CN103012942B - A kind of plastic film for wrapping that contains modification dolomite powder - Google Patents

A kind of plastic film for wrapping that contains modification dolomite powder Download PDF

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Publication number
CN103012942B
CN103012942B CN201210482130.4A CN201210482130A CN103012942B CN 103012942 B CN103012942 B CN 103012942B CN 201210482130 A CN201210482130 A CN 201210482130A CN 103012942 B CN103012942 B CN 103012942B
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China
Prior art keywords
powder
modification
wrapping
plastic film
dolomite powder
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CN201210482130.4A
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CN103012942A (en
Inventor
王立新
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Guangdong Li Xinfeng Printing Co. Ltd.
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Hefei Hongjie New Material Science And Technology Co Ltd
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Abstract

The invention discloses a kind of plastic film for wrapping that contains modification dolomite powder, it is to be made by the raw material of following weight parts: homogeneous ethylene/alpha olefin polymer 12-16, LDPE low density polyethylene (LDPE) 25-28, SG-1 type polyvinyl chloride 10-15, epoxy cottonseed oil 2.8-4.5, Tissuemat E powder 2-3, isopropyl distearyl acyl-oxygen base Aluminate 1-2, polyisobutene 1.2-2.1, poly--4-methyl-1-pentene 0.5-1.5, barium sulfate 1-1.9, modification dolomite powder 5-8, nano diatomite 0.5-1, trees ashes 0.3-0.6, diglycol benzoic ether 1-2, dibatyl phithalate 0.8-1.5, dolomol 0.8-1.6, VTES 1-2, ferrocene 0.5-1, modification kaolinite powder 1.5-3. barrier of the present invention and air-tightness are good, and resistance to pressure and resistance to impact are outstanding, have again the feature that heat seal strength is high, heat sealability is good simultaneously.

Description

A kind of plastic film for wrapping that contains modification dolomite powder
Technical field
The present invention relates to packaging material field, is exactly a kind of plastic film for wrapping that contains modification dolomite powder.
Background technology
China is that world's packaging is manufactured and consumption big country, and the ratio of plastics package in the Packaging Industry gross output value exceeded 30%, becomes the fresh combatants in Packaging Industry, bringing into play irreplaceable effect in food, beverage, commodity and industrial and agricultural production every field. In recent years, packaging product, the packaging material of plastics package industry grow steadily, and new packaging materials, new technology, new technology, new product continue to bring out. Food packing plastic substrate film is produced with polyethylene raw material conventionally, has the polyethylene raw material that can be used for making food packing plastic substrate film of multiple superior performance on Vehicles Collected from Market. From main plastics variety, in plastics package field, the consumption of density polyethylene film with high will continue steady growth. The polyethylene film of individual layer is poor to the barrier of the gases such as oxygen, while packing the food such as fried class, easily cause sealing part to pollute, general flexible package punch polyethylene film is poor to the sealing property of this type of packaging, can not meet its technology of the package and the requirement of connection with wrapping of piece storage period, therefore must adopt barrier property and be mingled with all good multilaminar polyethylene modified film or laminated films of sealing property.
Summary of the invention
The object of the present invention is to provide a kind of plastic film for wrapping that contains modification dolomite powder, this material heat sealability is good.
Above-mentioned purpose realizes by following scheme:
A kind of plastic film for wrapping that contains modification dolomite powder, it is characterized in that: it is to be made by the raw material of following weight parts: homogeneous ethylene/alpha olefin polymer 12-16, LDPE low density polyethylene (LDPE) 25-28, SG-1 type polyvinyl chloride 10-15, epoxy cottonseed oil 2.8-4.5, Tissuemat E powder 2-3, isopropyl distearyl acyl-oxygen base Aluminate 1-2, polyisobutene 1.2-2.1, poly--4-methyl-1-pentene 0.5-1.5, barium sulfate 1-1.9, modification dolomite powder 5-8, nano diatomite 0.5-1, trees ashes 0.3-0.6, diglycol benzoic ether 1-2, dibatyl phithalate 0.8-1.5, dolomol 0.8-1.6, VTES 1-2, ferrocene 0.5-1, modification kaolinite powder 1.5-3,
The preparation method of described modification kaolinite powder is: the hydrogen peroxide solution that is 18-22% by kaolinite concentration soaks 4-6 hour, at 600-700 DEG C, calcine 4-6 hour again, pulverize, cross 200-400 mesh sieve, mix with the peregal that is equivalent to powder weight 3-5% again, after stirring, to obtain final product;
The preparation method of described modification dolomite powder is: dolomite is soaked to 3-4 hour with the hydrochloric acid solution of 10-15%, at 500-650 DEG C, calcine 3-4 hour, be ground into 400-500 object powder, mix with the polyoxyethylene sorbitan monoleate that is equivalent to dolomite weight 3-5%, to obtain final product.
Described a kind of plastic film for wrapping that contains modification dolomite powder, is characterized in that: preparation method comprises the following steps:
(1), epoxy cottonseed oil, Tissuemat E powder are joined in batch mixer, be warming up to 80-85 DEG C, add SG-1 type polyvinyl chloride to stir after 4-8 minute, add isopropyl distearyl acyl-oxygen base Aluminate to stir after 12-16 minute, add again modification kaolinite powder, modification dolomite powder, be heated to 100-110 DEG C, stir 25-35 minute;
(2) after adding, again other raw material to stir, send into extrusion machine fused mass and extrude, melt temperature is 180-190 DEG C; Carry out the sizing of die head blown film, die head temperature is to raise gradually from bottom to top, and its scope control is at 185-200 DEG C; Then traction cutting; Last rolling, to obtain final product.
Described a kind of plastic film for wrapping that contains modification dolomite powder, is characterized in that: the melt index of homogeneous ethylene/alpha olefin polymer is between 2.0-5.0g/10min, and density is 0.89-0.92g/cm3Between.
Described a kind of plastic film for wrapping that contains modification dolomite powder, is characterized in that: the rotating speed of described extruder is controlled at 95-100r/min.
Beneficial effect of the present invention is: barrier of the present invention and air-tightness are good, and resistance to pressure and resistance to impact are outstanding, has again the feature that heat seal strength is high, heat sealability is good simultaneously.
Detailed description of the invention
A kind of plastic film for wrapping that contains modification dolomite powder, it is to be made by the raw material of following weight parts (kg): homogeneous ethylene/alpha olefin polymer 16, LDPE low density polyethylene (LDPE) 26.5, SG-1 type polyvinyl chloride 12.5, epoxy cottonseed oil 3.5, Tissuemat E powder 2.5, isopropyl distearyl acyl-oxygen base Aluminate 1.3, polyisobutene 1.7, poly--4-methyl-1-pentene 0.7, barium sulfate 1.3, modification dolomite powder 6, nano diatomite 0.6, trees ashes 0.4, diglycol benzoic ether 2, dibatyl phithalate 1.2, dolomol 0.8, VTES 2, ferrocene 0.7, modification kaolinite powder 1.5,
The preparation method of described modification kaolinite powder is: the hydrogen peroxide solution that is 18% by kaolinite concentration soaks 6 hours, then at 700 DEG C, calcines pulverize 6 hours, cross 200 mesh sieves, mix with the peregal that is equivalent to powder weight 5% again, after stirring, to obtain final product;
The preparation method of described modification dolomite powder is: dolomite is soaked 4 hours with 15% hydrochloric acid solution, calcine 4 hours at 650 DEG C, be ground into 400 object powder, mix with the polyoxyethylene sorbitan monoleate that is equivalent to dolomite weight 4.4%, to obtain final product.
Described a kind of plastic film for wrapping that contains modification dolomite powder, preparation method comprises the following steps:
(1), epoxy cottonseed oil, Tissuemat E powder are joined in batch mixer, be warming up to 85 DEG C, add SG-1 type polyvinyl chloride to stir after 8 minutes, add isopropyl distearyl acyl-oxygen base Aluminate to stir after 14 minutes, add again modification kaolinite powder, modification dolomite powder, be heated to 110 DEG C, stir 35 minutes;
(2) after adding, again other raw material to stir, send into extrusion machine fused mass and extrude, the rotating speed of described extruder is controlled at 95r/min, and melt temperature is 190 DEG C; Carry out the sizing of die head blown film, die head temperature is to raise gradually from bottom to top, and its scope control is at 200 DEG C; Then traction cutting; Last rolling, to obtain final product.
The melt index of homogeneous ethylene/alpha olefin polymer is between 2.0-5.0g/10min, and density is 0.89-0.92g/cm3Between.
The performance parameter of the product that the present embodiment is produced is: hot strength: 47Mpa; Elongation at break: 1025%; Heat seal strength: 11.3; Coefficient of friction: 0.198.

Claims (4)

1. a plastic film for wrapping that contains modification dolomite powder, it is characterized in that: it is to be made by the raw material of following weight parts: homogeneous ethylene/alpha olefin polymer 12-16, LDPE low density polyethylene (LDPE) 25-28, SG-1 type polyvinyl chloride 10-15, epoxy cottonseed oil 2.8-4.5, Tissuemat E powder 2-3, isopropyl distearyl acyl-oxygen base Aluminate 1-2, polyisobutene 1.2-2.1, poly--4-methyl-1-pentene 0.5-1.5, barium sulfate 1-1.9, modification dolomite powder 5-8, nano diatomite 0.5-1, trees ashes 0.3-0.6, diglycol benzoic ether 1-2, dibatyl phithalate 0.8-1.5, dolomol 0.8-1.6, VTES 1-2, ferrocene 0.5-1, modification kaolinite powder 1.5-3, the preparation method of described modification kaolinite powder is: the hydrogen peroxide solution that is 18-22% by kaolinite concentration soaks 4-6 hour, at 600-700 DEG C, calcine 4-6 hour again, pulverize, cross 200-400 mesh sieve, mix with the peregal that is equivalent to powder weight 3-5% again, after stirring, to obtain final product, the preparation method of described modification dolomite powder is: dolomite is soaked to 3-4 hour with the hydrochloric acid solution of 10-15%, at 500-650 DEG C, calcine 3-4 hour, be ground into 400-500 object powder, mix with the polyoxyethylene sorbitan monoleate that is equivalent to dolomite weight 3-5%, to obtain final product.
2. a kind of plastic film for wrapping that contains modification dolomite powder according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) epoxy cottonseed oil, Tissuemat E powder are joined in batch mixer, be warming up to 80-85 DEG C, add SG-1 type polyvinyl chloride to stir after 4-8 minute, add isopropyl distearyl acyl-oxygen base Aluminate to stir after 12-16 minute, add again modification kaolinite powder, modification dolomite powder, be heated to 100-110 DEG C, stir 25-35 minute;
(2) after adding, again other raw material to stir, send into extruder fusing and extrude, melt temperature is 180-190 DEG C; Carry out the sizing of die head blown film, die head temperature is to raise gradually from bottom to top, and its scope control is at 185-200 DEG C; Then traction cutting; Last rolling, to obtain final product.
3. a kind of plastic film for wrapping that contains modification dolomite powder according to claim 1, is characterized in that: the melt index of homogeneous ethylene/alpha olefin polymer is between 2.0-5.0g/10min, and density is 0.89-0.92g/cm3Between.
4. a kind of plastic film for wrapping that contains modification dolomite powder according to claim 2, is characterized in that: the rotating speed of described extruder is controlled at 95-100r/min.
CN201210482130.4A 2012-11-25 2012-11-25 A kind of plastic film for wrapping that contains modification dolomite powder Expired - Fee Related CN103012942B (en)

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CN103483639A (en) * 2013-06-20 2014-01-01 安徽春辉仪表线缆集团有限公司 Reciprocating motion sealing ring for high pressure oil cylinders
CN103772977A (en) * 2013-12-20 2014-05-07 安徽孟凌精密电子有限公司 Super-black and bright high-glossiness nylon PA66 nylon gasket composite material combined material
CN106009660A (en) * 2016-06-28 2016-10-12 安徽富乐泰水泵***有限公司 Composite fiber-reinforced high-performance gasket for pump
CN107841019A (en) * 2017-10-25 2018-03-27 高兴国 A kind of use for electronic products thin-film material and preparation method thereof
CN108976572A (en) * 2018-04-26 2018-12-11 湖州亚文纸模包装有限公司 A kind of degradable package plastic film and its preparation process

Citations (3)

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CN101831106A (en) * 2010-05-10 2010-09-15 宁波市青湖弹性体科技有限公司 Thermoplastic elastic self-sealing film and preparation method thereof
CN102295793A (en) * 2011-07-07 2011-12-28 宋旭 Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof
CN102321287A (en) * 2011-07-22 2012-01-18 蚌埠蓝天塑料包装有限公司 Biodegradable polyethylene thin film and preparation method thereof

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US7622179B2 (en) * 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101831106A (en) * 2010-05-10 2010-09-15 宁波市青湖弹性体科技有限公司 Thermoplastic elastic self-sealing film and preparation method thereof
CN102295793A (en) * 2011-07-07 2011-12-28 宋旭 Highly extended oxidation-degradable high-molecular packaging material and preparation method thereof
CN102321287A (en) * 2011-07-22 2012-01-18 蚌埠蓝天塑料包装有限公司 Biodegradable polyethylene thin film and preparation method thereof

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Address after: 230031 Hefei high tech Zone, Zhejiang Province, venture building, room A-914

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Applicant before: Anhui Liufang Zhonglian Mechanical Share Co.,Ltd.

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Address after: 515000 Qishan, Guangdong, Hebei Province, Chaozhou Shantou Road, North Industrial Zone, A building, building No. 1, No.

Patentee after: Guangdong Li Xinfeng Printing Co. Ltd.

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