CN103265334B - Method for cladding glaze and colors on ceramic whiteware by using laser - Google Patents

Method for cladding glaze and colors on ceramic whiteware by using laser Download PDF

Info

Publication number
CN103265334B
CN103265334B CN201310203454.4A CN201310203454A CN103265334B CN 103265334 B CN103265334 B CN 103265334B CN 201310203454 A CN201310203454 A CN 201310203454A CN 103265334 B CN103265334 B CN 103265334B
Authority
CN
China
Prior art keywords
glaze
ceramic whiteware
ceramic
laser
cladding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201310203454.4A
Other languages
Chinese (zh)
Other versions
CN103265334A (en
Inventor
范积伟
焦志强
张小立
赵慧君
张旺玺
***
张振国
张照军
张瑞杰
刘�英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongyuan University of Technology
Original Assignee
Zhongyuan University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongyuan University of Technology filed Critical Zhongyuan University of Technology
Priority to CN201310203454.4A priority Critical patent/CN103265334B/en
Publication of CN103265334A publication Critical patent/CN103265334A/en
Application granted granted Critical
Publication of CN103265334B publication Critical patent/CN103265334B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Surface Treatment Of Glass (AREA)

Abstract

The invention relates to a method for cladding glaze and colors on ceramic whiteware by using a laser. The method comprises the following steps of: adding a transparent solvent glaze material in ceramic pigment and drying so as to form a structure with the transparent solvent glaze at the upper layer and the ceramic pigment at the lower layer, wherein the proportion of the transparent solvent glaze material is smaller than that of the ceramic pigment; and cladding colored glaze by utilizing high energy of lasers so as to obtain colored ceramic glaze and colors. With the method for cladding the glaze and colors on the ceramic whiteware by using the laser, the laser is used as a burning heat source of the ceramic glaze and colors, and patterns of the glaze and colors are designed and formed by a computer connected with the laser. The method is simple in technology, short in manufacturing time and small in energy consumption, and is suitable for manufacturing single-piece or a small quantity of ceramic glaze and colors decorations by matching with the control of the computer. The production efficiency is improved, and the effects of energy conservation and emission reduction are also achieved.

Description

A kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware
Technical field
The invention belongs to the technical field of ceramic glaze decoration firing processing method processed, relate in particular to the method that uses laser apparatus cladding muffle painting on ceramic whiteware.
Background technology
The making method of traditional ceramic glaze color equipment decorations is to adopt color glaze or color base and solvent to coordinate the beramic color of making, by certain processing method (comprise pallet, repeatedly chromatography or describe etc.) on ceramic, form pattern, then fire and form muffle painting and decorate through burning color kiln.This making processes complex process and cause power consumption source high, therefore needs to develop a kind of high temperature rapid technology and changes the technological problems that traditional ceramics muffle painting is fired.Along with the raising of socioeconomic development and living standards of the people, people are more tending towards personalized to beautiful pursuit, and the ceramic glaze illuminated product of " thousand people's one sides " of production in enormous quantities can not meet the culture and arts demand that people are more and more higher.By customized pattern, short run even single-piece make will become high-grade ceramic decorate the direction of Future Development, internet is universal also for client's personalized customization brings larger convenience simultaneously.Making method energy consumption for the ceramic glaze illuminated product of single-piece or short run of traditional ceramic glaze color equipment decorations is excessive, and therefore high cost more needs a kind of technology of novel cladding on ceramic whiteware pottery muffle painting.
Laser technology is the fine selection of high temperature rapid firing, and the laser processing parameter of controlling well can reduce the Production Time of ceramic muffle painting, has improved labour productivity, simultaneously the more energy-conservation cost that reduces personalized product.But not yet find up to now the domestic and international report with laser cladding muffle painting on ceramic whiteware.
Summary of the invention
To be solved by this invention is to improve ceramic glaze illuminated product production efficiency and the technical problem such as energy-conservation, thereby a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware is provided.
In order to address the above problem by the following technical solutions: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware, by add transparent solvent glaze in beramic color, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
Concrete grammar is as follows: the first step, and getting weight ratio is transparent solvent glaze and the beramic color of 3:2, and transparent solvent glaze and beramic color are ground to form to powder and mix; Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds into colour glaze; The 3rd step, is sprayed on ceramic whiteware surface by the good colour glaze of ball milling, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier dry; The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting.
In the first step, transparent solvent glaze powder and beramic color powder are crossed respectively to 200 mesh sieves and evenly mixed.
The melt temperature of transparent solvent glaze is 1200 oc.
In second step, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.
The powder weighing 20g mixing is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min, obtains color glaze slurry after 200 mesh sieves fast.
The hydroxylated cellulose that the preparation method of CMC dilute solution is is C1000 by viscosity model is added to the water and makes, and the weight ratio of hydroxylated cellulose and water is 1:200.
The hydroxylated cellulose 5g that is C1000 by viscosity model joins and in 1000ml water, makes CMC dilute solution.
In the 3rd step, color glaze pulp spraying is coated in ceramic whiteware surface thickness between 0.1mm-0.25mm, and in loft drier, drying temperature is 40 oc.
Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Adopt the present invention to use the method for laser apparatus cladding muffle painting on ceramic whiteware, what use laser was ceramic muffle painting fires thermal source, muffle painting pattern is that the computer design that laser apparatus connects forms, technique is simple, Production Time is short, energy consumption is little, and matching computer control is applicable to the making of the ceramic glaze illuminated product of single-piece or short run.Production efficiency energy-saving and emission-reduction have again been improved.
Embodiment
Embodiment 1: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware, by add transparent solvent glaze in beramic color, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
Transparent solvent glaze has the raw material of following weight part to be prepared from as 5 parts, 8 parts, 45 parts of clear frits, Suzhou soil, calcite 12wt part, 30 parts of lithium feldspars and quartz, and the proportion of transparent solvent glaze is 1.36 g/cm 3; The ratio weight average of beramic color used for example, higher than the proportion of transparent solvent glaze, peacock blue 1.59 g/cm 3, cobalt black 2.10g/cm 3.
Embodiment 2: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.The first step, crosses respectively 200 mesh sieves by the transparent solvent glaze of pulverizing and beramic color; Getting weight ratio is transparent solvent glaze and the beramic color of 3:2, and mixes; Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds into colour glaze; The 3rd step, is sprayed on ceramic whiteware surface by the good colour glaze of ball milling, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier dry; The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting.
Embodiment 3: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.
The first step, getting beramic color and melt temperature is 1200 othe transparent solvent glaze of C is crossed respectively 200 mesh sieves, and by weight for 3:2, transparent solvent glaze powder and beramic color powder evenly being mixed.
Second step, puts into ball grinder by the powder weighing 20g mixing, and adds 20ml CMC dilute solution and 4ml water, fast after ball milling 30min by color glaze slurry good ball milling after 200 mesh sieves; The hydroxylated cellulose 5g that the preparation method of CMC dilute solution is is C1000 by viscosity model joins in 1000ml water.
The 3rd step, is coated in ceramic whiteware surface by color glaze pulp spraying good ball milling, and colour glaze is sprayed on ceramic whiteware surface thickness between 0.1mm-0.25mm, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier and are dried, and drying temperature is 40 oc.
The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting; Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Embodiment 4: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.Wherein, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.The weight ratio of hydroxylated cellulose and water is 1:200.
Other steps are with embodiment 2.
Embodiment 5: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.
(1), selecting of laser apparatus: should select low-power laser, as 80W CO 2laser engraving machine.
(2), the preparation of colour glaze: colour glaze is made up of transparent solvent glaze and beramic color, ground transparent solvent glaze and beramic color are crossed respectively to 200 mesh sieves, then by weight carrying out proportioning for the ratio of 3:2, be in harmonious proportion with Walocel MT 20.000PV (CMC) aqueous solution and the pure water that prepare again, obtain after mixing liquid is put into the ball milling that ball grinder carries out half hour finally obtaining color glaze slurry after 200 mesh sieves.
(3), glazing: the color glaze slurry preparing is sprayed to existing ceramic whiteware product surface in the mode of spraying, uniform spraying ceramic whiteware sample is put into drying baker and dry, when oven dry, temperature is unsuitable too high, is advisable for 40 DEG C.
(4), draw muffle painting pattern: on the computer that connects laser engraving machine, carrying out the drafting of pattern with mapping software, can be that character and graphic can be also other pattern.
(5), laser processing: the ceramic whiteware goods of the good color glaze of dried coating are placed on the processing platform of laser engraving machine, the machined parameters of laser engraving machine is set to: laser power (30W-80W), sweep velocity (100mm/min-600mm/min), laser spot diameter (1mm-2.5mm).Then just can realize the laser melting coating of ceramic muffle painting on ceramic whiteware according to the drawn figure of computer.

Claims (7)

1. use a method for laser apparatus cladding muffle painting on ceramic whiteware, it is characterized in that concrete grammar is as follows:
The first step, getting weight ratio is transparent solvent glaze and the beramic color of 3:2, transparent solvent glaze and beramic color are ground to form to powder and mix, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color;
Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds quality glaze slurry, and wherein, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml;
The 3rd step, is coated in ceramic whiteware surface by color glaze pulp spraying good ball milling, and color glaze pulp spraying is coated in ceramic whiteware surface thickness between 0.1mm-0.25mm, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier and are dried, and drying temperature is 40 DEG C;
The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting, and the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain in-glaze decoration pottery muffle painting.
2. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: in the first step, transparent solvent glaze powder and beramic color powder are crossed respectively to 200 mesh sieves and evenly mixed.
3. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: the melt temperature of transparent solvent glaze is 1200 DEG C.
4. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: the powder weighing 20g mixing is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min, obtains color glaze slurry after 200 mesh sieves fast.
5. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1 or 4, it is characterized in that: the hydroxylated cellulose that the preparation method of CMC dilute solution is is C1000 by viscosity model is added to the water and makes, the weight ratio of hydroxylated cellulose and water is 1:200.
6. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 5, it is characterized in that: the hydroxylated cellulose 5g that is C1000 by viscosity model joins and in 1000ml water, makes CMC dilute solution.
7. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
CN201310203454.4A 2013-05-28 2013-05-28 Method for cladding glaze and colors on ceramic whiteware by using laser Expired - Fee Related CN103265334B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310203454.4A CN103265334B (en) 2013-05-28 2013-05-28 Method for cladding glaze and colors on ceramic whiteware by using laser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310203454.4A CN103265334B (en) 2013-05-28 2013-05-28 Method for cladding glaze and colors on ceramic whiteware by using laser

Publications (2)

Publication Number Publication Date
CN103265334A CN103265334A (en) 2013-08-28
CN103265334B true CN103265334B (en) 2014-10-22

Family

ID=49009013

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310203454.4A Expired - Fee Related CN103265334B (en) 2013-05-28 2013-05-28 Method for cladding glaze and colors on ceramic whiteware by using laser

Country Status (1)

Country Link
CN (1) CN103265334B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104961500A (en) * 2015-06-01 2015-10-07 重庆大学 Ceramic glaze decoration method
CN105799412B (en) * 2016-03-07 2019-05-03 温州职业技术学院 A kind of monochromatic automatic line drawing machine of ceramics
CN106626849A (en) * 2016-09-13 2017-05-10 山东镭泽智能科技有限公司 Color laser marking method for ceramic
CN109249140B (en) * 2018-11-27 2021-01-26 杜拉维特(中国)洁具有限公司 Laser marking method
CN110255907A (en) * 2019-08-06 2019-09-20 淄博中升机械有限公司 A kind of wide bandgap semiconductor nanometer enamel and enamel firing method for reaction kettle
JP2021187725A (en) * 2020-06-01 2021-12-13 洋二 丸谷 Method for painting on porcelain

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101372422A (en) * 2008-10-09 2009-02-25 傅涛 In-glaze decoration method for bright red glazed ceramic

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101372422A (en) * 2008-10-09 2009-02-25 傅涛 In-glaze decoration method for bright red glazed ceramic

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
A New Method for Processing Ceramics with Cracked Glaze;Jiwei Fan.et.al;《Advanced Materials Research》;20121231;第63页最后1段至第64页第2段,第64页倒数第1段、第2段 *
Jiwei Fan.et.al.A New Method for Processing Ceramics with Cracked Glaze.《Advanced Materials Research》.2012,第63页最后1段至第64页第2段,第64页倒数第1段、第2段.

Also Published As

Publication number Publication date
CN103265334A (en) 2013-08-28

Similar Documents

Publication Publication Date Title
CN103265334B (en) Method for cladding glaze and colors on ceramic whiteware by using laser
CN104193208B (en) The color sand of high temperature sintering and its preparation method
CN102795892B (en) Soluble salt ceramic tile and production method thereof
CN101993237B (en) Method for manufacturing low-temperature red clay colour-painted and glazed ecological ceramic product
CN107827363A (en) A kind of high temperature golden yellow pearly-lustre glaze and its application
CN106396638A (en) Low-temperature lightweight lime gradient glaze ceramic and production process thereof
CN110357428A (en) A kind of preparation method and Ceramic Tiles of the controllable Ceramic Tiles of glaze glossiness
CN103396162A (en) Method for founding scaled glaze on ceramic substrate by adopting laser
CN108996909A (en) A kind of ceramic exterior wall brick and preparation method thereof of artificial granite speckle
CN107056060B (en) The peacock blue glaze ceramics of gradual change and its preparation process
CN106746655A (en) A kind of method that imitative pottery rough flambe is fired under the conditions of oxidizing atmosphere
CN104193411A (en) Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof
CN105780480A (en) Preparation method of flexible surface lining material
CN102674894B (en) Method for coloring surface of ceramic body and ceramic colorant
CN104176977A (en) Stone like coating prepared by using waste ceramic, and its preparation method
CN107721175A (en) A kind of heat-insulated pottery glaze and its enameling method
CN109133626A (en) A kind of tile glaze and its enameling method for pottery
CN108046843A (en) A kind of ceramic coloring technique
CN105884398B (en) A kind of imitative preparation method for naturally flowing stone texture ceramic tile true to nature
CN103570338B (en) Low-temperature energy-saving manufacture method for once-sintered printed glazed red soil pottery products
CN106242499A (en) A kind of production technology twisting tire porcelain
CN104230395B (en) A kind of adobe of once-firing crystallite glass composite plate
CN103204675B (en) Manufacturing method of novel porcelain artwork
CN106957543A (en) It is a kind of to make the coating and its spraying coating process of ceramic surface formation natural figure
CN105541414A (en) Method for forming hand-painted texture pattern with uneven color depth through transmutation glaze beat-coating with colored glaze

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20141022

Termination date: 20170528

CF01 Termination of patent right due to non-payment of annual fee