CN102998870A - Electro-chromic material - Google Patents
Electro-chromic material Download PDFInfo
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- CN102998870A CN102998870A CN2011102654660A CN201110265466A CN102998870A CN 102998870 A CN102998870 A CN 102998870A CN 2011102654660 A CN2011102654660 A CN 2011102654660A CN 201110265466 A CN201110265466 A CN 201110265466A CN 102998870 A CN102998870 A CN 102998870A
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Abstract
The invention provides an electro-chromic material. The electro-chromic material comprises an upper glass substrate, a conducting reflective layer, an electro-chromic material, a transparent conducting layer and a lower glass substrate which are stacked in sequence. The material performance of the conducting reflective layer of the electro-chromic material is excellent, the electro-chromic material has high reflectivity and stability, a contact-potential barrier between an electrode and the electro-chromic material is reduced, drive voltage is reduced, the electro-chromic efficiency is improved, and the service life of a device is prolonged. In addition, silver alloy having excellent performance serves as a conducting reflective film, and an electro-chromic device is stable in performance.
Description
Technical field
The present invention relates to a kind of electrochromic material, belong to automobile and use the anti-glare inner rear-view mirror field.
Background technology
Electrochromic device refers to that reversible variation occurs the optical property of off-color material under the outside alive driving, shows will occur painted on the color and variation that fade, can realize the purpose of light modulation according to painted and contrast that fade.Compare with traditional CRT display technique, electrochromic device has very low driving voltage; The characteristics such as color is adjustable.The particularly important is, electrochromic device super clearly contrast and broad visual angle will become one of main flow of paper type flat-panel monitor of new generation.In addition, because the change of electrochromic device color can be played the modulation to light, in auto industry, can be used for anti-dazzle driving mirror, in building construction as a kind of novel intelligent glass.
Electrochromic device generally comprises glass substrate, glue frame, electrochromic material, transparency conducting layer, conductive reflective.Because electrochromic material contains cathode electrochromic material and anode electrochromic material, and transparency conducting layer and conductive reflective are had certain corrosivity, therefore need transparency conducting layer and the certain corrosion resistance of conductive reflective needs.Generally select ITO at present transparency conducting layer, the ITO of doped with fluorine, ZnO, Zn
3In
2O
6, ITO/ metal/ITO (IMI) etc., materials belong to inorganic aspect, and corrosion resistance is better.Al has high reflectance in conductive reflective, but stability is poor, be easy to be subject to the corrosion of environment, generally seldom be used for doing independent conductive reflective, therefore conductive reflective is generally selected the metal alloy of silver alloy and so on, mainly be because silver has higher reflectivity, being coated on reflectivity on glass can arrive more than 98%, but silver is stable poor simultaneously, easily cohesion, apparent defective occurs, therefore have a lot of products and select silver alloy as the material of conduction reflectance coating.These materials mainly contain Ag/Au, and the alloy that the noble metals such as Ag/Pt or Ag/Pd form has higher stability, but because cost is higher, and just someone had added Cu or Ti or stainless steel afterwards, Ni etc. are used for improving stability, reduce cost.
Principle of work in electrochromic device provides electronics for conductive reflective, and transparency conducting layer provides the hole.In order to reduce driving voltage, just need to improve electronics and hole such as efficient.Therefore require the work function of anode.(least energy that work function refers to make an electronics to overflow and must provide from solid surface immediately) is high as far as possible, and the work function of negative electrode is low as far as possible.Anode generally is to adopt transparent metal (such as Au), transparent conductive polymer (such as polyaniline) and the ITO electro-conductive glass with high work function, and the material that brings disaster to that the most generally adopts is ITO, and the work function that it has is 4.7eV.The work function of above-mentioned silver alloy negative electrode is also relatively high, has reduced the injection efficiency of electronics.Cause that thus driving voltage raises, and makes the device accelerated deteriorations such as electrochromic device or LCD, hydraulic performance decline.
Summary of the invention
For solving the problems of the technologies described above, the object of the present invention is to provide a kind of performance of improving electrochromic device, prolong its serviceable life, improve yield rate, the electrochromic material that reduces production costs.
Electrochromic material of the present invention comprises: mutual stacked top glass substrate, conductive reflective, electrochromics material, transparency conducting layer, lower glass substrate successively; Described electrochromic material also further comprises a painting protective layer, and described painting protective layer is layered on the described top glass substrate.Described electrochromic material also further comprises a glue frame, and described glue frame is arranged on the both sides of described electrochromics material, and the two ends of described glue frame are connected with described conductive reflective and described transparency conducting layer respectively.Described electrochromic material also further comprises a transition bed, and described transition bed is arranged between described conductive reflective and described top glass substrate and described transparency conducting layer and the described lower glass substrate.
The material in described reflection horizon is the potpourri of Ag and Au or Pt or Pd or Rh or Ru.The addition of described Au or Pt or Pd or Rh or Ru is 0.01%～15% of reflection horizon quality.LI or Na or Al or K or Ca or Hf or Nb or Sr or Ce or Nd or Lu or In or Mg or Rb or Th or Tb or Y are also further arranged in described reflection horizon.The addition of described Au or Pt or Pd or Rh or Ru is 0.001%～3% of reflection horizon quality.The thickness of described transition bed is the interior rice in 5 nanometers～200.The material of described glue frame is epoxy resin.
Electrochromic material conductive reflective material property of the present invention is good, has higher reflectivity and stability, reduce simultaneously the contact berrier between electrode and the off-color material, reduce driving voltage, improve variable color efficient, prolong the serviceable life of device, in addition with this silver alloy with premium properties as the conduction reflectance coating, a kind of electrochromic device of stable performance is provided.
Description of drawings
Fig. 1 is electrochromic material structural representation of the present invention.
Description of reference numerals in the electrochromic material accompanying drawing of the present invention:
1-painting protective layer 2-top glass substrate 3-conductive reflective 4-electrochromics material
5-glue frame 6-transparency conducting layer 7-lower glass substrate
Embodiment
Below in conjunction with accompanying drawing electrochromic material of the present invention is described in further detail.
As shown in Figure 1, electrochromic material of the present invention comprises: mutual stacked top glass substrate, conductive reflective, electrochromics material, transparency conducting layer, lower glass substrate successively; Electrochromic material also further comprises a painting protective layer, and painting protective layer is layered on the top glass substrate.Electrochromic material also further comprises a glue frame, and the glue frame is arranged on the both sides of electrochromics material, and the two ends of glue frame are connected with conductive reflective and transparency conducting layer respectively.Electrochromic material also further comprises a transition bed, and transition bed is arranged between conductive reflective and top glass substrate and transparency conducting layer and the lower glass substrate.
The material in reflection horizon is the potpourri of Ag and Au or Pt or Pd or Rh or Ru.The addition of Au or Pt or Pd or Rh or Ru is 0.01%～15% of reflection horizon quality.LI or Na or Al or K or Ca or Hf or Nb or Sr or Ce or Nd or Lu or In or Mg or Rb or Th or Tb or Y are also further arranged in the reflection horizon.The addition of Au or Pt or Pd or Rh or Ru is 0.001%～3% of reflection horizon quality.The thickness of transition bed is 5 nanometers～200 nanometers.The material of glue frame is epoxy resin.
Electrochromic material conductive reflective material property of the present invention is good, has higher reflectivity and stability, reduce simultaneously the contact berrier between electrode and the off-color material, reduce driving voltage, improve variable color efficient, prolong the serviceable life of device, in addition with this silver alloy with premium properties as the conduction reflectance coating, a kind of electrochromic device of stable performance is provided.
Below the preferred embodiment of the invention is specified, but the invention is not limited to embodiment, those of ordinary skill in the art also can make all modification that is equal to or replacement under the prerequisite of the invention spirit, the modification that these are equal to or replacement all are included in the application's claim limited range.
Claims (10)
1. electrochromic material is characterized in that, comprising: mutual stacked top glass substrate, conductive reflective, electrochromics material, transparency conducting layer, lower glass substrate successively.
2. electrochromic material according to claim 1 is characterized in that, described electrochromic material also further comprises a painting protective layer, and described painting protective layer is layered on the described top glass substrate.
3. electrochromic material according to claim 2, it is characterized in that, described electrochromic material also further comprises a glue frame, and described glue frame is arranged on the both sides of described electrochromics material, and the two ends of described glue frame are connected with described conductive reflective and described transparency conducting layer respectively.
4. electrochromic material according to claim 3, it is characterized in that, described electrochromic material also further comprises a transition bed, and described transition bed is arranged between described conductive reflective and described top glass substrate and described transparency conducting layer and the described lower glass substrate.
5. electrochromic material according to claim 1 is characterized in that, the material in described reflection horizon is the potpourri of Ag and Au or Pt or Pd or Rh or Ru.
6. electrochromic material according to claim 5 is characterized in that, the addition of described Au or Pt or Pd or Rh or Ru is 0.01%～15% of reflection horizon quality.
7. electrochromic material according to claim 6 is characterized in that, LI or Na or Al or K or Ca or Hf or Nb or Sr or Ce or Nd or Lu or In or Mg or Rb or Th or Tb or Y are also further arranged in described reflection horizon.
8. electrochromic material according to claim 7 is characterized in that, the addition of described Au or Pt or Pd or Rh or Ru is 0.001%～3% of reflection horizon quality.
9. electrochromic material according to claim 4 is characterized in that, the thickness of described transition bed is 5 nanometers～200 nanometers.
10. electrochromic material according to claim 3 is characterized in that, the material of described glue frame is epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102654660A CN102998870A (en) | 2011-09-08 | 2011-09-08 | Electro-chromic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102654660A CN102998870A (en) | 2011-09-08 | 2011-09-08 | Electro-chromic material |
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| CN102998870A true CN102998870A (en) | 2013-03-27 |
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| CN2011102654660A Pending CN102998870A (en) | 2011-09-08 | 2011-09-08 | Electro-chromic material |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106462022A (en) * | 2014-05-02 | 2017-02-22 | 唯景公司 | Electrochromic devices |
| CN106926781A (en) * | 2015-12-29 | 2017-07-07 | 宁波祢若电子科技有限公司 | The electrochromism air locking that a kind of high pressure resistant water vapour corrodes |
| CN110133930A (en) * | 2019-06-04 | 2019-08-16 | 爱卓智能科技(上海)有限公司 | A kind of electrochomeric glass structure on automobile |
| CN110764330A (en) * | 2019-09-16 | 2020-02-07 | 中国建筑材料科学研究总院有限公司 | Flexible filament electrochromic fiber and preparation method and application thereof |
| US10585321B2 (en) | 2014-11-26 | 2020-03-10 | View, Inc. | Counter electrode for electrochromic devices |
| US10591795B2 (en) | 2009-03-31 | 2020-03-17 | View, Inc. | Counter electrode for electrochromic devices |
| US10591797B2 (en) | 2009-03-31 | 2020-03-17 | View, Inc. | Electrochromic devices |
| US10599001B2 (en) | 2010-04-30 | 2020-03-24 | View, Inc. | Electrochromic devices |
| CN111176047A (en) * | 2020-01-07 | 2020-05-19 | 中国人民解放军国防科技大学 | Flexible electrogenerated variable emissivity device and preparation method thereof |
| US10663830B2 (en) | 2009-03-31 | 2020-05-26 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US10684523B2 (en) | 2014-09-05 | 2020-06-16 | View, Inc. | Counter electrode for electrochromic devices |
| US10690987B2 (en) | 2009-03-31 | 2020-06-23 | View, Inc. | Counter electrode for electrochromic devices |
| US10852613B2 (en) | 2009-03-31 | 2020-12-01 | View, Inc. | Counter electrode material for electrochromic devices |
| US10996533B2 (en) | 2010-04-30 | 2021-05-04 | View, Inc. | Electrochromic devices |
| US11187954B2 (en) | 2009-03-31 | 2021-11-30 | View, Inc. | Electrochromic cathode materials |
| US11891327B2 (en) | 2014-05-02 | 2024-02-06 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US11947232B2 (en) | 2009-03-31 | 2024-04-02 | View, Inc. | Fabrication of low defectivity electrochromic devices |
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| CN1536935A (en) * | 2003-04-07 | 2004-10-13 | 林月良 | Reflected color-developing component containing electrochromic material |
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| CN1536935A (en) * | 2003-04-07 | 2004-10-13 | 林月良 | Reflected color-developing component containing electrochromic material |
| JP2008282012A (en) * | 2007-05-09 | 2008-11-20 | Samsung Electronics Co Ltd | Electrochromic device having improved color property and method for manufacturing the same |
| US20090002799A1 (en) * | 2007-06-26 | 2009-01-01 | Kabushiki Kaisha Tokai-Rika-Denki-Seisakusho | Electrochromic mirror |
| CN101419374A (en) * | 2008-11-21 | 2009-04-29 | 宁波市金榜汽车电子有限公司 | Reflection layer material for electrochromic lens and device thereof |
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Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11187954B2 (en) | 2009-03-31 | 2021-11-30 | View, Inc. | Electrochromic cathode materials |
| US11966140B2 (en) | 2009-03-31 | 2024-04-23 | View, Inc. | Counter electrode for electrochromic devices |
| US11947232B2 (en) | 2009-03-31 | 2024-04-02 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US11898233B2 (en) | 2009-03-31 | 2024-02-13 | View, Inc. | Electrochromic devices |
| US11635665B2 (en) | 2009-03-31 | 2023-04-25 | View, Inc. | Counter electrode material for electrochromic devices |
| US10591795B2 (en) | 2009-03-31 | 2020-03-17 | View, Inc. | Counter electrode for electrochromic devices |
| US10591797B2 (en) | 2009-03-31 | 2020-03-17 | View, Inc. | Electrochromic devices |
| US11525181B2 (en) | 2009-03-31 | 2022-12-13 | View, Inc. | Electrochromic devices |
| US11440838B2 (en) | 2009-03-31 | 2022-09-13 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US10663830B2 (en) | 2009-03-31 | 2020-05-26 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US11409177B2 (en) | 2009-03-31 | 2022-08-09 | View, Inc. | Counter electrode for electrochromic devices |
| US10690987B2 (en) | 2009-03-31 | 2020-06-23 | View, Inc. | Counter electrode for electrochromic devices |
| US10852613B2 (en) | 2009-03-31 | 2020-12-01 | View, Inc. | Counter electrode material for electrochromic devices |
| US11370699B2 (en) | 2009-03-31 | 2022-06-28 | View, Inc. | Counter electrode for electrochromic devices |
| US10599001B2 (en) | 2010-04-30 | 2020-03-24 | View, Inc. | Electrochromic devices |
| US10996533B2 (en) | 2010-04-30 | 2021-05-04 | View, Inc. | Electrochromic devices |
| US11592722B2 (en) | 2010-04-30 | 2023-02-28 | View, Inc. | Electrochromic devices |
| CN106462022A (en) * | 2014-05-02 | 2017-02-22 | 唯景公司 | Electrochromic devices |
| US11891327B2 (en) | 2014-05-02 | 2024-02-06 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US11422426B2 (en) | 2014-09-05 | 2022-08-23 | View, Inc. | Counter electrode for electrochromic devices |
| US10684523B2 (en) | 2014-09-05 | 2020-06-16 | View, Inc. | Counter electrode for electrochromic devices |
| US11327382B2 (en) | 2014-11-26 | 2022-05-10 | View, Inc. | Counter electrode for electrochromic devices |
| US10585321B2 (en) | 2014-11-26 | 2020-03-10 | View, Inc. | Counter electrode for electrochromic devices |
| US11960188B2 (en) | 2014-11-26 | 2024-04-16 | View, Inc. | Counter electrode for electrochromic devices |
| CN106926781A (en) * | 2015-12-29 | 2017-07-07 | 宁波祢若电子科技有限公司 | The electrochromism air locking that a kind of high pressure resistant water vapour corrodes |
| CN110133930B (en) * | 2019-06-04 | 2024-03-19 | 爱卓智能科技(上海)有限公司 | Electrochromic glass structure for automobile |
| CN110133930A (en) * | 2019-06-04 | 2019-08-16 | 爱卓智能科技(上海)有限公司 | A kind of electrochomeric glass structure on automobile |
| CN110764330A (en) * | 2019-09-16 | 2020-02-07 | 中国建筑材料科学研究总院有限公司 | Flexible filament electrochromic fiber and preparation method and application thereof |
| CN111176047A (en) * | 2020-01-07 | 2020-05-19 | 中国人民解放军国防科技大学 | Flexible electrogenerated variable emissivity device and preparation method thereof |
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Application publication date: 20130327 |