CN103238957B - A kind of Anti-electromagneticantistatic antistatic woolen sweater - Google Patents

A kind of Anti-electromagneticantistatic antistatic woolen sweater Download PDF

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CN103238957B
CN103238957B CN201310010762.5A CN201310010762A CN103238957B CN 103238957 B CN103238957 B CN 103238957B CN 201310010762 A CN201310010762 A CN 201310010762A CN 103238957 B CN103238957 B CN 103238957B
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powder
mass ratio
wire
ratio
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CN103238957A (en
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魏元龙
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Ningxia Hengfeng rester science and Technology Co., Ltd.
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Sharp Next Ecological Textile Technology Co Ltd Is Come In Shandong
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Abstract

The invention belongs to textile material field, specifically disclose a kind of Anti-electromagneticantistatic antistatic woolen sweater, this woollen sweater is formed by the blending according to a certain percentage of weaving of wire and wool fiber.To be spinned the woollen sweater be formed by weaving by metal wire mixed of the present invention, there is environment friendly and pollution-free, metallic element difficult drop-off and the performance such as Radiation-proof antistatic effect is good, possess good market prospects.

Description

A kind of Anti-electromagneticantistatic antistatic woolen sweater
Technical field
The invention belongs to textile material field, relate to a kind of Anti-electromagneticantistatic antistatic fabric, be specifically related to a kind of Anti-electromagneticantistatic antistatic woolen sweater.
Background technology
Woollen sweater originally refers to the sweater knitting system with wool, and this is also the implication that common people admit, and in fact " woollen sweater " has become the synonym of a series products now, is namely used for making a general reference " sweater knitted " or claiming " woollen knitwear ".Woollen knitwear refers to mainly with being with the fabric of animal fiber for being made into after primary raw material spun yarn such as wool, cashmere, the rabbit hairs, such as the angora sweater, to avenge blue sweater, the young sweater of sheep, acrylic apparel etc. be all " woollen sweater " extended familys.Woollen sweater is autumn and winter season main resisting cold dress ornament, and its warming and attractive in appearance performance obtains the consistent accreditation of people.
The electromagnetic wave that the mutual change of Electric and magnetic fields produces, electromagnetic wave, to the phenomenon of air-launched or leakage, is named electromagnetic radiation.Electromagnetic radiation be a kind ofly to cannot see, the material that exists of impalpable specific form.A earth inherently large magnetic field of human survival, the heat radiation on its surface and thunder and lightning all can produce electromagnetic radiation, and the sun and other celestial bodies are also former from outer space constantly produces electromagnetic radiation.Be centered around mankind's natural magnetic field at one's side, sunshine, household electrical appliance etc. and all can send the different radiation of intensity, the electromagnetic wave of its radiation more and more receives the concern of the mankind on the impact of health.Electromagnetic harm is more, and the first, it causes one of leukemic reason, and increasing research shows, amount of radiation and ill ratio are proportionate; The second, affect the reproductive system of people, main manifestations be man's sperm quality reduce, pregnant woman occur aborted fetus deformity etc.; 3rd, affect the cardiovascular system of people, show as palpitaition, insomnia, some women disorder of menstrual cycle, bradycardia, heartbeat oligemia, sinus rate is uneven, degradation under immunologic function.
Electrostatic is a kind of electric charge remained static.At dry and windy fall and winter, people usually can encounter this phenomenon: undress evening in bed, often hear crack the sound in dark, and with blue light, meet when shaking hands, and point just to touch the other side, can feel suddenly shouting pain as finger tip acupuncture; Morning is when getting up to comb one's hair, and hair can often " wafing ", unreasonable more random, sliding door handle, all can " get an electric shock " when turning on the tap, and often sends the sound of ", ", and Here it is occurs in the electrostatic of human body.During physical activity, rub mutually between skin and clothes and between clothes and clothes, just can produce electrostatic.Along with household electrical appliance increase and winter people wear chemical fibre clothes more, the electrostatic charge that household electrical appliance produce can be absorbed by the body and accumulate, in addition room interior walls and floor many genus insulator, and air oxygen detrition, is therefore more easily subject to electrostatic interference.Skin due to the elderly compares the factors such as young man dry and the elderly's cardiovascular system aging, antijamming capability weaken, and therefore the elderly is more easily by the impact of electrostatic.
In view of the harm of electromagnetic radiation and electrostatic, be developed a lot of yarn fabric reducing its harm, comprise woollen sweater etc.In recent years, studying more is adopt metal wire mixed spinning technique to prepare woollen sweater, to reach anti-electromagnetic radiation and anlistatig effect.Wire has anti-electromagnetic radiation, not electromagnetic wave absorption, permanence antistatic, anti-oxidant, corrosion resistant function, and wire is applied in woollen sweater, and its manufactured goods are just provided with anti-electromagnetic radiation and anlistatig function simultaneously.
Wire of the prior art spins and there is more defect, mainly contains: metal component wiry easily drops, and pollutes; Poor with the binding ability of wool fiber, as easy as rolling off a log separation; Soft comfortable is poor and Radiation-proof antistatic performance is not high.Document CN2008100186965 discloses a kind of antistatic, ray-proof worsted cloth, and this fabric possesses certain radioresistance electrostatic-proof function, but metallic element wiry easily comes off, and poor with the binding ability of yarn fabric, and service life is shorter; Document CN2012101691402 is the achievement of applicant's early-stage Study, the special metal silk blend yarn of preparation is obtained by wire and wool fiber blending according to a certain percentage, but the compatibility of metal wire mixed yarn and skin is poor, and metallic element easily comes off, and antistatic effect is undesirable.
Urgently need to study a kind of pollution-free, the woollen sweater that strong with the adhesion of yarn fabric and Radiation-proof antistatic effect is good in prior art.
Summary of the invention
The present invention mainly solves the technical problem existing for prior art, thus provides a kind of pollution-free, strong with the adhesion of yarn fabric, difficult drop-off and the good textile of Radiation-proof antistatic effect.
Above-mentioned technical problem of the present invention is mainly solved by following technical proposals:
A kind of woollen sweater, it is spinned by metal wire mixed and is formed by weaving, described metal wire mixed spins to be prepared as follows and forms: material A, material B and material C are mixed according to the mass ratio of 3:1:2, stir, prepare alloy by hot pressed sintering, adopt single wire drawing to be prepared into the wire that diameter is 2 microns; Then be that 1:40 blending forms by wire and wool fiber according to weight ratio, be then soaked in 2%(mass volume ratio) in collagen solution, be slowly warmed up to 45 DEG C, be incubated after 30 minutes and take out, low temperature drying and get final product.
The preparation method of above-mentioned material A is as follows:
Get in the ball grinder that stainless steel powder, titanium valve and chromium powder put into containing absolute ethyl alcohol, the mass ratio of described stainless steel powder, titanium valve and chromium powder is 20:1:1; The weight ratio being 50:1 according to ratio of grinding media to material adds aluminium oxide ceramic ball, and Ball-milling Time is 12 hours, and ball milling temperature is room temperature, and drum's speed of rotation 500 revs/min, is milled to 1 microns the diameter of metal powder, evaporates absolute ethyl alcohol,
The preparation method of above-mentioned material B is as follows:
Mix according to the mass ratio of 1:1 according to vulcanized lead and ethylene-vinyl acetate copolymer, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes; In ethylene-vinyl acetate copolymer, vinylacetate preferred content is 10%;
The preparation method of above-mentioned material C is as follows:
In barium sulfate powder, add slurry reagent, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes; Described slurry reagent is ethene, styrene and the maleic acid mixture according to 1:1:1 mass ratio, and the mass ratio of described barium sulfate powder and slurry reagent is 1:3;
Wherein, preferably, the particle diameter≤1um of vulcanized lead and barium sulfate;
Above-mentioned blending step can adopt conventional blending method, also can refer to method disclosed in CN2012101691402.
Present invention also offers a kind of metal wire mixed to spin, it is prepared as follows and forms:
The preparation of material A: get in the ball grinder that stainless steel powder, titanium valve and chromium powder put into containing absolute ethyl alcohol, the mass ratio of described stainless steel powder, titanium valve and chromium powder is 20:1:1; The weight ratio being 50:1 according to ratio of grinding media to material adds aluminium oxide ceramic ball, and Ball-milling Time is 12 hours, and ball milling temperature is room temperature, and drum's speed of rotation 500 revs/min, is milled to 1 microns the diameter of metal powder, evaporates absolute ethyl alcohol,
The preparation of material B: mix according to the mass ratio of 1:1 according to vulcanized lead and ethylene-vinyl acetate copolymer, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes;
The preparation of material C: in barium sulfate powder, add slurry reagent, mixer stirs, then carries out ultrasonic wave and disperses 10 minutes; Described slurry reagent is ethene, styrene and the maleic acid mixture according to 1:1:1 mass ratio, and the mass ratio of described barium sulfate powder and slurry reagent is 1:3;
Wherein, preferably, the particle diameter≤1um of vulcanized lead and barium sulfate;
Mixed material: material A, material B and material C are mixed according to the mass ratio of 3:1:2, stir, prepare alloy by hot pressed sintering, adopts single wire drawing to be prepared into the wire that diameter is 2 microns; Then be that 1:40 blending forms by wire and wool fiber according to weight ratio, be then soaked in 2%(mass volume ratio) in collagen solution, be slowly warmed up to 45 DEG C, be incubated after 30 minutes and take out, low temperature drying and get final product.
Present invention also offers the preparation method that a kind of metal wire mixed spins.
The beneficial effect that the present invention obtains:
1, the present invention is by test of many times and exploration, on the basis of aforementioned operation, with the addition of material B and material C, substantially increases the binding ability of wire and wool fiber, improve Radiation-proof antistatic performance.
2, the present invention selects to adopt suitable collagen attachment to soak, and improves woollen sweater to the compatibility of skin and softness;
3, with the addition of chemical complexing agent in the woollen sweater that prepared by the present invention, make metallic element difficult drop-off, pollution-free, long service life, and improve fracture strength.
4, the woollen sweater prepared of the present invention, with the addition of certain titanium elements, possesses certain health care.
Detailed description of the invention
Below in conjunction with specific embodiment, set forth the present invention further.It should be noted that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.
Embodiment 1
A kind of woollen sweater, it spins primarily of metal wire mixed and is formed by weaving, metal wire mixed spins to be prepared as follows and forms: material A, material B and material C are mixed according to the mass ratio of 3:1:2, stir, prepare alloy by hot pressed sintering, adopt single wire drawing to be prepared into the wire that diameter is 2 microns; Then be that 1:40 blending forms by wire and wool fiber according to weight ratio, be then soaked in 2%(mass volume ratio) in collagen solution, be slowly warmed up to 45 DEG C, be incubated after 30 minutes and take out, low temperature drying and get final product.
The preparation method of above-mentioned material A is as follows:
Get in the ball grinder that stainless steel powder, titanium valve and chromium powder put into containing absolute ethyl alcohol, the mass ratio of described stainless steel powder, titanium valve and chromium powder is 20:1:1; The weight ratio being 50:1 according to ratio of grinding media to material adds aluminium oxide ceramic ball, and Ball-milling Time is 12 hours, and ball milling temperature is room temperature, and drum's speed of rotation 500 revs/min, is milled to 1 microns the diameter of metal powder, evaporates absolute ethyl alcohol,
The preparation method of above-mentioned material B is as follows:
Mix according to the mass ratio of 1:1 according to vulcanized lead and ethylene-vinyl acetate copolymer, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes;
The preparation method of above-mentioned material C is as follows:
In barium sulfate powder, add slurry reagent, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes; Slurry reagent is ethene, styrene and the maleic acid mixture according to 1:1:1 mass ratio, and the mass ratio of barium sulfate powder and slurry reagent is 1:3.
Embodiment 2
A kind of metal wire mixed spins, and it is prepared as follows and forms:
The preparation of material A: get in the ball grinder that stainless steel powder, titanium valve and chromium powder put into containing absolute ethyl alcohol, the mass ratio of described stainless steel powder, titanium valve and chromium powder is 20:1:1; The weight ratio being 50:1 according to ratio of grinding media to material adds aluminium oxide ceramic ball, and Ball-milling Time is 12 hours, and ball milling temperature is room temperature, and drum's speed of rotation 500 revs/min, is milled to 1 microns the diameter of metal powder, evaporates absolute ethyl alcohol,
The preparation of material B: mix according to the mass ratio of 1:1 according to vulcanized lead and ethylene-vinyl acetate copolymer, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes;
The preparation of material C: in barium sulfate powder, add slurry reagent, mixer stirs, then carries out ultrasonic wave and disperses 10 minutes; Described slurry reagent is ethene, styrene and the maleic acid mixture according to 1:1:1 mass ratio, and the mass ratio of described barium sulfate powder and slurry reagent is 1:3;
Mixed material: material A, material B and material C are mixed according to the mass ratio of 3:1:2, stir, prepare alloy by hot pressed sintering, adopts single wire drawing to be prepared into the wire that diameter is 2 microns; Then be that 1:40 blending forms by wire and wool fiber according to weight ratio, be then soaked in 2%(mass volume ratio) in collagen solution, be slowly warmed up to 45 DEG C, be incubated after 30 minutes and take out, low temperature drying and get final product.
Embodiment 3
The present invention prepares the performance that metal wire mixed spins: adopt CN2012101691402 to prepare metal wire mixed and spin as contrast.Detect each performance parameter in table 1.
Table 1 metal wire mixed spin performance parameter detect
Properties of product X-ray shielding rate (%) Fracture strength (cN/dtex) Elongation at break (%) 48h at 100 DEG C, then 48h at-20 DEG C Mildness
Embodiment 2 82.4 3.45 30.9 Metal comes off without any Better
Contrast 71.6 3.01 24.8 A little metal dust detected Generally
Utilize metal wire mixed of the present invention spin preparation woollen sweater, its point-to-point resistance≤0.8 × 10 5, electrically charged amount≤0.2 μ c/ part, possesses good antistatic performance.
Although inventor has done comparatively detailed elaboration to technical scheme of the present invention and has enumerated; be to be understood that; for one of ordinary skill in the art; according to disclosed content; amendment is made to above-described embodiment and/or changes or adopt equivalent replacement scheme to be apparent; it all can not depart from the scope of protection of present invention, and the protection domain in the present invention is as the criterion with the claim limited in detail in the claims.

Claims (1)

1. a woollen sweater, it is spinned by metal wire mixed and is formed by weaving, it is characterized in that, described metal wire mixed spins to be prepared as follows and forms: material A, material B and material C are mixed according to the mass ratio of 3:1:2, stir, prepare alloy by hot pressed sintering, adopt single wire drawing to be prepared into the wire that diameter is 2 microns; Then be that 1:40 blending forms by wire and wool fiber according to weight ratio, being then soaked in mass volume ratio is in 2% collagen solution, is slowly warmed up to 45 DEG C, is incubated after 30 minutes and takes out, low temperature drying and get final product; The preparation method of described material A is as follows: get in the ball grinder that stainless steel powder, titanium valve and chromium powder put into containing absolute ethyl alcohol, the mass ratio of described stainless steel powder, titanium valve and chromium powder is 20:1:1; The weight ratio being 50:1 according to ratio of grinding media to material adds aluminium oxide ceramic ball, and Ball-milling Time is 12 hours, and ball milling temperature is room temperature, and drum's speed of rotation 500 revs/min, is milled to 1 micron the diameter of metal powder, evaporates absolute ethyl alcohol;
The preparation method of described material B is as follows:
Vulcanized lead and ethylene-vinyl acetate copolymer mix according to the mass ratio of 1:1, and mixer stirs, and then carry out ultrasonic wave and disperse 10 minutes; Particle diameter≤the 1um of described vulcanized lead;
The preparation method of described material C is as follows:
In barium sulfate powder, add slurry reagent, mixer stirs, and then carries out ultrasonic wave and disperses 10 minutes; Described slurry reagent is ethene, styrene and the maleic acid mixture according to 1:1:1 mass ratio, and the mass ratio of described barium sulfate powder and slurry reagent is 1:3; Particle diameter≤the 1um of described barium sulfate.
CN201310010762.5A 2013-01-13 2013-01-13 A kind of Anti-electromagneticantistatic antistatic woolen sweater Expired - Fee Related CN103238957B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103243427B (en) * 2013-01-13 2015-08-12 山东来利来生态纺织科技有限公司 A kind of Anti-electromagneticantistatic antistatic fabric
CN108866730A (en) * 2018-07-09 2018-11-23 佛山市南海区佳妍内衣有限公司 A kind of anti-electron radiation wool product

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1793484A (en) * 2005-12-29 2006-06-28 苏州大学 Process for preparing modified cotton fibre
CN102585341A (en) * 2012-02-08 2012-07-18 上海交通大学 Preparation method for anti-radiation ethylene-vinyl acetate copolymer composite material
CN102704110A (en) * 2012-05-29 2012-10-03 山东来利来毛纺有限公司 Textile made of metal wire blended yarns
CN102719963A (en) * 2012-05-29 2012-10-10 山东来利来毛纺有限公司 Process for producing metal wire blended yarns
CN102733028A (en) * 2012-05-29 2012-10-17 山东来利来毛纺有限公司 Metal wire blended yarn

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1793484A (en) * 2005-12-29 2006-06-28 苏州大学 Process for preparing modified cotton fibre
CN102585341A (en) * 2012-02-08 2012-07-18 上海交通大学 Preparation method for anti-radiation ethylene-vinyl acetate copolymer composite material
CN102704110A (en) * 2012-05-29 2012-10-03 山东来利来毛纺有限公司 Textile made of metal wire blended yarns
CN102719963A (en) * 2012-05-29 2012-10-10 山东来利来毛纺有限公司 Process for producing metal wire blended yarns
CN102733028A (en) * 2012-05-29 2012-10-17 山东来利来毛纺有限公司 Metal wire blended yarn

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Address after: 276017 Shandong Province, Linyi city Luozhuang District Po Road Middle Shandong Lilai Woolen Co. Ltd.

Applicant after: Sharp next ecological textile technology Co., Ltd is come in Shandong

Address before: 276017 Shandong Province, Linyi city Luozhuang District Po Road Middle Shandong Lilai Woolen Co. Ltd.

Applicant before: Shandong Lalela Wool Spinning Co., Ltd.

COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: SHANDONG LAILILAI WOOL SPINNING CO., LTD. TO: SHANDONG LAILILAI ECO-TEXTILE TECHNOLOGY CO., LTD.

C14 Grant of patent or utility model
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Effective date of registration: 20180428

Address after: 751101 the Ningxia Hui Autonomous Region Wuzhong Jin Ji industrial park wool textile industrial park two phase

Patentee after: Ningxia Hengfeng rester science and Technology Co., Ltd.

Address before: 276017 Shandong province Linyi Luozhuang Baoquan road middle section Shandong Lai Lai Lai Wool Textile Co., Ltd.

Patentee before: Sharp next ecological textile technology Co., Ltd is come in Shandong

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150902

Termination date: 20210113