CN103046334A - Benzyl tertiary amine anti-fouling material and coating structure - Google Patents
Benzyl tertiary amine anti-fouling material and coating structure Download PDFInfo
- Publication number
- CN103046334A CN103046334A CN2012105413571A CN201210541357A CN103046334A CN 103046334 A CN103046334 A CN 103046334A CN 2012105413571 A CN2012105413571 A CN 2012105413571A CN 201210541357 A CN201210541357 A CN 201210541357A CN 103046334 A CN103046334 A CN 103046334A
- Authority
- CN
- China
- Prior art keywords
- tertiary amine
- benzyl tertiary
- benzyl
- coating structure
- fouling material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a benzyl tertiary amine antifouling material, and also discloses the application of the material as a benzyl tertiary amine antifouling material coating structure, including a substrate of synthetic resin fibers. The synthetic resin fibers are provided with the benzyl tertiary amine coating. The present invention has the advantage of available raw materials and easy preparation, can be used as an anti-fouling agent for marine anti-fouling coatings, and has environmental friendliness.
Description
Technical field
The present invention relates to a kind of anti-fouling material and coating structure, relate in particular to a kind of benzyl tertiary amine anti-fouling material and coating structure.
Background technology
Tertiary amine compound is widely used in Fine Chemical, is used for antifouling paint and is exactly wherein a kind of.Japan Patent JP08-034770 has reported a kind of giantreed bases tertiary amine, it is 5,6-dichloro donaxine or 2-methyl-5-chloro donaxine or 2-methyl-5-bromine donaxine or 2-methyl-5,6-dibromo donaxine or 1-methyl-5,6-dichloro donaxine or 1-methyl-2-methyl-6-bromine donaxine, have good antifouling activity, can be used for preparing marine antifouling coating.This giantreed bases tertiary amine complex manufacturing, cost is high, has limited promoting the use of of it.
Summary of the invention
To the object of the invention is to provide a kind of benzyl tertiary amine antifouling paint and coating structure thereof take dihalo benzyl chlorine, secondary amine as raw material for prior art, and it is simple and easy to, and leaves reaction at alkaline matter during preparation, and production technology is simple, and cost is low, is fit to produce.
The present invention solves the problems of the technologies described above the technical scheme that adopts: a kind of benzyl tertiary amine anti-fouling material is characterized in that molecular structure is
R in the formula
1Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; R
2Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; X
1Be F or Cl or Br; X
2Be F or Cl or Br.
The invention also discloses above-mentioned material as a kind of application of benzyl tertiary amine anti-fouling material coating structure, including synthetic resin fiber is base material, and this synthetic resin fiber has benzyl tertiary amine coating.
The advantage of a kind of benzyl tertiary amine material of the present invention is that raw material is easy to get, and prepares easily, can be used as the anti-fouling agent of marine antifouling coating, has environment friendly.
Description of drawings
Fig. 1 is embodiment of the invention structural representation.
The specific embodiment
Below in conjunction with attached embodiment the present invention is described in further detail.
Drawing reference numeral explanation: synthetic resin rope 1, coating 2.
Embodiment: with reference to Fig. 1, the present invention solves the problems of the technologies described above the technical scheme that adopts and is: a kind of benzyl tertiary amine anti-fouling material is characterized in that molecular structure is
R in the formula
1Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; R
2Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; X
1Be F or Cl or Br; X
2Be F or Cl or Br.
The invention also discloses above-mentioned material as a kind of application of benzyl tertiary amine anti-fouling material coating structure, including synthetic resin fiber is base material, changes synthetic resin fiber and has benzyl tertiary amine coating.
Marine antifouling coating is comprised of resin solution, plasticizer, stuffing and anti-fouling agent, and their percetage by weight scope is respectively 25～60,1～20,1～30 and 5～40.Described resin solution is concentration range 30～60%(concentration expressed in percentage by weight, acrylate resin organic solvent solution down together), described organic solvent is one or more of ethyl acetate, butyl acetate, dimethylbenzene, toluene, butanols, cyclohexanone, butanone or methyl iso-butyl ketone (MIBK); Described plasticizer is vaseline, chlorinated paraffin wax, dibutyl phthalate or dioctyl phthalate; Described stuffing is one or more of iron oxide red, talcum powder, titanium dioxide, lithopone, aerosil solid particle or zinc oxide; Described anti-fouling agent is one or more among benzyl tertiary amine, cuprous oxide, tetramethylthiuram disulfide, pyrithione (mantoquita or zinc salt), pyridine triphenyl borine or the Seanine-211.During preparation, the vibration 3 hours in a paint shaker that contains porcelain bead of the mixture of the toluene solution of the acrylate resin that 55g is above-mentioned, 9g vaseline, 5g benzyl tertiary amine, 8g cuprous oxide, 5g pyridine triphenyl borine, 13g iron oxide red and 5g aerosil solid particle, then filter with 100 purpose filters, get marine antifouling coating compositions.
The evaluation of antifouling property:
With reference to national standard " anti-fouling paint model shallow sea soak test method " (GB/T 5370-2007), to be coated with ocean brushing be 350 mm in plate length with antifouling, wide is 250mm, and thick is that the experiment model adopts the rectangular batten of trough of belt two to use iron bolt to fix on the mild steel experiment model of 3mm.To test model and hang over Oceanography Institute Of Zhejiang aquaculture base cage culture district, utmost point island, Zhoushan east, respectively at 1,4, measure blank model after June, be coated with the acrylic resin that is brushed with the suspended side chain epoxy radicals and be coated with the model that is brushed with the antifouling paint compositions that makes, obtained goodish experimental result, following expression.
| ? | 1 month | 4 months | 6 months |
| Blank model | 80 | 35 | 5 |
| Marine antifouling coating compositions | 100 | 90 | 85 |
Although described the present invention in conjunction with preferred embodiment; so it is not to limit the present invention; any those skilled in the art; in the situation that does not break away from the spirit and scope of the present invention; can implement to the theme of listing displacement and the modification of various changes, coordinate here, so protection scope of the present invention is as the criterion when looking the claim restricted portion that proposes.
Claims (3)
1. a benzyl tertiary amine anti-fouling material is characterized in that molecular structure is
R in the formula
1Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; R
2Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; X
1Be F or Cl or Br; X
2Be F or Cl or Br.
2. benzyl tertiary amine anti-fouling material coating structure, including synthetic resin fiber (1) is base material, it is characterized in that: described synthetic resin fiber (1) has benzyl tertiary amine coating (2).
3. a kind of benzyl tertiary amine anti-fouling material coating structure as claimed in claim 2, it is characterized in that: described benzyl tertiary amine molecular structure is
R in the formula
1Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; R
2Be CH
3Or CH
3CH
2Or CH
3CH
2CH
2Or (CH
3)
2CH or CH
3CH
2CH
2CH
2Or (CH
3)
2CHCH
2Or CH
3CH
2(CH
3) CH or (CH
3)
3C; X
1Be F or Cl or Br; X
2Be F or Cl or Br.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105413571A CN103046334A (en) | 2012-12-14 | 2012-12-14 | Benzyl tertiary amine anti-fouling material and coating structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105413571A CN103046334A (en) | 2012-12-14 | 2012-12-14 | Benzyl tertiary amine anti-fouling material and coating structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103046334A true CN103046334A (en) | 2013-04-17 |
Family
ID=48059176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105413571A Pending CN103046334A (en) | 2012-12-14 | 2012-12-14 | Benzyl tertiary amine anti-fouling material and coating structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103046334A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110725062A (en) * | 2019-09-16 | 2020-01-24 | 浙江海洋大学 | Method for preparing netting by compounding multi-strand antifouling net wire |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298455A (en) * | 1997-04-23 | 1998-11-10 | Nippon Paint Co Ltd | Antifouling coating composition |
| CN102127185A (en) * | 2010-12-15 | 2011-07-20 | 浙江海洋学院 | Acrylic resin with epoxy cycle on side chain and preparation and use thereof |
| CN102503837A (en) * | 2011-10-17 | 2012-06-20 | 太原理工大学 | Tertiary amines and organic silicon quaternary ammonium salts containing double long chains and benzyl groups and preparation methods thereof |
| CN102791812A (en) * | 2010-03-23 | 2012-11-21 | 中国涂料株式会社 | Antifouling coating composition and use for same |
| CN203212912U (en) * | 2012-12-14 | 2013-09-25 | 浙江海洋学院 | Benzyl tertiary amine anti-dirt coating structure |
-
2012
- 2012-12-14 CN CN2012105413571A patent/CN103046334A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298455A (en) * | 1997-04-23 | 1998-11-10 | Nippon Paint Co Ltd | Antifouling coating composition |
| CN102791812A (en) * | 2010-03-23 | 2012-11-21 | 中国涂料株式会社 | Antifouling coating composition and use for same |
| CN102127185A (en) * | 2010-12-15 | 2011-07-20 | 浙江海洋学院 | Acrylic resin with epoxy cycle on side chain and preparation and use thereof |
| CN102503837A (en) * | 2011-10-17 | 2012-06-20 | 太原理工大学 | Tertiary amines and organic silicon quaternary ammonium salts containing double long chains and benzyl groups and preparation methods thereof |
| CN203212912U (en) * | 2012-12-14 | 2013-09-25 | 浙江海洋学院 | Benzyl tertiary amine anti-dirt coating structure |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110725062A (en) * | 2019-09-16 | 2020-01-24 | 浙江海洋大学 | Method for preparing netting by compounding multi-strand antifouling net wire |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104109450B (en) | A kind of Graphene anti-corrosive powder paint and preparation method thereof | |
| DE602005005326T2 (en) | ANTIFOULIN COMPOSITIONS WITH SALT GROUP HAVING POLYMER | |
| DK2975095T3 (en) | Antifouling coating composition, antifouling coating film formed using said composition and coated articles with surface antifouling coating film | |
| CN108307625B (en) | Antifouling composite coating film, antifouling substrate, and method for producing antifouling substrate | |
| CN107022273B (en) | Epoxy resin anticorrosive coating composition, anticorrosive coating film, laminated antifouling coating film, antifouling substrate, and method for producing same | |
| CN102933665B (en) | The control method of the hydrolysis rate of antifouling paint compositions, antifouling coat and antifouling coat | |
| JP6383085B2 (en) | Antifouling coating composition comprising at least two salt-containing copolymers | |
| CN103122187B (en) | ionic liquid modified marine antifouling paint | |
| CN107960090B (en) | Antifouling coating composition, antifouling coating film, antifouling substrate, method for producing antifouling substrate, and method for storing antifouling coating composition | |
| CN108368376B (en) | Antifouling coating composition, antifouling coating film, antifouling substrate, and method for producing antifouling substrate | |
| TW200406473A (en) | Antifouling coating composition, antifouling coating film, ship, underwater construction, fishing gear and fishnet coated with the antifouling coating film | |
| WO2016190242A1 (en) | Antifouling coating composition, antifouling coating film, non-fouling base, process for producing non-fouling base, and method for storing antifouling coating composition | |
| WO2014142035A1 (en) | Antifouling coating film with low frictional resistance with water or seawater | |
| KR102656962B1 (en) | Antifouling paint composition, antifouling film, antifouling film attachment base material, manufacturing method thereof, and repair method | |
| CN102257077A (en) | Resin composition, antifouling coating comprising barnacle antifoulant and processes of production thereof | |
| JPWO2018088377A1 (en) | Antifouling paint composition, antifouling coating film, substrate with antifouling coating film and method for producing the same, and antifouling method | |
| CN103709319A (en) | Preparation method and application of copper/zinc-containing metal polyacrylate resin | |
| CN104761991A (en) | Environmental-protection type multi-element collaborative marine anti-fouling coating | |
| JP2008248058A (en) | Underwater antifouling paint and subaqua structure | |
| JP3451786B2 (en) | Paint composition | |
| CN203212912U (en) | Benzyl tertiary amine anti-dirt coating structure | |
| CN103046334A (en) | Benzyl tertiary amine anti-fouling material and coating structure | |
| CN107573828B (en) | Broad-spectrum antifouling paint for fishing nets and preparation method thereof | |
| CN102732106B (en) | Antifouling coating composition for marine structures, coating preparation method and obtained coating | |
| TW200826840A (en) | Quaternary ammonium salt anti-bacterial and water-borne coating material having antibiotic property containing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130417 |