CN102994834B - Heatproof magnesium alloy containing Nb - Google Patents
Heatproof magnesium alloy containing Nb Download PDFInfo
- Publication number
- CN102994834B CN102994834B CN201110267000.4A CN201110267000A CN102994834B CN 102994834 B CN102994834 B CN 102994834B CN 201110267000 A CN201110267000 A CN 201110267000A CN 102994834 B CN102994834 B CN 102994834B
- Authority
- CN
- China
- Prior art keywords
- magnesium alloy
- alloy
- present
- weight percent
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 113
- 239000011777 magnesium Substances 0.000 claims abstract description 37
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 11
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 10
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 36
- 239000000956 alloy Substances 0.000 claims description 36
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 4
- 229910052691 Erbium Inorganic materials 0.000 claims description 4
- 229910052689 Holmium Inorganic materials 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 238000005266 casting Methods 0.000 abstract description 35
- 238000004512 die casting Methods 0.000 abstract description 8
- 238000000034 method Methods 0.000 description 33
- 239000007789 gas Substances 0.000 description 14
- 229910000838 Al alloy Inorganic materials 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000007670 refining Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000007689 inspection Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910017143 AlSr Inorganic materials 0.000 description 3
- 229910017150 AlTi Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000005495 investment casting Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910017863 MgGd Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910017916 MgMn Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010120 permanent mold casting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a heatproof magnesium alloy containing Nb, which belongs to the magnesium alloy field. The magnesium alloy is composed of Mg, Al, Si, Mn, rare earth, Nb and M, and comprises the following components by weight: 1.6-9.8% of Al, 0.5-2.5% of Si, 0.05-0.7% of Mn, 0.0001-10% of rare earth, 0.0002-4% of Nb, 0.0001-0.3% of M and the balance of Mg. M element is at least one selected in Ti, Sr, C and B. According to the invention, a rare earth element and an Nb element are added in the magnesium alloy, a structure of a beta phase is changed, thereby the high temperature resistance performance of the magnesium alloy is enhanced, the heatproof magnesium alloy containing Nb has excellent mechanical property and machinery processability, and good fluidity and die casting performance, and is suitable for casting the heatproof magnesium alloy and die casting of the heatproof magnesium alloy.
Description
Technical field
The present invention relates to a kind of magnesium alloy, particularly a kind of MgAlSi is the heat resistance magnesium alloy that is applicable to cast especially die casting.
Background technology
Along with scientific and technological development, the vehicles taking automobile as representative need to, by alleviating the weight of vehicle body, further be researched and developed the product innovation that fuel availability is higher.In automobile industry, magnesium alloy, as a kind of novel lightweight metal material, is used for substituting traditional cast iron by automaker, to realize the object that alleviates tare.
At present, domestic MgAlSi is that the diecast magnesium alloy trade mark has YM102, YM103, YM104, YM105, YM106; The MgAlSi of USS ASTM B is that the diecast magnesium alloy trade mark has AS21A, AS21B, AS41A, AS41B; The MgAlSi of Nippon Standard JIS H is that the diecast magnesium alloy trade mark has MDC6, MDC3B; The MgAlSi of European standard EN is that the diecast magnesium alloy trade mark has EN-MC21310, EN-MC21320.The alloy of these trades mark has mobility, feature that castability is good, and is widely used in the forging types such as die casting, low-pressure casting, permanent mold casting, precision casting, semi-solid casting, sand mold casting.Owing to containing more silicon addition, grain boundaries has part Mg
2si has replaced Mg mutually
17al
12the position of phase, with respect to AZ system and AM series magnesium alloy, its high-temperature behavior increases, and MgAlSi is that diecast magnesium alloy is suitable for 150 DEG C of following workplaces.
Realizing in process of the present invention, contriver finds that prior art at least exists following problem: because β in the alloy structure of above-mentioned MgAlSi series magnesium alloy is mutually still with Mg
17al
12be main, Mg
17al
12fusing point is lower, makes existing MgAlSi series magnesium alloy cannot adapt to 150 DEG C of above high temperature, thereby cannot be applied in 150 DEG C of above hot environments.
Summary of the invention
In order to solve above-mentioned problems of the prior art, the embodiment of the present invention provides a kind of heat resistance magnesium alloy containing Nb with good die casting.Described technical scheme is as follows:
A kind of heat resistance magnesium alloy containing Nb, described magnesium alloy is elementary composition by Mg, Al, Si, Mn, rare earth, Nb and M, its weight percent consists of Al1.6%-9.8%, Si0.5%-2.5%, Mn0.05%-0.7%, rare earth 0.001%-10%, Nb0.0002%-4%, M element 0.001%-0.3%, and all the other are Mg; Wherein, M element is at least one in Ti, Sr, C, B, and described Nb adds in described magnesium alloy by the form of AlNb master alloy or NbAl master alloy.Wherein, described rare earth is at least one in Gd, Y, Sc, Sm, Nd, Pr, Yb, La, Ce, Tb, Dy, Ho and Er.
Preferably, described rare earth is at least one in Gd or Gd and Y, Sc, Sm, Nd, Pr, Yb, La, Ce, Tb, Dy, Ho and Er.
Preferably, its weight percent consists of Al1.8%-2.5%, Si0.7%-1.2%, Mn0.05%-0.7%, Gd0.1%-4%, Nb0.05%-1%, M element 0.001%-0.3%, and all the other are Mg.
Preferably, its weight percent consists of Al3.5%-5%, Si0.5%-1.5%, Mn0.18%-0.7%, Gd0.1%-2%, Nb0.05%-1%, M element 0.001%-0.3%, and all the other are Mg.
More preferably, its weight percent consists of Al2.2%, Si1%, Mn0.2%, Gd0.5%, Nb0.2%, M element 0.2%, and all the other are Mg.
More preferably, its weight percent consists of Al4.6%, Si0.5%, Mn0.4%, Gd0.5%, Nb0.2%, M element 0.2%, and all the other are Mg.
The beneficial effect that the technical scheme that the embodiment of the present invention provides is brought is: in diecast magnesium alloy provided by the invention, because RE can form MgRE compound with Mg, Nb can form some resistant to elevated temperatures metallic compounds with other elements (as Al), these metallic compounds are distributed on crystal boundary, have substituted part Mg
17al
12β phase, has changed the structure of β phase; M element can crystal grain thinning in addition, delays growing up of crystal grain, carries heavy alloyed elongation, and elongation is the index of weighing metallic substance plasticity, refers to metallic substance under external force, produces tension set and unlikely ability of breaking.Under the combined action of above-mentioned element, improve the resistance to elevated temperatures of diecast magnesium alloy, obtain one and there is good mechanical property, machinability, mobility and die casting are good, and applicable casting is the heat resistance magnesium alloy of die casting especially.
Embodiment
For making the object, technical solutions and advantages of the present invention clearer, below embodiment of the present invention is described further in detail.
Manufacture craft, the heat treating method of the magnesium alloy that the embodiment of the present invention provides are described as follows:
1, the magnesium alloy that the embodiment of the present invention provides can be made by following three kinds of melting technologies:
Technique one: the magnesium alloy composition providing according to the embodiment of the present invention and cubage are also ready to the starting material of aequum, in resistance furnace, add magnesium ingot, aluminium ingot, AlSi master alloy, MgMn master alloy, AlNb master alloy or NbAl master alloy, in addition, also add at least one in AlTi master alloy, MgSr master alloy or AlSr master alloy, Graphite Powder 99, AlB master alloy.Heat up to resistance furnace used, in the time that the above-mentioned metal adding melts soon, adopt gas shield or magnesium alloy covering agent protection.While being warmed up to 720 DEG C-780 DEG C, add MgRE master alloy (as MgGd, MgY, MgNd etc.) or AlRE master alloy, and stir, leave standstill insulation 30 minutes at 720 DEG C-780 DEG C, obtain aluminium alloy.Water a fritter sample with gained aluminium alloy, detect its Melting Quality, as: carry out gas content inspection according to gas content inspection method, if second-rate, need carry out refining treatment; If up-to-standard, described aluminium alloy temperature adjustment to 700 DEG C-740 DEG C is skimmed, then pour into a mould, obtain the foundry goods of alloy of the present invention.
In this technique, resistance furnace also can replace with other smelting furnaces; Shielding gas is argon gas; Magnesium alloy covering agent and master alloy product are market sale product; Refining treatment method adopts the ordinary method of the industry.
Technique two: the magnesium alloy composition providing according to the embodiment of the present invention and cubage are also ready to the starting material of aequum, in vacuum oven, add aluminium ingot, AlSi master alloy, AlMn master alloy or Mn agent, AlNb master alloy, in addition, also add at least one in AlTi master alloy, MgSr master alloy or AlSr master alloy, Graphite Powder 99, AlB master alloy.Be warming up to 820 DEG C, insulation 2-8 hour, then cools to 720 DEG C-780 DEG C, adds magnesium ingot and RE.After added melting of metal, 720 DEG C-780 DEG C insulations 30 minutes, obtain aluminium alloy, adopt gas shield or magnesium alloy covering agent protection to prevent aluminium alloy oxidation.Water a fritter sample with gained aluminium alloy, detect its Melting Quality, as: the inspection of gas content, if second-rate, need carry out refining treatment; If up-to-standard, described aluminium alloy temperature adjustment to 700 DEG C-740 DEG C is skimmed, then pour into a mould, obtain the foundry goods of alloy of the present invention.
In this technique, vacuum oven can substitute with other smelting furnaces such as main frequency furnaces; Shielding gas is argon gas; Magnesium alloy covering agent, RE, Mn agent and master alloy are sell goods on market; Refining treatment method adopts the ordinary method of the industry.
Technique three: magnesium alloy composition and the cubage providing according to the embodiment of the present invention the starting material that are ready to aequum, in smelting furnace, adding standard brand MgAlSi is diecast magnesium alloy, AlNb master alloy, in addition, also add at least one in AlTi master alloy, MgSr master alloy or AlSr master alloy, Graphite Powder 99, AlB master alloy.Above-mentioned metal adopts gas shield or magnesium alloy covering agent protection while fusing soon.While being warmed up to 720 DEG C-780 DEG C, add MgRE master alloy (as MgGd, MgY, MgNd etc.) or AlRE master alloy, and stir, leave standstill insulation 30 minutes at 720 DEG C-780 DEG C, obtain aluminium alloy.Water a fritter sample with gained aluminium alloy, detect its Melting Quality, as: carry out gas content inspection according to gas content inspection method, if second-rate, need carry out refining treatment; If up-to-standard, described aluminium alloy temperature adjustment to 700 DEG C-740 DEG C is skimmed, then pour into a mould, obtain the foundry goods of alloy of the present invention.
In this technique, shielding gas is argon gas; Magnesium alloy covering agent and master alloy are sell goods on market; Refining treatment method adopts the ordinary method of the industry.
Thermal treatment and the treatment process thereof of the magnesium alloy that 2, the embodiment of the present invention provides:
Die casting in the magnesium alloy that the embodiment of the present invention provides can not heat-treated, and the cast member of other form can be heat-treated, and generally adopts T4 solution treatment.The embodiment of the present invention adopt thermal treatment be that T4 solid solution treatment process is: cast member is warming up in chamber type electric resistance furnace to 440 DEG C, is incubated 10 hours, cast member come out of the stove after shrend, 40 DEG C of water temperatures.
Be subject to fusion process to select the impact of some other inevitable factor in the purity of raw material and melting, castingprocesses, the Mg alloy castings that the embodiment of the present invention provides can contain inevitable impurity, as Zn, Fe, Cu etc., as long as weight percent≤0.5% of described inevitable total impurities in described magnesium alloy finished product, weight percent≤0.1% of single contaminant in described magnesium alloy finished product, just can not cause obvious impact to the performance of magnesium alloy.
Embodiment 1
Prepare heat resistance magnesium alloy by step described in above-mentioned technique one, foundry goods adopts die cast, and the weight percent of described magnesium alloy consists of Al1.6%, Si0.5%, Mn0.05%, Y0.001%, Nb0.0002%, Ti0.001%, and all the other are Mg.
Foundry goods is heat-treated.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 2
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts semi-solid casting, and the weight percent of described magnesium alloy consists of Al9.8%, Si2.5%, Mn0.7%, Sm10%, Nb4%, Sr0.3%, and all the other are Mg.
Foundry goods is heat-treated.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 3
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of heat resistance magnesium alloy consists of Al4%, Si0.6%, Mn0.06%, Nd9%, Nb3%, C0.3%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 4
Prepare heat resistance magnesium alloy by step described in above-mentioned technique one, foundry goods adopts low-pressure casting, and the weight percent of described magnesium alloy consists of Al1.8%, Si0.7%, Mn0.05%, La0.1%, Nb0.05%, B0.001%, and all the other are Mg.
Foundry goods is heat-treated.The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 5
Prepare heat resistance magnesium alloy by step described in above-mentioned technique three, the described standard brand diecast magnesium alloy using in preparation process is YM103, foundry goods adopts precision casting, the weight percent of described magnesium alloy consists of Al2.5%, Si1.2%, Mn0.1%, Ce4%, Nb1%, C0.1%, and all the other are Mg.
Foundry goods is heat-treated.The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 6
Prepare heat resistance magnesium alloy by step described in above-mentioned technique one, foundry goods adopts sand mold casting, and the weight percent of described magnesium alloy consists of Al2.2%, Si1%, Mn0.2%, Gd0.5%, Nb0.2%, Ti0.2%, and all the other are Mg.Foundry goods is heat-treated.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 7
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al2.2%, Si1%, Mn0.2%, Gd0.3%, Tb0.2%, Nb0.2%, Ti0.2%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 8
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al2.2%, Si1%, Mn0.2%, Tb0.5%, Nb0.2%, Ti0.2%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 9
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al3.5%, Si0.5%, Mn0.18%, Dy0.1%, Nb0.05%, B0.001%, and all the other are Mg.
The performance of the magnesium alloy that the present embodiment provides is referring to table 1.
Embodiment 10
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al5%, Si1.5%, Mn0.7%, Ho2%, Nb1%, Sr0.3%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 11
Prepare heat resistance magnesium alloy by step described in above-mentioned technique one, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al4%, Si1%, Mn0.5%, Er1%, Nb0.5%, C0.01%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 12
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al4.6%, Si0.5%, Mn0.4%, Gd0.5%, Nb0.2%, Ti0.2%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 13
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al4.6%, Si0.5%, Mn0.4%, Gd0.3%, Sc0.2%, Nb0.2%, Ti0.2%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Embodiment 14
Prepare heat resistance magnesium alloy by step described in above-mentioned technique two, foundry goods adopts Hpdc, and the weight percent of described magnesium alloy consists of Al4.6%, Si0.5%, Mn0.4%, Sc0.5%, Nb0.2%, Ti0.2%, and all the other are Mg.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
Comparative example
Prepare heat resistance magnesium alloy by step described in above-mentioned technique one, foundry goods adopts Hpdc, and described magnesium alloy weight percent consists of Al4.6%, Si0.5%, Mn0.4%, Gd0.5%, Ti0.2%, and all the other are Mg and inevitable impurity.
The performance of the Mg alloy castings that the present embodiment provides is referring to table 1.
The Mg alloy castings that each embodiment provides above all contains inevitable impurity, weight percent≤0.5% of described inevitable total impurities in described magnesium alloy finished product, weight percent≤0.1% of single contaminant in described magnesium alloy finished product.
The same with AS21A, AS41A, magnesium alloy provided by the invention is applicable to the forging types such as die cast, Hpdc, semi-solid casting, low-pressure casting, precision casting, sand mold casting.
The Mechanics Performance Testing of foundry goods is carried out on electronic universal tester.The mechanical property of the Mg alloy castings that various embodiments of the present invention and comparative example provide is referring to table 1.
The mechanical property parameters table of the Mg alloy castings that the each embodiment of table 1 provides
As shown in Table 1, the Mg alloy castings that the embodiment of the present invention provides tensile strength under 200 DEG C of high temperature is all greater than 180MPa, be diecast magnesium alloy higher than existing MgAlSi far away, there is good resistance toheat, simultaneously referring to embodiment 12 and comparative example, the Mg alloy castings that the embodiment of the present invention provides, compared with not adding the Mg alloy castings of Nb, has better resistance toheat; By the contrast between embodiment 6-8 and embodiment 12-14, in the known RE containing, there is the effect of Gd better; The Mg alloy castings that embodiment 6 and 12 provides tensile strength under 200 DEG C of high temperature is the highest, and the Mg alloy castings thermotolerance that embodiment 6 and 12 provides is the strongest.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any amendment of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (7)
1. the heat resistance magnesium alloy containing Nb, it is characterized in that, described magnesium alloy is elementary composition by Mg, Al, Si, Mn, rare earth, Nb and M, its weight percent consists of Al1.6%-9.8%, Si0.5%-2.5%, Mn0.05%-0.7%, rare earth 0.001%-10%, Nb0.0002%-4%, M element 0.001%-0.3%, and all the other are Mg; Wherein, M element is at least one in Ti, Sr, C, B, and described Nb adds in described magnesium alloy by the form of AlNb master alloy or NbAl master alloy.
2. magnesium alloy according to claim 1, is characterized in that, described rare earth is at least one in Gd, Y, Sc, Sm, Pr, Yb, Nd, La, Ce, Tb, Dy, Ho and Er.
3. magnesium alloy according to claim 1 and 2, is characterized in that, described rare earth is at least one in Gd or Gd and Y, Sc, Sm, Pr, Yb, Nd, La, Ce, Tb, Dy, Ho and Er.
4. magnesium alloy according to claim 1, is characterized in that, its weight percent consists of Al1.8%-2.5%, Si0.7%-1.2%, Mn0.05%-0.7%, Gd0.1%-4%, Nb0.05%-1%, M element 0.001%-0.3%, and all the other are Mg.
5. magnesium alloy according to claim 1, is characterized in that, its weight percent consists of Al3.5%-5%, Si0.5%-1.5%, Mn0.18%-0.7%, Gd0.1%-2%, Nb0.05%-1%, M element 0.001%-0.3%, and all the other are Mg.
6. magnesium alloy according to claim 4, is characterized in that, its weight percent consists of Al2.2%, Si1%, Mn0.2%, Gd0.5%, Nb0.2%, M element 0.2%, and all the other are Mg.
7. magnesium alloy according to claim 5, is characterized in that, its weight percent consists of Al4.6%, Si0.5%, Mn0.4%, Gd0.5%, Nb0.2%, M element 0.2%, and all the other are Mg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110267000.4A CN102994834B (en) | 2011-09-09 | 2011-09-09 | Heatproof magnesium alloy containing Nb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110267000.4A CN102994834B (en) | 2011-09-09 | 2011-09-09 | Heatproof magnesium alloy containing Nb |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102994834A CN102994834A (en) | 2013-03-27 |
| CN102994834B true CN102994834B (en) | 2014-12-10 |
Family
ID=47923939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110267000.4A Active CN102994834B (en) | 2011-09-09 | 2011-09-09 | Heatproof magnesium alloy containing Nb |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102994834B (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313426B (en) * | 2014-10-16 | 2017-01-11 | 辽宁石油化工大学 | Alkaline-earth element modified heat-resistant magnesium alloy and preparation method thereof |
| CN104498795A (en) * | 2014-12-15 | 2015-04-08 | 春兴精工（常熟）有限公司 | Preparation method of Mg alloy |
| CN107815577A (en) * | 2017-11-08 | 2018-03-20 | 广西超盛网络科技有限责任公司 | A kind of heat resistance magnesium alloy |
| CN108707798A (en) * | 2018-06-19 | 2018-10-26 | 苏州爱盟机械有限公司 | Wheel hub alloy material |
| CN108707799A (en) * | 2018-06-28 | 2018-10-26 | 太仓新浏精密五金有限公司 | Magnesium alloy |
| CN109022974A (en) * | 2018-08-24 | 2018-12-18 | 重庆元和利泰镁合金制造有限公司 | A kind of magnesium alloy motor casing production method and motor housing |
| CN109280832B (en) * | 2018-10-17 | 2020-01-17 | 河南科技大学 | High-strength flame-retardant magnesium alloy and preparation method thereof |
| CN109930044B (en) * | 2019-03-29 | 2021-07-09 | 江苏中翼汽车新材料科技有限公司 | High-strength-toughness heat-resistant Mg-Gd-Y alloy suitable for gravity casting and preparation method thereof |
| CN109811224B (en) * | 2019-03-29 | 2021-07-09 | 南京航空航天大学 | High-strength high-toughness heat-resistant die-casting Mg-Y-Er alloy and preparation method thereof |
| CN109881064B (en) * | 2019-03-29 | 2021-09-24 | 上海交通大学 | High-strength high-toughness heat-resistant die-casting Mg-Gd-Y alloy and preparation method thereof |
| CN109943759B (en) * | 2019-03-29 | 2021-07-20 | 凤阳爱尔思轻合金精密成型有限公司 | High-strength-toughness heat-resistant Mg-Er alloy suitable for gravity casting and preparation method thereof |
| CN109852859B (en) * | 2019-03-29 | 2021-07-20 | 凤阳爱尔思轻合金精密成型有限公司 | High-strength-toughness heat-resistant Mg-Y-Er alloy suitable for gravity casting and preparation method thereof |
| CN109868402B (en) * | 2019-03-29 | 2021-08-17 | 上海交通大学 | High-strength-toughness heat-resistant die-casting Mg-Y alloy and preparation method thereof |
| CN109852858B (en) * | 2019-03-29 | 2021-07-09 | 江苏中翼汽车新材料科技有限公司 | High-strength high-toughness heat-resistant Mg-Er alloy suitable for low-pressure casting and preparation method thereof |
| CN109881065B (en) * | 2019-03-29 | 2021-07-20 | 凤阳爱尔思轻合金精密成型有限公司 | High-strength high-toughness heat-resistant Mg-Gd-Er alloy suitable for low-pressure casting and preparation method thereof |
| CN109852860B (en) * | 2019-03-29 | 2021-07-09 | 南京航空航天大学 | High-strength-toughness heat-resistant Mg-Y alloy suitable for low-pressure casting and preparation method thereof |
| CN109797332B (en) * | 2019-03-29 | 2021-01-19 | 南京航空航天大学 | High-strength-toughness heat-resistant Mg-Gd-Y alloy suitable for low-pressure casting and preparation method thereof |
| CN109943757B (en) * | 2019-03-29 | 2021-07-20 | 上海交通大学 | High-strength-toughness heat-resistant Mg-Y-Er alloy suitable for low-pressure casting and preparation method thereof |
| CN109807302B (en) * | 2019-03-29 | 2022-01-11 | 江苏中翼汽车新材料科技有限公司 | High-strength high-toughness heat-resistant die-casting Mg-Gd alloy and preparation method thereof |
| CN109881066B (en) * | 2019-03-29 | 2021-09-28 | 上海交通大学 | High-strength-toughness heat-resistant Mg-Gd alloy suitable for low-pressure casting and preparation method thereof |
| CN109930045B (en) * | 2019-03-29 | 2021-07-09 | 南京航空航天大学 | High-strength-toughness heat-resistant Mg-Gd alloy suitable for gravity casting and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06330216A (en) * | 1993-05-19 | 1994-11-29 | Nippon Steel Corp | Magnesium alloy |
| CN1382823A (en) * | 2001-03-14 | 2002-12-04 | 利优比株式会社 | Creep resistance Dow metal |
| JP2005187896A (en) * | 2003-12-26 | 2005-07-14 | Mitsubishi Alum Co Ltd | Heat resistant magnesium alloy casting |
| CN101512027A (en) * | 2006-09-01 | 2009-08-19 | 独立行政法人产业技术综合研究所 | High-strength flame resistant magnesium alloy |
-
2011
- 2011-09-09 CN CN201110267000.4A patent/CN102994834B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06330216A (en) * | 1993-05-19 | 1994-11-29 | Nippon Steel Corp | Magnesium alloy |
| CN1382823A (en) * | 2001-03-14 | 2002-12-04 | 利优比株式会社 | Creep resistance Dow metal |
| JP2005187896A (en) * | 2003-12-26 | 2005-07-14 | Mitsubishi Alum Co Ltd | Heat resistant magnesium alloy casting |
| CN101512027A (en) * | 2006-09-01 | 2009-08-19 | 独立行政法人产业技术综合研究所 | High-strength flame resistant magnesium alloy |
Non-Patent Citations (1)
| Title |
|---|
| 粉末高温铝合金及其复合材料;单玲;《中国钼业》;19970430;第21卷(第1期);第20-23页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102994834A (en) | 2013-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102994834B (en) | Heatproof magnesium alloy containing Nb | |
| CN102618758B (en) | Cast magnesium alloy of low linear shrinkage | |
| CN102618760B (en) | MgAlZn series heat resistant magnesium alloy containing niobium | |
| CN102994835B (en) | Heatproof magnesium alloy | |
| CN102618757B (en) | Heat-resistant magnesium alloy | |
| CN102618762B (en) | Heat-resisting magnesium alloy | |
| CN109487107B (en) | Composite modifier for cast aluminum alloy with iron-rich phase modification and modification method thereof | |
| CN102618764A (en) | Magnesium alloy with hot cracking resistance and low linear shrinkage | |
| CN107881378B (en) | Aluminum alloy composition, aluminum alloy element, communication product and preparation method of aluminum alloy element | |
| CN102994847B (en) | Heatproof magnesium alloy | |
| WO2011090451A1 (en) | CASTING ALLOY OF THE AIMgSI TYPE | |
| WO2016068494A1 (en) | Aluminum alloy for die-casting, having improved corrosion resistance | |
| CN102230116A (en) | High-hardness cast magnesium alloy | |
| CN102994840B (en) | MgAlZn heat resistance magnesium alloy | |
| Liao et al. | Effect of RE addition on solidification process and high-temperature strength of Al− 12% Si− 4% Cu− 1.6% Mn heat-resistant alloy | |
| CN102618765B (en) | Magnesium alloy with hot cracking resistance and low linear shrinkage | |
| CN102618763A (en) | Heat resistant magnesium alloy | |
| JP2019065344A (en) | Low thermal expansion alloy | |
| CN102994838B (en) | MgAlSi heat resistance magnesium alloy | |
| CN102994836B (en) | Tough magnesium alloy with high elongation rate | |
| CN110306084B (en) | High-strength low-friction low-expansion high-silicon aluminum alloy and preparation method thereof | |
| CN102618759B (en) | Low-shrinkage magnesium alloy | |
| CN104561709B (en) | High-creep-performance casting magnesium alloy and preparation method thereof | |
| CN102994839B (en) | Heatproof casting magnesium alloy | |
| CN109161767B (en) | Creep-resistant magnesium alloy containing W phase and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Zengshi Inventor before: Feng Jun |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20171106 Address after: 533000, No. 55, Zhongshan Road, Youjiang District, the Guangxi Zhuang Autonomous Region, Baise Patentee after: Institute of scientific and technical information, Youjiang District, Baise Address before: 430056 Hubei, Zhuankou economic and Technological Development Zone, the new road,, Jianghan University, No. 8 Patentee before: Jianghan University |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171227 Address after: 530029 Nanning Road, Qingxiu District Thailand No. 9 the Guangxi Zhuang Autonomous Region Tianjian International Mansion block A No. 2803 Patentee after: GUANGXI ONE BELT ONE ROAD TECHNOLOGY CO.,LTD. Address before: 533000, No. 55, Zhongshan Road, Youjiang District, the Guangxi Zhuang Autonomous Region, Baise Patentee before: Institute of scientific and technical information, Youjiang District, Baise |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191125 Address after: 313000 1-C, building 1, No. 656, Qixing Road, high tech Zone, Wuxing District, Huzhou City, Zhejiang Province Patentee after: Huzhou xinbeilian Network Technology Co.,Ltd. Address before: No.2803, building a, Tianjian International Mansion, No.9 Zhongtai Road, Qingxiu District, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: GUANGXI ONE BELT ONE ROAD TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191223 Address after: 314413 No.9 Lianbao Road, Qianjiang Industrial Park, Dingqiao Town, Haining City, Jiaxing City, Zhejiang Province Patentee after: Haining Qianjiang Xingye Investment Development Co.,Ltd. Address before: 313000 1-C, building 1, No. 656, Qixing Road, high tech Zone, Wuxing District, Huzhou City, Zhejiang Province Patentee before: Huzhou xinbeilian Network Technology Co.,Ltd. |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130327 Assignee: Haining Xinfeng Machinery Co.,Ltd. Assignor: Haining Qianjiang Xingye Investment Development Co.,Ltd. Contract record no.: X2022330000847 Denomination of invention: A heat-resistant magnesium alloy containing Nb Granted publication date: 20141210 License type: Common License Record date: 20221226 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A heat-resistant magnesium alloy containing Nb Granted publication date: 20141210 Pledgee: Haining rural commercial bank Limited by Share Ltd. Zhejiang branch Pledgor: Haining Qianjiang Xingye Investment Development Co.,Ltd. Registration number: Y2024980001393 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |