CN103113135A - Microbead-like dry granules, as well as preparation method and application thereof - Google Patents
Microbead-like dry granules, as well as preparation method and application thereof Download PDFInfo
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- CN103113135A CN103113135A CN2013100434129A CN201310043412A CN103113135A CN 103113135 A CN103113135 A CN 103113135A CN 2013100434129 A CN2013100434129 A CN 2013100434129A CN 201310043412 A CN201310043412 A CN 201310043412A CN 103113135 A CN103113135 A CN 103113135A
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- dry granular
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Abstract
The invention belongs to a substance for being applied on the surface of a billet for forming a glaze and specifically relates to microbead-like dry granules, as well as a preparation method and an application thereof. The surfaces of the microbead-like dry granules are closed curved surfaces. The preparation method comprises the steps of taking ordinary dry granules or a fused block as raw materials/a raw material and processing through a flame floating method. A dry granular glaze ceramic tile is obtained by applying glaze slip prepared by the microbead-like dry granules on the surface of the billet and then firing. The microbead-like dry granules provided by the invention can greatly improve the specific gravity of the dry granules in a glaze material, the glaze material is good in flowability, and the loss of equipment caused by the irregular crystal dry granules can be further greatly reduced. Glaze spraying, glaze pouring, screen printing and rubber roll printing can be used for production process step of dry granular glaze cloth. The decorative surface of the produced dry granular glaze ceramic tile has a diffusion effect, and the artistic expression is stronger and richer.
Description
Technical field
The invention belongs to and execute at billet surface formation glaze material, be specifically related to a kind of microballon shape dry granular and its preparation method and application.
Background technology
The dry granular glaze is that the ceramic tile of R﹠D and production is decorated new variety, and the glaze of dry granular glaze is dry granular.This vitreous brick pattern texture levels are rich has the effect of inferior light, wear-resisting, anti-skidding, anti-soil, and being praised is the new era of having started the ceramic tile production technology.
Ceramic glaze generally can be by drenching the method clothes such as glaze, glaze spraying, screen printing or rubber roll stamp.
Described pouring glaze refers to glaze slip suction high level tank, by the shock absorption of glaze groove and screen cloth lattice, makes glaze slip evenly cover the surface of base substrate, described pouring glaze glaze slip as waterfall
Described glaze spraying refers to make the glaze slip atomizing be sprayed onto the surface of base substrate with spray gun or atomizer glaze slip.
Described screen painting and glue roller printing refer to spend net or engraving rubber roll according to the pattern of design in advance by transfer printing, and the pore of glaze slip through mesh or rubber roll is transferred on glazed body.
In prior art, the preparation method of common dry granular is as follows: be mixed with compound by proportioning raw materials, then mix with blender, again the compound that fully mixes is added high-temperature calcination melting in Cinker clew furnace, the molten slurry of melting flows in cold water and just becomes frit after shrend, with pulverizer, its pulverizing, screening combination treatment etc. is become common dry granular after the frit oven dry, production craft step is: batching-mixing-melting-shrend-oven dry-pulverizing-screening-mixing.This kind pulverizes, screens with pulverizer the common dry granular that combination treatment obtains, observe with 40 times of magnifying glasses, as shown in Figure 1, can find that 95% common dry granular surface is the section crushed particles, the glaze slip poor fluidity that common dry granular is configured to, therefore all not satisfactory by above any mode cloth.If by drenching the glaze cloth slip shower that can wear and tear, and in billet surface, a large amount of bubbles are arranged after having drenched, to drenching the glaze edge of a knife, damage is arranged; If by the glaze spraying cloth could seriously stop up spray gun or the spraying gas; If adopt the screen painting cloth, need a large amount of stamp-pad ink to improve liquidity in formula, and the easy network blocking of dry granular hole be larger to the half tone equipment loss; If adopt the glue roller printing cloth to the rubber roll serious wear.In order to improve the glaze slip mobility, need to reduce glaze content in glaze slip, repeatedly can complete cloth just need to apply, reduced working efficiency.
Therefore, the cloth of present common dry granular mainly is equipped with stationary liquid by the dry granular broadcast application again and completes.But the dry granular glaze pattern color that this method forms is single, and the pattern stereoeffect is poor, and the uneven surface finish of cloth is undesirable, easily produces surface imperfection.
Summary of the invention
Technical problem to be solved by this invention is dry granular poor fluidity in prior art, and working method is single, and the glazing effect is undesirable, in order to overcome above deficiency, provides a kind of microballon shape dry granular and its preparation method and application.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: the surface of described microballon shape dry granular is closed surface.
Further, the surface of described microballon shape dry granular is sphere.
Further, the granularity of described microballon shape dry granular is 60 ~ 200 orders.
The present invention also provides the preparation method of above-mentioned microballon shape dry granular: described preparation method refers to take common dry granular or frit as raw material, obtains by the processing of flame floating method.
Described flame floating method refers to that the particle of certain particle size floats in flame, the process of softening under the effect of flame and air-flow, melting, pearlization and cooling curing.
Further, described common dry granular or frit are comprised of the component of following weight proportion:
The per-cent sum of above each component is 100%.
Further, Al in component
2O
3Content be 5 ~ 15wt%, guarantee the suitable high temperature viscosity of dry granular, improve row yielding.
Further, the granularity of described common dry granular is 60 ~ 200 orders.
Further, described flame floating method Flame temperature is controlled at 800～1000 ℃.
The present invention also provides a kind of dry granular vitreous brick, and described dry granular vitreous brick is the glaze slip that is made into by above-mentioned microballon shape dry granular, fires acquisition after imposing on the surface of base substrate.
Further, described microballon shape dry granular imposes on the surface of base substrate by drenching glaze, glaze spraying, screen painting or glue roller printing method.
Further, the glaze slip of described pouring glaze comprises the component of following weight proportion:
30 ~ 40 parts of microballon shape dry granulars
15 ~ 25 parts of water-soluble copolymer adhesives
15 ~ 25 parts, water,
The viscosity of described water-soluble copolymer adhesive is 800 ~ 1200mPas.
Further, the glaze slip of described glaze spraying comprises the component of following weight proportion:
20 ~ 40 parts of microballon shape dry granulars
2 ~ 4 parts, Walocel MT 20.000PV tackiness agent
100 parts, water,
The viscosity of described Walocel MT 20.000PV tackiness agent is 30 ~ 100mPas.
Further, the glaze slip of described screen painting comprises the component of following weight proportion:
100 parts of lithographic plate stamp-pad ink
250 ~ 300 parts of microballon shape dry granulars.
If in glaze be common dry granular, in 100 parts of dull and stereotyped stamp-pad ink, the addition of common dry granular can not surpass 200 parts, and solid content descends, and needs repeatedly printing just can complete the cloth of dry granular glaze.
Microballon shape dry granular provided by the invention can greatly improve the proportion of the dry granular in glaze, the glaze good fluidity, and greatly reduced the loss of random crystal dry granular to equipment in the past.Make glaze spraying, drench the production process that glaze, screen painting and glue roller printing all can be used for dry granular glaze cloth.The decorative cover of the dry granular vitreous brick of producing has diffusion effect, and artistic expression is stronger, abundanter.
Description of drawings
Fig. 1 is the photo after in prior art, common dry granular amplifies 40 times;
Fig. 2 is the photo after microballon shape dry granular of the present invention amplifies 40 times.
Embodiment
The preparation of embodiment 1 microballon shape dry granular
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, borax, zinc oxide and cerium oxide, be milled to respectively 200 orders, mix, fired 1.5～2 hours for 1530～1540 ℃, obtain frit through shrend, frit is comprised of the component of following weight proportion:
Frit is made microballon shape dry granular A through the flame floating method in the glass microsphere manufacturing installation, flame temperature is controlled at 900 ℃ of left and right, and the size range of microballon shape dry granular A is 60 ~ 170 orders, and row yielding is 70%, and as shown in Figure 2, the surface of microballon shape dry granular A is sphere.
The preparation of embodiment 2 microballon shape dry granulars
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, zircon, boric acid, zinc oxide, be milled to respectively 200 orders, mix, fired 1.5～2 hours for 1530～1540 ℃, obtain frit through shrend, then being crushed to the 100-200 order through oven dry, i.e. common dry granular, common dry granular is comprised of the component of following weight proportion:
Common dry granular is made microballon shape dry granular B through the flame floating method in the glass microsphere manufacturing installation, flame temperature is controlled at 860 ℃ of left and right, and the granularity of microballon shape dry granular B is the 100-200 order, and row yielding is 95%, and as shown in Figure 2, the surface of microballon shape dry granular B is sphere.
Embodiment 3 screen paintings prepare the dry granular vitreous brick
Be printed on ornamental brick with the glaze slip of the 32T half tone that is provided with pattern with the screen painting for preparing, then fire and obtain the dry granular vitreous brick, decorative pattern is three-dimensional, and effect is rich and varied.
The glaze slip of screen painting comprises the component of following weight proportion:
100 parts of lithographic plate stamp-pad ink
260 parts of microballon shape dry granular B.
Embodiment 4 drenches glaze and prepares the dry granular vitreous brick
Adopt the glaze slip that the straight line slip shower will drench glaze to impose on the brick face, glaze slip proportion is 1.45 ± 5g/ml, and flow velocity is 40 ± 10sec, drenches in the glaze slip of glaze not bubbles and glaze steady flow good, the stable not jag of glaze curtain, and pouring is not producing pin hole and pit on the brick face.The smooth smooth defective that do not have of the glaze of the dry granular vitreous brick of firing.
The glaze slip that drenches glaze comprises the component of following weight proportion:
40 parts of microballon shape dry granulars
24 parts of GRANICER7010
16 parts, water,
The viscosity of GRANICER7010 is about 1000mPas, is purchased from Si Mahuagong (Foshan) company limited.
Embodiment 5 glaze sprayings prepare the dry granular vitreous brick
Adopt Water-cutting type glaze spraying device that the glaze slip of glaze spraying is imposed on the brick face, glaze slip proportion is 1.25 ± 0.05g/ml, flow velocity is 10 ± 2sec, and the glaze slip mobility of glaze spraying is very good, and the glaze slip of glaze spraying is sprayed on the smooth smooth defective that do not have of glaze of the dry granular vitreous brick of firing acquisition on the brick face.
The glaze slip of glaze spraying comprises the component of following weight proportion:
25 parts of microballon shape dry granulars
3.5 parts of the high sticking CMC of C50G
100 parts, water,
The viscosity of the high sticking CMC of C50G is 30 ~ 100mPas, is purchased from the happy many chemical industry of Chancheng District of Foshan City.
Claims (13)
1. a microballon shape dry granular, is characterized in that, the dry granular surface is closed surface.
2. according to claim 1, it is characterized in that, the surface of described microballon shape dry granular is sphere.
3. according to claim 1, it is characterized in that, the granularity of described microballon shape dry granular is 60 ~ 170 orders.
4. the preparation method of the arbitrary described microballon shape dry granular of claim 1 ~ 3, is characterized in that, take common dry granular or frit as raw material, obtains by the processing of flame floating method.
5. the preparation method of a described microballon shape dry granular according to claim 4, is characterized in that, described common dry granular or frit are comprised of the component of following weight proportion:
The per-cent sum of above each component is 100%.
6. the preparation method of a described microballon shape dry granular according to claim 5, is characterized in that Al in component
2O
3Content be 5 ~ 15wt%.
7. the preparation method of a described microballon shape dry granular according to claim 4, is characterized in that, the granularity of described common dry granular is 60 ~ 200 orders.
8. the preparation method of a described microballon shape dry granular according to claim 4, is characterized in that, described flame floating method Flame temperature is controlled at 800 ~ 1000 ℃.
9. a dry granular vitreous brick, is characterized in that, described dry granular vitreous brick is the glaze slip that is made into by the arbitrary described microballon shape dry granular of claim 1 ~ 4, fires acquisition after imposing on the surface of base substrate.
10. a kind of dry granular vitreous brick according to claim 9, is characterized in that, the glaze slip that described microballon shape dry granular is made into imposes on the surface of base substrate by drenching glaze, glaze spraying, screen painting or glue roller printing method.
11. a kind of dry granular vitreous brick, is characterized in that according to claim 10, the glaze slip of described pouring glaze comprises the component of following weight proportion:
30 ~ 40 parts of microballon shape dry granulars
15 ~ 25 parts of water-soluble copolymer adhesives
15 ~ 25 parts, water,
The viscosity of described water-soluble copolymer adhesive is 800 ~ 1200mPas.
12. a kind of dry granular vitreous brick, is characterized in that according to claim 10, the glaze slip of described glaze spraying comprises the component of following weight proportion:
20 ~ 40 parts of microballon shape dry granulars
2 ~ 4 parts, Walocel MT 20.000PV tackiness agent
100 parts, water,
The viscosity of described Walocel MT 20.000PV tackiness agent is 30 ~ 100mPas.
13. a kind of dry granular vitreous brick, is characterized in that according to claim 10, the glaze slip of described screen painting comprises the component of following weight proportion:
100 parts of lithographic plate stamp-pad ink
250 ~ 300 parts of microballon shape dry granulars.
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| CN201310043412.9A CN103113135B (en) | 2013-01-31 | 2013-01-31 | A kind of microballon shape dry granular and its preparation method and application |
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| CN103113135B CN103113135B (en) | 2015-08-05 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105016780A (en) * | 2014-04-28 | 2015-11-04 | 佛山市纳来建材有限公司 | Dry particle glaze rock simulated ceramic tile production process |
| CN105060932A (en) * | 2015-07-17 | 2015-11-18 | 星谊精密陶瓷科技（昆山）有限公司 | Low-viscosity ink for dry granules and application |
| CN105218158A (en) * | 2015-08-27 | 2016-01-06 | 广东博华陶瓷有限公司 | A kind of happy ceramic tile |
| CN105271751A (en) * | 2015-10-16 | 2016-01-27 | 湖南天欣科技股份有限公司 | High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze |
| CN105622168A (en) * | 2015-12-23 | 2016-06-01 | 佛山市唯格瓷砖有限责任公司 | Anti-slipping wearproof dry granules and application thereof to anti-slipping wearproof ceramic tile |
| CN105776872A (en) * | 2016-03-17 | 2016-07-20 | 鹰牌陶瓷实业（河源）有限公司 | Colored high-transparency melt block and method for preparing same |
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
| CN109354413A (en) * | 2018-12-12 | 2019-02-19 | 清远市坚瓷陶瓷有限公司 | A kind of dry granular vitreous brick and preparation method thereof |
| CN109516691A (en) * | 2018-11-02 | 2019-03-26 | 广东萨米特陶瓷有限公司 | A kind of full burnishing surface ceramic of dark images and preparation method thereof |
| CN109849163A (en) * | 2019-03-28 | 2019-06-07 | 江西和美陶瓷有限公司 | The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization |
| CN110304828A (en) * | 2019-07-31 | 2019-10-08 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect |
| CN110845126A (en) * | 2019-11-04 | 2020-02-28 | Oppo广东移动通信有限公司 | Method for preparing electronic equipment shell, electronic equipment shell and electronic equipment |
| CN113354281A (en) * | 2021-08-09 | 2021-09-07 | 广东兴辉陶瓷集团有限公司 | Dew dry particle and dew effect glaze ink, preparation method thereof, rock plate and preparation method thereof |
| CN113651613A (en) * | 2021-07-06 | 2021-11-16 | 蓝思科技（长沙）有限公司 | Zirconia ceramic rear cover, preparation method thereof and 3D glaze |
| CN113735443A (en) * | 2021-10-22 | 2021-12-03 | 新明珠集团股份有限公司 | Dry bead granules and preparation method thereof |
| CN113860739A (en) * | 2021-10-22 | 2021-12-31 | 蒙娜丽莎集团股份有限公司 | Modified ball dry particle ultra-flat thin ceramic plate and preparation method thereof |
| CN113860887A (en) * | 2021-10-22 | 2021-12-31 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102503435A (en) * | 2011-09-22 | 2012-06-20 | 佛山市科捷制釉有限公司 | Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles |
| CN102515774A (en) * | 2011-11-02 | 2012-06-27 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
-
2013
- 2013-01-31 CN CN201310043412.9A patent/CN103113135B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102503435A (en) * | 2011-09-22 | 2012-06-20 | 佛山市科捷制釉有限公司 | Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles |
| CN102515774A (en) * | 2011-11-02 | 2012-06-27 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
Non-Patent Citations (2)
| Title |
|---|
| 张云洪: "《陶瓷工艺技术》", 31 July 2006, 化学工业出版社•北京 * |
| 赵永田: "《玻璃工艺学》", 31 August 1996, 武汉工业大学出版社 * |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105016780A (en) * | 2014-04-28 | 2015-11-04 | 佛山市纳来建材有限公司 | Dry particle glaze rock simulated ceramic tile production process |
| CN105016780B (en) * | 2014-04-28 | 2017-02-08 | 佛山市纳来建材有限公司 | Dry particle glaze rock simulated ceramic tile production process |
| CN105060932A (en) * | 2015-07-17 | 2015-11-18 | 星谊精密陶瓷科技（昆山）有限公司 | Low-viscosity ink for dry granules and application |
| CN105218158A (en) * | 2015-08-27 | 2016-01-06 | 广东博华陶瓷有限公司 | A kind of happy ceramic tile |
| CN105271751A (en) * | 2015-10-16 | 2016-01-27 | 湖南天欣科技股份有限公司 | High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze |
| CN105622168A (en) * | 2015-12-23 | 2016-06-01 | 佛山市唯格瓷砖有限责任公司 | Anti-slipping wearproof dry granules and application thereof to anti-slipping wearproof ceramic tile |
| CN105622168B (en) * | 2015-12-23 | 2018-07-24 | 佛山市唯格瓷砖有限责任公司 | A kind of anti-skid wearable dry granular and its application in anti-skid wearable ceramic tile |
| CN105776872A (en) * | 2016-03-17 | 2016-07-20 | 鹰牌陶瓷实业（河源）有限公司 | Colored high-transparency melt block and method for preparing same |
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
| CN109516691A (en) * | 2018-11-02 | 2019-03-26 | 广东萨米特陶瓷有限公司 | A kind of full burnishing surface ceramic of dark images and preparation method thereof |
| CN109354413A (en) * | 2018-12-12 | 2019-02-19 | 清远市坚瓷陶瓷有限公司 | A kind of dry granular vitreous brick and preparation method thereof |
| CN109354413B (en) * | 2018-12-12 | 2020-04-14 | 泰州市津专知识产权服务有限公司 | Dry-grain glaze ceramic tile and preparation method thereof |
| CN109849163A (en) * | 2019-03-28 | 2019-06-07 | 江西和美陶瓷有限公司 | The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization |
| CN110304828A (en) * | 2019-07-31 | 2019-10-08 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect |
| CN110845126A (en) * | 2019-11-04 | 2020-02-28 | Oppo广东移动通信有限公司 | Method for preparing electronic equipment shell, electronic equipment shell and electronic equipment |
| CN110845126B (en) * | 2019-11-04 | 2022-03-22 | Oppo广东移动通信有限公司 | Method for preparing electronic equipment shell, electronic equipment shell and electronic equipment |
| CN113651613A (en) * | 2021-07-06 | 2021-11-16 | 蓝思科技（长沙）有限公司 | Zirconia ceramic rear cover, preparation method thereof and 3D glaze |
| CN113354281A (en) * | 2021-08-09 | 2021-09-07 | 广东兴辉陶瓷集团有限公司 | Dew dry particle and dew effect glaze ink, preparation method thereof, rock plate and preparation method thereof |
| CN113354281B (en) * | 2021-08-09 | 2021-12-07 | 广东兴辉陶瓷集团有限公司 | Dew dry particle and dew effect glaze ink, preparation method thereof, rock plate and preparation method thereof |
| CN113735443A (en) * | 2021-10-22 | 2021-12-03 | 新明珠集团股份有限公司 | Dry bead granules and preparation method thereof |
| CN113860739A (en) * | 2021-10-22 | 2021-12-31 | 蒙娜丽莎集团股份有限公司 | Modified ball dry particle ultra-flat thin ceramic plate and preparation method thereof |
| CN113860887A (en) * | 2021-10-22 | 2021-12-31 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
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