CN103102561B - 一种ldpe/epmd/pom复合发泡材料及其制备方法 - Google Patents
一种ldpe/epmd/pom复合发泡材料及其制备方法 Download PDFInfo
- Publication number
- CN103102561B CN103102561B CN201210452912.3A CN201210452912A CN103102561B CN 103102561 B CN103102561 B CN 103102561B CN 201210452912 A CN201210452912 A CN 201210452912A CN 103102561 B CN103102561 B CN 103102561B
- Authority
- CN
- China
- Prior art keywords
- ldpe
- epmd
- pom
- speed
- composite foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001684 low density polyethylene Polymers 0.000 title claims abstract description 29
- 239000004702 low-density polyethylene Substances 0.000 title claims abstract description 29
- 239000006261 foam material Substances 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004927 clay Substances 0.000 claims abstract description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 13
- -1 phthalic acid ester Chemical class 0.000 claims abstract description 11
- 238000012986 modification Methods 0.000 claims abstract description 10
- 230000004048 modification Effects 0.000 claims abstract description 10
- 239000007822 coupling agent Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 7
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 7
- 150000004645 aluminates Chemical class 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 4
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 4
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 4
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000008116 calcium stearate Substances 0.000 claims abstract description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000005453 pelletization Methods 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 238000004898 kneading Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 3
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- AHIBWURJLGCHAY-UHFFFAOYSA-N [S].C1=CC=CC=C1 Chemical compound [S].C1=CC=CC=C1 AHIBWURJLGCHAY-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 206010000269 abscess Diseases 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 238000000280 densification Methods 0.000 abstract description 2
- 238000005187 foaming Methods 0.000 abstract description 2
- 239000002956 ash Substances 0.000 description 10
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- MEJAPGGFIJZHEJ-UHFFFAOYSA-N 5-acetamido-1,3,4-thiadiazole-2-sulfonyl chloride Chemical compound CC(=O)NC1=NN=C(S(Cl)(=O)=O)S1 MEJAPGGFIJZHEJ-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
检测项目 | 结果 |
拉伸强度(MPa) | 6.8 |
冲击回弹率(%) | 38 |
撕裂强度(kN·m-1) | 128 |
断裂伸长率(%) | 195 |
压缩永久变形(%) | 23.6 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210452912.3A CN103102561B (zh) | 2012-11-13 | 2012-11-13 | 一种ldpe/epmd/pom复合发泡材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210452912.3A CN103102561B (zh) | 2012-11-13 | 2012-11-13 | 一种ldpe/epmd/pom复合发泡材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103102561A CN103102561A (zh) | 2013-05-15 |
CN103102561B true CN103102561B (zh) | 2016-05-04 |
Family
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CN201210452912.3A Expired - Fee Related CN103102561B (zh) | 2012-11-13 | 2012-11-13 | 一种ldpe/epmd/pom复合发泡材料及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN103102561B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105778401B (zh) * | 2014-12-18 | 2020-01-31 | 国家能源投资集团有限责任公司 | 聚甲醛泡沫组合物、制法及包括其的结构泡沫材料 |
CN107557111A (zh) * | 2017-08-14 | 2018-01-09 | 合肥市田源精铸有限公司 | 一种汽车钢板弹簧用润滑剂 |
CN110628111A (zh) * | 2019-09-20 | 2019-12-31 | 安徽滁州德威新材料有限公司 | 一种物理法防白蚁高硬度聚乙烯护套料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1631961A (zh) * | 2004-11-09 | 2005-06-29 | 杨永健 | 橡塑建筑装饰材料 |
CN102030940A (zh) * | 2010-12-07 | 2011-04-27 | 河北科技大学 | 汽车用聚乙烯/橡胶膨胀胶块及其制备方法 |
-
2012
- 2012-11-13 CN CN201210452912.3A patent/CN103102561B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1631961A (zh) * | 2004-11-09 | 2005-06-29 | 杨永健 | 橡塑建筑装饰材料 |
CN102030940A (zh) * | 2010-12-07 | 2011-04-27 | 河北科技大学 | 汽车用聚乙烯/橡胶膨胀胶块及其制备方法 |
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CN103102561A (zh) | 2013-05-15 |
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Effective date of registration: 20170612 Address after: 401573 Chongqing city Fuling District Jiangdong Fu Road No. 21 Patentee after: CHONGQING FENGSHENG PACKAGING MATERIAL CO.,LTD. Address before: 231200, Anhui, Hefei County, Feixi Province peach blossom town east of Changan Road, north of Tang Road Patentee before: Hefei Hongfang New Material Co.,Ltd. |
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CP02 | Change in the address of a patent holder |
Address after: 404100 Chongqing Hechuan grass street Agricultural Innovation Road No. 201 building 4 1-3 Patentee after: CHONGQING FENGSHENG PACKAGING MATERIAL CO.,LTD. Address before: 401573 Chongqing city Fuling District Jiangdong Fu Road No. 21 Patentee before: CHONGQING FENGSHENG PACKAGING MATERIAL CO.,LTD. |
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CF01 | Termination of patent right due to non-payment of annual fee |
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CF01 | Termination of patent right due to non-payment of annual fee |