CN103254686B - High-covering property glass lens ink and preparation method thereof - Google Patents
High-covering property glass lens ink and preparation method thereof Download PDFInfo
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- CN103254686B CN103254686B CN201310154946.9A CN201310154946A CN103254686B CN 103254686 B CN103254686 B CN 103254686B CN 201310154946 A CN201310154946 A CN 201310154946A CN 103254686 B CN103254686 B CN 103254686B
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Abstract
The invention discloses high-covering property glass lens ink and a preparation method thereof. The high-covering property glass lens ink comprises components A and B, wherein the component A comprises the following ingredients in percentage by weight: 60-75% of epoxy resin solution, 0.1-3% of dispersing agent, 1-38.7% of toner, 0.1-5% of defoaming agent and 0.1-6% of filler; the viscosity of the component A is 10000-20000cps at the room temperature of 20 DEG C; and the component B is a curing agent and accounts for 10-20% of the weight of the component A. The two-component high-covering property glass lens ink formed by mixing the component A(the ink) and the component B (the curing agent) is capable of effectively solving the problems existing when conventional glass lens ink is printed on the toughened glass lenses, good in printing effect, easy in achieving high covering and high resistance value properties, excellent in adhesive force to the glass lenses and good in solvent resistance.
Description
Technical field
The present invention relates to ink, relate in particular to a kind of high covering glass eyeglass ink that meets environmental requirement and preparation method thereof.
Background technology
Mobile phone, navigating instrument, LCD TV etc. relate in the industry of chilled glass eyeglass, need to use specific glass mirror ink, when the glass mirror ink of prior art prints on segment glass eyeglass, exist printing effect undesirable, the shortcoming that opacifying power is low, on glass mirror, do not reach the performance of high covering and high resistance, OD(optical density particularly, optical density(OD)) value is lower than 4 time, must improve OD value by increasing the pass of ink printing, but increase the increase that ink printing pass can cause the fraction defective of product, can not meet the requirement of production capacity.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
The technical problem to be solved in the present invention is, above-mentioned defect for prior art, a kind of high covering glass eyeglass ink and preparation method thereof is provided, is intended to solve and when traditional glass eyeglass ink prints on segment glass eyeglass, has the problem that opacifying power is low and resistance value is low.
The technical scheme that technical solution problem of the present invention adopts is as follows:
A high covering glass eyeglass ink, wherein, described high covering glass eyeglass ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Epoxy resin liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
Described B component is solidifying agent, accounts for the 10-20% of component A weight.
Described high covering glass eyeglass ink, wherein, by weight percentage, described component A comprises following component:
Epoxy resin liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Described high covering glass eyeglass ink, wherein, the solids content of described epoxy resin liquid is equal to or greater than 50%.
Described high covering glass eyeglass ink, wherein, described defoamer is silicone antifoam agent.
Described high covering glass eyeglass ink, wherein, described filler is nano-calcium carbonate.
Described high covering glass eyeglass ink, wherein, described toner is the pigment of halogen-containing organic or inorganic not.
Described high covering glass eyeglass ink, wherein, described dispersion agent is amino acid ester copolymer solution.
Described high covering glass eyeglass ink, wherein, described solidifying agent is aliphatic cyclic amine solidifying agent.
A preparation method for described high covering glass eyeglass ink, wherein, comprises step:
Extracting epoxy resin liquid, adds dispersion agent, filler and toner, and stirs with the rotating speed of 600 rpms;
Grinding distribution;
Add defoamer, then with the rotating speed of 1200 rpms, stir.
A kind of high covering glass eyeglass ink provided by the present invention and preparation method thereof, its beneficial effect is: the problem that when effectively having overcome existing glass mirror ink and printing on the segment glass eyeglasses such as chilled glass eyeglass, existing opacifying power is low and resistance value is low.High covering glass eyeglass ink of the present invention meets environmental requirement, and its sticking power on glass mirror is good, has opacifying property height, the feature that resistance value is large, and the patience of each side is all quite excellent.Due to without repeatedly printing and just can reach higher OD value, also improved yield and the working (machining) efficiency of product simultaneously.
Embodiment
A kind of high covering glass eyeglass ink provided by the invention and preparation method thereof, for making object of the present invention, technical scheme and advantage clearer, clear and definite, the present invention is described in more detail by the following examples.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
When being printed on glass mirror, ink there is opacifying property height, resistance value is large, without repeatedly printing the feature of the OD value that just can reach higher, the invention provides a kind of high covering glass eyeglass ink, described high covering glass eyeglass ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Epoxy resin liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
Described B component is solidifying agent, accounts for the 10-20% of component A weight.
Wherein, described component A, according to weight percent meter, is preferably and is composed of the following componentsly:
Epoxy resin liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Preferably, the solids content of described epoxy resin liquid is equal to or greater than 50%.In described epoxy resin liquid, solvent for use is different Fu Er ketone.
Preferably, described defoamer is silicone antifoam agent, and its effect is to reduce the bubble producing in manufacture and use procedure.
Preferably, described dispersion agent is amino acid ester copolymer solution, and its effect is that dispersed those are difficult to be dissolved in the solid particulate of liquid, also can prevent sedimentation and the cohesion of solid particulate simultaneously.
Preferably, described filler is nano-calcium carbonate, and it has extremely excellent printing performance, the sliding sense in excellent surface and anti scuffing performance.Will acting on of filler is the printing performance that increases ink.
Preferably, described toner is the pigment of halogen-containing organic or inorganic not, and described toner, except coloration, also makes ink on glass mirror, have good opacifying power.Also make the performances such as photostabilization, thermotolerance, solvent resistance, resistance to chemical reagents of ink be promoted simultaneously.
Preferably, described solidifying agent is aliphatic cyclic amine solidifying agent, and its effect is solvent resistance and the scratch-resistant performance that improves China ink layer.
Further, in the specific embodiment of the invention, the preparation method of described component A comprises step:
Extracting epoxy resin liquid, adds dispersion agent, filler and toner, and stirs with the rotating speed of 600 rpms;
Grinding distribution;
Add defoamer, then with the rotating speed of 1200 rpms, stir.
By following examples 1-3, the component A of high covering glass eyeglass ink of the present invention is described in further detail.
Embodiment 1:
The component A of a kind of high covering glass eyeglass ink of the present invention, by weight percentage, comprises following component:
Epoxy resin liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Accordingly, its preparation method is:
60.5 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 6 parts of (weight) and 32 parts of toner carbon blacks (weight), the rotating speed stirring at low speed of 600 rpms 15 minutes, after stirring, cross three-roller six times, add again 1 part of (weight) defoamer, then with the rotating speed of 1200 rpms, stir 20 minutes, after being uniformly dispersed, get product.
Embodiment 2:
The component A of a kind of high covering glass eyeglass ink of the present invention, by weight percentage, comprises following component:
Epoxy resin liquid 65;
Dispersion agent 0.5;
Toner 30;
Defoamer 0.5;
Filler 4.
Accordingly, its preparation method is:
65 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 4 parts of (weight) and 30 parts of toner carbon blacks (weight), the rotating speed stirring at low speed of 600 rpms 15 minutes, after stirring, cross three-roller six times, add again 0.5 part of (weight) defoamer, then with the rotating speed of 1200 rpms, stir 20 minutes, after being uniformly dispersed, get product.
Embodiment 3:
The component A of a kind of high covering glass eyeglass ink of the present invention, by weight percentage, comprises following component:
Epoxy resin liquid 65;
Dispersion agent 0.5;
Toner 30;
Defoamer 1;
Filler 4.5.
Accordingly, its preparation method is:
65 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 4.5 parts of (weight) and 30 parts of toner carbon blacks (weight), the rotating speed stirring at low speed of 600 rpms 15 minutes, after stirring, cross three-roller six times, add again 1 part of (weight) defoamer, then with the rotating speed of 1200 rpms, stir 20 minutes, after being uniformly dispersed, get product.
The component A of the described high covering glass eyeglass ink being obtained by above-described embodiment meets environmental requirement, and they are under 20 ℃ of room temperatures, and its viscosity is 10000~30000cps, has opacifying property height, the feature that resistance value is large.
The component A being obtained by the above embodiment of the present invention before printing, adds component B on glass mirror in described component A, and described component B is solidifying agent, and the component B adding accounts for the 10-20% of component A weight.Preferably, the B of component described in embodiment of the present invention solidifying agent is aliphatic cyclic amine solidifying agent, and solid content is absolutely.The effect of described component B solidifying agent is solvent resistance and the scratch-resistant performance that improves China ink layer.
Preferably, the component A of corresponding above-described embodiment 1-3, is described in further detail high covering glass eyeglass ink of the present invention by following examples 4-6.
Embodiment 4:
A described high covering glass eyeglass ink, by the component A of above-described embodiment 1 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 10% of described component A weight.
Embodiment 5:
A described high covering glass eyeglass ink, by the component A of above-described embodiment 2 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 20% of described component A weight.
Embodiment 6:
A described high covering glass eyeglass ink, by the component A of above-described embodiment 3 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 20% of described component A weight.
Corresponding, the concrete preparation method of the high covering glass eyeglass ink described in above-described embodiment 4-6 is: get component A, add component B aliphatic cyclic amine solidifying agent.After mixing, can use.
Respectively the high covering glass eyeglass of the two components ink of above-described embodiment 4-6 gained is printed and brushed one times on glass mirror, its physics and chemistry China ink layer resistance value and OD value are referring to table 1.
Table 1
? | Resistance value (voltage=500 volt time) | OD value |
Embodiment 4 | ≥1GΩ | 4 |
Embodiment 5 | +∞ | 4 |
Embodiment 6 | ≥1GΩ | 4 |
In sum, a kind of high covering glass eyeglass ink that the above embodiment of the present invention provides and preparation method thereof, described high covering glass eyeglass ink comprises component A and B component; By weight percentage, described component A comprises following component: epoxy resin liquid 60-75, dispersion agent 0.1-3, toner 1-38.7, defoamer 0.1-5, filler 0.1-6, and described component A is under 20 ℃ of room temperatures, and its viscosity is 10000~20000cps; Described B component is solidifying agent, accounts for the 10-20% of component A weight.The high covering glass eyeglass of the two components ink being mixed by described component A and B component, its sticking power on glass mirror is good, during 350-420 order printing-ink layer thickness≤6um, OD value >=4; 500v voltage, 1cm distance, resistance value is greater than 1G Ω, and halogen is less than 1000ppm, and has good solvent resistance.And owing to containing appropriate defoamer and filler, make it to there is good printing performance, easily reach high and hide and high resistance performance.Existing problem when effectively having overcome existing glass mirror ink and printing on chilled glass eyeglass, the patience of each side is all quite excellent.Due to without repeatedly printing and just can reach higher OD value, also improved the yield of product simultaneously.
Should be understood that, application of the present invention is not limited to above-mentioned giving an example, and for those of ordinary skills, can be improved according to the above description or convert, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.
Claims (3)
1. a high covering glass eyeglass ink, is characterized in that, described high covering glass eyeglass ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Epoxy resin liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
The solids content of described epoxy resin liquid is equal to or greater than 50%;
Described defoamer is silicone antifoam agent;
Described filler is nano-calcium carbonate;
Described dispersion agent is amino acid ester copolymer solution;
Described toner is the pigment of halogen-containing organic or inorganic not;
Described B component is solidifying agent, accounts for the 10-20% of component A weight;
Described solidifying agent is aliphatic cyclic amine solidifying agent.
2. high covering glass eyeglass ink according to claim 1, is characterized in that, by weight percentage, described component A comprises following component:
Epoxy resin liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
3. a preparation method for high covering glass eyeglass ink as claimed in claim 1, is characterized in that, comprises step:
Extracting epoxy resin liquid, adds dispersion agent, filler and toner, and stirs with the rotating speed of 600 rpms;
Grinding distribution;
Add defoamer, then with the rotating speed of 1200 rpms, stir.
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CN105925067A (en) * | 2016-07-04 | 2016-09-07 | 湖北世安科技有限公司 | Color paste used for preparing whiteboard marker ink and preparation method thereof |
CN106433300A (en) * | 2016-08-31 | 2017-02-22 | 金湖宇迪光学有限责任公司 | Mobile phone cover plate glass black ink formula |
CN106883674B (en) * | 2017-04-21 | 2020-10-30 | 深圳市美丽华油墨涂料有限公司 | Glass lens ink and preparation method thereof |
CN108864812B (en) * | 2018-08-01 | 2021-05-25 | 佛山市高明绿色德化工有限公司 | Laminated glass ink and preparation method thereof |
CN110607093B (en) * | 2019-10-17 | 2022-04-12 | 广东嘉宝莉科技材料有限公司 | Solvent-free glass screen printing ink and preparation method thereof |
CN113354978A (en) * | 2021-06-18 | 2021-09-07 | 重庆京东方电子科技有限公司 | Display device, ink composition and preparation method thereof, cover plate and preparation method thereof |
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CN102719136A (en) * | 2012-05-11 | 2012-10-10 | 佛山市高明绿色德化工有限公司 | Colorful crystal glass printing ink |
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DE10142382A1 (en) * | 2001-08-30 | 2003-03-27 | Clariant Gmbh | Colorant composition and its use for coloring powder coatings |
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CN1471563A (en) * | 2000-08-24 | 2004-01-28 | �̿˹�˾ | Fluorescent inks for writing instruments using fluorescent dyes and white pigments |
CN1480493A (en) * | 2002-08-02 | 2004-03-10 | 大日本印刷株式会社 | Mimeograph ink for correcting tiny coloured pattern defect colour filter, correction method for such defect and mfg. process for mimeographo ink |
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Address after: Shenzhen, Guangdong, Baoan District province Fuyong street, Feng Tong Avenue and Yonghe Road intersection Patentee after: Shenzhen beautiful Polytron Technologies Inc Address before: 518103, Feng Tong Road 243, Fuyong Town, Shenzhen, Guangdong, Baoan District Patentee before: Shenzhen Meilihua Ink & Coating Co., Ltd. |
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