CN103242729B - A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint and preparation method thereof - Google Patents
A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint and preparation method thereof Download PDFInfo
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- CN103242729B CN103242729B CN201310215328.0A CN201310215328A CN103242729B CN 103242729 B CN103242729 B CN 103242729B CN 201310215328 A CN201310215328 A CN 201310215328A CN 103242729 B CN103242729 B CN 103242729B
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Abstract
The invention discloses a kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, mosquito-proof essential oil 5 parts, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part; Described wall paint also comprises by dispersion agent, lubricant, the auxiliary material part of biological preservative composition, described auxiliary material subtotalled 20 parts; The TVOC value of described mosquito proof Water-soluble environment-friendlyanticorrosive preservative property wall paint is 0g/l, and burst size of methanal is 0g/l.Wall paint of the present invention is nonpoisonous and tasteless not containing conventional toxic chemical organic solvent, does not add poisonous wall paint sanitas, is conducive to environmental requirement.
Description
Technical field
The present invention relates to a kind of wall paint, relate to a kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint and preparation method thereof specifically, belong to chemical industry wall paint technical field.
Background technology
House fitting pollution refers to the pollution and a large amount of chemical used such as sterilant, reodorant, perfume compound that in fitment process, various buildings material and finishing material discharge, to the pollution that indoor environment causes.People have accounted for 80 ~ 90% of whole day in the time of indoor study, work and life; " room air pollution " is paid attention to by increasing people; and wall paint to pollute be the arch-criminal of indoor environmental pollution, be coated on body surface and other materials and bind very well and the material forming whole and tough and tensile protective membrane is called wall paint.Identical concept at architectural wall paint and paint.Wall paint in the market is mainly divided into waterborne wall surface paint and solvent-borne type wall paint.50 gas chromatographies such as a large amount of benzene, toluene, ethylbenzene, dimethylbenzene, acetone, N-BUTYL ACETATE, acetaldehyde, butanols, formic acid can be detected in the space air of just brushing wall paint, produce organic solvent volatile matter (voc) contaminate environment.Above-mentioned organic volatile contained by traditional solvent-borne type wall paint can damage respiratory system, hematopoietic function, the immunity system of people, even causes the disease of the aspects such as some heredity.
Due to the attention to environmental protection and house health, waterborne wall surface paint progressively instead of traditional solvent-borne wall paint, and because the technology content of waterborne wall surface paint is higher, most domestic manufacturers production difficulty is comparatively large, and solvent borne wall paint is still propagated its belief on a large scale, and accounts for absolute main flow.Before gac has powerful adsorption function, people are placed on certain position formaldehyde adsorption charcoal bag, but are limited in scope after all, just can not adsorb, become source of pollution after saturated, how to be the Main way of research at present fast and effectively by regeneration of activated carbon.
Summary of the invention
The object of the invention is to overcome above-mentioned the deficiencies in the prior art, a kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint and preparation method thereof is provided, this mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint is nonpoisonous and tasteless not containing conventional toxic chemical organic solvent, do not add poisonous wall paint sanitas, be conducive to environmental requirement, meanwhile, effectively mosquito can also be prevented.
Mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint of the present invention realizes with following technical scheme:
A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, mosquito-proof essential oil 5 parts, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part; Described wall paint also comprises by dispersion agent, lubricant, the auxiliary material part of biological preservative composition, described auxiliary material subtotalled 20 parts; The TVOC value of described mosquito proof Water-soluble environment-friendlyanticorrosive preservative property wall paint is 0 g/l., and burst size of methanal is 0 g/l.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, described dispersion agent is: paraffin and Calcium hydrogen carbonate mixture, and the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, described lubricant is oleum lini.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, described mosquito-proof essential oil is Oil of Eucalyptus, eucalyptus globolus tree oil, Herba Lysimachiae foenumgraeci quintessence oil, Peppermint essential oil, oil of Cymbopogon winterianus and lemon quintessence oil with etc. mass mixing form.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, is characterized in that, described mosquito-proof essential oil is Oil of Eucalyptus, eucalyptus globolus tree oil, Peppermint essential oil, oil of Cymbopogon winterianus are that 1:1:2:1 is formulated by volume.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, is characterized in that, described biological preservative is selected from as the one in volatile oil and person's tea-polyphenol or its combination.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, is characterized in that, in volatile oil and tea-polyphenol combination, the volume ratio of volatile oil and tea-polyphenol is 5:3.
As preferably, described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, is characterized in that, working concentration be 5% the sodium bicarbonate water wiping metope that scribbles this wall paint can make wherein active carbon nanoparticles regeneration.
As preferably, the preparation method of described aqueous environment protection active carbon nanoparticles wall paint, is characterized in that, comprise the steps:
(1) following component is taken according to mass fraction: composed of the following components in its feedstock portions of mass fraction formula: water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, mosquito-proof essential oil 5 parts, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part of Homogeneous phase mixing, obtains composition of raw materials mixture, adds deionized water 20 parts in composition of raw materials mixture, use agitator stirs, agitator speed is 20 revs/min, and stirring at normal temperature 30 minutes, obtains feedstock portions mixing solutions;
(2) in the above-mentioned feedstock portions aqueous solution, add dispersion agent, lubricant, anti-settling agent, biological preservative, adjustment rotating speed is 150 revs/min, and stirring at normal temperature 60 minutes regulates ph value to be 7 simultaneously, obtains crude product mixed solution;
(3) above-mentioned crude product mixed solution normal temperature is ground to without particle, obtains aqueous environment protection anti-corrosive type wall paint.
Below in conjunction with embodiment, the present invention will be further described:
embodiment:
Embodiment 1
The preparation of 1.1 mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paintes
A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, Oil of Eucalyptus 1 part, eucalyptus globolus tree oil 1 part, Peppermint essential oil 2 parts, oil of Cymbopogon winterianus 1 part, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part; Described wall paint also comprises: 6 parts of paraffin and Calcium hydrogen carbonate mixture, and the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1,6 portions of oleum lini, the auxiliary material part of 8 parts of volatile oil compositions.
The preparation method of described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, is characterized in that, comprise the steps:
(1) composed of the following components in its feedstock portions of mass fraction formula: water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, Oil of Eucalyptus 1 part, eucalyptus globolus tree oil 1 part, Peppermint essential oil 2 parts, oil of Cymbopogon winterianus 1 part, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part obtains composition of raw materials mixture, deionized water 20 parts is added in composition of raw materials mixture, use agitator stirs, agitator speed is 20 revs/min, stirring at normal temperature 30 minutes, obtain feedstock portions mixing solutions,
(2) in the above-mentioned feedstock portions aqueous solution, add 6 parts of paraffin and Calcium hydrogen carbonate mixture, the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1,6 portions of oleum lini, 8 parts of volatile oil, adjustment rotating speed is 150 revs/min, stirring at normal temperature 60 minutes, regulate ph value to be 7.5 simultaneously, obtain crude product mixed solution;
(3) above-mentioned crude product mixed solution normal temperature is ground to without particle, obtains mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint.
1.2 measure total volatile organic compound (TVOC) of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint and the content of free formaldehyde
1.2.1 reference standard mixing solutions is prepared: comprise diethylene glycol monobutyl ether, butyl carbitol acetate, butanols, butyl acrylate, 2-ethylhexyl acrylate, vinylbenzene, vinyl acetate;
Above-mentioned reference material will wait quality to take, and often kind claims 1 g, accurately true to 0.001 mg, is placed in the bottle that barrier film is airtight, using PH be the citrate buffer solution 1L of 5 as solvent, obtain reference standard mixing solutions.
1.2.2 Gas chromatography detects
With reference standard mixing solutions for benchmark, aqueous environment protection anti-corrosive type wall paint 1:1000 embodiment 1 prepared dilutes, and carries out stratographic analysis.
1.2.3 measurement result
| Mensuration project | National standard | Aqueous environment protection anti-corrosive type wall paint prepared by embodiment 1 |
| TVOC g/l. | ≤200 | 0 |
| Free formaldehyde g/l | ≤0.1 | 0 |
The preservative effect of the described wall paint of 1.3 mensuration
| Test event | Mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint prepared by embodiment 1 | National standard | Testing method |
| Immersion | Meet national standard | Without wrinkling, bubble, loses sticking power and other considerable changes | Boiling water boiling 8 hours |
| Humidity resistance | Meet national standard | Corrosion-free after 30 days, bubble, wrinkling or lose sticking power | 49±1℃，RH＞95 |
| Salt spray resistance | Meet national standard | Corrosion-free after 30 days, bubble, wrinkling or lose sticking power | Continuous spraying 35 ± 1 DEG C, 5%NACL |
| Sticking power | Meet national standard | Without having stung and flaking | Chiastron interior extrapolation |
The adsorptive power of the described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint of 1.4 mensuration and regeneration of activated carbon ability thereof
The internal surface of the sealing detection room of 1 ㎡ is brushed mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint prepared by embodiment 1, pass into the gas that TVOC concentration is 30mg/m3 wherein, use VOC PRO total volatile organism TVOC detector to detect simultaneously, after 60min, the TVOC of sealing detection indoor maintains 3mg/m3 and no longer changes, and namely active carbon nanoparticles absorption is saturated.
Working concentration be 5% the wiping of sodium bicarbonate water scribble the metope of this wall paint after, dry, repeat above-mentioned adsorption test, the TVOC value step-down over time of sealing detection indoor, as can be seen here, working concentration be 5% the sodium bicarbonate water wiping metope that scribbles this wall paint active carbon nanoparticles can be made to regenerate.
The mosquito-proof effect experimental of the described mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint of 1.5 mensuration
The house of same structure under same environment, one of them sprays wall paint of the present invention, another one is not coated with, each house medially on place the suds that a basin fills with flowery odour, suds are all around around placement 8 mosquito sticking papers, the number of the number of mosquito on larvae and mosquito sticking paper in suds is observed respectively after 7 days, wherein, the house spraying wall paint of the present invention does not have larvae, mosquito sticking paper do not have mosquito yet, what another did not spray then has 42 larvaes, mosquito sticking paper has 21 mosquitoes, illustrate that wall paint of the present invention has good mosquito-proof effect.
Embodiment 2
A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, eucalyptus globolus tree oil 1 part, Herba Lysimachiae foenumgraeci quintessence oil 1 part, Peppermint essential oil 1 part, oil of Cymbopogon winterianus 1 part and lemon quintessence oil 1 part, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part, 6 parts of paraffin and Calcium hydrogen carbonate mixture, the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1, 6 portions of oleum lini, the auxiliary material part of 8 parts of tea-polyphenol compositions.
Embodiment 3
A kind of mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, eucalyptus globolus tree oil 1 part, Oil of Eucalyptus 1 part, Peppermint essential oil 1 part, oil of Cymbopogon winterianus 1 part and lemon quintessence oil 1 part, propylene glycol, 0.3 part, kaolin 0.3 part, talcum powder 0.4 part, 6 parts of paraffin and Calcium hydrogen carbonate mixture, the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1, 6 portions of oleum lini, 8 parts of volatile oil and tea polyphenol composition, wherein the volume ratio of volatile oil and tea-polyphenol is the auxiliary material part of 5:3 composition.
The above; only to preferred embodiment of the present invention; not other forms of restriction is done to the present invention; any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the Equivalent embodiments of equal change; every disengaging the present invention program content; according to technical spirit of the present invention to any simple modification made for any of the above embodiments, equivalent variations and remodeling, all drop in protection scope of the present invention.
Claims (7)
1. a mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint, it is characterized in that, composed of the following components in its feedstock portions of mass fraction formula: deionized water 20 parts, water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, mosquito-proof essential oil 5 parts, propylene glycol 0.3 part, kaolin 0.3 part, talcum powder 0.4 part; Described wall paint also comprises by dispersion agent, lubricant, the auxiliary material part of biological preservative composition, described auxiliary material subtotalled 20 parts; The TVOC value of described mosquito proof Water-soluble environment-friendlyanticorrosive preservative property wall paint is 0 g/L, and burst size of methanal is 0 g/L; Described mosquito-proof essential oil is that Oil of Eucalyptus, eucalyptus globolus tree oil, Peppermint essential oil, oil of Cymbopogon winterianus are by volume for 1:1:2:1 is formulated.
2. mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint according to claim 1, it is characterized in that, described dispersion agent is: paraffin and Calcium hydrogen carbonate mixture, and the mass ratio of paraffin and Calcium hydrogen carbonate is 8:1.
3. mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint according to claim 1, it is characterized in that, described lubricant is oleum lini.
4. mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint according to claim 1, is characterized in that, described biological preservative is selected from as the one in volatile oil and tea-polyphenol or its combination.
5. mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint according to claim 4, is characterized in that, during volatile oil and tea-polyphenol combine, the volume ratio of volatile oil and tea-polyphenol is 5:3.
6. the mosquito proof Water-soluble environment-friendlyanticorrosive active carbon nanoparticles wall paint according to any one of claim 1-5, is characterized in that, working concentration be 5% the sodium bicarbonate water wiping metope that scribbles this wall paint can make wherein active carbon nanoparticles regeneration.
7. the preparation method of mosquito proof aqueous environment protection active carbon nanoparticles wall paint according to any one of claim 1-5, is characterized in that, comprise the steps:
(1) following component is taken according to mass fraction: water soluble acrylic resin 15 parts, Trisodium Citrate 12 parts, 8 parts, zinc oxide, 10 parts, zinc sulfate, active carbon nanoparticles 15 parts, mosquito-proof essential oil 5 parts, propylene glycol 0.3 part, kaolin 0.3 part, talcum powder 0.4 part, Homogeneous phase mixing, obtains composition of raw materials mixture, adds deionized water 20 parts in composition of raw materials mixture, use agitator stirs, agitator speed is 20 revs/min, and stirring at normal temperature 30 minutes, obtains feedstock portions mixing solutions;
(2) in above-mentioned feedstock portions mixing solutions, add dispersion agent, lubricant, biological preservative, adjustment rotating speed is 150 revs/min, stirring at normal temperature 60 minutes, and adjust ph is 7 simultaneously, obtains crude product mixed solution;
(3) above-mentioned crude product mixed solution normal temperature is ground to without particle, obtains mosquito proof Water-soluble environment-friendlyanticorrosive anticorrosive wall paint.
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| CN106318115A (en) * | 2016-08-19 | 2017-01-11 | 广西鑫雅皇庭园林工程有限责任公司 | Environment-friendly floor paint |
| CN106318136A (en) * | 2016-08-19 | 2017-01-11 | 广西鑫雅皇庭园林工程有限责任公司 | Odorless floor paint |
| CN108559345A (en) * | 2018-04-11 | 2018-09-21 | 晴隆县申利普涂料有限公司 | A kind of processing method of anti-Spider Webs survival-type wall finiss |
| CN108753078A (en) * | 2018-04-11 | 2018-11-06 | 晴隆县申利普涂料有限公司 | A kind of anti-Spider Webs survival-type wall finiss |
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| US20050258093A1 (en) * | 2004-05-24 | 2005-11-24 | Microban Products Company | Antimicrobial activated carbon and method of making |
| CN1730583A (en) * | 2005-08-17 | 2006-02-08 | 马金山 | Lavender flavor type environment protective latex paint and its preparation method |
| CN101210143A (en) * | 2006-12-31 | 2008-07-02 | 北京金源化学集团有限公司 | Environment-friendly type long-acting mildew-resisting paint and preparing method thereof |
| KR20090114497A (en) * | 2008-04-30 | 2009-11-04 | 경상대학교산학협력단 | Bamboo activated carbon paint |
| CN101967327A (en) * | 2010-09-30 | 2011-02-09 | 江苏大象东亚制漆有限公司 | Long-acting formaldehyde-resistant water-based crylic acid wood lacquer composite |
| CN102925018A (en) * | 2012-11-30 | 2013-02-13 | 刘凯 | Indoor decoration coating |
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Inventor after: Wang Hao Inventor after: Wang Ping Inventor after: Zou Zhongqing Inventor before: Wang Xinzhi |
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Effective date of registration: 20170421 Address after: Door Tongziling Road eight 414000 economic and Technological Development Zone Hunan city Yueyang province No. 116 Patentee after: Hunan Huibo Chemical Technology Co., Ltd. Address before: 239050 Hongshan Industrial Park, Chuzhou, Anhui Patentee before: Chuzhou Hongyuan Spraying Co., Ltd. |
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