CN103159993A - Oil-resistant non-skid sole material and preparation method thereof - Google Patents
Oil-resistant non-skid sole material and preparation method thereof Download PDFInfo
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- CN103159993A CN103159993A CN2013101268658A CN201310126865A CN103159993A CN 103159993 A CN103159993 A CN 103159993A CN 2013101268658 A CN2013101268658 A CN 2013101268658A CN 201310126865 A CN201310126865 A CN 201310126865A CN 103159993 A CN103159993 A CN 103159993A
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Abstract
The invention discloses an oil-resistant non-skid sole material which is prepared from butadiene-nitrile rubber, cis-1,4-polybutadiene rubber, white carbon black, diethylene glycol, white oil, zinc oxide, stearic acid, dispersing agent, accelerator, anti-aging agent, RX-80 and polyvinyl chloride resin. The preparation method of the oil-resistant non-skid sole material comprises the following steps: evenly mixing the materials, adding into a Banbury mixer, banburying, adding the banburying mixture into a screw extruder, carrying out melt blending, granulating, mixing the granules in an open mill, and carrying out mold pressing to obtain the oil-resistant non-skid sole material. The oil-resistant non-skid sole material disclosed by the invention has the advantages of excellent oil resistance, solvent resistance, non-skid property and bending resistance; the combination of the polyvinyl chloride resin and butadiene-nitrile rubber improves the luster surface of the product, keeps no defogging for a long time, and enhances the aesthetic degree of the product.
Description
Technical field
The present invention relates to a kind of material for sole of shoe, relate in particular to a kind of oil-proof anti-skid sole material and preparation method thereof.
Background technology
Shoes are article of usually using in our daily life, and sole is to make the requisite part of shoes.Along with the progress of the development of science and technology and society, people's standard of living improves constantly, and improves the quality and performance of all kinds of shoes, allow the wearer more safety and comfort be ultimate aim and the direction of whole shoe-making industry.
The material that is used at present the making sole has rubber, thermoplastic elastomer, plastics etc.It is poor that but existing material for sole of shoe mostly exists oil-proofness, can not well play the shortcomings such as anti-skidding effect, can not satisfy people's demand.
Summary of the invention
Exist oil-proofness poor for solving existing formula of soles material, the problem that anti-skid is poor the invention provides a kind of oil-proof anti-skid material and preparation method thereof.
Technical scheme of the present invention is as follows:
Oil-proof anti-skid sole material disclosed in this invention is comprised of butadiene acrylonitrile rubber, cis-butadiene cement, white carbon black, glycol ether, white oil, zinc oxide, stearic acid, dispersion agent, promotor, anti-aging agent, RX-80 and polyvinyl chloride (PVC) RESINS.
The weight part of oil-proof anti-skid sole material disclosed in this invention consists of:
Preferably:
More preferably:
Oil-proof anti-skid sole material disclosed in this invention, wherein, dispersion agent is PEG.
Oil-proof anti-skid sole material disclosed in this invention, wherein, promotor is altax.
Oil-proof anti-skid sole material disclosed in this invention, wherein, anti-aging agent is anti-aging agent RD.
Oil-proof anti-skid sole material preparation method disclosed in this invention comprises the following steps:
(1) butadiene acrylonitrile rubber, cis-butadiene cement, white carbon black, glycol ether, white oil, zinc oxide, stearic acid, dispersion agent, promotor, anti-aging agent, RX-80 and polyvinyl chloride (PVC) RESINS are obtained mixture according to the certain part by weight mixing and stirring;
(2) mixture is joined in Banbury mixer, at 145 ℃～150 ℃ lower banburying 12～15min, obtain the banburying mixture;
(3) the banburying mixture is joined in screw extrusion press, carry out melt blending, granulation under 110 ℃～150 ℃;
(4) particle is joined in mill mix, then mold pressing makes the oil-proof anti-skid sole material.
Oil-proof anti-skid sole material disclosed in this invention has the following advantages:
1, material for sole of shoe of the present invention has good oil resistant, solvent resistance.
2, material for sole of shoe of the present invention has good non-skid property.
3, material for sole of shoe of the present invention has good folding quality.
4, add polyvinyl chloride (PVC) RESINS and butadiene-acrylonitrile rubber combination, can improve the shining surfaces of product, keep not moving back for a long time mist, strengthen the aesthetic measure of product.
Embodiment
The following examples are to describe in further detail of the present invention:
Embodiment 1
1.1 oil-proof anti-skid sole material weight part forms
1.2 preparation method
(1) butadiene acrylonitrile rubber, cis-butadiene cement, white carbon black, glycol ether, white oil, zinc oxide, stearic acid, dispersion agent, promotor, anti-aging agent, RX-80 and polyvinyl chloride (PVC) RESINS are obtained mixture according to the certain part by weight mixing and stirring;
(2) mixture is joined in Banbury mixer, at 145 ℃～150 ℃ lower banburying 12～15min, obtain the banburying mixture;
(3) the banburying mixture is joined in screw extrusion press, carry out melt blending, granulation under 110 ℃～150 ℃;
(4) particle is joined in mill mix, then mold pressing makes the oil-proof anti-skid sole material.
1.3 the performance of oil-proof anti-skid sole material
1, oil resistance
Adopt the EN-345 international standard to carry out oil resistant test to the oil-proof anti-skid sole material that embodiment 1 prepares.
Soaked 22 hours in the octane-iso oil of 50 ℃, its cubical expansivity is less than 13%.
2, non-skid property
Adopt JAMES on-slip tester, the material for sole of shoe of test implementation example 1 preparation and the frictional coefficient of smooth ceramic tile surface are pressed the test of ASTM-F489 international standard, and result is as follows:
In the dry type situation: 1.0
In the wet type situation: 0.65
In oil formula situation: 0.30
In the wet oil situation: 0.40
3, folding quality
According to GB G B/T3903.1-2008 " footwear universal test method folding quality ", get 50 ° ± 1 ° of angle of flexure, subdue frequency (230 ± 10) inferior/mi n, pre-scarfing 5mm under temperature (23 ± 2) ℃ condition, subdues 40,000 times continuously.
Material for sole of shoe to embodiment 1 preparation is tested as stated above, gets scarfing extension length 8.8mm, without new crackle.
Embodiment 2
2.1 oil-proof anti-skid sole material weight part forms
2.2 preparation method
The preparation method is with embodiment 1.
2.3 the performance of oil-proof anti-skid sole material
1, oil resistance
Adopt the EN-345 international standard to carry out oil resistant test to the oil-proof anti-skid sole material that embodiment 2 prepares.
Soaked 22 hours in the octane-iso oil of 50 ℃, its cubical expansivity is less than 11%.
2, non-skid property
Adopt JAMES on-slip tester, the material for sole of shoe of test implementation example 2 preparations and the frictional coefficient of smooth ceramic tile surface are pressed the test of ASTM-F489 international standard, and result is as follows:
In the dry type situation: 1.15
In the wet type situation: 0.75
In oil formula situation: 0.45
In the wet oil situation: 0.50
3, folding quality
According to GB G B/T3903.1-2008 " footwear universal test method folding quality ", get 50 ° ± 1 ° of angle of flexure, subdue frequency (230 ± 10) inferior/mi n, pre-scarfing 5mm under temperature (23 ± 2) ℃ condition, subdues 40,000 times continuously.
Material for sole of shoe to embodiment 2 preparations is tested as stated above, gets scarfing extension length 8.6mm, without new crackle.
Embodiment 3
3.1 oil-proof anti-skid sole material weight part forms
3.2 preparation method
The preparation method is with embodiment 1.
3.3 the performance of oil-proof anti-skid sole material
1, oil resistance
Adopt the EN-345 international standard to carry out oil resistant test to the oil-proof anti-skid sole material that embodiment 3 prepares.
Soaked 22 hours in the octane-iso oil of 50 ℃, its cubical expansivity is less than 10%.
2, non-skid property
Adopt JAMES on-slip tester, the material for sole of shoe of test implementation example 3 preparations and the frictional coefficient of smooth ceramic tile surface are pressed the test of ASTM-F489 international standard, and result is as follows:
In the dry type situation: 1.30
In the wet type situation: 0.80
In oil formula situation: 0.50
In the wet oil situation: 0.65
3, folding quality
According to GB G B/T3903.1-2008 " footwear universal test method folding quality ", get 50 ° ± 1 ° of angle of flexure, subdue frequency (230 ± 10) inferior/mi n, pre-scarfing 5mm under temperature (23 ± 2) ℃ condition, subdues 40,000 times continuously.
Material for sole of shoe to embodiment 3 preparations is tested as stated above, gets scarfing extension length 8.1mm, without new crackle.
Embodiment 4
4.1 oil-proof anti-skid sole material weight part forms
4.2 preparation method
The preparation method is with embodiment 1.
4.3 the performance of oil-proof anti-skid sole material
1, oil resistance
Adopt the EN-345 international standard to carry out oil resistant test to the oil-proof anti-skid sole material that embodiment 4 prepares.
Soaked 22 hours in the octane-iso oil of 50 ℃, its cubical expansivity is less than 12%.
2, non-skid property
Adopt JAMES on-slip tester, the material for sole of shoe of test implementation example 4 preparations and the frictional coefficient of smooth ceramic tile surface are pressed the test of ASTM-F489 international standard, and result is as follows:
In the dry type situation: 1.08
In the wet type situation: 0.63
In oil formula situation: 0.32
In the wet oil situation: 0.44
3, folding quality
According to GB G B/T3903.1-2008 " footwear universal test method folding quality ", get 50 ° ± 1 ° of angle of flexure, subdue frequency (230 ± 10) inferior/mi n, pre-scarfing 5mm under temperature (23 ± 2) ℃ condition, subdues 40,000 times continuously.
Material for sole of shoe to embodiment 4 preparations is tested as stated above, gets scarfing extension length 8.7mm, without new crackle.
Although illustrated and described embodiments of the invention, for the ordinary skill in the art, be appreciated that without departing from the principles and spirit of the present invention and can carry out multiple variation, modification, replacement and modification to these embodiment, scope of the present invention is limited by claims and equivalent thereof.
Claims (8)
1. oil-proof anti-skid sole material, it is characterized in that: this material is comprised of butadiene acrylonitrile rubber, cis-butadiene cement, white carbon black, glycol ether, white oil, zinc oxide, stearic acid, dispersion agent, promotor, anti-aging agent, RX-80 and polyvinyl chloride (PVC) RESINS.
2. a kind of oil-proof anti-skid sole material as claimed in claim 1, it is characterized in that: the weight part of this material consists of:
3. a kind of oil-proof anti-skid sole material as claimed in claim 1, it is characterized in that: the weight part of this material consists of:
4. a kind of oil-proof anti-skid sole material as claimed in claim 1, it is characterized in that: the weight part of this material consists of:
5. a kind of oil-proof anti-skid sole material as described in claim 1-4 any one claim, it is characterized in that: dispersion agent is PEG.
6. a kind of oil-proof anti-skid sole material as described in claim 1-4 any one claim, it is characterized in that: promotor is altax.
7. a kind of oil-proof anti-skid sole material as described in claim 1-4 any one claim, it is characterized in that: anti-aging agent is anti-aging agent RD.
8. method for preparing as the described a kind of oil-proof anti-skid sole of claim 1-7 any one claim, it is characterized in that: the method comprises the following steps:
(1) butadiene acrylonitrile rubber, cis-butadiene cement, white carbon black, glycol ether, white oil, zinc oxide, stearic acid, dispersion agent, promotor, anti-aging agent, RX-80 and polyvinyl chloride (PVC) RESINS are obtained mixture according to the certain part by weight mixing and stirring;
(2) mixture is joined in Banbury mixer, at 145 ℃～150 ℃ lower banburying 12～15min, obtain the banburying mixture;
(3) the banburying mixture is joined in screw extrusion press, carry out melt blending, granulation under 110 ℃～150 ℃;
(4) particle is joined in mill mix, then mold pressing makes the oil-proof anti-skid sole material.
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| CN2013101268658A CN103159993A (en) | 2013-04-03 | 2013-04-03 | Oil-resistant non-skid sole material and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104544720A (en) * | 2014-11-17 | 2015-04-29 | 中国人民解放军总后勤部军需装备研究所 | Oil-resistant anti-static-electricity rubber/EVA (ethylene-vinyl acetate copolymer) sole recipe as well as preparing method and application thereof |
| CN104710658A (en) * | 2013-12-16 | 2015-06-17 | 天津市星兴橡胶制品有限公司 | Antislip rubber sole material |
| CN105440341A (en) * | 2015-12-14 | 2016-03-30 | 桐乡市亿源鞋业有限公司 | Anti-skid sole material |
| CN105837880A (en) * | 2016-06-17 | 2016-08-10 | 谭丽娜 | Oil-resistant rubber cup material for automotive hydraulic brake and preparation method thereof |
| CN106317506A (en) * | 2016-08-24 | 2017-01-11 | 际华三五三实业有限公司 | Anti-skid and oil-resistant rubber soles with dual density |
| CN107964140A (en) * | 2017-12-08 | 2018-04-27 | 温州市成城鞋材有限公司 | A kind of good rubber soles of brightness |
| CN109096558A (en) * | 2018-07-30 | 2018-12-28 | 泉州鑫泰鞋材有限公司 | A kind of oil-resisting antistatic material and its production technology |
| CN110551330A (en) * | 2019-07-25 | 2019-12-10 | 福建省莆田市联盛鞋业有限公司 | high-temperature-resistant rubber sole and processing method thereof |
| CN112778588A (en) * | 2021-01-26 | 2021-05-11 | 广州群道生物科技有限公司 | Preparation method and application of oil-water anti-slip rubber material |
| CN114426708A (en) * | 2020-10-09 | 2022-05-03 | 中国石油化工股份有限公司 | Rubber composition based on nitrile rubber and butadiene rubber, application of rubber composition, vulcanized rubber, preparation method of vulcanized rubber and application of vulcanized rubber |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710658A (en) * | 2013-12-16 | 2015-06-17 | 天津市星兴橡胶制品有限公司 | Antislip rubber sole material |
| CN104544720A (en) * | 2014-11-17 | 2015-04-29 | 中国人民解放军总后勤部军需装备研究所 | Oil-resistant anti-static-electricity rubber/EVA (ethylene-vinyl acetate copolymer) sole recipe as well as preparing method and application thereof |
| CN105440341A (en) * | 2015-12-14 | 2016-03-30 | 桐乡市亿源鞋业有限公司 | Anti-skid sole material |
| CN105837880A (en) * | 2016-06-17 | 2016-08-10 | 谭丽娜 | Oil-resistant rubber cup material for automotive hydraulic brake and preparation method thereof |
| CN106317506A (en) * | 2016-08-24 | 2017-01-11 | 际华三五三实业有限公司 | Anti-skid and oil-resistant rubber soles with dual density |
| CN106317506B (en) * | 2016-08-24 | 2018-07-27 | 际华三五一三实业有限公司 | A kind of anti-skidding and oil resistant dual-density rubber sole |
| CN107964140A (en) * | 2017-12-08 | 2018-04-27 | 温州市成城鞋材有限公司 | A kind of good rubber soles of brightness |
| CN109096558A (en) * | 2018-07-30 | 2018-12-28 | 泉州鑫泰鞋材有限公司 | A kind of oil-resisting antistatic material and its production technology |
| CN110551330A (en) * | 2019-07-25 | 2019-12-10 | 福建省莆田市联盛鞋业有限公司 | high-temperature-resistant rubber sole and processing method thereof |
| CN114426708A (en) * | 2020-10-09 | 2022-05-03 | 中国石油化工股份有限公司 | Rubber composition based on nitrile rubber and butadiene rubber, application of rubber composition, vulcanized rubber, preparation method of vulcanized rubber and application of vulcanized rubber |
| CN114426708B (en) * | 2020-10-09 | 2023-11-10 | 中国石油化工股份有限公司 | Rubber composition based on nitrile rubber and butadiene rubber, application thereof, vulcanized rubber, and preparation method and application thereof |
| CN112778588A (en) * | 2021-01-26 | 2021-05-11 | 广州群道生物科技有限公司 | Preparation method and application of oil-water anti-slip rubber material |
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Application publication date: 20130619 |