CN103044784A - 一种高导热三元橡胶 - Google Patents
一种高导热三元橡胶 Download PDFInfo
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- CN103044784A CN103044784A CN201210573974XA CN201210573974A CN103044784A CN 103044784 A CN103044784 A CN 103044784A CN 201210573974X A CN201210573974X A CN 201210573974XA CN 201210573974 A CN201210573974 A CN 201210573974A CN 103044784 A CN103044784 A CN 103044784A
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- Prior art keywords
- rubber
- agent
- heat conduction
- high heat
- phenyl
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Cited By (9)
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CN103275396A (zh) * | 2013-06-19 | 2013-09-04 | 福建和盛塑业有限公司 | 导热绝缘电力电缆护套管专用料及其生产工艺 |
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CN109852096A (zh) * | 2019-01-15 | 2019-06-07 | 浙江博门汽车零配件有限公司 | 一种高耐低温和耐候性抗臭氧物性的三元胶及其制备方法 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55127002A (en) * | 1979-03-26 | 1980-10-01 | Kanegafuchi Chem Ind Co Ltd | Electric wave absorbing material with high heat resistance |
CN1793215A (zh) * | 2005-12-30 | 2006-06-28 | 何霖 | 三元乙丙橡胶防水卷材及其生产方法 |
CN101225293A (zh) * | 2008-02-01 | 2008-07-23 | 南京凯汇工业科技有限公司 | 一种相变导热材料及其制备方法 |
CN102174254A (zh) * | 2010-12-27 | 2011-09-07 | 东莞劲胜精密组件股份有限公司 | 一种高导热绝缘工程塑料及其制备方法 |
CN102504358A (zh) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | 一种高导热橡胶复合材料及其制备方法 |
CN102516674A (zh) * | 2011-12-09 | 2012-06-27 | 广东工业大学 | 一种导热三元乙丙橡胶复合材料及其制备方法 |
-
2012
- 2012-12-26 CN CN201210573974.XA patent/CN103044784B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55127002A (en) * | 1979-03-26 | 1980-10-01 | Kanegafuchi Chem Ind Co Ltd | Electric wave absorbing material with high heat resistance |
CN1793215A (zh) * | 2005-12-30 | 2006-06-28 | 何霖 | 三元乙丙橡胶防水卷材及其生产方法 |
CN101225293A (zh) * | 2008-02-01 | 2008-07-23 | 南京凯汇工业科技有限公司 | 一种相变导热材料及其制备方法 |
CN102174254A (zh) * | 2010-12-27 | 2011-09-07 | 东莞劲胜精密组件股份有限公司 | 一种高导热绝缘工程塑料及其制备方法 |
CN102504358A (zh) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | 一种高导热橡胶复合材料及其制备方法 |
CN102516674A (zh) * | 2011-12-09 | 2012-06-27 | 广东工业大学 | 一种导热三元乙丙橡胶复合材料及其制备方法 |
Cited By (11)
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CN104592567A (zh) * | 2014-02-20 | 2015-05-06 | 泌阳恒茂服饰制品有限公司 | 一种发热体组成方法 |
CN104558729A (zh) * | 2014-02-21 | 2015-04-29 | 泌阳恒茂服饰制品有限公司 | 一种发热体的制作工艺 |
CN104744800A (zh) * | 2015-03-30 | 2015-07-01 | 安徽省高沟电缆有限公司 | 一种用于电缆外护套的纳米阻燃缆料及其制备方法 |
CN109096635A (zh) * | 2018-07-02 | 2018-12-28 | 芜湖航天特种电缆厂股份有限公司 | 抗紫外电缆包装膜及其制备方法 |
CN109180412A (zh) * | 2018-09-29 | 2019-01-11 | 狄风君 | 一种化工品生产工艺优化方法 |
CN109180412B (zh) * | 2018-09-29 | 2021-09-03 | 安徽昊源化工集团有限公司 | 一种化工品生产工艺优化方法 |
CN109852096A (zh) * | 2019-01-15 | 2019-06-07 | 浙江博门汽车零配件有限公司 | 一种高耐低温和耐候性抗臭氧物性的三元胶及其制备方法 |
CN116535778A (zh) * | 2023-04-19 | 2023-08-04 | 沈阳橡胶研究设计院有限公司 | 一种导热绝缘性橡胶及其制造方法 |
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