CN103193549A - Degradable resin envelop slow-control fertilizer-releasing production process - Google Patents

Degradable resin envelop slow-control fertilizer-releasing production process Download PDF

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Publication number
CN103193549A
CN103193549A CN201310160431XA CN201310160431A CN103193549A CN 103193549 A CN103193549 A CN 103193549A CN 201310160431X A CN201310160431X A CN 201310160431XA CN 201310160431 A CN201310160431 A CN 201310160431A CN 103193549 A CN103193549 A CN 103193549A
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Prior art keywords
fertilizer
release
parts
resin
weight
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CN201310160431XA
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付增传
付传俊
刘成菊
石兆君
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Fu Zengchuan
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Abstract

The invention belongs to the technical field of the fertilizer production, and relates to a degradable resin envelop slow-control fertilizer-releasing production process. Tung oil, urea resin, thermoplastic resin, thermosetting resin, polyacrylamide, modified starch and polyvinyl alcohol are reasonably processed into an envelope material; and urea, composite fertilizer and granular potassic fertilizer are used as granulation base stock. The production method is simple in process, the polymer resin material which can be completely and biologically degraded is elaborately selected as the envelope material to envelope the granular urea or the granular composite fertilizer, the special polymer envelop can intelligent control the release of nutrients according to the temperature of soil and the requirement of crops so as to improve the utilization rate of the fertilizer, the envelop shell which is remained in the soil can be completely degraded after the nutrients are completely released, no harm on the environment exists, and the environment-friendly fertilizer can be obtained.

Description

Degradable resin coating slow-release or control-release fertilizer production technique
Technical field
The invention belongs to the fertilizer production technology field, relate to a kind of degradable resin coating slow-release or control-release fertilizer production technique.
Background technology
Soil fertilizer is two big fundamentals of agriculture production.From the eighties in last century, China can plough the soil and use chemical fertilizer in a large number, cause that land deterioration, soil compaction, soil fertility decline, organic matter and beneficial microorganism reduce, agricultural ecological is unbalance, deterioration in quality, water resources and environment like pollution in various degree, makes human health like potential threat.Research, development of new, nuisanceless, degradable fertilizer are vast agricultural sciences worker's important topics.Biochemical fertilizer has become a kind of important organic fertilizer.Existing coating slow-release or control-release fertilizer is because there are following two kinds of phenomenons in the defective of coated fertilizer: when 1) adopting water-soluble stronger coated fertilizer, the chemical fertilizer granule dissolving is very fast, and the fertilizer efficiency short period of time discharges, and is unfavorable to the operation growth; When 2) adopting water-soluble strong poor coated fertilizers such as sulphur, though can prolong the time of releasing of fertilizer efficiency, sulphur decomposes slower in soil, and the degraded several years time to decades of needs is bigger to the harm of environment and soil fully.
Summary of the invention
The object of the present invention is to provide simple, the easy-operating degradable resin coating of a kind of technology slow-release or control-release fertilizer production technique, for the production of fertilizer efficiency slowly discharge, the coated fertilizer degradable fertilizer, avoid the coated fertilizer residue to the pollution of environment.
For achieving the above object, the present invention adopts following technical scheme:
Degradable resin coating slow-release or control-release fertilizer production technique of the present invention is characterized in that production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 50-65 ℃ in the tung oil adding reactor with the 30-50 weight part, when stirring, add following substances in parts by weight successively, the insoluble type urea-formaldehyde resin of cold water 50-65 part, vinylformic acid thermoplastic resin 5-15 part, thermosetting phenolic resin 5-15 part, poly-propionic acid amide 3-5 part, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 90-95 ℃, continue to stir 30-40 minute, reduce the temperature to 40-50 ℃, add the n-butyl acetate of 10-40 weight part again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 50-60 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 80-95 ℃ of baker temperature; dry to water content 1-2%; particle after will drying is then sent into coating machine, and the control temperature is to 50-80 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is the 2%-3% that treats coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
The insoluble type urea-formaldehyde resin of above-mentioned cold water is the mixture of 4 methylene radical, 5 nitrogen of 3 methylene radical, 4 nitrogen of parts by weight 40-50% and 50-60%.
This production method technology is simple, the macromolecule resin material of meticulously preferred totally biodegradable is as coated fertilizer, granular urea or granular compound fertilizer are carried out coating, distinctive polymer capsule can need the intelligent control nutrient to discharge with the soil moisture and crop, thereby raising utilization rate of fertilizer, the involucrum that nutrient remains in the soil after discharging fully can be degraded again fully, can not cause any infringement to environment, is a kind of environmental friendly fertilizer.
Embodiment
Embodiment 1:
Degradable resin coating slow-release or control-release fertilizer production technique of the present invention, its production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 50-65 ℃ in the tung oil adding reactor with the 30-50 weight part, when stirring, add following substances in parts by weight successively, the insoluble type urea-formaldehyde resin of cold water 50-65 part, vinylformic acid thermoplastic resin 5-15 part, thermosetting phenolic resin 5-15 part, poly-propionic acid amide 3-5 part, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 90-95 ℃, continue to stir 30-40 minute, reduce the temperature to 40-50 ℃, add the n-butyl acetate of 10-40 weight part again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 50-60 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 80-95 ℃ of baker temperature; dry to water content 1-2%; particle after will drying is then sent into coating machine, and the control temperature is to 50-80 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is the 2%-3% that treats coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
Above-mentioned urea-formaldehyde resin is the mixture of 4 methylene radical, 5 nitrogen of 3 methylene radical, 4 nitrogen of parts by weight 40-50% and 50-60%.
Above-mentioned granulation base-material is a kind of in the materials such as urea, compound manure, granular potash fertilizer.Certainly, also can adopt any other fertilizer that promotes plant-growth as the granulation base-material.
The insoluble type urea-formaldehyde resin of this coated fertilizer main raw material cold water does not dissolve in cold water, along with the participation of low temperature rise and microorganism is slowly degraded, in soil, slowly decompose and discharge plant nutrient nitrogen element, 40-60 days decomposition phase, can satisfy nutrient deenergized period, along with the decomposition of urea-formaldehyde resin, the nutrient accelerate decomposition of sustained-controll-release fertiliser, reach nutrient and discharge the peak, be made for thing and absorb the utilization of nutrient peak period, can not cause the waste of fertilizer nutrient in early stage.As coated fertilizer, film forming is also fast, and is more stable, easy to operate in conjunction with afterwards for materials such as special and thermoplastic resin, thermosetting resin, poly-propionic acid amide, treated starch, polyvinyl alcohol.
In addition, coated fertilizer contains high-hydroscopicity, but water conservation, for good microenvironment is created in the coated fertilizer degraded.The insoluble type urea-formaldehyde resin of the essential substance cold water of this coated fertilizer itself has the moisture absorption swelling action, treated starch and poly-propionic acid amide all have this effect, the crosslinked back wettability power that experimental results show that these materials is strengthened greatly, and degradation speed and slow controlled-release material mate fully.
Simultaneously, this coated fertilizer also has fast, the characteristics completely of degrading of degradation speed.This coated fertilizer is to mix cross-linking products, under microorganism and the temperature action, can be degraded into innoxious substance fully in soil, finally is converted into carbon source, plant nutrient and part water.Degradation cycle 200 days is complete substantially, thus be more satisfactory coated fertilizer, and this method technological process is simple, production cost is low, the utilization ratio advantages of higher.
Embodiment 2:
Degradable resin coating slow-release or control-release fertilizer production technique, its production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 50 ℃ in the tung oil adding reactor with 50 weight parts, when stirring, add following substances in parts by weight successively, 50 parts of the insoluble type urea-formaldehyde resins of cold water, 5 parts of vinylformic acid thermoplastic resins, 5 parts of thermosetting phenolic resins, 3 parts of poly-propionic acid amides, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 90 ℃, continue to stir 30 minutes, reduce the temperature to 40 ℃, add the n-butyl acetate of 10 weight parts again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 50 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 80 ℃ of baker temperature; dry to water content 1%; particle after will drying is then sent into coating machine, control temperature to 50 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is to treat 2% of coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
Above-mentioned urea-formaldehyde resin is 3 methylene radical, 4 nitrogen of parts by weight 40% and the mixture of 60% 4 methylene radical, 5 nitrogen.
Embodiment 3:
Degradable resin coating slow-release or control-release fertilizer production technique of the present invention, its production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 65 ℃ in the tung oil adding reactor with 30 weight parts, when stirring, add following substances in parts by weight successively, 65 parts of the insoluble type urea-formaldehyde resins of cold water, 15 parts of vinylformic acid thermoplastic resins, 15 parts of thermosetting phenolic resins, 5 parts of poly-propionic acid amides, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 95 ℃, continue to stir 40 minutes, reduce the temperature to 50 ℃, add the n-butyl acetate of 40 weight parts again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 60 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 95 ℃ of baker temperature; dry to water content 2%; particle after will drying is then sent into coating machine, control temperature to 80 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is to treat 3% of coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
Above-mentioned urea-formaldehyde resin is 3 methylene radical, 4 nitrogen of parts by weight 50% and the mixture of 50% 4 methylene radical, 5 nitrogen.
Embodiment 4:
Degradable resin coating slow-release or control-release fertilizer production technique of the present invention, its production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 60 ℃ in the tung oil adding reactor with 40 weight parts, when stirring, add following substances in parts by weight successively, 60 parts of the insoluble type urea-formaldehyde resins of cold water, 10 parts of vinylformic acid thermoplastic resins, 10 parts of thermosetting phenolic resins, 4 parts of poly-propionic acid amides, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 92 ℃, continue to stir 35 minutes, reduce the temperature to 45 ℃, add the n-butyl acetate of 20 weight parts again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 55 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 90 ℃ of baker temperature; dry to water content 1.5%; particle after will drying is then sent into coating machine, control temperature to 70 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is to treat 2% of coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
Above-mentioned urea-formaldehyde resin is 3 methylene radical, 4 nitrogen of parts by weight 45% and the mixture of 55% 4 methylene radical, 5 nitrogen.

Claims (2)

1. degradable resin coating slow-release or control-release fertilizer production technique is characterized in that production stage is as follows:
A) preparation of coated fertilizer; Be warmed to 50-65 ℃ in the tung oil adding reactor with the 30-50 weight part, when stirring, add following substances in parts by weight successively, the insoluble type urea-formaldehyde resin of cold water 50-65 part, vinylformic acid thermoplastic resin 5-15 part, thermosetting phenolic resin 5-15 part, poly-propionic acid amide 3-5 part, 5 parts of treated starches, 5 parts of polyvinyl alcohol; After stirring, be warmed to 90-95 ℃, continue to stir 30-40 minute, reduce the temperature to 40-50 ℃, add the n-butyl acetate of 10-40 weight part again, namely obtain described coated fertilizer;
B) granulation; The granulation base-material is heated to 50-60 ℃, sends into the tablets press granulation;
C) particle coating; The particle that tablets press is formed enters dryer; 80-95 ℃ of baker temperature; dry to water content 1-2%; particle after will drying is then sent into coating machine, and the control temperature is to 50-80 ℃; spray into steps A) described coated fertilizer; the coated fertilizer consumption is the 2%-3% that treats coated granule weight, after the cooling, namely obtains described degradable resin coating slow-release or control-release fertilizer through the screening metering packing.
2. degradable resin coating slow-release or control-release fertilizer production technique according to claim 1 is characterized in that: the insoluble type urea-formaldehyde resin of described cold water is the mixture of 4 methylene radical, 5 nitrogen of 3 methylene radical, 4 nitrogen of parts by weight 40-50% and 50-60%.
CN201310160431XA 2013-05-05 2013-05-05 Degradable resin envelop slow-control fertilizer-releasing production process Pending CN103193549A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103539516A (en) * 2013-09-22 2014-01-29 苏州市湘园特种精细化工有限公司 Method for preparing slow-controlled release fertilizer
CN104262019A (en) * 2014-10-11 2015-01-07 辽宁芦田肥业有限公司 Coated degradation type slow release potassium fertilizer
CN104609957A (en) * 2015-01-20 2015-05-13 山东聊城鲁西化工第四化肥有限公司 Fully-degradable plant oil coating material for controlled-release fertilizer and preparation method
CN109206212A (en) * 2018-09-14 2019-01-15 仲恺农业工程学院 A kind of preparation method of modified tung oil coated carbamide
CN111727851A (en) * 2019-03-22 2020-10-02 东莞市乐为现代农业科技有限公司 Naturally degradable plant seedling raising substrate and manufacturing method and application thereof
CN113493361A (en) * 2021-08-02 2021-10-12 西安唯拓尔农业科技有限公司 Biological nano resin coated controlled-release boron fertilizer and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103539516A (en) * 2013-09-22 2014-01-29 苏州市湘园特种精细化工有限公司 Method for preparing slow-controlled release fertilizer
CN103539516B (en) * 2013-09-22 2015-05-20 苏州市湘园特种精细化工有限公司 Method for preparing slow-controlled release fertilizer
CN104262019A (en) * 2014-10-11 2015-01-07 辽宁芦田肥业有限公司 Coated degradation type slow release potassium fertilizer
CN104609957A (en) * 2015-01-20 2015-05-13 山东聊城鲁西化工第四化肥有限公司 Fully-degradable plant oil coating material for controlled-release fertilizer and preparation method
CN109206212A (en) * 2018-09-14 2019-01-15 仲恺农业工程学院 A kind of preparation method of modified tung oil coated carbamide
CN111727851A (en) * 2019-03-22 2020-10-02 东莞市乐为现代农业科技有限公司 Naturally degradable plant seedling raising substrate and manufacturing method and application thereof
CN113493361A (en) * 2021-08-02 2021-10-12 西安唯拓尔农业科技有限公司 Biological nano resin coated controlled-release boron fertilizer and preparation method thereof

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