CN103147299A - Method for producing fabric for antifouling mosquito-repellent terylene and nylon interweaving mesh shoe - Google Patents
Method for producing fabric for antifouling mosquito-repellent terylene and nylon interweaving mesh shoe Download PDFInfo
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- CN103147299A CN103147299A CN2013100982636A CN201310098263A CN103147299A CN 103147299 A CN103147299 A CN 103147299A CN 2013100982636 A CN2013100982636 A CN 2013100982636A CN 201310098263 A CN201310098263 A CN 201310098263A CN 103147299 A CN103147299 A CN 103147299A
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Abstract
The invention relates to a method for producing a fabric for an antifouling mosquito-repellent terylene and nylon interweaving mesh shoe. The method comprises the following steps of: selecting terylene and nylon interweaving mesh woven fabric structure and raw materials, weaving the fabric, removing oil stains on the fabric, preparing an antifouling working solution, performing antifouling functional finishing, performing oven drying, drying, preparing a mosquito-repellent finishing working solution, performing mosquito-repellent finishing and performing oven drying. The fabric produced by the method is used on vamps, is breathable and cool, has antifouling and mosquito-repellent functions, is easy to clean after being contaminated and can repel mosquitoes.
Description
Technical field
The invention belongs to the manufacturing field of fabric, particularly a kind of antifouling mosquito repellent polyester polyamide manufacture method of mesh shoe fabric that interweaves.
Background technology
The terylene mesh fabric has ventilative, cooling function, is widely used in the vamp fabric.But the terylene mesh fabric is due to the existence in a large amount of holes of cloth cover gap, clean difficulty after polluting large, mosquito easily bites human body by mesh simultaneously, causes the itch puzzlement, particularly in the situation that in the outdoor sports in summer human body do not wear socks, more easily cause bite by mosquitos and itch situation.
Therefore, to polyester polyamide interweave mesh fabric appendix anti-pollution function and function of driving mosquitoes, for solving the existence of mesh fabric due to a large amount of holes of cloth cover gap, clean difficulty after polluting large, mosquito easily bites human body by mesh simultaneously, causes the itch puzzlement significant.Simultaneously, can improve the interweave surcharge of mesh fabric of polyester polyamide, improve the economic benefit of product.
Summary of the invention
Technical problem to be solved by this invention is to provide the interweave manufacture method of mesh shoe fabric of a kind of antifouling mosquito repellent polyester polyamide, the shoe fabric that the method prepares has can antifouling function of driving mosquitoes, easily clean after polluting, can mosquito repellent, be with a wide range of applications.
The interweave manufacture method of mesh shoe fabric of antifouling mosquito repellent polyester polyamide, comprise following thinking, during design mesh fabric tissue, in fabric, mesh diminishes from the inside to surface gradually, on the one hand can guarantee that still air-flow is normally unimpeded, can alleviate dirt on the other hand, foreign material go deep into the fabric nexine; Fabric is carried out soil resistant finish, after fabric pollutes, easily clean; Fabric is carried out mosquito repellent arrange, the mosquito repellent smell that utilizes the mosquito repellent finishing agent to discharge stops mosquito to get involved fabric.
For the effect that realizes that in fabric, mesh diminishes from the inside to surface gradually, fabric outer adopts the thicker yarn of line density, and middle level and nexine adopt the thinner yarn of line density.
In order to make fabric obtain anti-pollution function and function persistence, adopt modification organo-fluorine polymer finishing technique, can give fabric face with protective layer, thereby make fabric have anti-pollution function.Adopt simultaneously the modification organo-fluorine polymer, make it have the perfluorinate side group.Polymer backbone main chain itself is not fluorine-containing, but the carrier of polymer key character, it affects the formation of polymer film, the hardness of film and the fastness on textile substrates.Reactivity side group is fixed on polymer on matrix, makes polymer have washing fastness.Organo-fluorine polymer can be reduced to the degree that water and spot can not infiltrate and penetrate fiber to fabric face.The best finishing effect of this effect is embodied in organo-fluorine polymer and can forms seamless invisible diaphragm, and this tunic gets up fibers encapsulation.Simultaneously, composite with organo-fluorine polymer and acrylic resin for further more protection film thickness and intensity, make the anti-pollution function finishing agent.For further more protection film water is washed fastness, by crosslinking agent and the effect of end-blocked isocyanates promoter, make diaphragm and fiber strong bonded.
In order to make fabric obtain function of driving mosquitoes and function persistence, preparation mosquito repellent housekeeping liquid, select with the inner textile layer POLYAMIDE YARNS certain chemically combined mosquito repellent finishing agent and environment friendly non-halogen element are arranged, formaldehydeless, heavy metal free, film forming is thin soft, and the acrylic crosslinking agent of crosslinked at low temperature and water carry out composite, to increase fastness to washing and the lasting medicine of mosquito repellent fabric.
Based on above thinking, the invention provides the interweave manufacture method of mesh shoe fabric of a kind of antifouling mosquito repellent polyester polyamide, comprise select polyester polyamide interweave the mesh fabric institutional framework, select the steps such as raw material and fabric knitting, fabric washing oil, the preparation of anti-pollution function finishing agent, the preparation of antifouling working solution, anti-pollution function arrange, dry, bake, the preparation of mosquito repellent housekeeping liquid, mosquito repellent arrangement, oven dry.Wherein said select polyester polyamide interweave the mesh fabric institutional framework, to select raw material and fabric knitting be to select three combs through netting ocular tissue structure, fabric outer raw material 150-250D terylene thread, fabric middle level raw material 50-100D terylene thread, fabric nexine raw material 50-100D POLYAMIDE YARNS, the braiding mesh fabric; Washing oil is the greasy dirt on laundering of textile fabrics, improves presentation quality and the anti-pollution function finishing agent fastness of fabric; Anti-pollution function finishing agent preparation is to mix with modification organic fluorine waterproof agent and acrylic resin, makes into that thickness, fastness are high, the functional finishing agent of stretch-proof; Antifouling working solution preparation is to add entry, anti-pollution function finishing agent in container, and further adds crosslinking agent, promoter, bleeding agent, makes composite anti-pollution function housekeeping liquid, further improves the anti-pollution function finishing effect; It is to soak two with common two to roll padding mangles fabric is arranged that anti-pollution function arranges; Baking is fabric high-temperature process certain hour in common baker with after oven dry, promotes the further polymeric adsorbent of fabric, resin solidification and auxiliary agent further to react, and realizes best finishing effect; The preparation of mosquito repellent housekeeping liquid is to select with the inner textile layer POLYAMIDE YARNS certain chemically combined mosquito repellent finishing agent and environment friendly non-halogen element are arranged, formaldehydeless, heavy metal free, film forming is thin soft, the acrylic crosslinking agent of crosslinked at low temperature and water carry out composite, to increase fastness to washing and the lasting medicine of mosquito repellent fabric; It is to adopt infusion process that fabric is arranged at normal temperatures that mosquito repellent arranges, at last with fabric dehydration, oven dry.
The interweave manufacture method of mesh shoe fabric of a kind of antifouling mosquito repellent polyester polyamide of the present invention comprises:
(1) with three combs through netting ocular tissue structure, fabric outer raw material 150-250D terylene thread, fabric middle level raw material 50-100D terylene thread, inner textile layer raw material 50-100D POLYAMIDE YARNS;
(2) fabric is cleaned, with finish and the spot of removing fiber surface, clean complete rear dehydration;
(3) be that the modification organic fluorine waterproof agent of 70-90% and the acrylic resin of 20-40% mix with percentage by weight, stir, obtain the anti-pollution function finishing agent;
(4) preparation anti-pollution function housekeeping liquid;
(5) fabric two is soaked two and rolls fabric is carried out padding finishing in anti-pollution function housekeeping liquid, pick-up is 50-70%, then oven dry;
(6) with textile impregnation mosquito repellent housekeeping liquid, dehydration after dipping is completed, oven dry namely gets the antifouling mosquito repellent polyester polyamide mesh shoe fabric that interweaves.
In described step (2), cleaning temperature is 60-80 ℃, and scavenging period is 20-30min, and dewatering time is 3-5min.
In described step (2), every processing 100kg fabric cleaning fluid component is: 500-600g emulsifying agent E1300(Nantong Hensel specialization work Co., Ltd), and 100-150g sheet alkali (the large negotiation trade of Wuxi City Co., Ltd) and 3000-3800kg water.
In described step (3), the agent of modification organic fluorine waterproof is AG-710 modification organic fluorine waterproof agent (Changzhou Chemical Research Industry Co., Ltd.), and acrylic resin is DT-150 water-soluble solid acrylic resin (Xi'an Great Sky Science ﹠ Technology Co., Ltd.).
In described step (3), mixing temperature is 50-60 ℃, and mixing time is 20-30min.
In described step (4), anti-pollution function housekeeping formula of liquid is:
During preparation anti-pollution function housekeeping liquid, each component mixing temperature is 50-60 ℃, and mixing time is 20-30min, namely gets anti-pollution function housekeeping liquid.
Melamine resin can react with the organic fluorine waterproof agent as crosslinking agent, forms tridimensional network at fiber surface, and the attenuation of waterproofing agent rete is obstructed; MgCl
26H
2O can emit proton and carry out catalysis as the slaine homogeneous catalyst when high temperature, so that methylol reaction in the crosslinked resin molecule reaches cross-linking effect; End-blocked isocyanates plays the promoter effect, can strengthen the fastness of protecting film; Isopropyl alcohol is mainly in order to prevent that waterproofing agent from producing gathering in dressing liquid, reach the effect of steady seepage.
In described step (5), to need anti-pollution function housekeeping liquid weight be 50-70kg to every 100kg fabric.
In described step (5), oven dry is for first drying fabric under 95-105 ℃ of condition, then the fabric after drying is placed in baker, at 150-160 ℃ of Temperature Treatment 1-3min, promote the further polymeric adsorbent of fabric, resin solidification and auxiliary agent further to react, realize best finishing effect.
Every processing 100kg fabric in described step (6), mosquito repellent housekeeping liquid consumption 1300-1500kg, mosquito repellent housekeeping fluid component is: weight ratio is (3-5): (3-50): (100-130) mosquito repellent finishing agent, acrylic crosslinking agent and water will fully stir evenly during preparation.
The model of described mosquito repellent finishing agent is to spin chemical inc in FK-812(Beijing), the acrylic crosslinking agent model is to spin chemical inc in FK-807(Beijing).
In described step (6), dewatering time is 2-3min, and bake out temperature is 40-60 ℃.
In the present invention, if not refer in particular to, all raw materials and equipment all can be buied from market, the conventional method in field under the compound method of each finishing agent all adopts.
Beneficial effect
(1) fabric of the present invention preparation is used for vamp, and is ventilative nice and cool, has antifouling function of driving mosquitoes, easily cleans after polluting, can mosquito repellent;
(2) fabric of the present invention's preparation is more antifouling than ordinary polyester mesh shoe fabric, function of driving mosquitoes good, has a wide range of applications.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used for explanation the present invention and be not used in and limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.
Embodiment 1
1, select three combs through netting ocular tissue structure, fabric outer raw material 150D terylene thread, fabric middle level raw material 50D terylene thread, fabric nexine raw material 50D POLYAMIDE YARNS, braiding mesh fabric.
2, fabric is put into common impregnating mangle and cleaned, with finish and the spot of removing fiber surface, 60 ℃ of cleaning temperatures, scavenging period 30min, the formula of every processing 100kg fabric cleaning liquid is:
Emulsifying agent E1300 500g
Sheet alkali 100g
Water 3000kg
Clean complete with the fabric 3min that dewaters.
3, the agent of modification organic fluorine waterproof and acrylic resin are put in container, stirred 30min under 50 ℃ of temperature conditions, make the anti-pollution function finishing agent, the percentage by weight formula of the agent of modification organic fluorine waterproof and acrylic resin is:
AG-710 modification organic fluorine waterproof agent 70%
DT-150 water-soluble solid acrylic resin 30%.
4, add entry, anti-pollution function finishing agent in container, and further add crosslinking agent, promoter, bleeding agent, stir 30min under 50 ℃ of temperature conditions, make composite anti-pollution function housekeeping liquid, further improve the anti-pollution function finishing effect, the volumetric concentration formula of each component of anti-pollution function housekeeping liquid is:
5, soak two with common two and roll padding mangles fabric is carried out padding finishing, pick-up 50%, padding finishing is complete dries fabric at 95 ℃ of temperature.
6, the fabric after drying is placed in common baker, processes 1min under 160 ℃ of high temperature, promotes the further polymeric adsorbent of fabric, resin solidification and auxiliary agent further to react, and realizes best finishing effect.
7, preparation mosquito repellent housekeeping liquid, each constituent weight ratio of mosquito repellent housekeeping liquid is FK-812 mosquito repellent finishing agent: FK-807 acrylic crosslinking agent: water=3:3:100 will fully stir evenly during preparation.
8, in common impregnating mangle to textile impregnation mosquito repellent housekeeping liquid, every processing 100kg fabric, mosquito repellent housekeeping liquid consumption 1300kg, dipping are finished fabric dehydration 2min, at last fabric are dried at 40 ℃ of temperature.
Embodiment 2
1, select three combs through netting ocular tissue structure, fabric outer raw material 200D terylene thread, fabric middle level raw material 75D terylene thread, fabric nexine raw material 75D POLYAMIDE YARNS, braiding mesh fabric.
2, fabric is put into common impregnating mangle and cleaned, with finish and the spot of removing fiber surface, 70 ℃ of cleaning temperatures, scavenging period 25min, the formula of every processing 100kg fabric cleaning liquid is:
Emulsifying agent E1300 550g
Sheet alkali 130g
Water 3500kg
Clean complete with the fabric 4min that dewaters.
3, the agent of modification organic fluorine waterproof and acrylic resin are put in container, stirred 25min under 55 ℃ of temperature conditions, make the anti-pollution function finishing agent, the percentage by weight formula of the agent of modification organic fluorine waterproof and acrylic resin is:
AG-710 modification organic fluorine waterproof agent 80%
DT-150 water-soluble solid acrylic resin 20%.
4, add entry, anti-pollution function finishing agent in container, and further add crosslinking agent, promoter, bleeding agent, stir 25min under 55 ℃ of temperature conditions, make composite anti-pollution function housekeeping liquid, further improve the anti-pollution function finishing effect, the volumetric concentration formula of each component of anti-pollution function housekeeping liquid is:
5, soak two with common two and roll padding mangles fabric is carried out padding finishing, pick-up 60%, padding finishing is complete dries fabric at 100 ℃ of temperature.
6, the fabric after drying is placed in common baker, processes 2min under 155 ℃ of high temperature, promotes the further polymeric adsorbent of fabric, resin solidification and auxiliary agent further to react, and realizes best finishing effect.
7, preparation mosquito repellent housekeeping liquid, each constituent weight ratio of mosquito repellent housekeeping liquid is FK-812 mosquito repellent finishing agent:
FK-807 acrylic crosslinking agent: water=4:4:120 will fully stir evenly during preparation.
8, in common impregnating mangle to textile impregnation mosquito repellent housekeeping liquid, every processing 100kg fabric, mosquito repellent housekeeping liquid consumption 1400kg, dipping are finished fabric dehydration 2.5min, at last fabric are dried at 50 ℃ of temperature.
Embodiment 3
1, select three combs through netting ocular tissue structure, fabric outer raw material 250D terylene thread, fabric middle level raw material 100D terylene thread, fabric nexine raw material 100D POLYAMIDE YARNS, braiding mesh fabric.
2, fabric is put into common impregnating mangle and cleaned, with finish and the spot of removing fiber surface, 80 ℃ of cleaning temperatures, scavenging period 20min, the formula of every processing 100kg fabric cleaning liquid is:
Emulsifying agent E1300 600g
Sheet alkali 150g
Water 3800kg
Clean complete with the fabric 5min that dewaters.
3, the agent of modification organic fluorine waterproof and acrylic resin are put in container, stirred 20min under 60 ℃ of temperature conditions, make the anti-pollution function finishing agent, the percentage by weight formula of the agent of modification organic fluorine waterproof and acrylic resin is:
AG-710 modification organic fluorine waterproof agent 90%
DT-150 water-soluble solid acrylic resin 10%.
4, add entry, anti-pollution function finishing agent in container, and further add crosslinking agent, promoter, bleeding agent, stir 20min under 60 ℃ of temperature conditions, make composite anti-pollution function housekeeping liquid, further improve the anti-pollution function finishing effect, the volumetric concentration formula of each component of anti-pollution function housekeeping liquid is:
5, soak two with common two and roll padding mangles fabric is carried out padding finishing, pick-up 70%, padding finishing is complete dries fabric at 105 ℃ of temperature.
6, the fabric after drying is placed in common baker, processes 3min under 150 ℃ of high temperature, promotes the further polymeric adsorbent of fabric, resin solidification and auxiliary agent further to react, and realizes best finishing effect.
7, preparation mosquito repellent housekeeping liquid, each constituent weight ratio of mosquito repellent housekeeping liquid is FK-812 mosquito repellent finishing agent: FK-807 acrylic crosslinking agent: water=5:5:130 will fully stir evenly during preparation.
8, in common impregnating mangle to textile impregnation mosquito repellent housekeeping liquid, every processing 100kg fabric, mosquito repellent housekeeping liquid consumption 1500kg, dipping are finished fabric dehydration 3min, at last fabric are dried at 60 ℃ of temperature.
The antifouling mosquito repellent polyester polyamide that makes with the inventive method interweave the mesh shoe fabric and existing ordinary polyester mesh shoe fabric performance as shown in table 1:
Table 1
By as seen from Table 1 upper, sample of the present invention is more antifouling than ordinary polyester mesh shoe fabric, function of driving mosquitoes good, has a wide range of applications.
Claims (10)
1. the antifouling mosquito repellent polyester polyamide manufacture method of mesh shoe fabric that interweaves comprises:
(1) with three combs through netting ocular tissue structure, fabric outer raw material 150-250D terylene thread, fabric middle level raw material 50-100D terylene thread, inner textile layer raw material 50-100D POLYAMIDE YARNS;
(2) fabric is cleaned, clean complete rear dehydration;
(3) be that the modification organic fluorine waterproof agent of 70-90% and the acrylic resin of 20-40% mix with percentage by weight, stir, obtain the anti-pollution function finishing agent;
(4) preparation anti-pollution function housekeeping liquid;
(5) fabric two is soaked two and rolls fabric is carried out padding finishing in anti-pollution function housekeeping liquid, pick-up is 50-70%, then oven dry;
(6) with textile impregnation mosquito repellent housekeeping liquid, dehydration after dipping is completed, oven dry namely gets the antifouling mosquito repellent polyester polyamide mesh shoe fabric that interweaves.
2. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (2), cleaning temperature is 60-80 ℃, and scavenging period is 20-30min, and dewatering time is 3-5min.
3. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (2), every processing 100kg fabric cleaning fluid component is: 500-600g emulsifying agent E1300,100-150g sheet alkali and 3000-3800kg water.
4. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (3), the agent of modification organic fluorine waterproof is the agent of AG-710 modification organic fluorine waterproof, and acrylic resin is DT-150 water-soluble solid acrylic resin; Mixing temperature is 50-60 ℃, and mixing time is 20-30min.
5. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (4), anti-pollution function housekeeping formula of liquid is:
6. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves is characterized in that: in described step (5), to need anti-pollution function housekeeping liquid weight be 50-70kg to every 100kg fabric.
7. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (5), oven dry is for first drying fabric under 95-105 ℃ of condition, then the fabric after drying is placed in baker, at 150-160 ℃ of Temperature Treatment 1-3min.
8. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: every processing 100kg fabric in described step (6), mosquito repellent housekeeping liquid consumption 1300-1500kg, mosquito repellent housekeeping fluid component is: weight ratio is (3-5): (3-50): (100-130) mosquito repellent finishing agent, acrylic crosslinking agent and water.
9. a kind of antifouling mosquito repellent polyester polyamide according to claim 8 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: the model of described mosquito repellent finishing agent is FK-812, the acrylic crosslinking agent model is FK-807.
10. a kind of antifouling mosquito repellent polyester polyamide according to claim 1 manufacture method of mesh shoe fabric that interweaves, it is characterized in that: in described step (6), dewatering time is 2-3min, and bake out temperature is 40-60 ℃.
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Cited By (10)
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| CN103976510A (en) * | 2014-05-30 | 2014-08-13 | 谢松芬 | Outdoor mosquito repellent shoes |
| CN104195816A (en) * | 2014-06-24 | 2014-12-10 | 沛县海情纺织有限责任公司 | Preparation technology for mosquito-repelling textile |
| CN104562646A (en) * | 2015-01-05 | 2015-04-29 | 广东德美精细化工股份有限公司 | Finishing method capable of improving durable waterproof function of chinlon fabric |
| CN105671940A (en) * | 2016-03-25 | 2016-06-15 | 宁波大千纺织品有限公司 | Polyester or blended fabric long-acting mosquito-repellent knitted fabric and making method thereof |
| CN108374284A (en) * | 2018-04-04 | 2018-08-07 | 石狮市三益织造染整有限公司 | A kind of water-proof finish technique of dacron |
| CN108998968A (en) * | 2018-06-28 | 2018-12-14 | 东莞市喜宝体育用品科技有限公司 | A kind of mould proof deodorizing antibiotic of gushet waterproof flies to knit vamp and its manufacture craft |
| CN109385904A (en) * | 2018-09-27 | 2019-02-26 | 常州旭荣针织印染有限公司 | Knitting fabric and preparation method thereof with three proofings and aromatic function |
| CN110344246A (en) * | 2019-08-01 | 2019-10-18 | 疏博（上海）纳米科技有限公司 | A kind of production method of the sun-proof mosquito-proof cool feeling fabric of all band |
| CN111155310A (en) * | 2020-01-15 | 2020-05-15 | 东莞市鸿运纺织助剂有限公司 | Water-proof and oil-proof finishing agent |
| WO2024055341A1 (en) * | 2022-09-14 | 2024-03-21 | 浙江泰斯德电气有限公司 | Coating for finishing fiber fabric, as well as use method thereof |
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| CN110344246A (en) * | 2019-08-01 | 2019-10-18 | 疏博（上海）纳米科技有限公司 | A kind of production method of the sun-proof mosquito-proof cool feeling fabric of all band |
| CN111155310A (en) * | 2020-01-15 | 2020-05-15 | 东莞市鸿运纺织助剂有限公司 | Water-proof and oil-proof finishing agent |
| WO2024055341A1 (en) * | 2022-09-14 | 2024-03-21 | 浙江泰斯德电气有限公司 | Coating for finishing fiber fabric, as well as use method thereof |
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Application publication date: 20130612 |