CN102919231A - Emulsible granule containing spirodiclofen composition and preparation method thereof - Google Patents
Emulsible granule containing spirodiclofen composition and preparation method thereof Download PDFInfo
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Abstract
Disclosed is an emulsible granule containing spirodiclofen composition and a preparation method thereof. The emulsible granule is composed of components of, by weight, 1-60% of active components, 5-30% of wetting dispersants, 2-15% of solvents, 5-40% of adsorbents, 0-10% of binders and the balance carriers. The active components and liquid auxiliary components in the formula are evenly mixed, and the mixture is absorbed to the carriers; or the active components, the solvents and the liquid auxiliary components are evenly mixed and then mixed with other solid components, an airflow pulverizer is used for smashing the mixture so that granularity of 98% of the mixture reaches 45 mu m, and then the smashed mixture is subjected to kneading and granulation to prepare the emulsible granule. The emulsible granule is reasonable in the components, obvious in mite killing effects instead of simple adding of activity of the components, low in drug use cost, long in lasting period, safe in using, simple in preparation method, safe in storage and transportation, convenient to apply and environment-friendly and is an ideal variety of miticide.
Description
Technical field
But the present invention relates to relate to the emulsification granula that contains spiral shell mite ester composition and its preparation method.
Background technology
Harmful mite kind on China's agricultural is many, and feeding habits are assorted, and host range is wide, and fertility is extremely strong, increases in case evil mite quantity is explosion type, will cause significant damage to crop.Long-term actual agriculture experience shows, on the one hand, repeats and single-mindedly uses a kind of reactive compound and come pest control, can produce resistance to particular active compounds under many circumstances, and the preventive effect of medicament is reduced.
Spiral shell mite ester (spirodiclofen) structure is brand-new, the tool action of contace poison, its mechanism of action is by suppressing the Fatty synthesis in the pest mite body, destroy the energy metabolism activity of acarid, the ovicidal effect is excellent especially, if simultaneously the children mite is also had good action of contace poison, the mite spectrum is wide extremely, the lasting period is long, low toxicity, low-residual, good to people and animals and crop safety, without cross resistance, there is not cross resistance with other existing miticides, be specially adapted to prevent and treat the pest mite class that existing miticide is produced resistance.The mite evil that can be used for the solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.Two spotted spider mite, yellow spider, Xiu Pi lice, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae etc. are all had fine preventive effect, and the harm of control citrus red mite (crm) reaches 40～50 days.Its main preparation is: the formulations such as missible oil, suspending agent, aqueous emulsion.Its chemical name and structural formula are as follows: 3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro [4,5]-last of the ten Heavenly stems-3-alkene 4-base-2,2-dimethyl butyrate acid esters.
Tebufenpyrad (tebufenpyrad) belongs to the amide-type miticide. to various mite classes and Semiptera, homoptera pest has tall and erect effect, and the dawn all has immediate effect with efficient to the mite class each vegetative period, and the lasting period is long. such as Tetranychidae (panonychus ulmi, citrus red mite, cotton spider mites, Tetranychus cinnabarinus etc.), Tarsonemidae (the many tarsonemids of side), Eriophyidae (thorn apple rust mite, grape rust mite etc.), Tenuipalpidae (grape brevipalpus), Aphidiadae (black peach aphid, cotten aphid, apple aphid), Aleyrodidae (cassava aleyrodid). with dicofol, fenbutatin oxide, thiazole mite ketone etc. are without cross resistance.Without interior absorption, but osmotically active is arranged, target crop is had splendid selectivity, its main preparation is: the formulations such as suspending agent, missible oil, wetting powder.Its chemical name and structural formula are as follows: N-(4-tertiary butyl benzyl)-4-chloro-3-ethyl-1-methylpyrazole-5-base formamide
And the quality of the formulations of pesticide and preparation is to determine that Pesticidal products is worth and the key factor of effect, adopts different types of auxiliary agent, and a kind of former medicine is processed into the product of different dosage form, different size, the produce an effect difference, even very big-difference is arranged.Missible oil preparation is relatively easy, and good drug efficacy is easy to use, but contains the organic solvents such as a large amount of toluene, dimethylbenzene in the missible oil, and environmental pollution is serious, and all there are hidden danger in production, storage, transportation etc.; Wetting powder has a large amount of dust in producing, using, contaminated environment affects operating personnel's health; Suspending agent then exists bin stability relatively poor, drug effect is not as good as missible oil, therefore, be necessary to develop a kind of environmentally friendly, miticidal effect good, and miticide kind safe to solanaceous crops such as the fruit trees such as citrus, grape and eggplant, capsicum, tomatoes, use cost economy is to satisfy the needs of agricultural production.But the emulsification granula is exactly a kind of novel form that grows up on this basis, advantage with solid pharmaceutical preparation and liquid preparation, be the more comprehensive product of combination property in the current pesticidal preparations, the exploitation of this environmental protection novel form will further strengthen it to the safety of environment, people and animals, crop.But the report of concrete emulsification granula that openly contains spiral shell mite ester composition and preparation method thereof that so far there are no.
Summary of the invention
But the invention provides a kind of emulsification granula that contains spiral shell mite ester composition and preparation method thereof, the present invention is devoted to spiral shell mite ester and tebufenpyrad composition research, with and the research of the novel form of composition, its purpose is: on the one hand, but provide a kind of safety, environmental protection, stable storage, the emulsification granula that contains spiral shell mite ester composition that miticidal effect is good, improve its quick-acting, the service life of lasting period extended period and spiral shell mite ester active component, reduce spraying times, to reach the purpose of the control efficiency that significantly improves crop pests.On the other hand, but a kind of preparation method who contains the emulsification granula of spiral shell mite ester miticide composition is provided.
For addressing the above problem, the present invention adopts following technical scheme:
But a kind of emulsification granula that contains spiral shell mite ester composition, but take the gross weight of emulsification granula as benchmark, its composition forms and the weight percent content of each component is: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, carrier surplus.Effective ingredient is spiral shell mite ester and tebufenpyrad, and the portion rate of spiral shell mite ester and tebufenpyrad weight is 1: 1.Preferably the weight percentage of active ingredient component is the 10%-30% of gross weight in the composition.
Wetting dispersing agent is selected from a kind of in the following material: naphthalenesulfonic acid-formaldehyde condensate (dispersant NNO); the castor oil ethylene oxide adduct; ethylene oxide-propylene oxide block copolymer; the alkylphenol polyoxyethylene formaldehyde condensation products; sodium lignin sulfonate; calcium lignosulfonate; methyl naphthalene sulfonate formaldehyde condensate (Dispersant MF); the sodium salt of alkyl naphthalene sulfonic acid condensation polymer (dispersant D425); N-methyl-fatty acyl group-sodium taurocholate; the alkylphenol polyoxyethylene formaldehyde condensation products; the methanonaphthalene sodium sulfonate; oleic acid methylamino ethylsulfonic acid sodium; epoxidized polyether; to tertbutyl ether; the dibutyl naphthalene sulfonic acid-formaldehyde condensation product; the alkylphenol-polyethenoxy based phosphates; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; aralkyl phenol polyethenoxy ether phosphate; alkylphenol polyoxyethylene; the alkylphenol-polyethenoxy polyethenoxy ether; ethoxylated castor oil; polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, the different thionic acid calcium of oleic acid, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, hexichol ethyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, diphenyl phenolic group polyoxyethylene (n
18) polyoxypropylene (n
20) ether, anion and the non-ionic surface active agent compound (agricultural newborn 0201B) of solvent, castor oil polyoxyethylene ether (agricultural newborn BY110), alkyl phenyl APEO (farming breast 100), dibutyl naphthalene sulfonic acids calcium (farming breast 2201), calcium dodecyl benzene sulfonate (farming breast 500), alkyl phenol formaldehyde resin polyoxyethylene ether (Nongru-700), phenethyl phenol polyethenoxy polyethenoxy ether (farming breast 1601), castor oil polyoxyethylene (40) ether (agricultural newborn EL-40), sldium lauryl sulfate, alkylol polyoxyethylene groups ether sodium sulfate, octylphenol polyethylene oxyethylene group ether sulfate, neopelex, Negel, dialkyl succinylsuccinate sulfonate, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, the alkyl amide taurate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, the polyoxyethylene poly-oxygen propylene aether block copolymer, in the sorbitan fatty acid ester polyoxyethylene ether one or more; Described adsorbent is selected from a kind of in the following material: one or more in white carbon, bentonite, diatomite, the attapulgite; Described solvent is one or more in 1-METHYLPYRROLIDONE, repefral, dibutyl phthalate, d-hesperidene, diethylene glycol dimethyl ether, solvent naphtha, dimethylbenzene, toluene, the DMF.Described binding agent is a kind of in xanthans, polyethylene glycol, dextrin, gelatin, polyvinyl alcohol, PVP, soluble starch, phenolic resins, shellac, carboxymethyl cellulose, methylcellulose, the sodium alginate.Described carrier is one or more in precipitated calcium carbonate, talcum, potter's clay, kaolin, the atlapulgite.
Method one of the present invention: as shown in Figure 1, select the raw material of following weight ratio: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, carrier surplus; First active ingredient, liquid adjuvants component in the above prescription are mixed and be adsorbed in first on the carrier afterwards, with after other solid constituent is mixed, pulverize by airslide disintegrating mill again, make it granularity and reach 98% by 45 μ m, then through kneading, granulation, make finished product.Method two: as shown in Figure 2, select the raw material of following weight ratio: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, carrier surplus; In will filling a prescription first behind active ingredient, solvent and the liquid adjuvants mixing, then evenly be adsorbed on the component that is crushed to the carrier of granularity 98% by 45 μ m and solid mixture, then through kneading, granulation.
But above-mentioned containing in the spiral shell mite ester composition emulsification granula prescription, preferred wetting dispersing agent is: naphthalenesulfonic acid-formaldehyde condensate (dispersant NNO); ethylene oxide-propylene oxide block copolymer; the alkylphenol polyoxyethylene formaldehyde condensation products; N-methyl-fatty acyl group-sodium taurocholate; the alkylphenol polyoxyethylene formaldehyde condensation products; oleic acid methylamino ethylsulfonic acid sodium; epoxidized polyether; the dibutyl naphthalene sulfonic acid-formaldehyde condensation product; the alkylphenol-polyethenoxy based phosphates; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; aralkyl phenol polyethenoxy ether phosphate; alkylphenol polyoxyethylene; the alkylphenol-polyethenoxy polyethenoxy ether; the sodium salt of alkyl naphthalene sulfonic acid condensation polymer (dispersant D425); anion and the non-ionic surface active agent compound (agricultural newborn 0201B) of solvent; phenethyl phenol polyethenoxy polyethenoxy ether (farming breast 1601); alkyl phenol formaldehyde resin polyoxyethylene ether (Nongru-700); castor oil polyoxyethylene ether (agricultural newborn BY110); polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, the different thionic acid calcium of oleic acid, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, hexichol ethyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, diphenyl phenolic group polyoxyethylene (n
18) polyoxypropylene (n
20) ether; Preferred solvent is d-hesperidene, diethylene glycol dimethyl ether, 1-METHYLPYRROLIDONE, dimethylbenzene, solvent naphtha; Preferred adsorbent is white carbon, bentonite; Preferred binder is polyethylene glycol, carboxymethyl cellulose, PVP, soluble starch, polyvinyl alcohol.Preferred vector is precipitated calcium carbonate, kaolin; But the prescription that preferably contains spiral shell mite ester composition emulsifier granula, but take the gross weight of emulsification granula as benchmark, the content of its composition and each component is: active ingredient 10～30%, wetting dispersing agent 10～20%, solvent 5～10%, adsorbent 10～30%, binding agent 0～5%, the carrier surplus.
But the spiral shell mite ester composition emulsification granula that contains of the present invention can directly be watered the rear spraying use of dilution before use by the user.
Using method of the present invention is: when the mites of the fruit trees such as citrus, grape evil reaches index for control (every leaf worm ovum number reaches 10 or every leaf nymph 3-4 head), but use the medicine liquid spray of 20% spiral shell mite ester tebufenpyrad emulsification granula, 1～2ppm concentration.The field medication is generally the first tenday period of a month in May, or 9, October.
Technique effect of the present invention is: but the spiral shell mite ester composition emulsification granula that contains of the present invention, when dilute with water, can make active ingredient well dispersion energy in water, form a kind of common oil-in-water (O/W) type emulsion, because the emulsion particle diameter that forms is very little, can be absorbed rapidly by plant, thereby so that the drug effect of active ingredient is not fully exerted, reduced using dosage, but of the present inventionly contain spiral shell mite ester composition emulsification granula compared with prior art, have the following advantages: 1) good fluidity, non-caked, do not lump.Be easy to packing and use, production, storage, transportation safety, environmentally friendly, to operator's safety; 2) but its liquid wetability of emulsification granula of preparation is good, liquid deposits at target, biologically active is high, quick-acting is good, the lasting period is long, safety is good; 3) preparation method is simple, uses conveniently; 4) component is reasonable, and its miticidal effect is not the simple addition of each composition activity, but it is remarkable to have a miticidal effect, and drug cost is low, and the lasting period is long, uses safety, and storing and transportation safety are environmentally friendly, are a kind of desirable miticide kinds.
Description of drawings
Fig. 1 is the flow chart of manufacture method one;
Fig. 2 is the flow chart of manufacture method two.
Embodiment
The below is described in detail the present invention with best embodiment.
Embodiment one
The part by weight of component is:
First with 2 parts of naphthalenesulfonic acid-formaldehyde condensates, 1.5 part lauryl sodium sulfate, the sodium salt of 3 parts of alkyl naphthalene sulfonic acid condensation polymers, 3 parts of alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, 20 parts of white carbons and 50.5 parts of diatomite mix mixing in beaker, then at normal temperature, under the condition of normal pressure, add while stirring by 5 parts of spiral shell mite esters, 5 parts of tebufenpyrads, 4 parts of newborn 0201B of farming, 3 parts of d-hesperidenes, 3 parts of mixtures that diethylene glycol dimethyl ether forms, mix, pulverize by airslide disintegrating mill, make it granularity and reach 98% by 45 μ m, at last, add in the material of a certain amount of 2% ethanol water after the above-mentioned pulverizing, through mediating, the scraper plate granulation; But can obtain 10% spiral shell mite ester tebufenpyrad emulsification granula.
Embodiment two
The part by weight of component is:
First with 1 part of carboxymethyl cellulose, 8 parts of bentonites, 1 part of neopelex, 3 parts of N-methyl-fatty acyl group-sodium taurocholates, the sodium salt of 3 parts of alkyl naphthalene sulfonic acid condensation polymers and 49 parts of atlapulgites mix mixing in beaker, then at normal temperature, under the condition of normal pressure, add while stirring by 7.5 parts of spiral shell mite esters, 7.5 part tebufenpyrad, 2 parts of castor oil polyoxyethylene ethers, 2 parts of phenethyl phenol polyethenoxy polyethenoxy ethers, 6 parts of newborn 0201B of farming, 5 parts of 1-METHYLPYRROLIDONEs, 5 parts of mixtures that dimethylbenzene forms, mix, pulverize by airslide disintegrating mill, make it granularity and reach 98% by 45 μ m, at last, add in the material of a certain amount of distilled water after the above-mentioned pulverizing, through mediating, the scraper plate granulation; But can obtain 15% spiral shell mite ester tebufenpyrad emulsification granula.
Embodiment three
The part by weight of component is:
First with 20 parts of white carbons and 36.5 parts of kaolin mixing mixings, pulverize by airslide disintegrating mill, make it granularity and reach 98% by 45 μ m, then under normal temperature, condition of normal pressure, add while stirring by 10 parts of spiral shell mite esters, 10 parts of tebufenpyrads, 3 parts of oleic acid methylamino ethylsulfonic acid sodium, 5 parts of aralkyl phenol polyethenoxy ether phosphates, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 1.5 parts of alkyl phenol formaldehyde resin polyoxyethylene ethers, 3 parts of d-hesperidenes, 5 parts of 1-METHYLPYRROLIDONEs, 1 part of mixture that PEG400 forms, mix, at last, add in the material of a certain amount of distilled water after the above-mentioned pulverizing, through kneading, the scraper plate granulation; But can obtain 20% spiral shell mite ester tebufenpyrad emulsification granula.
Embodiment four
The part by weight of component is:
First with 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 20 parts of white carbons, 10 parts of bentonites, 0.5 part of PVP and 8.5 parts of attapulgite mixing mixings, pulverize by airslide disintegrating mill, make it granularity and reach 98% by 45 μ m, then under normal temperature, condition of normal pressure, add while stirring by 15 parts of spiral shell mite esters, 15 parts of tebufenpyrads, 3 parts of oleic acid methylamino ethylsulfonic acid sodium, 6 parts of hexichol ethyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, 3 parts of alkylaryl formaldehyde resin APEOs, 5 parts of newborn 0201B of farming, 5 parts of diethylene glycol dimethyl ethers, 5 parts of mixtures that dimethylbenzene forms, mix, at last, add in the material of a certain amount of 2% ethanol water after the above-mentioned pulverizing, through kneading, the scraper plate granulation; But can obtain 30% spiral shell mite ester tebufenpyrad emulsification granula.
Embodiment five
First with the sodium salt of 4 parts of alkyl naphthalene sulfonic acid condensation polymers, 25 parts of white carbons, 5 portions of soluble starches and 13 parts of precipitated calcium carbonate mixing mixings, pulverize by airslide disintegrating mill, make it granularity and reach 98% by 45 μ m, then at normal temperature, under the condition of normal pressure, add while stirring by 15 parts of spiral shell mite esters, 15 parts of tebufenpyrads, 4 parts of alkylphenol polyoxyethylene formaldehyde condensation products, 3 parts of aralkyl phenol polyethenoxy ether phosphates, 5 parts of newborn 0201B of farming, 2 parts of farming breasts 1601,4 parts of diethylene glycol dimethyl ethers, 5 parts of mixtures that 1-METHYLPYRROLIDONE forms, mix, at last, add in the material of a certain amount of distilled water after the above-mentioned pulverizing, through mediating, the scraper plate granulation; But can obtain 20% spiral shell mite ester tebufenpyrad emulsification granula.
Embodiment six
With the sodium salt of 15 parts of spiral shell mite esters, 15 parts of tebufenpyrads, 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 2 parts of alkyl naphthalene sulfonic acid condensation polymers, 5 parts of newborn 0201B of farming, 1601,0.1 parts of xanthans of 2 parts of farming breasts, 0.5 part of white carbon, 5 parts of ethylene glycol, 51.4 part deionized water is mixed, start high-shear emulsion machine, after stirring corase grind, under cooling condition, carry out the sand mill fine grinding, grind situation with particles distribution instrument monitoring material, (common d after raw meal particle size is qualified
97Till during less than 10 μ m), can obtain 30% spiral shell mite ester tebufenpyrad suspending agent
Embodiment seven
The test of pesticide effectiveness:
Using method: when the mites of the fruit trees such as citrus, grape evil reaches index for control (every leaf worm ovum number reaches 10 or every leaf nymph 3-4 head), but use the medicine liquid spray of 20% spiral shell mite ester tebufenpyrad emulsification granula, 1～2ppm concentration.The field medication is generally the first tenday period of a month in May, or 9, October.
Indoor biological activity test measurement result (control Tetranychus cinnabarinus)
The characteristics such as the test of pesticide effectiveness result by upper table can find out, but the emulsification granula that contains spiral shell mite ester composition of the present invention compared with prior art, and it is remarkable to have a miticidal effect, and biologically active is high, and the lasting period is long, and cost is low.But the spiral shell mite ester composition emulsification granula that contains provided by the invention, safety in production, use, storage, transportation not only, and the advantage such as it is simple to have processing technology, uses conveniently, environmentally friendly are a kind of desirable miticide kinds.
It should be noted that at last: obviously, above-described embodiment only is for example of the present invention clearly is described, and is not the restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here need not also can't give all embodiments exhaustive.And the apparent variation of being amplified out thus or change still are among protection scope of the present invention.
Claims (9)
1. but emulsification granula that contains spiral shell mite ester composition, it is characterized in that, but take the gross weight of emulsification granula as benchmark, its composition forms and the weight percent content of each component is: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, the carrier surplus.
2. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1 is characterized in that described effective ingredient is spiral shell mite ester and tebufenpyrad, and the portion rate of spiral shell mite ester and tebufenpyrad weight is 1: 1.
3. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1; it is characterized in that described wetting dispersing agent is selected from naphthalenesulfonic acid-formaldehyde condensate (dispersant NNO); the castor oil ethylene oxide adduct; ethylene oxide-propylene oxide block copolymer; the alkylphenol polyoxyethylene formaldehyde condensation products; sodium lignin sulfonate; calcium lignosulfonate; methyl naphthalene sulfonate formaldehyde condensate; the sodium salt of alkyl naphthalene sulfonic acid condensation polymer; N-methyl-fatty acyl group-sodium taurocholate; the alkylphenol polyoxyethylene formaldehyde condensation products; the methanonaphthalene sodium sulfonate; oleic acid methylamino ethylsulfonic acid sodium; epoxidized polyether; to tertbutyl ether; the dibutyl naphthalene sulfonic acid-formaldehyde condensation product; the alkylphenol-polyethenoxy based phosphates; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; aralkyl phenol polyethenoxy ether phosphate; alkylphenol polyoxyethylene; the alkylphenol-polyethenoxy polyethenoxy ether; ethoxylated castor oil; polyoxyethylene phenethyl phenol ether through reaction oleate; the alkylaryl polyoxyethylene poly-oxygen propylene aether; alkylaryl formaldehyde resin APEO; the different thionic acid calcium of oleic acid; triphenyl vinyl phenol APEO phosphorylation triethanolamine salt; hexichol ethyl phenolic group APEO formaldehyde condensation products; diphenyl phenolic group polyoxyethylene poly-oxygen propylene aether; anion and the non-ionic surface active agent compound of solvent; castor oil polyoxyethylene ether; the alkyl phenyl APEO; dibutyl naphthalene sulfonic acids calcium; calcium dodecyl benzene sulfonate; alkyl phenol formaldehyde resin polyoxyethylene ether; phenethyl phenol polyethenoxy polyethenoxy ether; castor oil polyoxyethylene; ether; sldium lauryl sulfate; alkylol polyoxyethylene groups ether sodium sulfate; octylphenol polyethylene oxyethylene group ether sulfate; neopelex; Negel; dialkyl succinylsuccinate sulfonate; lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium; the alkyl amide taurate; aliphatic alcohol polyethenoxy base ether; alkylphenol-polyethenoxy base ether; the polyoxyethylene poly-oxygen propylene aether block copolymer; in the sorbitan fatty acid ester polyoxyethylene ether one or more.
4. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1 is characterized in that described adsorbent is selected from one or more in white carbon, bentonite, diatomite, the attapulgite.
5. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1, it is characterized in that, described solvent is selected from one or more in 1-METHYLPYRROLIDONE, repefral, dibutyl phthalate, d-hesperidene, diethylene glycol dimethyl ether, solvent naphtha, dimethylbenzene, toluene, the DMF.
6. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1, it is characterized in that described binding agent is selected from a kind of in xanthans, polyethylene glycol, dextrin, gelatin, polyvinyl alcohol, PVP, soluble starch, phenolic resins, shellac, carboxymethyl cellulose, methylcellulose and the sodium alginate.
7. but a kind of emulsification granula that contains spiral shell mite ester composition as claimed in claim 1 is characterized in that described carrier is selected from one or more in precipitated calcium carbonate, talcum, potter's clay, kaolin, the atlapulgite.
8. but a preparation method who contains the emulsification granula of spiral shell mite ester composition is characterized in that, selects the raw material of following weight ratio: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, the carrier surplus; First active ingredient, liquid adjuvants component in the above prescription are mixed and be adsorbed in first on the carrier afterwards, with after other solid constituent is mixed, pulverize by airslide disintegrating mill again, make it granularity and reach 98% by 45 μ m, then through kneading, granulation, make finished product.
9. but a preparation method who contains the emulsification granula of spiral shell mite ester composition is characterized in that, selects the raw material of following weight ratio: active ingredient 1～60%, wetting dispersing agent 5～30%, solvent 2～15%, adsorbent 5～40%, binding agent 0～10%, the carrier surplus; In will filling a prescription first behind active ingredient, solvent and the liquid adjuvants mixing, then evenly be adsorbed on the component that is crushed to the carrier of granularity 98% by 45 μ m and solid mixture, then through kneading, granulation.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105104390A (en) * | 2015-08-19 | 2015-12-02 | 天峨县平昌生态农业有限公司 | Anti-mite composition containing cycloxaprid and spirodiclofen |
| CN105854728A (en) * | 2016-04-21 | 2016-08-17 | 允发化工（上海）有限公司 | Synthesis method of non-ionic surfactant |
| CN107047548A (en) * | 2017-03-28 | 2017-08-18 | 黑龙江华夏统联农业技术开发有限公司 | A kind of anti-drift agent and the spray adjuvantses including it and its preparation method and application |
| CN111264551A (en) * | 2020-03-30 | 2020-06-12 | 江西汇和化工有限公司 | Method for preparing prochloraz emulsifiable granules by novel feeding machine |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101406185A (en) * | 2008-10-31 | 2009-04-15 | 淄博新农基农药化工有限公司 | Compositional agent for killing insects and mites with synergistic interaction containing spirodiclofen |
| CN101406192A (en) * | 2008-11-28 | 2009-04-15 | 深圳诺普信农化股份有限公司 | Compositional acaricide and uses thereof |
| CN101543213A (en) * | 2008-03-25 | 2009-09-30 | 山东京博控股发展有限公司 | Composition of insecticide and acaricide |
| CN101999346A (en) * | 2010-12-17 | 2011-04-06 | 山西绿海农药科技有限公司 | Emulsifiable granule containing etofenprox composition and preparation method thereof |
| WO2012042002A1 (en) * | 2010-10-01 | 2012-04-05 | Syngenta Participations Ag | Methods for controlling varro mites |
-
2012
- 2012-11-06 CN CN201210436248.3A patent/CN102919231B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101543213A (en) * | 2008-03-25 | 2009-09-30 | 山东京博控股发展有限公司 | Composition of insecticide and acaricide |
| CN101406185A (en) * | 2008-10-31 | 2009-04-15 | 淄博新农基农药化工有限公司 | Compositional agent for killing insects and mites with synergistic interaction containing spirodiclofen |
| CN101406192A (en) * | 2008-11-28 | 2009-04-15 | 深圳诺普信农化股份有限公司 | Compositional acaricide and uses thereof |
| WO2012042002A1 (en) * | 2010-10-01 | 2012-04-05 | Syngenta Participations Ag | Methods for controlling varro mites |
| CN101999346A (en) * | 2010-12-17 | 2011-04-06 | 山西绿海农药科技有限公司 | Emulsifiable granule containing etofenprox composition and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105104390A (en) * | 2015-08-19 | 2015-12-02 | 天峨县平昌生态农业有限公司 | Anti-mite composition containing cycloxaprid and spirodiclofen |
| CN105854728A (en) * | 2016-04-21 | 2016-08-17 | 允发化工（上海）有限公司 | Synthesis method of non-ionic surfactant |
| CN107047548A (en) * | 2017-03-28 | 2017-08-18 | 黑龙江华夏统联农业技术开发有限公司 | A kind of anti-drift agent and the spray adjuvantses including it and its preparation method and application |
| CN107047548B (en) * | 2017-03-28 | 2020-11-13 | 黑龙江华夏统联农业技术开发有限公司 | Anti-drift agent, spraying aid comprising anti-drift agent, and preparation method and application of spraying aid |
| CN111264551A (en) * | 2020-03-30 | 2020-06-12 | 江西汇和化工有限公司 | Method for preparing prochloraz emulsifiable granules by novel feeding machine |
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