CN103265334B - Method for cladding glaze and colors on ceramic whiteware by using laser - Google Patents
Method for cladding glaze and colors on ceramic whiteware by using laser Download PDFInfo
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- CN103265334B CN103265334B CN201310203454.4A CN201310203454A CN103265334B CN 103265334 B CN103265334 B CN 103265334B CN 201310203454 A CN201310203454 A CN 201310203454A CN 103265334 B CN103265334 B CN 103265334B
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Abstract
The invention relates to a method for cladding glaze and colors on ceramic whiteware by using a laser. The method comprises the following steps of: adding a transparent solvent glaze material in ceramic pigment and drying so as to form a structure with the transparent solvent glaze at the upper layer and the ceramic pigment at the lower layer, wherein the proportion of the transparent solvent glaze material is smaller than that of the ceramic pigment; and cladding colored glaze by utilizing high energy of lasers so as to obtain colored ceramic glaze and colors. With the method for cladding the glaze and colors on the ceramic whiteware by using the laser, the laser is used as a burning heat source of the ceramic glaze and colors, and patterns of the glaze and colors are designed and formed by a computer connected with the laser. The method is simple in technology, short in manufacturing time and small in energy consumption, and is suitable for manufacturing single-piece or a small quantity of ceramic glaze and colors decorations by matching with the control of the computer. The production efficiency is improved, and the effects of energy conservation and emission reduction are also achieved.
Description
Technical field
The invention belongs to the technical field of ceramic glaze decoration firing processing method processed, relate in particular to the method that uses laser apparatus cladding muffle painting on ceramic whiteware.
Background technology
The making method of traditional ceramic glaze color equipment decorations is to adopt color glaze or color base and solvent to coordinate the beramic color of making, by certain processing method (comprise pallet, repeatedly chromatography or describe etc.) on ceramic, form pattern, then fire and form muffle painting and decorate through burning color kiln.This making processes complex process and cause power consumption source high, therefore needs to develop a kind of high temperature rapid technology and changes the technological problems that traditional ceramics muffle painting is fired.Along with the raising of socioeconomic development and living standards of the people, people are more tending towards personalized to beautiful pursuit, and the ceramic glaze illuminated product of " thousand people's one sides " of production in enormous quantities can not meet the culture and arts demand that people are more and more higher.By customized pattern, short run even single-piece make will become high-grade ceramic decorate the direction of Future Development, internet is universal also for client's personalized customization brings larger convenience simultaneously.Making method energy consumption for the ceramic glaze illuminated product of single-piece or short run of traditional ceramic glaze color equipment decorations is excessive, and therefore high cost more needs a kind of technology of novel cladding on ceramic whiteware pottery muffle painting.
Laser technology is the fine selection of high temperature rapid firing, and the laser processing parameter of controlling well can reduce the Production Time of ceramic muffle painting, has improved labour productivity, simultaneously the more energy-conservation cost that reduces personalized product.But not yet find up to now the domestic and international report with laser cladding muffle painting on ceramic whiteware.
Summary of the invention
To be solved by this invention is to improve ceramic glaze illuminated product production efficiency and the technical problem such as energy-conservation, thereby a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware is provided.
In order to address the above problem by the following technical solutions: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware, by add transparent solvent glaze in beramic color, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
Concrete grammar is as follows: the first step, and getting weight ratio is transparent solvent glaze and the beramic color of 3:2, and transparent solvent glaze and beramic color are ground to form to powder and mix; Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds into colour glaze; The 3rd step, is sprayed on ceramic whiteware surface by the good colour glaze of ball milling, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier dry; The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting.
In the first step, transparent solvent glaze powder and beramic color powder are crossed respectively to 200 mesh sieves and evenly mixed.
The melt temperature of transparent solvent glaze is 1200
oc.
In second step, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.
The powder weighing 20g mixing is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min, obtains color glaze slurry after 200 mesh sieves fast.
The hydroxylated cellulose that the preparation method of CMC dilute solution is is C1000 by viscosity model is added to the water and makes, and the weight ratio of hydroxylated cellulose and water is 1:200.
The hydroxylated cellulose 5g that is C1000 by viscosity model joins and in 1000ml water, makes CMC dilute solution.
In the 3rd step, color glaze pulp spraying is coated in ceramic whiteware surface thickness between 0.1mm-0.25mm, and in loft drier, drying temperature is 40
oc.
Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Adopt the present invention to use the method for laser apparatus cladding muffle painting on ceramic whiteware, what use laser was ceramic muffle painting fires thermal source, muffle painting pattern is that the computer design that laser apparatus connects forms, technique is simple, Production Time is short, energy consumption is little, and matching computer control is applicable to the making of the ceramic glaze illuminated product of single-piece or short run.Production efficiency energy-saving and emission-reduction have again been improved.
Embodiment
Embodiment 1: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware, by add transparent solvent glaze in beramic color, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
Transparent solvent glaze has the raw material of following weight part to be prepared from as 5 parts, 8 parts, 45 parts of clear frits, Suzhou soil, calcite 12wt part, 30 parts of lithium feldspars and quartz, and the proportion of transparent solvent glaze is 1.36 g/cm
3; The ratio weight average of beramic color used for example, higher than the proportion of transparent solvent glaze, peacock blue 1.59 g/cm
3, cobalt black 2.10g/cm
3.
Embodiment 2: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.The first step, crosses respectively 200 mesh sieves by the transparent solvent glaze of pulverizing and beramic color; Getting weight ratio is transparent solvent glaze and the beramic color of 3:2, and mixes; Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds into colour glaze; The 3rd step, is sprayed on ceramic whiteware surface by the good colour glaze of ball milling, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier dry; The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting.
Embodiment 3: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.
The first step, getting beramic color and melt temperature is 1200
othe transparent solvent glaze of C is crossed respectively 200 mesh sieves, and by weight for 3:2, transparent solvent glaze powder and beramic color powder evenly being mixed.
Second step, puts into ball grinder by the powder weighing 20g mixing, and adds 20ml CMC dilute solution and 4ml water, fast after ball milling 30min by color glaze slurry good ball milling after 200 mesh sieves; The hydroxylated cellulose 5g that the preparation method of CMC dilute solution is is C1000 by viscosity model joins in 1000ml water.
The 3rd step, is coated in ceramic whiteware surface by color glaze pulp spraying good ball milling, and colour glaze is sprayed on ceramic whiteware surface thickness between 0.1mm-0.25mm, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier and are dried, and drying temperature is 40
oc.
The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting; Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Embodiment 4: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.Wherein, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.The weight ratio of hydroxylated cellulose and water is 1:200.
Other steps are with embodiment 2.
Embodiment 5: a kind of method that uses laser apparatus cladding muffle painting on ceramic whiteware.
(1), selecting of laser apparatus: should select low-power laser, as 80W CO
2laser engraving machine.
(2), the preparation of colour glaze: colour glaze is made up of transparent solvent glaze and beramic color, ground transparent solvent glaze and beramic color are crossed respectively to 200 mesh sieves, then by weight carrying out proportioning for the ratio of 3:2, be in harmonious proportion with Walocel MT 20.000PV (CMC) aqueous solution and the pure water that prepare again, obtain after mixing liquid is put into the ball milling that ball grinder carries out half hour finally obtaining color glaze slurry after 200 mesh sieves.
(3), glazing: the color glaze slurry preparing is sprayed to existing ceramic whiteware product surface in the mode of spraying, uniform spraying ceramic whiteware sample is put into drying baker and dry, when oven dry, temperature is unsuitable too high, is advisable for 40 DEG C.
(4), draw muffle painting pattern: on the computer that connects laser engraving machine, carrying out the drafting of pattern with mapping software, can be that character and graphic can be also other pattern.
(5), laser processing: the ceramic whiteware goods of the good color glaze of dried coating are placed on the processing platform of laser engraving machine, the machined parameters of laser engraving machine is set to: laser power (30W-80W), sweep velocity (100mm/min-600mm/min), laser spot diameter (1mm-2.5mm).Then just can realize the laser melting coating of ceramic muffle painting on ceramic whiteware according to the drawn figure of computer.
Claims (7)
1. use a method for laser apparatus cladding muffle painting on ceramic whiteware, it is characterized in that concrete grammar is as follows:
The first step, getting weight ratio is transparent solvent glaze and the beramic color of 3:2, transparent solvent glaze and beramic color are ground to form to powder and mix, the proportion of transparent solvent glaze is less than the proportion of beramic color, after dry, form be above transparent solvent glaze, below be the structure of beramic color;
Second step, puts into ball grinder by the powder mixing, and adds CMC dilute solution and water, and fire ball grinds quality glaze slurry, and wherein, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml;
The 3rd step, is coated in ceramic whiteware surface by color glaze pulp spraying good ball milling, and color glaze pulp spraying is coated in ceramic whiteware surface thickness between 0.1mm-0.25mm, and the ceramic whiteware goods that sprayed colour glaze are put in loft drier and are dried, and drying temperature is 40 DEG C;
The 4th step, is placed on dried ceramic whiteware goods on the worktable of laser apparatus, carries out laser melting coating pottery muffle painting, and the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain in-glaze decoration pottery muffle painting.
2. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: in the first step, transparent solvent glaze powder and beramic color powder are crossed respectively to 200 mesh sieves and evenly mixed.
3. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: the melt temperature of transparent solvent glaze is 1200 DEG C.
4. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: the powder weighing 20g mixing is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min, obtains color glaze slurry after 200 mesh sieves fast.
5. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1 or 4, it is characterized in that: the hydroxylated cellulose that the preparation method of CMC dilute solution is is C1000 by viscosity model is added to the water and makes, the weight ratio of hydroxylated cellulose and water is 1:200.
6. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 5, it is characterized in that: the hydroxylated cellulose 5g that is C1000 by viscosity model joins and in 1000ml water, makes CMC dilute solution.
7. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that: laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104961500A (en) * | 2015-06-01 | 2015-10-07 | 重庆大学 | Ceramic glaze decoration method |
CN105799412B (en) * | 2016-03-07 | 2019-05-03 | 温州职业技术学院 | A kind of monochromatic automatic line drawing machine of ceramics |
CN106626849A (en) * | 2016-09-13 | 2017-05-10 | 山东镭泽智能科技有限公司 | Color laser marking method for ceramic |
CN109249140B (en) * | 2018-11-27 | 2021-01-26 | 杜拉维特(中国)洁具有限公司 | Laser marking method |
CN110255907A (en) * | 2019-08-06 | 2019-09-20 | 淄博中升机械有限公司 | A kind of wide bandgap semiconductor nanometer enamel and enamel firing method for reaction kettle |
JP2021187725A (en) * | 2020-06-01 | 2021-12-13 | 洋二 丸谷 | Method for painting on porcelain |
Citations (1)
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CN101372422A (en) * | 2008-10-09 | 2009-02-25 | 傅涛 | In-glaze decoration method for bright red glazed ceramic |
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CN101372422A (en) * | 2008-10-09 | 2009-02-25 | 傅涛 | In-glaze decoration method for bright red glazed ceramic |
Non-Patent Citations (2)
Title |
---|
A New Method for Processing Ceramics with Cracked Glaze;Jiwei Fan.et.al;《Advanced Materials Research》;20121231;第63页最后1段至第64页第2段,第64页倒数第1段、第2段 * |
Jiwei Fan.et.al.A New Method for Processing Ceramics with Cracked Glaze.《Advanced Materials Research》.2012,第63页最后1段至第64页第2段,第64页倒数第1段、第2段. |
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