CN103030871B - 聚乙烯/hips包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 - Google Patents
聚乙烯/hips包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 Download PDFInfo
- Publication number
- CN103030871B CN103030871B CN201210551016.2A CN201210551016A CN103030871B CN 103030871 B CN103030871 B CN 103030871B CN 201210551016 A CN201210551016 A CN 201210551016A CN 103030871 B CN103030871 B CN 103030871B
- Authority
- CN
- China
- Prior art keywords
- coconut shell
- shell flour
- hips
- polyethylene
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 235000013162 Cocos nucifera Nutrition 0.000 title claims abstract description 46
- 244000060011 Cocos nucifera Species 0.000 title claims abstract description 46
- 235000013312 flour Nutrition 0.000 title claims abstract description 43
- 239000002245 particle Substances 0.000 title claims abstract description 33
- -1 Polyethylene Polymers 0.000 title claims abstract description 29
- 238000005187 foaming Methods 0.000 title claims abstract description 28
- 229920005669 high impact polystyrene Polymers 0.000 title claims abstract description 28
- 239000004797 high-impact polystyrene Substances 0.000 title claims abstract description 28
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000002156 mixing Methods 0.000 title claims abstract description 26
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 24
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 24
- 239000008187 granular material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims description 7
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000010436 fluorite Substances 0.000 claims abstract description 15
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 238000012986 modification Methods 0.000 claims abstract description 10
- 230000004048 modification Effects 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 7
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 7
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 7
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 6
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 6
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 4
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003112 inhibitor Substances 0.000 claims abstract description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 239000008117 stearic acid Substances 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 230000004927 fusion Effects 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- ULUZGMIUTMRARO-UHFFFAOYSA-N (carbamoylamino)urea Chemical compound NC(=O)NNC(N)=O ULUZGMIUTMRARO-UHFFFAOYSA-N 0.000 claims description 3
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 3
- 238000003490 calendering Methods 0.000 claims description 3
- 235000013339 cereals Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 4
- 238000000280 densification Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 210000000497 foam cell Anatomy 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000006261 foam material Substances 0.000 description 7
- 230000035939 shock Effects 0.000 description 3
- 230000035882 stress Effects 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
检测项目 | 结果 |
拉伸强度(MPa) | 6.3 |
冲击强度(kJ·m-2) | 12.5 |
冲击回弹率(%) | 41 |
撕裂强度(kN·m-1) | 132 |
断裂伸长率(%) | 194 |
压缩永久变形(%) | 22.3 |
弯曲模量(MPa) | 145 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210551016.2A CN103030871B (zh) | 2012-12-18 | 2012-12-18 | 聚乙烯/hips包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210551016.2A CN103030871B (zh) | 2012-12-18 | 2012-12-18 | 聚乙烯/hips包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103030871A CN103030871A (zh) | 2013-04-10 |
CN103030871B true CN103030871B (zh) | 2015-12-02 |
Family
ID=48018297
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210551016.2A Active CN103030871B (zh) | 2012-12-18 | 2012-12-18 | 聚乙烯/hips包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103030871B (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1482165A (zh) * | 2002-12-23 | 2004-03-17 | 北京欧尼克环保技术有限公司 | 木塑发泡材料及其加工成型工艺 |
CN102690459A (zh) * | 2012-04-27 | 2012-09-26 | 华东理工大学 | 高回弹化学交联聚乙烯发泡材料及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008011562A1 (de) * | 2008-02-28 | 2009-09-03 | Lanxess Deutschland Gmbh | Schalldämpfende Dämmstoffe mit hoher Feuerwiderstandsdauer |
-
2012
- 2012-12-18 CN CN201210551016.2A patent/CN103030871B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1482165A (zh) * | 2002-12-23 | 2004-03-17 | 北京欧尼克环保技术有限公司 | 木塑发泡材料及其加工成型工艺 |
CN102690459A (zh) * | 2012-04-27 | 2012-09-26 | 华东理工大学 | 高回弹化学交联聚乙烯发泡材料及其制备方法 |
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Publication number | Publication date |
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CN103030871A (zh) | 2013-04-10 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190618 Address after: 211112 No. 3 Fengyi Road, Jiling Street, Jiangning District, Nanjing City, Jiangsu Province Patentee after: Ni Shujun Address before: 239236 18 Gaoxin Road, Cha He New District, Lai An county, Chuzhou, Anhui Patentee before: 63975 Forces, PLA |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190911 Address after: 213200 No. 198 Yijing Road, Jintan District, Changzhou City, Jiangsu Province Patentee after: Changzhou Guanrong New Packaging Material Co., Ltd. Address before: 211112 No. 3 Fengyi Road, Jiling Street, Jiangning District, Nanjing City, Jiangsu Province Patentee before: Ni Shu Jun |