CN102017969B - Pesticide composition containing Bifenazate and Diafenthiuron - Google Patents
Pesticide composition containing Bifenazate and Diafenthiuron Download PDFInfo
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Abstract
The invention relates to a pesticide composition containing Bifenazate and Diafenthiuron, comprising effective active ingredients, accessory ingredient and filler. The invention is characterized in that the weight percentage of the Bifenazate and the Diafenthiuron, which are effective active ingredients, is 1:70-1-60. After the Bifenazate and the Diafenthiuron are compounded, the composition has obvious effects on synergy and continuous control, an expanded insecticidal spectrum, and higher activity on fruit tree and cotton mites, brassicaceous vegetable plutella xylostella and Empoasca pirisuga Matumura.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of effective active composition and contain the composition pesticide of Bifenazate and butyl ether urea for the application of control crop mite class.
Technical background
Bifenazate (bifenazate) chemical name: 3-(4-methoxyl biphenyl base-3-yl) carbazic acid isopropyl ester, molecular formula: C
17H
20N
2O
3, Bifenazate is a kind of new selective foliar spray miticide, and is effective to each life stage of mite.Have ovicidal activity and knock down activity rapidly to what become mite, minimum to the predacious mite influence, be very suitable for the comprehensive regulation of insect.Plant is not poisoned.
Butyl ether urea (diafenthiuron) chemical name: 1-tertiary butyl-3-(2,6-diisopropyl-4-Phenoxyphenyl) thiocarbamide, molecular formula: C
23H
23N
2OS,
Structural formula:
The butyl ether urea is a kind of new type disinsection, miticide, is widely used on cotton, fruit, vegetables and the tealeaves.This medicine is a kind of selective insecticide, inhale and fumigation action in having, the sensitive strain that can control aphid reaches the aphid that carbamate, organic phosphor and pyrethroid is produced resistance, and cicadellid and coconut palm aleyrodid etc. can also be controlled diamond-back moth, imported cabbageworm and noctuid and cause harm.This medicine can be used with most of insecticides tested and bactericide.
At present, Bifenazate and butyl ether urea composite and be applied in both at home and abroad unexposed mistake still.
Summary of the invention
Goal of the invention: in order to satisfy the needs of agricultural chemicals on producing, take full advantage of two kinds of active components be mixed the synergistic effect that produces, improve preventive effect, reduce pesticide cost and delay the drug-fast generation of evil mite, the present invention proposes the composition pesticide of composite Bifenazate and butyl ether urea.
The object of the present invention is achieved like this: a kind of composition pesticide that contains Bifenazate and butyl ether urea, comprise effective active component, auxiliary agent and filler, it is characterized in that: the percentage by weight of effective active composition Bifenazate and butyl ether urea is 1～70: 1～60.
The described composition pesticide that contains Bifenazate and butyl ether urea is characterized in that: the percentage by weight of Bifenazate and butyl ether urea is 5～50: 5～40.
The described composition pesticide that contains Bifenazate and butyl ether urea is characterized in that: the percentage by weight of Bifenazate and butyl ether urea is 10～30: 10～20.
The described composition pesticide that contains Bifenazate and butyl ether urea, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion.
When making wetting powder, composition comprises following constituent content: Bifenazate 1～70%, butyl ether urea 1～60%, dispersant 5～10%, wetting agent 1～5%, filler 8～92%.
The former medicine of Bifenazate, the former medicine of butyl ether urea, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into Bifenazate butyl ether urea wetting powder.
When making water dispersible granules, composition comprises following constituent content: Bifenazate 1～70%, butyl ether urea 1～60%, dispersant 2～10%, wetting agent 1～5%, disintegrant 4～15%, binding agent 1～8%, filler 10～90%.
The former medicine of Bifenazate, the former medicine of butyl ether urea, dispersant, wetting agent, disintegrant, filler etc. are pulverized the particle diameter that obtains needs through air-flow together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the Bifenazate diafenthiuron water dispersible granule.
Comprise following constituent content when composition is made suspending agent: Bifenazate 1～30%, butyl ether urea 1～30%, dispersant 2～8%, wetting agent 1～5%, defoamer 0.1～1%, thickener 0.1～2%, antifreezing agent 2～8%, stabilizing agent 0.05～3%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreezing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of Bifenazate, the former medicine of butyl ether urea, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes Bifenazate butyl ether urea suspending agent.
Comprise following constituent content when composition is made suspension emulsion: Bifenazate 1～30%, butyl ether urea 1～30%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of Bifenazate, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the Bifenazate suspending agent, then with the former medicine of butyl ether urea, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make Bifenazate butyl ether urea suspension emulsion.
The described composition pesticide of Bifenazate and butyl ether urea that contains is in control fruit tree, cotton mite class, the application of brassicaceous vegetable diamond-back moth and tea lesser leafhopper is mainly used in panonychus citri, brassicaceous vegetable diamond-back moth, apple Tetranychus urticae, cotton red spider, red spider mite, European red mite, tea lesser leafhopper control.
The invention has the advantages that: (1) Bifenazate and butyl ether urea, different fully to the mechanism of action of target pest, both are composite to have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, to fruit tree, cotton mite class, brassicaceous vegetable diamond-back moth and tea lesser leafhopper all have greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with the further instruction of the present invention of embodiment, the percentage among the embodiment all is weight percentage, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Earlier by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Implementation of an application example one:
A kind of composition pesticide that contains Bifenazate and butyl ether urea is tested the European red mite Toxicity Determination
For trying insect: European red mite
Test medicine: provide by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: adopt and to soak the method that connects worm behind the leaf earlier, the fresh apple leaf of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then for examination 3 instar larvaes, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The European red mite corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (be standard medicament with the Bifenazate, its toxicity index is 100):
The TI of the TI of theoretical toxicity index (TTI)=Bifenazate of M * P Bifenazate+butyl ether urea * P butyl ether urea
In the formula: M is the mixture of different proportionings
P
The butyl ether ureaBe butyl ether urea shared ratio in composition
P
BifenazateBe Bifenazate shared ratio in composition
Table 1 Bifenazate and butyl ether urea and composite toxicity test to European red mite thereof
As shown in Table 1, Bifenazate and butyl ether urea and composite product are to European red mite Toxicity Determination experiment discovery, when Bifenazate and butyl ether urea proportioning in the time of 70: 1 to 1: 60 co-toxicity coefficient all greater than 120, show obvious synergistic effect, especially synergistic effect is obviously outstanding when Bifenazate and butyl ether urea proportioning are 10: 1 to 1: 5, Bifenazate thus: the butyl ether urea all had synergistic function between 70: 1 to 1: 60, especially when Bifenazate: during butyl ether urea=1: 1, co-toxicity coefficient maximum, synergistic effect are the most obvious.
Application Example two:
Application Example 1
40% Bifenazate diafenthiuron water dispersible granule control red spider mite
Bifenazate 20%, butyl ether urea 20%, lignosulfonates 5%, neopelex 3%, ammonium sulfate 2%, aluminium-magnesium silicate 5%, kaolin adds to 100%, the mixed 40% Bifenazate diafenthiuron water dispersible granule that gets.This proportioning is by 3000 times of dilution sprayings, seven days control efficiency are 96.72% behind the medicine, 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute 2000 times and 1000 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 79.80% and 73.62% behind the medicine.
Application Example 2
60% Bifenazate diafenthiuron water dispersible granule control citrus red mite
Bifenazate 10%, butyl ether urea 50%, sodium phosphate trimer 4%, lauryl sodium sulfate 3%, ammonium sulfate 5%, bentonite adds to 100%, with the even mixed 60% Bifenazate diafenthiuron water dispersible granule that gets of aforementioned formula material.This prescription is by 4000 times of liquid dilution sprayings, seven days control efficiency are 93.71% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil is according to diluting 2000 times and 1000 times of uses respectively with quadrat method, and seven days control efficiency are respectively 80.73% and 74.14% behind the medicine.
Application Example 3
60% Bifenazate diafenthiuron water dispersible granule control European red mite
Bifenazate 50%, butyl ether urea 10%, sodium lignin sulfonate 5%, SDS 5%, sodium carbonate 5%, polyethylene glycol 1%, bentonite adds to 100%, mixes namely to make 60% Bifenazate diafenthiuron water dispersible granule.This prescription is by 3500 times of liquid dilution sprayings, seven days control efficiency are 94.71% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil is according to diluting 2000 times and 1000 times of uses respectively with quadrat method, and seven days control efficiency are respectively 80.41% and 75.14% behind the medicine.
Application Example 4
61% Bifenazate diafenthiuron water dispersible granule control brassicaceous vegetable diamond-back moth
Bifenazate 1%, butyl ether urea 60%, sldium lauryl sulfate 2%, sodium lignin sulfonate 5%, xanthans 3%, sodium carbonate 10%, diatomite adds to 100%, with the even mixed 61% Bifenazate diafenthiuron water dispersible granule that gets of aforementioned formula material.This prescription is pressed preparation consumption 25g/ mu dilution spraying, seven days control efficiency are 91.58% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil are pressed preparation consumption 20g/ mu and 40g/ mu respectively to use according to same quadrat method, and seven days control efficiency are 78.14% and 73.36% behind the medicine.
Application Example 5
40% Bifenazate butyl ether urea wetting powder control apple Tetranychus urticae
Bifenazate 10%, butyl ether urea 30%, neopelex 3%, bay alcohol radical sodium sulphate 4%, kaolin adds to 100%, and the aforementioned formula material is mixed, in stirred tank, evenly stir, behind airslide disintegrating mill, mix again, namely make 40% Bifenazate butyl ether urea wetting powder.This prescription is by 2500 times of liquid dilution sprayings, seven days control apple Tetranychus urticae effects are 93.86% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute use according to dilute 2000 times and 1000 times respectively with quadrat method, and seven days control efficiency are respectively 80.31% and 77.32% behind the medicine.
Application Example 6
42% Bifenazate butyl ether urea wetting powder control apple Tetranychus urticae
Bifenazate 40%, butyl ether urea 2%, neopelex 3%, bay alcohol radical sodium sulphate 4%, kaolin adds to 100%, and the aforementioned formula material is mixed, in stirred tank, evenly stir, behind airslide disintegrating mill, mix again, namely make 42% Bifenazate butyl ether urea wetting powder.This prescription is by 2500 times of liquid dilution sprayings, seven days control apple Tetranychus urticae effects are 93.86% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute use according to dilute 2000 times and 1000 times respectively with quadrat method, and seven days control efficiency are respectively 79.61% and 74.52% behind the medicine.
Application Example 7
60% Bifenazate butyl ether urea wetting powder control tea lesser leafhopper
Bifenazate 30%, butyl ether urea 30%, polycarboxylate 4%, spaonin powder 4%, kaolin adds to 100%, and mixture carries out air-flow to be pulverized, and makes 60% Bifenazate butyl ether urea wetting powder.This prescription is pressed preparation consumption 18g/ mu dilution spraying, and seven days control tea lesser leafhopper effects are 97.86% behind the medicine.480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil are pressed preparation consumption 20g/ mu and 40g/ mu respectively and are used according to same quadrat method, and seven days preventive effects are respectively 83.85% and 80.45% behind the medicine.
Application Example 8
72% Bifenazate butyl ether urea wetting powder control cotton red spider
Bifenazate 70%, butyl ether urea 2%, alkyl benzene sulfonate calcium salt 5%, alkylphenol-polyethenoxy is phonetic 5%, lauryl sodium sulfate 3%, moistening bleeding agent F 2%, diatomite adds to 100% mixture and carries out the air-flow pulverizing, makes 72% Bifenazate butyl ether urea wetting powder.This prescription is pressed preparation consumption 22g/ mu dilution spraying, and seven days control cotton red spider effects are 95.62% behind the medicine.480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil are according to same quadrat method, and amount of formulation 20g/ mu and 40g/ mu use respectively, and seven days preventive effects are respectively 82.74% and 76.25% behind the medicine.
Application Example 9
75% Bifenazate butyl ether urea wetting powder control apple Tetranychus urticae
Bifenazate 40%, butyl ether urea 35%, neopelex 3%, bay alcohol radical sodium sulphate 4%, kaolin adds to 100%, and the aforementioned formula material is mixed, in stirred tank, evenly stir, behind airslide disintegrating mill, mix again, namely make 75% Bifenazate butyl ether urea wetting powder.This prescription is by 3000 times of liquid dilution sprayings, seven days control apple Tetranychus urticae effects are 96.86% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute use according to dilute 2000 times and 1000 times respectively with quadrat method, and seven days control efficiency are respectively 80.31% and 77.32% behind the medicine.
Application Example 10
20% Bifenazate butyl ether urea suspending agent control cotton red spider
Bifenazate 10%, butyl ether urea 10%, alkylphenol polyoxyethylene 6%, lauryl sodium sulfate 4%, silicone compound 0.1%, polyvinyl alcohol 0.3%, propane diols 3%, deionized water adds to 100%, the mixed 20% Bifenazate butyl ether urea suspending agent that gets.This proportioning is pressed preparation consumption 25g/ mu dilution spraying, seven days control efficiency are 95.21% behind the medicine, 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil are pressed preparation consumption 20g/ mu and 40g/ mu respectively and are used according to same quadrat method, and seven days preventive effects are respectively 82.35% and 77.99% behind the medicine.
Application Example 11
38% Bifenazate butyl ether urea suspending agent control panonychus citri
Bifenazate 8%, butyl ether urea 30%, neopelex 6%, xanthans 0.6%, organic silicone 0.3%, ethylene glycol 4% adds water to 100%, mixes namely to make 38% Bifenazate butyl ether urea suspending agent.This prescription is by 2500 times of liquid dilution sprayings, seven days control efficiency are 95.70% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute 2000 times and 1000 times of uses after the same method respectively, and seven days control efficiency are 71.16% and 78.11% behind the medicine.
Application Example 12
40% Bifenazate butyl ether urea suspending agent control European red mite
Bifenazate 30%, butyl ether urea 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, silicone oil 0.1%, polyethylene glycol 0.2%, deionized water adds to 100%, the mixed 40% Bifenazate butyl ether urea suspending agent that gets.This proportioning is by 3000 times of dilution sprayings, seven days control European red mite effects are 93.15% behind the medicine, 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute 2000 times and 1000 times of uses respectively according to same quadrat method, and seven days preventive effects are respectively 81.13% and 74.05%. behind the medicine
Application Example 13
45% Bifenazate butyl ether urea suspending agent control panonychus citri
Bifenazate 40%, butyl ether urea 5%, neopelex 6%, xanthans 0.6%, organic silicone 0.3%, ethylene glycol 4% adds water to 100%, mixes namely to make 45% Bifenazate butyl ether urea suspending agent.This prescription is by 2500 times of liquid dilution sprayings, seven days control efficiency are 92.70% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute 2000 times and 1000 times of uses after the same method respectively, and seven days control efficiency are 78.16% and 74.11% behind the medicine.
Application Example 14
20% Bifenazate butyl ether urea suspension emulsion control citrus red mite
Bifenazate 10%, butyl ether urea 10%, Negel 7%, alkylbenzenesulfonate 3%, isooctanol 1%, melon glue 2%, ethylene glycol 7%, water adds to 100%, and the aforementioned formula material is mixed, and namely makes 20% Bifenazate butyl ether urea suspension emulsion.This prescription is by 1500 times of liquid dilution sprayings, seven days control citrus red mite effects are 96.86% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil dilute use according to dilute 2000 times and 1000 times respectively with quadrat method, and seven days control efficiency are respectively 79.31% and 72.32% behind the medicine.
Application Example 15
35% Bifenazate butyl ether urea suspension emulsion control tea lesser leafhopper
Bifenazate 15%, butyl ether urea 20%, alkylphenol polyoxyethylene class 4%, sodium lignin sulfonate 6%, xanthans 1%, propane diols 5%, lauric acid 1%, water adds to 100%, the mixed 35% Bifenazate butyl ether urea suspension emulsion that gets.This prescription is pressed preparation consumption 17g/ mu dilution spraying, seven days control efficiency are 96.37% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil are according to using with quadrat method, press preparation consumption 20g/ mu and 40g/ mu and use, seven days control efficiency are respectively 79.18% and 72.44% behind the medicine.
Application Example 16
36% Bifenazate butyl ether urea suspension emulsion control cotton red spider
Bifenazate 10%, butyl ether urea 26%, alkylphenol polyoxyethylene 6%, lignosulfonates 8%, xanthans 3%, polyethylene glycol 2%, isoamyl alcohol 2%, water adds to 100%, the mixed 36% Bifenazate butyl ether urea suspension emulsion that gets.This prescription is pressed preparation consumption 18g/ mu dilution spraying, seven days control cotton red spider effects are 93.63% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil is according to using with quadrat method preparation consumption 20g/ mu and 40g/ mu, and seven days control efficiency are respectively 79.56% and 71.27% behind the medicine.
Application Example 17
42% Bifenazate butyl ether urea suspension emulsion control European red mite
Bifenazate 7%, butyl ether urea 35%, ethylnaphthalene sodium sulfonate 4%, alkylaryl APEO 6%, lauryl sodium sulfate 3%, diethylene glycol (DEG) 2%, isooctanol 2%, water adds to 100%, the mixed 42% Bifenazate butyl ether urea suspension emulsion that gets.This prescription is by 2000 times of liquid dilution sprayings, seven days control European red mite effects are 94.36% behind the medicine, and 480 grams per liter Bifenazate suspending agents and 25% butyl ether urea missible oil is according to diluting 2000 times and 1000 times of uses respectively with quadrat method, and seven days control efficiency are respectively 80.01% and 73.62% behind the medicine.
Claims (5)
1. a composition pesticide that contains Bifenazate and butyl ether urea comprises effective active component, auxiliary agent and filler, it is characterized in that: the weight ratio of effective active composition Bifenazate and butyl ether urea is 1:60 ~ 70:1.
2. the composition pesticide that contains Bifenazate and butyl ether urea according to claim 1, it is characterized in that: the weight ratio of Bifenazate and butyl ether urea is 10:1 ~ 1:5.
3. the composition pesticide that contains Bifenazate and butyl ether urea according to claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion.
4. the composition pesticide of Bifenazate and butyl ether urea that contains according to claim 1 is in control fruit tree, cotton mite class, the application of brassicaceous vegetable diamond-back moth and tea lesser leafhopper.
5. application according to claim 4 is characterized in that: described mite class is panonychus citri, apple Tetranychus urticae, cotton red spider, red spider mite, European red mite.
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| CN1943349A (en) * | 2006-06-22 | 2007-04-11 | 深圳诺普信农化股份有限公司 | Composition with pest killing function containing diafenthiuron and methyl amino abamectin benzoate |
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Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Patentee after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Patentee before: Shanxi Thompson Biological Technology Co., Ltd. |
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