CN103112850B - Method for preparing high-quality graphene through catalytic oxidation multiple-intercalation - Google Patents
Method for preparing high-quality graphene through catalytic oxidation multiple-intercalation Download PDFInfo
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- CN103112850B CN103112850B CN201310080369.3A CN201310080369A CN103112850B CN 103112850 B CN103112850 B CN 103112850B CN 201310080369 A CN201310080369 A CN 201310080369A CN 103112850 B CN103112850 B CN 103112850B
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- graphene
- intercalation
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000009830 intercalation Methods 0.000 title claims abstract description 26
- 230000003647 oxidation Effects 0.000 title claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 8
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 230000002687 intercalation Effects 0.000 claims abstract description 24
- 238000001914 filtration Methods 0.000 claims abstract description 19
- 238000005406 washing Methods 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 229910002804 graphite Inorganic materials 0.000 claims description 14
- 239000010439 graphite Substances 0.000 claims description 14
- 238000002203 pretreatment Methods 0.000 claims description 12
- 238000010907 mechanical stirring Methods 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000006392 deoxygenation reaction Methods 0.000 claims description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- 238000011946 reduction process Methods 0.000 claims description 5
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- 238000011085 pressure filtration Methods 0.000 claims description 3
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 claims description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims description 2
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 claims description 2
- 230000010354 integration Effects 0.000 claims description 2
- 239000000138 intercalating agent Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002356 single layer Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 17
- 239000010410 layer Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310080369.3A CN103112850B (en) | 2013-03-13 | 2013-03-13 | Method for preparing high-quality graphene through catalytic oxidation multiple-intercalation |
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CN201310080369.3A CN103112850B (en) | 2013-03-13 | 2013-03-13 | Method for preparing high-quality graphene through catalytic oxidation multiple-intercalation |
Publications (2)
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CN103112850A CN103112850A (en) | 2013-05-22 |
CN103112850B true CN103112850B (en) | 2015-02-18 |
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CN201310080369.3A Expired - Fee Related CN103112850B (en) | 2013-03-13 | 2013-03-13 | Method for preparing high-quality graphene through catalytic oxidation multiple-intercalation |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106672957A (en) * | 2016-07-18 | 2017-05-17 | 中国科学院兰州化学物理研究所 | Method for preparing graphene oxide according to Fenton oxidation method |
CN106744911B (en) * | 2017-01-23 | 2021-08-17 | 宣城亨旺新材料有限公司 | Production method of graphene oxide |
CN107285302B (en) * | 2017-08-17 | 2020-05-26 | 中国科学院宁波材料技术与工程研究所 | Preparation method of graphene |
CN107601489A (en) * | 2017-10-30 | 2018-01-19 | 嘉兴烯成新材料有限公司 | A kind of preparation method of graphene oxide |
CN107673340B (en) * | 2017-11-22 | 2019-05-24 | 肇庆中特能科技投资有限公司 | The preparation method of graphene |
CN110642241A (en) * | 2019-06-16 | 2020-01-03 | 嘉兴烯成新材料有限公司 | Preparation method of semiconductor carbon material |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9428394B2 (en) * | 2009-05-22 | 2016-08-30 | William Marsh Rice University | Highly oxidized graphene oxide and methods for production thereof |
CA2800874A1 (en) * | 2010-05-28 | 2011-12-01 | Graphea, Inc. | Carbocatalysts for chemical transformations |
CN102452649B (en) * | 2010-10-18 | 2014-04-02 | 中国科学院宁波材料技术与工程研究所 | Preparation method for graphene |
CN102336404B (en) * | 2011-07-19 | 2013-04-03 | 上海交通大学 | Preparation method of graphene oxide quantum dot based on photocatalytic oxidation |
CN102431998A (en) * | 2011-09-20 | 2012-05-02 | 深圳市长宜景鑫投资有限公司 | Method for preparing high-quality graphene in large scale by intercalation stripping of graphite by chemical method |
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- 2013-03-13 CN CN201310080369.3A patent/CN103112850B/en not_active Expired - Fee Related
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Owner name: SHANGHAI SECOND POLYTECHNIC UNIVERSITY ASSET MANAG Free format text: FORMER OWNER: SHANGHAI NO.2 POLYTECHNIC UNIV. Effective date: 20141209 |
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Free format text: CORRECT: ADDRESS; FROM: 201209 PUDONG NEW AREA, SHANGHAI TO: 200041 JING'AN, SHANGHAI |
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Effective date of registration: 20141209 Address after: 200041 No. 80, Jingan District, Shanghai, North Shaanxi Road Applicant after: SHANGHAI SECOND POLYTECHNIC UNIVERSITY, ASSETS MANAGEMENT CO., LTD. Address before: 201209 Shanghai City, Pudong New Area Jinhai Road No. 2360 Applicant before: Shanghai No.2 Polytechnic Univ. |
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Effective date of registration: 20170815 Address after: 201209, A252, building 1, building 2588, Golden Sea Road, Shanghai, Pudong New Area Patentee after: Shanghai Yueda New Material Technology Co., Ltd. Address before: 200041 No. 80, Jingan District, Shanghai, North Shaanxi Road Patentee before: SHANGHAI SECOND POLYTECHNIC UNIVERSITY, ASSETS MANAGEMENT CO., LTD. |
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Effective date of registration: 20190125 Address after: 201822 J3330 room 912, Yecheng Road, Jiading Industrial Zone, Jiading District, Shanghai. Patentee after: Shanghai Mstar Technology Ltd Address before: 201209 room 1, building 1, Jinhai Road, Pudong New Area, Shanghai, A252 Patentee before: Shanghai Yueda New Material Technology Co., Ltd. |
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Effective date of registration: 20190521 Address after: No. 80 Shaanxi North Road, Jing'an District, Shanghai 200041 Patentee after: SHANGHAI SECOND POLYTECHNIC UNIVERSITY, ASSETS MANAGEMENT CO., LTD. Address before: 201822 J3330 room 912, Yecheng Road, Jiading Industrial Zone, Jiading District, Shanghai. Patentee before: Shanghai Mstar Technology Ltd |
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