CN103184696A - Digital printing non-slurry preprocessing method for silk cloth - Google Patents

Digital printing non-slurry preprocessing method for silk cloth Download PDF

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Publication number
CN103184696A
CN103184696A CN2013101065653A CN201310106565A CN103184696A CN 103184696 A CN103184696 A CN 103184696A CN 2013101065653 A CN2013101065653 A CN 2013101065653A CN 201310106565 A CN201310106565 A CN 201310106565A CN 103184696 A CN103184696 A CN 103184696A
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Prior art keywords
softener
water repellent
water
padding
treating method
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Pending
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CN2013101065653A
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Chinese (zh)
Inventor
林旭
孙思恒
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HUATAI SILK CO Ltd ZHEJIANG
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HUATAI SILK CO Ltd ZHEJIANG
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Priority to CN2013101065653A priority Critical patent/CN103184696A/en
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Abstract

The invention relates to a digital printing non-slurry preprocessing method for silk cloth. The method comprises a padding step, a drying step, a jet printing step, an ageing step, a washing step and a drying step, wherein padding liquid configured in the padding step comprises 0.2-1 g/l of softener, 0.2-1 g/l of water repellent, 20-40 g/l of sodium chloride and water; the solution concentration ratio of the softener to the water repellent is 1 to 1; the padding liquid is prepared by the steps as follows: adding the water, the softener and the water repellent, uniformly stirring, and adding sodium chloride; the softener belongs to a mixture of a cationic softener or cations and a nonionic softener, and comprises a quaternary ammonium salt softener, fatty acid ester softener and a paraffin wax softener; and the water repellent belongs to a weak cation water repellent and is a perfluoroalkyl polyacrylic copolymer. Due to the adoption of the non-slurry preprocessing process, the printed product is excellent in fineness, the obtained color is rich and gaudy, the color light is stable, and the overall quality is improved.

Description

A kind of silk digit printing does not have the slurry pre-treating method
Technical field
The present invention relates to a kind of silk digit printing and do not have the slurry pre-treating method.
Background technology
Digital ink-jet printed as a kind of brand-new stamp mode, obtained development rapidly in recent years, represented the development trend in following printing in textiles field.The more traditional stamp of digit printing has 4 advantages: (1) has saved the plate-making process in traditional printing method, and printing and proofing speed is accelerated greatly, and the cost of drawing a design reduces.(2) be not subjected to the flower of style to enclose the restriction of size, tricks, to anthosin standard, levels are rich, printing quality is good, can be used for the stamp of grade textiles.(3) realize the customer demand of small lot, fast response, can produce superior, personalized stamp product.(4) pollution before and after the drop on demand ink jet, stamp seldom.The superiority of logarithmic code stamp has been reached common recognition in the dyeing industry, is referred to as " revolution of a textile printing technology ".Digit printing can be divided into active digit printing, Acid Techno stamp, disperse digit printing and coating digit printing etc. according to the difference of colouring agent.What the present invention relates to is active digit printing.Pre-treatment process is exactly the last slurry process of fabric under the present state of the art of active digit printing.Auxiliary agents such as thickener, alkaline agent, urea have mainly been comprised in the starching thickener.The purpose that adds thickener is for not imbibition of flower type in spray printing or the process of evaporating.It plays a part carrier in the stamp process, after fabric evaporates, thickener will be removed in washing step.No matter be natural paste or synthetic thickener, its existence not only can prolong the washing time, and energy consumption rises, and also can cause the wastewater treatment difficulty to increase.The effect of alkaline agent in the starching thickener is the set REACTIVE DYES.But owing to not alkaline-resisting dose of real silk, to selecting which kind of alkaline agent and concrete consumption most important, phenomenons such as the powerful decline of slim silk or color development instability appear easily on technology.Urea is a kind of common hygroscopic agent, helps the better color development of dyestuff, but is the biggest factor that causes the ammonia nitrogen index to increase.Therefore, though digit printing is compared traditional handicraft greater advantage is arranged, but still have very big progressive space.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned defective of the prior art, provides a kind of silk digit printing not have the slurry pre-treating method.
The present invention addresses the above problem the technical scheme that adopts: this silk digit printing does not have the slurry pre-treating method, may further comprise the steps:
Pad operation: prepare the padding liquid of being made up of softener, water repellent, sodium chloride and water in advance in groove, make the silk fabrics open width enter groove, the speed of a motor vehicle is at 20 meters/minute, and pick-up rate is controlled at 80%-100%;
Baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-140 ℃, and the time of tentering oven dry is 2-3 minute;
Spray printing operation: adopt Numerical Control Printer to spend the type spray printing;
Evaporate operation: evaporate in cylinder evaporates equipment, evaporating temperature is 116 ℃-120 ℃, and the time of evaporating is 45 minutes-60 minutes;
Washing step;
Baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-130 ℃, and the time of tentering oven dry is 2-3 minute.
The mass concentration of softener is the 0.2-1 grams per liter in the padding liquid of the present invention, and the mass concentration of water repellent is the 0.2-1 grams per liter, and the mass concentration of sodium chloride is the 20-40 grams per liter, and all the other are water, and the mass concentration ratio of softener and water repellent is 1:1.
The order of padding liquid preparation of the present invention is: water, softener, water repellent add earlier, and the back that stirs adds sodium chloride.
Washing step of the present invention adopts open width rinsing machine washing 2 times, and washing temperature is at 95 ℃-100 ℃, and 20 meters/minute of the speed of a motor vehicle were washed 2-3 minute at every turn.
Washing step of the present invention adopts the rope form rinsing machine, and washing temperature is at 95 ℃-100 ℃, soap boiling after 30 minutes again clear water wash.
Softener of the present invention belongs to the mixture of cationic softener or CATION and NON IONIC SOFTNER, comprises quaternary softener, fatty acid ester type softener, paraffin wax type softener.
Water repellent of the present invention belongs to the weak cation type, is the perfluoroalkyl acrylic copolymer.
The beneficial effect that the present invention has is: after digital spray printing adopts no slurry pre-treatment process, the fabric clear-cut of spray printing, the level solid is true to nature, bright in luster, pliability is good, compares the starching pre-treatment process, and spray printing product quality integral body is obviously promoted, solved that the rich and gaudy degree of Dry Sack that often occurs in the spray printing process in the past contradicts with fineness and slim fabric owing to destarch not to the utmost, feel problem such as harden.In addition, owing to there is not thickener to exist, therefore alleviated the washing burden greatly in the no slurry pre-treatment process; Do not have alkaline agent to exist, therefore do not have fabric yellowing, powerful degradation problem down; Do not have urea to exist, therefore do not have the too high problem of ammonia nitrogen index.Pre-treating method provided by the invention is fit to large-scale production, and technological process is succinctly easy to operate, constant product quality.
The specific embodiment
Embodiment of the invention silk digit printing does not have the slurry pre-treating method, comprises three kinds of most preferred embodiments:
Embodiment 1:
No slurry pre-treating method at the enterprising line number sign indicating number of plain crepe-back satin fabric stamp spray printing may further comprise the steps:
1) pad operation: prepare the padding liquid of being made up of softener, water repellent, sodium chloride and water in advance in groove, make the silk fabrics open width enter groove, the speed of a motor vehicle is at 20m/min, and pick-up rate is controlled at 80%-100%.
2) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-140 ℃, and the time of tentering oven dry is 2-3min.
3) spray printing operation: adopt Numerical Control Printer to spend the type spray printing.
4) evaporate operation: in cylinder evaporates equipment, evaporate, evaporate 116 ℃-120 ℃ of temperature, evaporate time 45min-60min.
5) washing step: 95 ℃-100 ℃ of open width rinsing machines, speed of a motor vehicle 20m/min, 2-3min washes 2 times altogether.
6) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-130 ℃, and the time of tentering oven dry is 2-3min.
The described padding liquid of present embodiment is by 0.2-1 g/l softener, and 0.2-1 g/l water repellent, 20-40 g/l sodium chloride and water are formed, and the mass concentration ratio of softener and water repellent is 1:1.
The order of the described padding liquid preparation of present embodiment is: water, softener, water repellent add earlier, and the back that stirs adds sodium chloride.
The described softener of present embodiment belongs to the mixture of cationic softener or CATION and NON IONIC SOFTNER, comprise quaternary softener, fatty acid ester type softener, paraffin wax type softener, can adopt the existing product on the market, for example the product of the prosperous sharp textile auxiliary in Hangzhou Co., Ltd.
The described water repellent of present embodiment belongs to the weak cation type, is the perfluoroalkyl acrylic copolymer, can adopt the existing product on the market, for example the product of Kekai Fine Chemical (Shanghai) Co., Ltd..
Embodiment 2:
No slurry pre-treating method at the enterprising line number sign indicating number of chiffon fabric stamp spray printing may further comprise the steps:
1) pad operation: prepare the padding liquid of being made up of softener, water repellent, sodium chloride and water in advance in groove, make the silk fabrics open width enter groove, the speed of a motor vehicle is at 20m/min, and pick-up rate is controlled at 80%-100%.
2) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-140 ℃, and the time of tentering oven dry is 2-3min.
3) spray printing operation: adopt Numerical Control Printer to spend the type spray printing.
4) evaporate operation: in cylinder evaporates equipment, evaporate, evaporate 116 ℃-120 ℃ of temperature, evaporate time 45min-60min.
5) washing step: 95 ℃-100 ℃ of open width rinsing machines, speed of a motor vehicle 20m/min, 2-3min washes 2 times altogether.
6) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-130 ℃, and the time of tentering oven dry is 2-3min.
The described padding liquid of present embodiment is made up of 0.2-1 g/l softener, 0.2-1 g/l water repellent, 20-40 g/l sodium chloride and water, and the mass concentration ratio of softener and water repellent is 1:1.
The order of the described padding liquid preparation of this example is: water, softener, water repellent add earlier, and the back that stirs adds sodium chloride.
The described softener of present embodiment belongs to the mixture of cationic softener or CATION and NON IONIC SOFTNER, comprise quaternary softener, fatty acid ester type softener, paraffin wax type softener, can adopt the existing product on the market, for example the product of the prosperous sharp textile auxiliary in Hangzhou Co., Ltd.
The described water repellent of present embodiment belongs to the weak cation type, is the perfluoroalkyl acrylic copolymer, can adopt the existing product on the market, for example the product of Kekai Fine Chemical (Shanghai) Co., Ltd..
Embodiment 3:
No slurry pre-treating method along the enterprising line number sign indicating number of winding tall fabric stamp spray printing may further comprise the steps:
1) pad operation: prepare the padding liquid of being made up of softener, water repellent, sodium chloride and water in advance in groove, make the silk fabrics open width enter groove, the speed of a motor vehicle is at 20m/min, and pick-up rate is controlled at 80%-100%.
2) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-140 ℃, and the time of tentering oven dry is 2-3min.
3) spray printing operation: adopt Numerical Control Printer to spend the type spray printing.
4) evaporate operation: in cylinder evaporates equipment, evaporate, evaporate 116 ℃-120 ℃ of temperature, evaporate time 45min-60min.
5) washing step: 95 ℃-100 ℃ of rope form rinsing machines, soap boiling 30min clear water again washes.
6) baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-130 ℃, and the time of tentering oven dry is 2-3min.
The described padding liquid of present embodiment is made up of 0.2-1 g/l softener, 0.2-1 g/l water repellent, 20-40 g/l sodium chloride and water, and wherein the mass concentration ratio of softener and water repellent is 1:1.
The order of the described padding liquid preparation of present embodiment is: water, softener, water repellent add earlier, and the back that stirs adds sodium chloride.
The described softener of present embodiment belongs to the mixture of cationic softener or CATION and NON IONIC SOFTNER, comprise quaternary softener, fatty acid ester type softener, paraffin wax type softener, can adopt the existing product on the market, for example the product of the prosperous sharp textile auxiliary in Hangzhou Co., Ltd.
The described water repellent of present embodiment belongs to the weak cation type, is the perfluoroalkyl acrylic copolymer, can adopt the existing product on the market, for example the product of Kekai Fine Chemical (Shanghai) Co., Ltd..
Compare with existing silk starching pre-treatment process technical merit, application on the no slurry pre-treatment process of the present invention, no matter in tinctorial yield, vividness, fineness, still on the feel, all be significantly improved, and solved the rich and gaudy degree of Dry Sack and the conflicting problem of fineness, advanced the perfect of digital ink-jet printed technology.

Claims (7)

1. a silk digit printing does not have the slurry pre-treating method, may further comprise the steps:
Pad operation: prepare the padding liquid of being made up of softener, water repellent, sodium chloride and water in advance in groove, make the silk fabrics open width enter groove, the speed of a motor vehicle is at 20 meters/minute, and pick-up rate is controlled at 80%-100%;
Baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-140 ℃, and the time of tentering oven dry is 2-3 minute;
Spray printing operation: adopt Numerical Control Printer to spend the type spray printing;
Evaporate operation: evaporate in cylinder evaporates equipment, evaporating temperature is 116 ℃-120 ℃, and the time of evaporating is 45 minutes-60 minutes;
Washing step;
Baking operation: the fabric after will padding is the tentering oven dry under the open width state, and bake out temperature is at 100 ℃-130 ℃, and the time of tentering oven dry is 2-3 minute.
2. silk digit printing according to claim 1 does not have the slurry pre-treating method, it is characterized in that: the mass concentration of softener is the 0.2-1 grams per liter in the described padding liquid, the mass concentration of water repellent is the 0.2-1 grams per liter, the mass concentration of sodium chloride is the 20-40 grams per liter, all the other are water, and the mass concentration ratio of softener and water repellent is 1:1.
3. silk digit printing according to claim 1 and 2 does not have the slurry pre-treating method, it is characterized in that: the order of described padding liquid preparation is: water, softener, water repellent add earlier, and the back that stirs adds sodium chloride.
4. silk digit printing according to claim 1 and 2 does not have the slurry pre-treating method, it is characterized in that: washing step adopts open width rinsing machine washing 2 times, and washing temperature is at 95 ℃-100 ℃, and 20 meters/minute of the speed of a motor vehicle were washed 2-3 minute at every turn.
5. silk digit printing according to claim 1 and 2 does not have the slurry pre-treating method, it is characterized in that: washing step adopt to adopt the rope form rinsing machine, and washing temperature is at 95 ℃-100 ℃, soap boiling after 30 minutes again clear water wash.
6. silk digit printing according to claim 1 and 2 does not have the slurry pre-treating method, it is characterized in that: described softener belongs to the mixture of cationic softener or CATION and NON IONIC SOFTNER, comprises quaternary softener, fatty acid ester type softener, paraffin wax type softener.
7. silk digit printing according to claim 1 and 2 does not have the slurry pre-treating method, it is characterized in that: described water repellent belongs to the weak cation type, is the perfluoroalkyl acrylic copolymer.
CN2013101065653A 2013-03-29 2013-03-29 Digital printing non-slurry preprocessing method for silk cloth Pending CN103184696A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831565A (en) * 2015-04-04 2015-08-12 山东黄河三角洲纺织科技研究院有限公司 Pigment ink jet printing pretreatment agent
CN105755723A (en) * 2016-03-21 2016-07-13 山东黄河三角洲纺织科技研究院有限公司 Old-imitation processing method of polyamide-ester fabric
CN106544907A (en) * 2016-09-28 2017-03-29 杭州万事利丝绸科技有限公司 It is a kind of to exempt to starch the real silk fabric digital printing method for processing
CN111809415A (en) * 2020-07-07 2020-10-23 山东黄河三角洲纺织科技研究院有限公司 Digital printing process of cellulose fiber fabric
CN112458757A (en) * 2020-11-25 2021-03-09 浙江喜得宝丝绸科技有限公司 Printing and dyeing method of gambiered canton
CN113969509A (en) * 2021-10-29 2022-01-25 东华大学 Digital printing fabric pretreatment method with water-repellent and antifouling functions

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JPH07279065A (en) * 1994-03-31 1995-10-24 Canon Inc Cloth for printing, ink-jet printing process and printed product
CN101037845A (en) * 2006-03-17 2007-09-19 内蒙古鄂尔多斯羊绒集团有限责任公司 Digit printing processing method of cashmere produce
CN101328684A (en) * 2008-07-31 2008-12-24 章传兴 Real silk and imitated silk digital printing process
CN102720059A (en) * 2012-06-20 2012-10-10 浙江华泰丝绸有限公司 Pretreatment method for numerical printing of silk

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JPH07279065A (en) * 1994-03-31 1995-10-24 Canon Inc Cloth for printing, ink-jet printing process and printed product
CN101037845A (en) * 2006-03-17 2007-09-19 内蒙古鄂尔多斯羊绒集团有限责任公司 Digit printing processing method of cashmere produce
CN101328684A (en) * 2008-07-31 2008-12-24 章传兴 Real silk and imitated silk digital printing process
CN102720059A (en) * 2012-06-20 2012-10-10 浙江华泰丝绸有限公司 Pretreatment method for numerical printing of silk

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831565A (en) * 2015-04-04 2015-08-12 山东黄河三角洲纺织科技研究院有限公司 Pigment ink jet printing pretreatment agent
CN105755723A (en) * 2016-03-21 2016-07-13 山东黄河三角洲纺织科技研究院有限公司 Old-imitation processing method of polyamide-ester fabric
CN106544907A (en) * 2016-09-28 2017-03-29 杭州万事利丝绸科技有限公司 It is a kind of to exempt to starch the real silk fabric digital printing method for processing
CN106544907B (en) * 2016-09-28 2019-07-02 杭州万事利丝绸科技有限公司 A kind of real silk fabric digital printing method for exempting from slurry processing
CN111809415A (en) * 2020-07-07 2020-10-23 山东黄河三角洲纺织科技研究院有限公司 Digital printing process of cellulose fiber fabric
CN112458757A (en) * 2020-11-25 2021-03-09 浙江喜得宝丝绸科技有限公司 Printing and dyeing method of gambiered canton
CN112458757B (en) * 2020-11-25 2022-05-13 浙江喜得宝丝绸科技有限公司 Printing and dyeing method of gambiered canton
CN113969509A (en) * 2021-10-29 2022-01-25 东华大学 Digital printing fabric pretreatment method with water-repellent and antifouling functions

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Application publication date: 20130703