CN103243879A - High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials - Google Patents
High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials Download PDFInfo
- Publication number
- CN103243879A CN103243879A CN 201210032732 CN201210032732A CN103243879A CN 103243879 A CN103243879 A CN 103243879A CN 201210032732 CN201210032732 CN 201210032732 CN 201210032732 A CN201210032732 A CN 201210032732A CN 103243879 A CN103243879 A CN 103243879A
- Authority
- CN
- China
- Prior art keywords
- nano
- heat
- face brick
- exterior wall
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
The invention belongs to the field of building materials, in particular to nano material applications to a building outer wall heat-preservation system, and provides a high-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials. Base coating, floating coating and decorative surface coating are performed on an inorganic light material base heat-preservation layer added with nano particles to form the face brick. By the aid of the nano particles added to a formula of the base heat-preservation layer, compressive strength, tensile strength and bonding strength of the base heat-preservation layer can be improved. A preparation method of the face brick includes evenly mixing the nano materials with the particle diameter at nanoscale, adding the nano materials to a mixed system of concrete, auxiliary solidifying materials, polymer binders, inorganic light heat-preservation materials, fibers and water and forming the mixed system through compression; after a cross-linking process of organic polymer materials and a hydration and drying process of the concrete, performing the base coating, the floating coating and the decorative surface coating on the inorganic light material base heat-preservation layer to form the inorganic heat-preservation decorative face brick. The outer wall heat-preservation brick prepared by the method is excellent in fireproof performance, high in pressure-resistance strength, tension-resistance strength and bonding strength and good in heat-preservation effects; the surface of the brick can be imitation metal, imitation stone and imitation timber; and decoration effects are great.
Description
Technical field
Present technique belongs to building material field, the particularly application of nano material in the building exterior wall heat preserving system.
Background technology
The development energy saving building is the important channel that solves resource, energy problem.Be example with China, in state-owned 44,000,000,000 square metres of existing buildings, energy consumption is generally higher.Architectural energy consumption generally accounts for 30% of the total power consumption of society, adds the consumption of constructional materials manufacturing process, and total accounting that consumes energy then reaches 46% to 47% in society.Wherein, the European countries that the construction unit area heating energy consumption of northern area is more close than weather conditions are high 1.5 to 2 times, because of the building energy consumption height, only the regional annual just many consumption standard coals of northern heating are several hundred million tons, more seriously, in the middle of every year nearly 2,000,000,000 square metres completed floor space, have only five, 60,000,000 square metres to be energy saving building, only account for about 3%, that is to say that 97% belongs to the highly energy-consuming building.According to present building energy consumption level development, to the year two thousand twenty, China's building energy consumption will reach 10.89 hundred million tons of standard coals.Relatively China and foreign countries' building energy consumption difference can be found, it is better that developed country builds the heat insulation effect of common building, at body of wall heat insulation layer efficiently arranged, and heat is difficult for transmitting inside and outside building.In recent years, for the needs of energy-saving and emission-reduction, China has formulated a series of code of building energy efficiency, requires new building must reach energy conservation standard, and externally body of wall must carry out outer insulation processing.External-wall heat-insulation material also must have following a few specific character except requiring outstanding heat insulation effect: 1, be non-inflammable thing, and satisfy the fire-fighting requirement.2, enough intensity is arranged, guarantee to resist the effect of various external force and internal force safely at work progress and building length of life.Application number is 200810052086.7,03140404.9 Deng patent report with the external wall insulation of foaming polymer material preparation, heat insulation effect is good, but because being main thermal insulation material with organic polymer, very easily burning also fails to make its flammability that the change of an essence is arranged even add fire retardant.Two massive losses that big fire causes of the big fire of Beijing CCTV and Jing'an District, Shanghai, it is enough prudent to remind people must have the use of organic external-wall heat-insulation material.Inorganic external-wall heat-insulation material has well solved the easy firing problem of organic external-wall heat-insulation material, most of standards that can reach A level fire protection flame retarding.But the common density of inorganic external-wall heat-insulation material is bigger, the coefficient of thermal conductivity height, and heat-insulating property has to be strengthened.For improving the heat-insulating property of inorganic external-wall heat-insulation material; reduce coefficient of thermal conductivity; usual method is for reducing the apparent density (apparent unit weight) of inorganic external-wall heat-insulation material; added light heat insulation material; be 201110168767.1 as application number; 200710304328.2 adopted foamed concrete or foaming magnesium chloride etc. to be that heat insulating material, other method adopt the low-density heat insulating material etc. patent, as materials such as asbestos, glass bead, haydite, vermiculite, expanded perlites.These material porous thermal conductive coefficients are lower, are the method insulation that 201110027771.6,200610012729.6 grades have taked to add glass bead as application number.But, these material porous, intensity is lower, with present production technology, the external wall insulation/brick intensity of making of these materials is corresponding lower, can not satisfy requirement of engineering, easily produce potential safety hazard again, for improving its intensity, need to add excessive cementitious material and supplementary cementitious material, can increase its coefficient of thermal conductivity widely again.
Summary of the invention
The objective of the invention is: when the substrate insulation layer of preparation exterior-wall heat insulation face brick, add the part nano material at inorganic lightweight material, it is carried out modification, to improve its resistance to compression, cracking resistance, shear strength and adhesive strength, again at substrate insulation layer coatings decoration, to obtain a kind of exterior wall inorganic heat-insulating decorative face brick that contains the high strength of nano material, high thermal insulation and very high decorative effect.
Technical scheme of the present invention is: add the part nano material at inorganic lightweight material during preparation substrate insulation layer, it is carried out modification, to improve its resistance to compression, cracking resistance, shear strength and adhesive strength, again the substrate insulation layer carry out primary coat, in be coated with decorative cover and be coated with, to obtain a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing.
The main preparation technology of exterior wall inorganic heat-insulating decorative face brick substrate insulation layer adds also evenly to mix particle diameter in nano level nano material in the mixed system of cement, supplementary cementitious material, polymer binder, inorganic light weight thermal insulation material, fiber and water, and mixed system is through extrusion forming.The moulding of exterior wall inorganic heat preservation face brick substrate insulation layer by high-molecular organic material cross-linking process and hydrated cementitious dry run the substrate insulation layer of exterior-wall heat insulation face brick.At above-mentioned prescription, for reducing cement consumption, increase workability, add water reducing agent in the preparation.For accelerating cement initial set speed, improve early strength, the reduction of erection time can add an amount of early strength admixture.
The number average bead diameter of nano material should be below 150nm, be preferably in below the 80nm, addition can account for 0.1% to 25% of gross weight, and nano material includes but not limited to one or more mixtures in the following nano material: nano-calcium carbonate calcium powder, nano titanium dioxide powder, nano-silica powder end, nano-bentonite powder, nanometer flyash powder, nano kaoline powder, nano-calcium carbonate magnesium dust, nano oxidized magnesium dust, nano barium sulfate particulate, nanometer bonding agent particulate, nano oxidized iron granules, nano aluminium oxide particulate and nanometer calcium silicates particulate.
At the cement described in the above-mentioned prescription can be but be not limited to a kind of or their two kinds and two or more mixture such as portland cement, sulphate aluminium cement, perhafnate cement, ferrous aluminate cement, white cement.
At the supplementary cementitious material described in the above-mentioned prescription can be but be not limited to agstone, natural volcanic ash, flyash, silicon ash, slag powders and phosphorus slag powder.
Addition at the polymer binder described in the above-mentioned prescription can be between 0.05% to 3%, polymer binder can be but be not limited to polyvinyl alcohol, polyvinyl ester, the modification polyethylene glycol oxide, the polyethylene acid esters, poly-fluorocarbon resin, polystyrene, polyacrylic acid, polyacrylate, polyacrylate, benzene emulsion, HPMA, the poly ester, polyvinyl chloride, ethene/vinyl laurate/vinyl chloride ternary polymerization rubber powder, ethene acetate/ethene bipolymer, starch and oxidized starch, starch ether, carboxylated cellulose, the hydroxylating cellulose, can be they one or more mixture or its connect skill, copolymer.Its form can be resin, can disperse micelle, emulsion, suspension, emulsion or solution.
Should be at 200kg/m in the inorganic light weight thermal insulation material apparent density described in the above-mentioned prescription
3Below, can be but be not limited to glass bead that hollow haydite, expanded vermiculite, expanded perlite, Hollow Glass Sphere can be their two or more mixtures.
Be preferably in below the 0.1mm at the fibre diameter described in the above-mentioned prescription, length is preferably in below the 70mm, can be but be not limited to organic synthesis macromolecular fibre such as nylon fiber, polypropylene fibre, polyester fiber, propionitrile fiber, Fypro, polycarbonate and natural polymer subbundle such as paper pulp fiber, wood pulp cellulose, tangerine rod fibers, viscose rayon, flaxen fiber, protein fibre and cutin fiber.Can be single fiber, also can be the mixture of two or more fiber.
The consumption of water reducing agent is less than 1%, can be but be not limited to high-efficiency water-reducing agent of poly-carboxylic acid, sodium lignin sulfonate, benzene sulfonate formaldehyde condensation products, polycyclic aromatic hydrocarbon sulfonate formaldehyde condensation products, melamine sulfonate and formaldehyde condensation polymer, sulfonated polystyrene, maleic acid sulfonate polyoxyethylene ester, polyalcohol sulfonate and oxirane and epoxy propane copolymer, alpha-sulfonated fatty acid polyoxyethylene ester etc., also can be the mixture of two or more water reducing agent.
Early strength admixture is used for shortening the initial setting time, improve early strength, can be but be not limited to calcium chloride, sodium chloride, potassium chloride, aluminium chloride, sodium formate, natrium nitrosum, sodium carbonate, gypsum, can be early strength water-reducing agent, also can be the mixture of two or more early strength admixture.
Be the high strength that fixedly contains nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick, can reserve two or more anchor holes at brick, in order to before bonding material works that exterior wall inorganic heat preservation face brick is fixing on the wall in work progress.
For strengthening the high strength of nano material, the waterproof moisture-proof effect of high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing of the present invention, can coat waterproof coating at the external surface of brick.Waterproof coating uses and includes but not limited to waterproofing agent of organosilicon.
Use the present invention, not only can prepare high strength, high thermal insulation contains the high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick, can also make inorganic heat preservation panel, inorganic exterior-wall heat insulation mortar.
Below be to represent that to the testing result of embodiment 1 and with diagram detection method is reference standard method GB/T 5486, JGJ 144, JG 149 and GB/T 10294 respectively.
Fig. 1 is the raising along with the nanoparticle addition, the variation of exterior wall inorganic heat preservation face brick substrate insulation layer compressive strength.In exterior wall inorganic heat preservation face brick substrate insulation layer, by embodiment 1 formulation (but not adding nanoparticle), compressive strength is 0.171MPa, and when improving the percentage by weight of nano-calcium carbonate particles gradually, exterior wall inorganic heat preservation face brick substrate insulation layer compressive strength increases substantially.
Fig. 2 is the raising along with the nanoparticle addition, the change of exterior wall inorganic heat preservation face brick substrate insulation layer tensile strength.In exterior wall inorganic heat preservation face brick substrate insulation layer, by embodiment 1 formulation (but not adding nanoparticle), tensile strength is 0.171MPa, and when improving the percentage by weight of nano-calcium carbonate particles gradually, exterior wall inorganic heat preservation face brick substrate insulation layer tensile strength increases substantially.
Fig. 3 is the raising along with the nanoparticle addition, the change (MPa) of the tensile bond strength between exterior wall inorganic heat preservation face brick substrate insulation layer and the cement mortar, (the destruction face is on the foam cement plate).In exterior wall inorganic heat preservation face brick substrate insulation layer, by embodiment 1 formulation (but not adding nanoparticle), tensile strength is 0.153MPa, and when improving the percentage by weight of nano-calcium carbonate particles gradually, exterior wall inorganic heat preservation face brick substrate insulation layer tensile bond strength increases substantially.
Fig. 4 is the raising along with the nanoparticle addition, and the variation of exterior wall inorganic heat preservation face brick substrate insulation layer coefficient of thermal conductivity is as seen, along with the increase of nanoparticle, very little to the influence of coefficient of thermal conductivity.
To embodiment 2,3,4 testing result shows that along with the increase of nanoparticle, variation tendency and the embodiment 1 of exterior wall inorganic heat preservation face brick substrate insulation layer compressive strength, tensile strength, adhesive strength and the coefficient of thermal conductivity of obtaining are in full accord.
The present invention's beneficial effect compared with the prior art is that the present invention adds nanoparticle to increase the uniformity of material, reduces the generation in crack, improves its mechanical strength.This is the hole in both shutoff cement mortar or the concrete because nanoparticle and polymer cooperatively interact, and reduces the generation of water evaporates speed and quantity inhibition microfissure by passage.Simultaneously, because nanoparticle is very little, good flowability is arranged, nanoparticle can infiltrate between the microcrack and exist, even also can permeate nanoparticle between the flat crystal of calcium hydroxide.Because of the relative sliding of nanoparticle, need add and contain nanoparticle polymer film modulus of elasticity and become lower, can improve tensile strength and fracture toughness.Simultaneously, along with hydrated cementitious absorbs moisture, the polymer after the dehydration is gathered into the continuous net structure of three dimensions gradually with nanoparticle under alkali condition, and the kind net structure penetrates mutually hands over knot to be intertwined, and forms the basal body structure of densification continuously.This nanoparticle polymeric web membrane structure is passed pore, the crack in the external-wall heat-insulation material, by the connection of shuttling back and forth, forms a rubber-like spacial framework, has disperseed stress, has increased deformability.Even under the stress effect, produce the crack, because the polymer of having filled nanoparticle strides across the crackle connection of shuttling back and forth, can suppress the development of crackle, improved fracture toughness, deformability and the crack resistance of hardenite.In addition, between nanoparticle and hydrated cementitious product, may exist the interaction of hydrogen bond, Van der Waals force, because of the nanoparticle particle diameter little, surface area is huge, and special quantum effect is arranged, some active group in the nanoparticle also may with hydrated cementitious product generation chemical action, form special bridged bond effect, improve the structure of hydrated cementitious product, alleviate internal stress, thereby reduce the generation of micro-crack in the cement slurry.This structure is not only absorption, the bonding of physics, and exists the chemical action that exists with the chemical bond form.Thereby the hardened paste structure is produced favorable influence.
In addition, can prepare patterns such as imitative metal, imitative stone material, imitative timber at the external surface of face brick with coating, have the excellent decoration effect.
Description of drawings
Fig. 1 is the raising along with the nanoparticle addition, exterior wall inorganic heat preservation face brick substrate insulation layer compressive strength variation diagram.Abscissa is the percentage by weight (%) that nanoparticle accounts for whole exterior wall inorganic heat preservation face brick substrate insulation layer, and ordinate is its compressive strength (MPa).
Fig. 2 is the raising along with the nanoparticle addition, the variation diagram of exterior wall inorganic heat preservation face brick substrate insulation layer compressive strength.Abscissa is the percentage by weight (%) that nanoparticle accounts for whole exterior wall inorganic heat preservation face brick substrate insulation layer, and ordinate is its tensile strength (MPa).
Fig. 3 is the raising along with the nanoparticle addition, the variation (MPa) of exterior wall inorganic heat preservation face brick substrate insulation layer and cement mortar tensile bond strength.(the destruction face is on exterior wall inorganic heat preservation face brick substrate insulation layer).Abscissa is the percentage by weight (%) that nanoparticle accounts for whole exterior wall inorganic heat preservation face brick substrate insulation layer, and ordinate is its stretch-proof adhesion strength (MPa).
Fig. 4 is the raising along with the nanoparticle addition, the variation diagram of exterior wall inorganic heat preservation face brick substrate insulation layer coefficient of thermal conductivity.Abscissa is the percentage by weight (%) that nanoparticle accounts for whole exterior wall inorganic heat preservation face brick substrate insulation layer, and ordinate is its coefficient of thermal conductivity W/ (m*K).
The specific embodiment
Embodiment 1; Portland cement 1000 grams, flyash 400 grams, polymer binder 50 grams; inorganic light weight thermal insulation material glass bead 1300 grams; polypropylene fibre 3 grams, modified plant fibers 3 grams, maleic acid sulfonate polyoxyethylene ester 1.5 grams; salt solution is an amount of; add and evenly mix particle diameter restraining at the nano-calcium carbonate 70 of 60 nanometers in mixed system, mixed system will be reserved anchor hole through extrusion forming in pressing process.After the moulding of substrate insulation layer, through high-molecular organic material cross-linking process and hydrated cementitious dry run, substrate insulation layer intensity is increased to predetermined value gradually, carries out application, produces imitative metal, imitates stone material, imitates the timber decorative effect with coating on the substrate insulation layer again.Can coat the organic silicon water-proofing coating at the external surface of brick.
Embodiment 3, white cement 950 grams, phosphorus slag powder 500 grams, polymer binder 50 grams, inorganic light weight thermal insulation material perlite 1250 grams, polyester fiber 3 grams, azelon 3 grams, polycyclic aromatic hydrocarbon sulfonate formaldehyde condensation products 2 grams, water is an amount of, add in the mixed system and evenly mix the maximum distribution particle diameter about 70 nanometers nano silicon dioxide particles 70 grams, mixed system will be reserved anchor hole through extrusion forming in pressing process.After the moulding of substrate insulation layer, through high-molecular organic material cross-linking process and hydrated cementitious dry run, substrate insulation layer intensity is increased to predetermined value gradually, carries out application, produces imitative metal, imitates stone material, imitates the timber decorative effect with coating on the substrate insulation layer again.Can coat the organic silicon water-proofing coating at the external surface of brick.
Embodiment 4; perhafnate cement 1000 grams, flyash 400 grams, polymer binder 50 grams; inorganic light weight thermal insulation material vermiculite and glass bead be totally 1300 grams; polycarbonate 2 grams, paper pulp fiber 3 grams, melamine sulfonate and formaldehyde condensation polymer 2.5 grams; water is an amount of; add in the mixed system and evenly mix particle diameter 40 nanometers nano-sized iron oxide 70 grams, mixed system will be reserved anchor hole through extrusion forming in pressing process.After the moulding of substrate insulation layer, through high-molecular organic material cross-linking process and hydrated cementitious dry run, substrate insulation layer intensity is increased to predetermined value gradually, carries out application, produces imitative metal, imitates stone material, imitates the timber decorative effect with coating on the substrate insulation layer again.Can coat the organic silicon water-proofing coating at the external surface of brick.
Claims (12)
1. one kind contains the high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick, it is characterized in that the inorganic lightweight material substrate insulation layer that has added nano particle carry out primary coat, in be coated with decorative cover and be coated with.
2. according to a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing of claim 1, it is characterized in that its substrate insulation layer by adding in the mixed system of cement, supplementary cementitious material, polymer binder, inorganic light weight thermal insulation material, fiber and water and evenly mixing particle diameter in nano level nano material, mixed system is through extrusion forming.Forming materials by high-molecular organic material cross-linking process and hydrated cementitious dry run reach the substrate insulation layer.
3. a kind of high strength that contains nano material according to claim 2, high adiabatic exterior wall inorganic heat-insulating decorative face brick, the number average bead diameter that it is characterized in that the nano material of adding should be below 150nm, addition can account for 0.1% to 25% of gross weight, and nano material includes but not limited to following nano material or its mixture: the nano-calcium carbonate calcium powder, nano titanium dioxide powder, the nano-silica powder end, the nano-bentonite powder, the nanometer flyash powder, the nano kaoline powder, the nano-calcium carbonate magnesium dust, nano oxidized magnesium dust, the nano barium sulfate particulate, nanometer bonding agent particulate, nano oxidized iron granules, nano aluminium oxide particulate and nanometer calcium silicates particulate.
4. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2 is characterized in that described cement can be but is not limited to a kind of or their two kinds and two or more mixture such as portland cement, sulphate aluminium cement, perhafnate cement, ferrous aluminate cement, white cement.
5. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2 is characterized in that described supplementary cementitious material can be but is not limited to agstone, natural volcanic ash, flyash, silicon ash, slag powders and phosphorus slag powder.
6. a kind of high strength that contains nano material according to claim 2, high adiabatic exterior wall inorganic heat-insulating decorative face brick, the addition that it is characterized in that described polymer binder can be between 0.05% to 5%, polymer binder can be but be not limited to polyvinyl alcohol, polyvinyl ester, the modification polyethylene glycol oxide, the polyethylene acid esters, poly-fluorocarbon resin, polystyrene, polyacrylic acid, polyacrylate, polyacrylate, benzene emulsion, HPMA, the poly ester, polyvinyl chloride, ethene/vinyl laurate/vinyl chloride ternary polymerization rubber powder, ethene acetate/ethene bipolymer, starch and oxidized starch, starch ether, carboxylated cellulose, the hydroxylating cellulose, can be they one or more mixture or its connect skill, copolymer.Its form can be resin, can disperse micelle, emulsion, suspension, emulsion or solution.
7. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2, the inorganic light weight thermal insulation material apparent density described in it is characterized in that filling a prescription is at 200kg/m
3Below, can be but be not limited to glass bead that hollow haydite, expanded vermiculite, expanded perlite, Hollow Glass Sphere can be their two or more mixtures.
8. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2, fibre diameter described in it is characterized in that filling a prescription is preferably in below the 0.1mm, length is preferably in below the 70mm, can be but be not limited to organic synthesis macromolecular fibre such as nylon fiber, polypropylene fibre, polyester fiber, propionitrile fiber, Fypro, polycarbonate and natural polymer subbundle such as paper pulp fiber, wood pulp cellulose, tangerine rod fibers, viscose rayon, flaxen fiber, protein fibre and cutin fiber.Can be single fiber, also can be the mixture of two or more fiber.
9. a kind of high strength that contains nano material according to claim 2, high adiabatic exterior wall inorganic heat-insulating decorative face brick, the consumption of the water reducing agent described in it is characterized in that filling a prescription is less than 1%, can be but be not limited to high-efficiency water-reducing agent of poly-carboxylic acid, sodium lignin sulfonate, the benzene sulfonate formaldehyde condensation products, the polycyclic aromatic hydrocarbon sulfonate formaldehyde condensation products, the melamine sulfonate and formaldehyde condensation polymer, sulfonated polystyrene, maleic acid sulfonate polyoxyethylene ester, polyalcohol sulfonate and oxirane and epoxy propane copolymer, alpha-sulfonated fatty acid polyoxyethylene ester etc. also can be the mixtures of two or more water reducing agent.
10. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2, early strength admixture described in it is characterized in that filling a prescription is used for shortening the initial setting time, improve early strength, can be but be not limited to calcium chloride, sodium chloride, potassium chloride, aluminium chloride, sodium formate, natrium nitrosum, sodium carbonate, the plaster of paris, can be early strength water-reducing agent, also can be the mixture of two or more early strength admixture.
11. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2 is characterized in that the external surface of brick is coated waterproof coating.Waterproof coating uses and includes but not limited to waterproofing agent of organosilicon.
12. a kind of high strength of nano material, high adiabatic exterior wall inorganic heat-insulating decorative face brick of containing according to claim 2 is characterized in that the external coating of brick includes but not limited to common coating, imitative metal, imitative stone material, imitative timber, imitative husky coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210032732 CN103243879A (en) | 2012-02-09 | 2012-02-09 | High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210032732 CN103243879A (en) | 2012-02-09 | 2012-02-09 | High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103243879A true CN103243879A (en) | 2013-08-14 |
Family
ID=48923727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210032732 Pending CN103243879A (en) | 2012-02-09 | 2012-02-09 | High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103243879A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478381A (en) * | 2014-11-19 | 2015-04-01 | 北新集团建材股份有限公司 | Heat-preservation fire-resistant paper-surface gypsum board and preparation method thereof |
| CN104609815A (en) * | 2014-12-31 | 2015-05-13 | 东莞市高能磁电技术有限公司 | Method for preparing porous baking-free product from solid waste and product |
| CN105421696A (en) * | 2015-11-05 | 2016-03-23 | 湖南卓一高科技股份有限公司 | Method for manufacturing external wall insulation and decoration integrated board |
| CN107199620A (en) * | 2016-03-16 | 2017-09-26 | 上海悦心健康集团股份有限公司 | A kind of distribution device of Ultramicro-powder vitreous stone base brick |
| CN107555887A (en) * | 2016-07-01 | 2018-01-09 | 白法平 | A kind of inorganic heat insulation mortar for adding nanometer Mg powder |
| CN107572891A (en) * | 2017-08-29 | 2018-01-12 | 无为县鑫品石业有限公司 | One kind synthesis toughness marble and its manufacture method |
| CN107578920A (en) * | 2017-08-31 | 2018-01-12 | 安徽智博新材料科技有限公司 | A kind of explosion-proof AC capacitor |
| CN108017348A (en) * | 2017-12-12 | 2018-05-11 | 大连理创科技有限公司 | A kind of preparation process of lightweight decorating material |
| CN108424040A (en) * | 2018-05-19 | 2018-08-21 | 童彬原 | Diatom waterproof hollow glass microbead heat-insulation system |
| CN108640622A (en) * | 2018-05-21 | 2018-10-12 | 侯伟旗 | A kind of insulating water-proof fire resistant doorsets |
| CN114477910A (en) * | 2022-02-22 | 2022-05-13 | 泰州市明新建设工程有限公司 | Artificial stone-like face brick and preparation method thereof |
-
2012
- 2012-02-09 CN CN 201210032732 patent/CN103243879A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478381A (en) * | 2014-11-19 | 2015-04-01 | 北新集团建材股份有限公司 | Heat-preservation fire-resistant paper-surface gypsum board and preparation method thereof |
| CN104609815A (en) * | 2014-12-31 | 2015-05-13 | 东莞市高能磁电技术有限公司 | Method for preparing porous baking-free product from solid waste and product |
| CN105421696A (en) * | 2015-11-05 | 2016-03-23 | 湖南卓一高科技股份有限公司 | Method for manufacturing external wall insulation and decoration integrated board |
| CN105421696B (en) * | 2015-11-05 | 2018-07-10 | 湖南卓一高科技股份有限公司 | A kind of method for making heat-insulation/decoration integrated plate |
| CN107199620A (en) * | 2016-03-16 | 2017-09-26 | 上海悦心健康集团股份有限公司 | A kind of distribution device of Ultramicro-powder vitreous stone base brick |
| CN107555887A (en) * | 2016-07-01 | 2018-01-09 | 白法平 | A kind of inorganic heat insulation mortar for adding nanometer Mg powder |
| CN107572891A (en) * | 2017-08-29 | 2018-01-12 | 无为县鑫品石业有限公司 | One kind synthesis toughness marble and its manufacture method |
| CN107578920A (en) * | 2017-08-31 | 2018-01-12 | 安徽智博新材料科技有限公司 | A kind of explosion-proof AC capacitor |
| CN108017348A (en) * | 2017-12-12 | 2018-05-11 | 大连理创科技有限公司 | A kind of preparation process of lightweight decorating material |
| CN108424040A (en) * | 2018-05-19 | 2018-08-21 | 童彬原 | Diatom waterproof hollow glass microbead heat-insulation system |
| CN108640622A (en) * | 2018-05-21 | 2018-10-12 | 侯伟旗 | A kind of insulating water-proof fire resistant doorsets |
| CN114477910A (en) * | 2022-02-22 | 2022-05-13 | 泰州市明新建设工程有限公司 | Artificial stone-like face brick and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103193420A (en) | Nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick | |
| CN103243878A (en) | High-strength, high-insulation exterior wall heat-preservation face brick compounded by aluminum plastic and nanometer materials | |
| CN103243879A (en) | High-strength high-heat-insulation inorganic heat-preservation decorative external wall face brick containing nano materials | |
| RU2662741C2 (en) | Insulating mortar composition | |
| CN100345791C (en) | Heat insulating glue powder material for wall and its prepn and usage | |
| CN101628802B (en) | Composite inorganic heat insulation and waterproof mortar and application thereof | |
| CN102503333B (en) | Siliceous heat-insulation composite material for wall | |
| CN101245613B (en) | Light mortar inside and outside combined exterior wall heat-preserving system | |
| CN110054461B (en) | Environment-friendly anti-cracking high-weather-resistance external thermal insulation plastering mortar and preparation method thereof | |
| CN102659354B (en) | A-grade non-ignitable heat insulating material and preparation method thereof | |
| CN101891440B (en) | Special finish coat mortar with desulfurized gypsum as base material for wall insulation system | |
| CN101913803A (en) | Mortar special for gas concrete building block and application thereof in wall self heat preservation system | |
| CN1939866A (en) | Mortar partner and its use | |
| CN101691800B (en) | General insulation composite material for exterior wall and application method | |
| CN105084833A (en) | High-strength thermal insulation full lightweight concrete and preparation method and application thereof | |
| CN107266114A (en) | A kind of aerogel heat-insulating masonry mortar and preparation method thereof | |
| CN105863083B (en) | A kind of inorganic heat insulation wall | |
| CN102976678B (en) | Partition board material | |
| CN107216105A (en) | A kind of lightweight water-resistant gypsum board and preparation method thereof | |
| CN103880376A (en) | Light-weight inorganic fireproof thermal-insulation board | |
| CN102976693B (en) | Outer-wall external thermal-insulation anti-crack mortar prepared from superfine sand | |
| CN100462323C (en) | Light aggregate concrete mould wall body construction material and its production technology | |
| CN111825414A (en) | High-temperature-resistant green multi-layer fireproof plate and manufacturing method thereof | |
| CN104446622A (en) | Foam concrete with high waterproofness and preparation method thereof | |
| CN101456712A (en) | Inorganic mineral earth surface insulating mortar |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| DD01 | Delivery of document by public notice |
Addressee: Pinghu City Faerte Building Thermal Insulation Science & Technology Co., Ltd. Document name: Notification of Publication of the Application for Invention |
|
| DD01 | Delivery of document by public notice |
Addressee: Pinghu City Faerte Building Thermal Insulation Science & Technology Co., Ltd. Document name: Notification of before Expiration of Request of Examination as to Substance |
|
| DD01 | Delivery of document by public notice |
Addressee: Pinghu City Faerte Building Thermal Insulation Science & Technology Co., Ltd. Document name: Notification that Application Deemed to be Withdrawn |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130814 |