CN102964753B - 稀土改性空心玻璃微珠/聚偏氟乙烯复合材料的制备方法 - Google Patents
稀土改性空心玻璃微珠/聚偏氟乙烯复合材料的制备方法 Download PDFInfo
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- CN102964753B CN102964753B CN201210308987.4A CN201210308987A CN102964753B CN 102964753 B CN102964753 B CN 102964753B CN 201210308987 A CN201210308987 A CN 201210308987A CN 102964753 B CN102964753 B CN 102964753B
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- Prior art keywords
- hollow glass
- glass micropearl
- rare earth
- polyvinylidene fluoride
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002981 polyvinylidene fluoride Polymers 0.000 title claims abstract description 110
- 239000011521 glass Substances 0.000 title claims abstract description 88
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 56
- 239000002131 composite material Substances 0.000 title claims abstract description 39
- 239000002033 PVDF binder Substances 0.000 title claims abstract description 38
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000011324 bead Substances 0.000 title abstract description 9
- -1 rare earth nitrate Chemical class 0.000 claims abstract description 33
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 230000004048 modification Effects 0.000 claims description 28
- 238000012986 modification Methods 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 238000001291 vacuum drying Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 abstract description 14
- 229910002651 NO3 Inorganic materials 0.000 abstract description 6
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 abstract description 4
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 abstract description 3
- CFYGEIAZMVFFDE-UHFFFAOYSA-N neodymium(3+);trinitrate Chemical compound [Nd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CFYGEIAZMVFFDE-UHFFFAOYSA-N 0.000 abstract description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract description 2
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000005616 pyroelectricity Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- DKWSBNMUWZBREO-UHFFFAOYSA-N terbium Chemical compound [Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb][Tb] DKWSBNMUWZBREO-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- BXJPTTGFESFXJU-UHFFFAOYSA-N yttrium(3+);trinitrate Chemical compound [Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O BXJPTTGFESFXJU-UHFFFAOYSA-N 0.000 description 1
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- Glass Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210308987.4A CN102964753B (zh) | 2012-08-28 | 2012-08-28 | 稀土改性空心玻璃微珠/聚偏氟乙烯复合材料的制备方法 |
Applications Claiming Priority (1)
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CN201210308987.4A CN102964753B (zh) | 2012-08-28 | 2012-08-28 | 稀土改性空心玻璃微珠/聚偏氟乙烯复合材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102964753A CN102964753A (zh) | 2013-03-13 |
CN102964753B true CN102964753B (zh) | 2014-07-16 |
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CN201210308987.4A Expired - Fee Related CN102964753B (zh) | 2012-08-28 | 2012-08-28 | 稀土改性空心玻璃微珠/聚偏氟乙烯复合材料的制备方法 |
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CN (1) | CN102964753B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106423135B (zh) * | 2016-10-12 | 2018-12-11 | 清华大学 | 一种负载型二氧化铈催化剂及其制备方法 |
CN113512326A (zh) * | 2021-08-04 | 2021-10-19 | 江苏美嘉包装有限公司 | 一种酒盒包装印刷用高抗污保护涂层及其加工工艺 |
CN113774681B (zh) * | 2021-11-11 | 2022-02-08 | 天津环球休闲用品有限公司 | 一种耐折隔热帐篷面料的制备方法 |
CN114085039B (zh) * | 2022-01-18 | 2022-04-01 | 山东墨匠新材料科技有限公司 | 高强度高模量玻璃纤维组合物及玻璃纤维的生产方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008520768A (ja) * | 2004-11-16 | 2008-06-19 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロスフェア充填高分子複合材料 |
WO2008081173A1 (en) * | 2006-12-29 | 2008-07-10 | World Minerals, Inc. | Polymer compositions comprising fluoro elastomers and expanded perlite |
WO2009091987A2 (en) * | 2008-01-18 | 2009-07-23 | Wild River Consulting Group, Llc | Melt molding polymer composite and method of making and using the same |
CN102439083A (zh) * | 2009-04-29 | 2012-05-02 | 腾德拉合成有限公司 | 复合组合物 |
-
2012
- 2012-08-28 CN CN201210308987.4A patent/CN102964753B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008520768A (ja) * | 2004-11-16 | 2008-06-19 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロスフェア充填高分子複合材料 |
WO2008081173A1 (en) * | 2006-12-29 | 2008-07-10 | World Minerals, Inc. | Polymer compositions comprising fluoro elastomers and expanded perlite |
WO2009091987A2 (en) * | 2008-01-18 | 2009-07-23 | Wild River Consulting Group, Llc | Melt molding polymer composite and method of making and using the same |
CN102439083A (zh) * | 2009-04-29 | 2012-05-02 | 腾德拉合成有限公司 | 复合组合物 |
Non-Patent Citations (2)
Title |
---|
稀土元素对玻璃纤维增强PTFE复合材料拉伸性能的影响;薛玉君等;《无机材料学报》;20020520;第17卷(第03期);第531-538页 * |
薛玉君等.稀土元素对玻璃纤维增强PTFE复合材料拉伸性能的影响.《无机材料学报》.2002,第17卷(第03期),第531-538页. |
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CN102964753A (zh) | 2013-03-13 |
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CB03 | Change of inventor or designer information | ||
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Inventor after: Jiang Yanxin Inventor before: Liu Zhifeng Inventor before: Li Junwei Inventor before: Tian Dongkui |
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Effective date of registration: 20170727 Address after: 050051 No. 2, No. 11, No. 598 Heping West Road, Xinhua District, Hebei, Shijiazhuang, 601 Patentee after: Jiang Yanxin Address before: 300381 Tianjin Huayuan Industrial Park Xiqing district (outer ring) six Haitai development road 6 green industrial base 3 door 501 seat F Patentee before: Tianjin Pharmacn Medical Technology Co., Ltd. |
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Granted publication date: 20140716 Termination date: 20180828 |