-butyl phenol and N, and N-di-isopropyl Ursol D forms with weight ratio 5:2:3 mixed preparing; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:4:3 mixed preparing by trialkylphosphate, phosphorous acid diphenyl ester and trolamine; Described catalysis burning-rate accelerator is formed with weight ratio 2:2:6 mixed preparing by cyclohexyl nitrate, isooctyl ester nitrate and methylcarbonate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by N, and accelerine and aromatic hydrocarbon solvent oil S100A form with weight ratio 1:1 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutenyl succinimide and polyetheramine; Described agent for repairing abrasion resistance is N, the inferior water bigcatkin willow of N '-two-2-cyclohexanediamine; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 2:5:3 mixed preparing by alkylphosphonic acid carboxylic acid amine salt, 2,6 ditertiary butyl p cresol and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 3:1 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
5. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
700 parts of methyl alcohol, 200 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 28 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 32 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 35:1 mixed preparing by dimethyl ether and Anaesthetie Ether; Described antioxidizing and antigum agent is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and p-hydroxydiphenylamine; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:3:4 mixed preparing by tributyl phosphate, dibutyl phosphite and Yi Bingchunan; Described catalysis burning-rate accelerator is formed with weight ratio 2:5 mixed preparing by isooctyl ester nitrate and methylcarbonate; Described static inhibitor is formed than mixed preparing with weight ratio 1:1 by ethylene glycol monomethyl ether and ethylene glycol ethyl ether; Described antiknock stablizer is by N, and accelerine, isobutyl acetate and methylphenylamine form with weight 2:2:1 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and N-two inferior bigcatkin willow-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight 3:3:4 mixed preparing by benzo three (nitrogen) azoles, linoleic acid dimer and 2,6 ditertiary butyl p cresol; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 5:2:3 mixed preparing by isopropylcarbinol, primary isoamyl alcohol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
6. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
800 parts of methyl alcohol, 150 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 2 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 3 parts in static inhibitor, 10 parts of antiknock stablizers, 3 parts of detergent-dispersant additives, 2 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 8 parts of pure modified additive solvents, 0.53 part in Aalcohols fuel sterilant, 0.07 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 5:2:3 mixed preparing by dimethyl ether, Anaesthetie Ether, tert amyl methyl ether(TAME); Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol, N, and N-di-isopropyl Ursol D and N-normal-butyl form with weight ratio 5:2:3 mixed preparing anilino phenol; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 3:5:2 mixed preparing by dioctylphosphoric acid ester, phosphorous acid diphenyl ester and diethanolamine; Described catalysis burning-rate accelerator is formed with weight ratio 4:2:1 mixed preparing by diethyl carbonate, isooctyl ester nitrate and fatty acid methyl ester; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by dimethyl malonate, N, and accelerine and C1-C8 fuel-grade alcohol mixture forms with weight ratio 3:4:3 mixed preparing; Described detergent-dispersant additive is formed with weight ratio 3:2 mixed preparing by polyisobutene imide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior water bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:1 mixed preparing by benzo three (nitrogen) azoles and linoleic acid dimer; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 3:2 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
7. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
400 parts of methyl alcohol, 350 parts of ethanol, 200 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 2 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 2 parts in static inhibitor, 10.4 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3 parts of swelling inhibitor of rubber and plastic spare corrosion, 7 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2 mixed preparing by dimethyl ether and Anaesthetie Ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol and N, and N-di-isopropyl Ursol D forms with weight ratio 1:1 mixed preparing; Described metal passivator is by N, N '-two inferior bigcatkin willow-1, and 2-propylene diamine and N, the inferior bigcatkin willow-1 of N '-two forms with weight ratio 1:1 mixed preparing; Described catalysis burning-rate accelerator is formed with weight ratio 5:3:2 mixed preparing by methylcarbonate, diethyl carbonate and isooctyl ester nitrate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is by dimethyl malonate, N, and accelerine and aromatic hydrocarbon solvent oil S100A form with weight 3:4:3 mixed preparing; Described detergent-dispersant additive is formed with weight 2:1 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:1 mixed preparing by linoleic acid dimer and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by B
R-7064 inhibitor and HFA-4902 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 4:1:2 mixed preparing by isopropylcarbinol, sodium perchlorate and potassium permanganate; Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
8. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
750 parts of ethanol, 200 parts of Aalcohols fuel ether stablizers, 3 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 10 parts of catalysis burning-rate accelerators, 2 parts in static inhibitor, 10.4 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 2 parts of agent for repairing abrasion resistance, 3 parts of Aalcohols fuel metal corrosion inhibitors, 3 parts of swelling inhibitor of rubber and plastic spare corrosion, 7 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 2:4 mixed preparing by Anaesthetie Ether, dimethyl ether; Described antioxidizing and antigum agent is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and p-hydroxydiphenylamine; Described metal passivator is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine; Described catalysis burning-rate accelerator is formed with weight ratio 3:1 mixed preparing by methylcarbonate and isooctyl ester nitrate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is formed with anharmonic ratio amount 3:2 mixed preparing by aromatic hydrocarbon solvent oil S100A and C1-C8 fuel-grade alcohol mixture; Described detergent-dispersant additive is formed with weight ratio 2:1 mixed preparing by polyisobutene succinimide and polyene amine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 2:1 mixed preparing; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 1:2 mixed preparing by benzo three (nitrogen) azoles and Aalcohols fuel metal corrosion inhibitor C1-1476; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 2:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 2:1 mixed preparing by isopropylcarbinol and primary isoamyl alcohol; Described Aalcohols fuel sterilant is by Rokafenol F 1; Described Aalcohols fuel identifier is that solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant form with weight ratio 4:2:4 mixed preparing.
9. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
200 parts of methyl alcohol, 400 parts of ethanol, 300 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 2.4 parts of Aalcohols fuel metal passivators, 2 parts of inhibiter, 30 parts of catalytic combustion-supportings, 3 parts in static inhibitor, 32 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of Aalcohols fuel metal corrosion inhibitors, 4 parts of swelling inhibitor of rubber and plastic spare corrosion, 11 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:1:1 mixed preparing by dimethyl ether, propyl ether, methyl tertiary butyl ether; Described antioxidizing and antigum agent is by 2,6 ditertiary butyl p cresol and N, and the N-di-sec-butyl-p-phenyl enediamine forms with weight ratio 5:2 mixed preparing; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 1:1:1 mixed preparing by dioctylphosphoric acid ester, Phosphorous acid diisooctyl phenyl ester and triphenyl phosphite; Described catalysis burning-rate accelerator is formed with weight ratio 0.5:0.5:3:6 mixed preparing by isoamyl nitrate, 2-methyl nitric acid n-pentyl ester, nitric acid n-pentyl ester and methylcarbonate; Described static inhibitor is formed with weight ratio 1:1 mixed preparing by static inhibitor T1501, static inhibitor T1502; Described antiknock stablizer is formed with weight ratio 2:1 mixed preparing by diethyl malonate and 2,2-dimethyl propylene acid anhydrides; Described detergent-dispersant additive is formed with weight ratio 1:2 mixed preparing by polyetheramine and polyisobutene succinimide; Described agent for repairing abrasion resistance is N, the inferior bigcatkin willow of N '-two-2-cyclohexanediamine; Described Aalcohols fuel metal corrosion inhibitor is formed with weight ratio 2:1 mixed preparing by 2,6 ditertiary butyl p cresol and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by B
R-7064 inhibitor and HFA-4902 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 2:1 mixed preparing by isopropylcarbinol and Methylal(dimethoxymethane); Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
10. according to each described automobile-used high definition environmental protection alcohol ether fuel among the claim 1-3, it is characterized in that: the preparation of raw material by following weight parts forms:
350 parts of methyl alcohol, 300 parts of ethanol, 250 parts of Aalcohols fuel ether stablizers, 4 parts of antioxidizing and antigum agents, 3 parts of metal passivators, 2 parts of inhibiter, 30 parts of catalytic combustion-supportings, 3 parts in static inhibitor, 30 parts of antiknock stablizers, 4 parts of detergent-dispersant additives, 3 parts of agent for repairing abrasion resistance, 4 parts of metal corrosion inhibitors, 4.4 parts of swelling inhibitor of rubber and plastic spare corrosion, 12 parts of pure modified additive solvents, 0.54 part in Aalcohols fuel sterilant, 0.06 part of Aalcohols fuel identifier;
Described Aalcohols fuel ether stablizer is formed with weight ratio 4:2:1 mixed preparing by dimethyl ether, Ethyl Tertisry Butyl Ether, methyl-propyl ether; Described antioxidizing and antigum agent is formed with weight 2:1 mixed preparing phenol by 2,6 ditertiary butyl p cresol and 2,6-di-t-butyl; Described metal passivator is N, N '-two inferior bigcatkin willow-1,2-propylene diamine; Described inhibiter is formed with weight ratio 1:1 mixed preparing by triphenylphosphate and phosphorous acid hexichol isodecyl ester; Described catalysis burning-rate accelerator is formed with weight ratio 4:1:1:1 mixed preparing by the positive butyl ester of methylcarbonate, diisopentyl oxalate, isooctyl ester nitrate and oxalic acid; Described static inhibitor is formed with weight ratio 1:2 mixed preparing by ethylene glycol ethyl ether and static inhibitor T1502; Described antiknock stablizer is formed with weight ratio 1:2 mixed preparing by dimethyl malonate and aromatic hydrocarbon solvent S100A; Described detergent-dispersant additive is formed with weight ratio 2:1 mixed preparing by polyisobutene succinimide and polyetheramine; Described agent for repairing abrasion resistance is by N, and the inferior bigcatkin willow of N '-two-2-cyclohexanediamine and 2,6-di-t-butyl mixed phenol form with weight ratio 1:1 mixed preparing; Described metal corrosion inhibitor is formed with weight ratio 2:1 mixed preparing by linoleic acid dimer and benzo three (nitrogen) azoles; Described rubber and plastic spare corrosion swelling inhibitor is by HFA-4902 inhibitor and B
R-7064 inhibitor form with weight ratio 1:1 mixed preparing; Described pure modification solubility promoter is formed with weight ratio 4:1:2 mixed preparing by isopropylcarbinol, sodium perchlorate and potassium permanganate; Described Aalcohols fuel sterilant is Rokafenol F 1; Described Aalcohols fuel identifier is formed with weight ratio 4:2:4 mixed preparing by solvent blue, disperse brilliant blue and pure molten sun-proof indigo plant.
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