CN103146164A - 用于快速成型的纳米增韧聚乳酸材料及其制备方法 - Google Patents
用于快速成型的纳米增韧聚乳酸材料及其制备方法 Download PDFInfo
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- CN103146164A CN103146164A CN201310117650XA CN201310117650A CN103146164A CN 103146164 A CN103146164 A CN 103146164A CN 201310117650X A CN201310117650X A CN 201310117650XA CN 201310117650 A CN201310117650 A CN 201310117650A CN 103146164 A CN103146164 A CN 103146164A
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- polylactic acid
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- acid ester
- polyacrylic acid
- microsphere
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- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 60
- 239000000463 material Substances 0.000 title claims abstract description 40
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000004005 microsphere Substances 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 21
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000001125 extrusion Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000005469 granulation Methods 0.000 claims abstract description 7
- 230000003179 granulation Effects 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 5
- -1 poly(lactic acid) Polymers 0.000 claims description 60
- 150000002148 esters Chemical class 0.000 claims description 36
- 229920002125 Sokalan® Polymers 0.000 claims description 33
- 239000004584 polyacrylic acid Substances 0.000 claims description 33
- 238000007493 shaping process Methods 0.000 claims description 11
- 230000007704 transition Effects 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000806 elastomer Substances 0.000 claims description 6
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000010907 mechanical stirring Methods 0.000 claims description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 239000011837 N,N-methylenebisacrylamide Substances 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 2
- 238000007580 dry-mixing Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000002715 modification method Methods 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000010146 3D printing Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 239000004160 Ammonium persulphate Substances 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 235000019395 ammonium persulphate Nutrition 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BUMBHRYBYOQTFV-UHFFFAOYSA-N butyl prop-2-enoate;ethyl prop-2-enoate Chemical compound CCOC(=O)C=C.CCCCOC(=O)C=C BUMBHRYBYOQTFV-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
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CN201310117650.XA CN103146164B (zh) | 2013-04-07 | 2013-04-07 | 用于快速成型的纳米增韧聚乳酸材料及其制备方法 |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103665802A (zh) * | 2013-11-29 | 2014-03-26 | 成都新柯力化工科技有限公司 | 一种用于3d打印的聚乳酸材料的制备方法 |
CN103980410A (zh) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 一种用于3d打印的组合物及其制备方法和制品 |
CN104312119A (zh) * | 2014-11-06 | 2015-01-28 | 芜湖瀚博电子科技有限公司 | 一种秸秆3d打印耗材及其制备方法 |
CN104356619A (zh) * | 2014-11-13 | 2015-02-18 | 常州汉邦工程塑料有限公司 | 一种3d打印机用改性pla材料的制备工艺 |
WO2015169257A1 (en) * | 2014-05-09 | 2015-11-12 | Jf Polymers (Suzhou) Co. Ltd. | Highly crystalline poly (lactic acid) filaments for material-extrusion based additive manufacturing |
WO2016037563A1 (en) * | 2014-09-09 | 2016-03-17 | Jf Polymers (Suzhou) Co., Ltd. | Polymeric composition for use as a temporary support material in extrusion based additive manufacturing |
KR20160033004A (ko) | 2014-09-17 | 2016-03-25 | 에스케이케미칼주식회사 | 3d 인쇄용 폴리유산 수지 조성물 |
US20160185050A1 (en) * | 2013-08-09 | 2016-06-30 | Kimberly-Clark Worldwide, Inc. | Polymeric Material for Three-Dimensional Printing |
CN108096638A (zh) * | 2015-04-07 | 2018-06-01 | 四川蓝光英诺生物科技股份有限公司 | 用于生物打印的生物砖及其用途 |
CN108164945A (zh) * | 2017-12-28 | 2018-06-15 | 诺思贝瑞新材料科技(苏州)有限公司 | 一种具有金属效果的3d打印用改性聚乳酸材料的制备方法 |
CN108178907A (zh) * | 2017-12-28 | 2018-06-19 | 诺思贝瑞新材料科技(苏州)有限公司 | 一种具有金属效果的3d打印用改性聚乳酸材料 |
US10684603B2 (en) | 2015-01-13 | 2020-06-16 | Bucknell University | Dynamically controlled screw-driven extrusion |
WO2021004410A1 (zh) * | 2019-07-08 | 2021-01-14 | 中国水利水电科学研究院 | 一种复合聚酯热熔胶、制备方法及抗冲刷土工布的制备方法 |
CN112898757A (zh) * | 2019-07-03 | 2021-06-04 | 杭州卓普新材料科技有限公司 | 基于硅橡胶微球制备透明增韧聚乳酸材料的方法 |
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CN101541853A (zh) * | 2006-11-21 | 2009-09-23 | 阿科玛股份有限公司 | 用于聚乳酸的半透明以及不透明的抗冲击改性剂 |
CN101605835A (zh) * | 2006-10-20 | 2009-12-16 | 自然工作有限责任公司 | 抗冲改性的聚丙交酯树脂 |
CN101983986A (zh) * | 2010-10-26 | 2011-03-09 | 中国科学院长春应用化学研究所 | 一种透明和增韧的聚乳酸树脂及其制备方法 |
WO2012006297A1 (en) * | 2010-07-08 | 2012-01-12 | Dow Global Technologies Llc | Thermoplastic composition, method of producing the same, and articles made therefrom |
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2013
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CN101605835A (zh) * | 2006-10-20 | 2009-12-16 | 自然工作有限责任公司 | 抗冲改性的聚丙交酯树脂 |
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Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
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US10919229B2 (en) * | 2013-08-09 | 2021-02-16 | Kimberly-Clark Worldwide, Inc. | Polymeric material for three-dimensional printing |
US20160185050A1 (en) * | 2013-08-09 | 2016-06-30 | Kimberly-Clark Worldwide, Inc. | Polymeric Material for Three-Dimensional Printing |
CN103665802B (zh) * | 2013-11-29 | 2015-09-02 | 成都新柯力化工科技有限公司 | 一种用于3d打印的聚乳酸材料的制备方法 |
CN103665802A (zh) * | 2013-11-29 | 2014-03-26 | 成都新柯力化工科技有限公司 | 一种用于3d打印的聚乳酸材料的制备方法 |
CN103980410B (zh) * | 2014-04-30 | 2016-02-24 | 中国科学院化学研究所 | 一种用于3d打印的组合物及其制备方法和制品 |
CN103980410A (zh) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | 一种用于3d打印的组合物及其制备方法和制品 |
WO2015169257A1 (en) * | 2014-05-09 | 2015-11-12 | Jf Polymers (Suzhou) Co. Ltd. | Highly crystalline poly (lactic acid) filaments for material-extrusion based additive manufacturing |
WO2015168922A1 (en) * | 2014-05-09 | 2015-11-12 | Jf Polymers (Suzhou) Co. Ltd. | Highly crystalline poly (lactic acid) filaments for material- extrusion based additive manufacturing |
WO2016037563A1 (en) * | 2014-09-09 | 2016-03-17 | Jf Polymers (Suzhou) Co., Ltd. | Polymeric composition for use as a temporary support material in extrusion based additive manufacturing |
CN107109035A (zh) * | 2014-09-09 | 2017-08-29 | 苏州聚复高分子材料有限公司 | 在基于挤出的增材制造中用作临时支撑材料的共混聚合物 |
CN107109035B (zh) * | 2014-09-09 | 2020-04-10 | 苏州聚复高分子材料有限公司 | 在基于挤出的增材制造中用作临时支撑材料的共混聚合物 |
US10246799B2 (en) | 2014-09-17 | 2019-04-02 | Sk Chemicals Co., Ltd. | Polylactic acid resin composition for 3D printing |
KR20160033004A (ko) | 2014-09-17 | 2016-03-25 | 에스케이케미칼주식회사 | 3d 인쇄용 폴리유산 수지 조성물 |
CN104312119A (zh) * | 2014-11-06 | 2015-01-28 | 芜湖瀚博电子科技有限公司 | 一种秸秆3d打印耗材及其制备方法 |
CN104356619A (zh) * | 2014-11-13 | 2015-02-18 | 常州汉邦工程塑料有限公司 | 一种3d打印机用改性pla材料的制备工艺 |
US10684603B2 (en) | 2015-01-13 | 2020-06-16 | Bucknell University | Dynamically controlled screw-driven extrusion |
CN108096638A (zh) * | 2015-04-07 | 2018-06-01 | 四川蓝光英诺生物科技股份有限公司 | 用于生物打印的生物砖及其用途 |
CN108178907A (zh) * | 2017-12-28 | 2018-06-19 | 诺思贝瑞新材料科技(苏州)有限公司 | 一种具有金属效果的3d打印用改性聚乳酸材料 |
CN108164945A (zh) * | 2017-12-28 | 2018-06-15 | 诺思贝瑞新材料科技(苏州)有限公司 | 一种具有金属效果的3d打印用改性聚乳酸材料的制备方法 |
CN112898757A (zh) * | 2019-07-03 | 2021-06-04 | 杭州卓普新材料科技有限公司 | 基于硅橡胶微球制备透明增韧聚乳酸材料的方法 |
CN112898757B (zh) * | 2019-07-03 | 2022-06-07 | 杭州卓普新材料科技有限公司 | 基于硅橡胶微球制备透明增韧聚乳酸材料的方法 |
WO2021004410A1 (zh) * | 2019-07-08 | 2021-01-14 | 中国水利水电科学研究院 | 一种复合聚酯热熔胶、制备方法及抗冲刷土工布的制备方法 |
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