CN102952441A - Heat-insulation waterproof coating - Google Patents
Heat-insulation waterproof coating Download PDFInfo
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- CN102952441A CN102952441A CN201110242834XA CN201110242834A CN102952441A CN 102952441 A CN102952441 A CN 102952441A CN 201110242834X A CN201110242834X A CN 201110242834XA CN 201110242834 A CN201110242834 A CN 201110242834A CN 102952441 A CN102952441 A CN 102952441A
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Abstract
The invention relates to a heat-insulation waterproof coating. The coating comprises 10-15% of a high-performance organic silicon emulsion, 23-25% of a pure acrylic emulsion, 18-22% of titanium dioxide, 3-5% of talcum powder, 2-3.5% of diatomite, 3-5.1% of heavy calcium carbonate, 1.7-2.2% of calcined kaolin, 7-10% of a ceramic bead, 8-10% of a hollow glass bead, 6-12% of water, 0.6-1.2% of a multifunctional assistant, 1.5-3.2% of a hydrophobic agent, 0.3-1.0% of a cosolvent and 0.2-0.3% of an antifoaming agent. The coating has the effects of heat insulation, water proofness, fire proofness, self cleaning, sound insulation, noise reduction and energy saving.
Description
Technical field
The present invention relates to a kind of heat-insulating waterproof coating, a kind of heat insulation, waterproof, fire prevention, self-cleaning, sound insulation and noise reduction, insulation, energy-conservation coating of integrating is provided especially, belong to the fine chemical technology field.
Background technology
Emulsion paint be to meet the health environment-friendly demand, but that the trouble of usually running into is water-absorbent is strong, when being used for the decoration supercoat of buildings, variable color can absorb water.If base material is cement composition, the moisture that enters can be piled up the saline and alkaline metope that takes to wherein when drying at coating surface, accelerate its corrosion the work-ing life of not only having reduced cement, and distortion and aging, and make the paint film variable color, destroy.In some building coatings that very low PVC is filled a prescription, paint film is dense, although entering of moisture is restricted, some moisture that slowly enter appear imbalance in transition process, be easy to occur the foaming phenomenon between coating surface or paint film and base material, cause paint film to destroy or come off.Another adverse consequences of paint film suction is moisture with coating surface, and a large amount of meetings that contacts is brought pollutent in the micropore of coating or is adhered to coating surface and forms ugly stain.
Thermal insulating coating has good heat-proof quality and simple construction process because of it, and the effect in modern industry and production is increasing.Thermal insulating coating is coated on surface at buildings, can obviously reduce room temp, makes people that a good Working environment be arranged in the summer of sweltering heat.Buildings Heat Reflection type thermal insulating coating has excellent heat-insulation and heat-preservation function, is the study hotspot of current energy-saving building materials.Along with wideling popularize of insulating mold coating for construction, the architectural reflective heat-insulation paint that exploiting economy, convenience and effect of heat insulation are good is of great immediate significance to social energy conservation.
According to mechanism of heat insulation, present thermal insulating coating can be divided into isolation-type thermal insulating coating, reflection type thermal insulation coating and Radiation Heat-insulated Paint.All there are its relative merits in this three classes thermal insulating coating, in research process, they can be integrated, and gives full play to characteristics separately, has complementary advantages.At present, along with deepening continuously of research and development, the continuous maturation of technical matters, the integrated Water-based thermal insulation coating of efficient thin layer heat insulating and corrosion that integrates three kinds of heat insulating functions will become the main direction of following thermal insulating coating research.
At present, also there be not a kind of heat insulation, waterproof, fire prevention, self-cleaning, sound insulation and noise reduction, insulation, energy-conservation heat-insulating waterproof coating of integrating of bibliographical information.
Summary of the invention
In view of the deficiencies in the prior art, the object of the present invention is to provide a kind of heat insulation, waterproof, fire prevention, self-cleaning, sound insulation and noise reduction, insulation, energy-conservation heat-insulating waterproof coating of integrating.
The object of the present invention is achieved like this:
A kind of heat-insulating waterproof coating comprises the component of following weight percent:
High performance organo-silicon emulsion 10%-15% | Pure-acrylic emulsion 23%-25% |
Titanium dioxide 18%-22% | Talcum powder 3%-5% |
Diatomite 2%-3.5% | Water-ground limestone 3%-5.1% |
Calcined kaolin 1.7%-2.2% | Ceramic fine bead 7%-10% |
Hollow glass bead 8%-10% | Water 6%-12% |
Multifunctional assistant 0.6%-1.2% | Solubility promoter 0.3%-1.0% |
Defoamer 0.2%-0.3% | Hydrophobizing agent 1.5%-3.2%. |
Above-mentioned heat-insulating waterproof coating, wherein, the fineness of titanium dioxide, talcum powder, diatomite, water-ground limestone or calcined kaolin is ground to the 700-800 order.
Above-mentioned heat-insulating waterproof coating, wherein, the fineness of ceramic fine bead or hollow glass bead is ground to the 250-350 order.
Above-mentioned heat-insulating waterproof coating, described multifunctional assistant is preferably the alkyl acid Soxylat A 25-7.
Above-mentioned heat-insulating waterproof coating, described solubility promoter is preferably the propylene glycol of concentration 96%-98%.
Above-mentioned heat-insulating waterproof coating, described defoamer is preferably the methyl-silicone oil of concentration 25%-33%.
Above-mentioned heat-insulating waterproof coating, described titanium dioxide are Rutile type Titanium Dioxide.
The heat-insulating waterproof coating that the present invention relates to is suitable for civil area, such as the heat-insulation and heat-preservation on the skins such as office building, hospital, hotel, school, dwelling house, warehouse, large supermarket, factory and roof.Be more suitable for simultaneously industrial circle.Insulated heat such as iron sheet factory building, hardware, oil tank, grain depot storage tank, refrigeration plant, moving oil tank car.
Compared with prior art, the heat-insulating waterproof coating that the present invention relates to has following advantage and significant progressive:
(1) infrared rays of reflection 99.5% and 90% above visible light, and isolated ultraviolet ray.In the situation that summer, direct sunlight reflected back most infrared rays and visible light, secondly again the heat of coatingsurface is launched back in the atmospheric environment up to the hemispherical emissivity of 86 ﹪, particularly to the special emissivity of ceramic particle when atmospheric temperature reduces in evening be transmitted into body of wall and indoor accumulation of heat outdoor again, indoor so just can not feel sultry, particularly the house effect of metal structure is particularly evident, such as iron sheet factory building, warehouse, oil tank, grain depot storage tank, refrigeration plant, moving oil tank car etc.Extremely low heat-conduction coefficient itself further plays heat insulation effect.The SSM sage who uses as interior wall in the winter nurse thermal insulating coating that walks slowly like a woman can be returned the thermal radiation of dispersing within doors, plays effect cool in summer and warm in winter.In air conditioner surroundings, save the mass energy expense.
(2) has the hydrophobic self-cleaning function of uniqueness " surface effects as the lotus leaf ", rainwater tumbles together with floating dust, emerges unstained from the filth, even through hose testing, the surface anhydrous stain that still keeps dry greatly improves because floating dust is accumulated in the thermal insulating coating surface for a long time and reduces reflection function.
(3) heat-insulating waterproof coating that the present invention relates to is a kind of " longevity " coating, and can reach 10~15 years working life, and the effect of heat insulation within the time limit does not have to change substantially.This reduces the frequency that repeats application with regard to the corresponding effect of heat insulation that prolongs coating.In the long run/term, the coating more with the recoat number of times, that price is relatively low is compared, and the heat-insulating waterproof coating that the present invention relates to is reducing construction cost effectively; The simultaneously minimizing of recoat number of times itself is energy-conservation, can alleviate environmental pressure.
(4) superpower sticking power and weather resisteant can guarantee that this coating is suitable for any interior exterior wall surface, metal color steel, concrete, putty, rubber, timber, glass etc.
(5) environmental protection, nontoxic, the V.O.C. quantity discharged is 67g/L only, and (the interior wall coating V.O.C. emission standard of China is 200g/L significantly to be better than national standard.Exterior coating V.O.C. emission standard is 700g/L).
(6) resist chemical, the particle alignment of thermal insulating coating of the present invention is tight when film forming, forms low porosity, makes coatingsurface forms barrier effect to damp vapour and causticize ion protective membrane, plays good protective effect.
What (7) thermal insulating coating of up-to-date composite adiabatic cavity technology formed is continuous " thermal insulation " layer, can realize lasting heat rejection, greatly reduce generation that heat transmits and the insulativity of sound, play the well effect of heat insulation and noise-reducing.
(8) have perfect cohesive force and the ductility of filming, even film crooked 180 degree, do not have any breakage, make coating have better waterproof, antifouling, Corrosion Protection.The anhydrous mark even process hose testing, surface are still kept dry.When coating of the present invention is used for layer top good water-repellancy is arranged.When being used for metope, prevent that moisture from entering coating and producing variable color, efflorescence, foaming comes off, and the use that greatly prolongs paint film is made an exception; On the other hand, pollutent (soy sauce, ink, tomato-sauce etc.) drop difficulty enters, and dust granule can be taken away by water droplet, has good contamination resistance.
Embodiment
Below be specific embodiments of the invention, technical scheme of the present invention is done further the description, but protection scope of the present invention is not limited to these embodiment.Every do not deviate from the change of the present invention design or be equal to substitute include within protection scope of the present invention.
The preparation of embodiment 1-3 heat-insulating waterproof coating
Component concentration:
? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
The high performance organo-silicon emulsion | 10% | 12% | 15% |
Pure-acrylic emulsion | 23% | 25% | 25% |
Titanium dioxide | 22% | 18% | 20% |
Talcum powder | 3% | 5% | 4% |
Diatomite | 2% | 3.5% | 3.4% |
Water-ground limestone | 3% | 5.1% | 4.3% |
Calcined kaolin | 1.7% | 2.2% | 2% |
Ceramic fine bead | 10% | 8% | 7% |
Hollow glass bead | 10% | 8% | 9% |
Water | 10.5% | 10.5% | 5.9% |
Multifunctional assistant | 1.1% | 0.8% | 0.6% |
Solubility promoter | 0.9% | 0.2% | 0.3% |
Defoamer | 0.3% | 0.2% | 0.3% |
Hydrophobizing agent | 2.5% | 1.5% | 3.2% |
Preparation technology:
At first Titanium Dioxide (Rutile) Top grade, talcum powder, diatomite, water-ground limestone, calcined kaolin are ground to fineness 700-800 order, the fineness of ceramic fine bead, hollow glass bead is to the 250-350 order.
By above-mentioned prescription multifunctional assistant, solubility promoter, hydrophobizing agent and a part of water are mixed in container; Under low rate mixing, add the color stuffings such as titanium dioxide, water-ground limestone, talcum powder, diatomite and calcined kaolin, behind the high-speed stirring 20min, detect fineness, require fineness less than 40 μ m.After reaching fineness requirement, high performance organo-silicon emulsion, pure-acrylic emulsion and defoamer are joined in the scattered dispersible pigment dispersion under low rate mixing according to prescription, stirred 45 minutes with 800 rev/mins speed; After stirring, under 200 rev/mins of states, slowly add hollow glass bead and ceramic bead powder, stir this mixed system, until be uniformly dispersed, then add excess water.Wherein, the defoamer of each embodiment, multifunctional assistant, solubility promoter, hydrophobizing agent are respectively:
? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Multifunctional assistant | The alkyl acid Soxylat A 25-7 | The alkyl acid Soxylat A 25-7 | The alkyl acid Soxylat A 25-7 |
Solubility promoter | 96% propylene glycol | 97% propylene glycol | 98% propylene glycol |
Defoamer | 25% methyl-silicone oil | 30% methyl-silicone oil | 33% methyl-silicone oil |
Hydrophobizing agent | Clean scholar S2 type hydrophobizing agent difficult to understand | Clean scholar S2 type hydrophobizing agent difficult to understand | Clean scholar S2 type hydrophobizing agent difficult to understand |
Heat-insulating waterproof coating according to embodiment of the invention 1-3 preparation has if any performance:
(1) distinctive high reflection and specific refractory power can reflect and reflect solar thermal energy and ultraviolet ray effectively, and the conduction of isolated heat energy makes buildings automatically regulate temperature, really accomplish cool in summer and warm in winterly, greatly reduce user's air-conditioning electric power energy consumption.
(2) the hydrophobic self-cleaning function of unique " surface effects as the lotus leaf ", rainwater tumbles together with floating dust, emerges unstained from the filth, even through hose testing, the surface anhydrous stain that still keeps dry greatly improves because floating dust is accumulated in the thermal insulating coating surface for a long time and reduces reflection function.
(3) heat-insulating waterproof coating that the present invention relates to is a kind of " longevity " coating, and can reach 10~15 years working life, and the effect of heat insulation within the time limit does not have to change substantially.This reduces the frequency that repeats application with regard to the corresponding effect of heat insulation that prolongs coating.In the long run/term, the coating more with the recoat number of times, that price is relatively low is compared, and the heat-insulating waterproof coating that the present invention relates to is reducing construction cost effectively; The simultaneously minimizing of recoat number of times itself is energy-conservation, can alleviate environmental pressure.
(4) superpower sticking power and weather resisteant can guarantee that this coating is suitable for any interior exterior wall surface, metal color steel, concrete, putty, rubber, timber, glass etc.
(5) environmental protection, nontoxic, the V.O.C. quantity discharged is 67g/L only, and (the interior wall coating V.O.C. emission standard of China is 200g/L significantly to be better than national standard.Exterior coating V.O.C. emission standard is 700g/L).
(6) resist chemical, the particle alignment of thermal insulating coating of the present invention is tight when film forming, forms low porosity, makes coatingsurface forms barrier effect to damp vapour and causticize ion protective membrane, plays good protective effect.
What (7) thermal insulating coating of up-to-date composite adiabatic cavity technology formed is continuous " thermal insulation " layer, can realize lasting heat rejection, greatly reduce generation that heat transmits and the insulativity of sound, play the well effect of heat insulation and noise-reducing.
(8) have perfect cohesive force and the ductility of filming, even film crooked 180 degree, do not have any breakage, make coating have better waterproof, antifouling, Corrosion Protection.The anhydrous mark even process hose testing, surface are still kept dry.When coating of the present invention is used for layer top good water-repellancy is arranged.When being used for metope, prevent that moisture from entering coating and producing variable color, efflorescence, foaming comes off, and the use that greatly prolongs paint film is made an exception; On the other hand, pollutent (soy sauce, ink, tomato-sauce etc.) drop difficulty enters, and dust granule can be taken away by water droplet, has good contamination resistance.
Its main thermal property sees Table 1.
Table 1 thermal property (physicals) index table
Technical indicator | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Reflection coefficient | 87% | 86% | 90% |
The sunlight specific absorption | 13% | 13% | 11% |
Heat-insulating efficiency | Reduce by 14.5 ℃ | Reduce by 13.7 ℃ | Reduce by 15.8 ℃ |
Breaking tenacity | 0.33kgf/sq mm | 0.35kgf/sq mm | 0.35kgf/sq mm |
Ultimate strength | 0.34kgf/sq mm | 0.35kgf/sq mm | 0.37kgf/sq mm |
Elongation (coefficient of elasticity) | 118% | 119% | 120% |
Solid content | 54% | 58% | 55% |
Adhesive strength | 1.6Mpa | 1.9Mpa | 2.0Mpa |
Water-intake rate (waterproof rate) | 0.5g/d㎡/day | 0.5g/d㎡/day | 0.6g/d㎡/day |
Water absorbs reduced rate | 82% | 84% | 88% |
Air penetrability | 11 g/d㎡/day | 11 g/d㎡/day | 12g/d㎡/day |
The chloride permeability reduced rate | 95% | 94% | 97% |
Claims (7)
1. heat-insulating waterproof coating is characterized in that: the component that comprises following weight percent:
High performance organo-silicon emulsion 10%-15% pure-acrylic emulsion 23%-25%
Titanium dioxide 18%-22% talcum powder 3%-5%
Diatomite 2%-3.5% water-ground limestone 3%-5.1%
Calcined kaolin 1.7%-2.2% ceramic fine bead 7%-10%
Hollow glass bead 8%-10% water 6%-12%
Multifunctional assistant 0.6%-1.2% solubility promoter 0.3%-1.0%
Defoamer 0.2%-0.3% hydrophobizing agent 1.5%-3.2%.
2. heat-insulating waterproof coating according to claim 1, it is characterized in that: the fineness of described titanium dioxide, talcum powder, diatomite, water-ground limestone or calcined kaolin is to the 700-800 order.
3. heat-insulating waterproof coating according to claim 1, it is characterized in that: the fineness of described ceramic fine bead or hollow glass bead is to the 250-350 order.
4. heat-insulating waterproof coating according to claim 1, it is characterized in that: described multifunctional assistant is the alkyl acid Soxylat A 25-7.
5. heat-insulating waterproof coating according to claim 1, it is characterized in that: described solubility promoter is the propylene glycol of concentration 96%-98%.
6. heat-insulating waterproof coating according to claim 1, it is characterized in that: described defoamer is the methyl-silicone oil of concentration 25%-33%.
7. heat-insulating waterproof coating according to claim 1, it is characterized in that: described titanium dioxide is Rutile type Titanium Dioxide.
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CN103540201A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Water-based heat-insulating waterproof coating |
CN104194534A (en) * | 2014-09-15 | 2014-12-10 | 中天联合节能建设发展(天津)股份有限公司 | Waterproof heat preservation coating for building external wall and preparation method of waterproof heat preservation coating |
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CN101200611A (en) * | 2007-11-30 | 2008-06-18 | 江南大学 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
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CN105246690A (en) * | 2013-05-30 | 2016-01-13 | 日本涂料有限公司 | Plate carrier having a grid pattern for a self-inking stamp and production method |
CN103540201A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Water-based heat-insulating waterproof coating |
CN104194534A (en) * | 2014-09-15 | 2014-12-10 | 中天联合节能建设发展(天津)股份有限公司 | Waterproof heat preservation coating for building external wall and preparation method of waterproof heat preservation coating |
CN104212284A (en) * | 2014-10-07 | 2014-12-17 | 江阴延利汽车饰件股份有限公司 | Reflective thermal insulation coating for car window |
CN104250498A (en) * | 2014-10-08 | 2014-12-31 | 中钢集团马鞍山矿山研究院有限公司 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
CN104559762A (en) * | 2015-01-10 | 2015-04-29 | 安徽省东瑞装饰材料有限公司 | Environment-friendly antistatic noise-reducing coating for machine room and preparation method thereof |
CN104610831A (en) * | 2015-01-14 | 2015-05-13 | 安徽宝翔建设集团有限责任公司 | Water-proof composite water-based exterior wall coating with good weatherability and preparation method of water-proof composite water-based exterior wall coating |
CN104974614A (en) * | 2015-07-09 | 2015-10-14 | 浙江传化涂料有限公司 | Reflective insulation and self-cleaning external wall stone-imitation coating material |
CN107216701A (en) * | 2015-09-27 | 2017-09-29 | 朱海燕 | A kind of self-cleaning ceramic coating |
CN107216701B (en) * | 2015-09-27 | 2019-12-27 | 朱海燕 | Self-cleaning ceramic coating |
CN105176279A (en) * | 2015-09-29 | 2015-12-23 | 蓝星(成都)新材料有限公司 | Paint for external wall |
CN105462301A (en) * | 2015-12-31 | 2016-04-06 | 辛范范 | Building exterior wall paint and preparation method thereof |
CN106221561A (en) * | 2016-08-01 | 2016-12-14 | 太仓顺如成建筑材料有限公司 | A kind of anticorrosion aging resistance exterior coating |
CN107163639A (en) * | 2017-05-31 | 2017-09-15 | 江苏达克罗涂装技术有限公司 | A kind of glass heat-proof hydrophobic coating and preparation method thereof |
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Application publication date: 20130306 |