CN102899913A - Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material - Google Patents
Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material Download PDFInfo
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- CN102899913A CN102899913A CN2011102174911A CN201110217491A CN102899913A CN 102899913 A CN102899913 A CN 102899913A CN 2011102174911 A CN2011102174911 A CN 2011102174911A CN 201110217491 A CN201110217491 A CN 201110217491A CN 102899913 A CN102899913 A CN 102899913A
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Abstract
The present invention relates to a manufacturing method for a terylene strengthened filament weaving pattern rubber bottom coiled material. The method comprises the following steps: processing a surface layer, preparing an adhesive, processing a bottom back layer, carrying out adhesion processing, and carrying out a UV surface treatment to prepare the terylene strengthened filament weaving pattern rubber bottom coiled material. Compared with the terylene strengthened filament weaving pattern rubber bottom coiled material in the prior art, the terylene strengthened filament weaving pattern rubber bottom coiled material of the present invention has advantages of wear resistance, stain resistance, easy cleaning, safety, no toxicity, no formaldehyde generation, good size stability, easy pavement, flexibility, excellent sound absorbing effect, no noise, good weathering resistance, durability and the like.
Description
Technical field
The present invention relates to a kind of manufacture method of coiled material, especially relate to a kind of manufacture method of terylene reinforced yarn woven patterns rubber-sole coiled material.
Background technology
Along with China's expanding economy, pavement also is varied.The pavement majority is composite floor board on the market now, floor tile, carpet, PVC coiled material or sheet material.They have the use limitation of oneself.
The floor: contain formaldehyde more, not environmental protection, harmful, not water-fast, only applicable indoor.
Floor tile: feel is bad, and radiation is arranged, and sound-absorbing is poor, feels not high-grade.
Carpet: bad cleaning, shelter evil people and countenance evil practices, only applicable indoor.
PVC coiled material or sheet material: simply unchanged, feel to step down on the plastics, not high-grade.
Terylene reinforced yarn woven patterns rubber-sole coiled material: overcome all shortcomings of appeal material, ABRASION RESISTANCE is stronger, easy cleaning, and the noiselessness pattern is clear and natural more, the carpet effect is arranged, use more environmental protection, be widely used in office building, high-grade coffee bar, high-grade retail shop, hotel, VIP recreating facility etc.
Summary of the invention
Purpose of the present invention is exactly the manufacture method that a kind of wear-resisting, resistant, good stability is provided in order to overcome the defective that above-mentioned prior art exists, is beneficial to the terylene reinforced yarn woven patterns rubber-sole coiled material of mating formation.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of manufacture method of terylene reinforced yarn woven patterns rubber-sole coiled material is characterized in that, the method may further comprise the steps:
(1) surface layer processing: inside is processed to form the multiply monomer by high tenacity polyester filament by warping, outside coating PVC thickener is crossed and is moulded, enter the 24M IR bake, at 170 ℃～190 ℃, oven dry, plasticizing, then cooling is formed by weaving at gripper machine, obtain different patterns, the woven pattern surface layer of different density degree;
(2) make binder: with vinyl chloride-vinyl acetate resin 100 weight portions, dioctyl phthalate 70 weight portions, crosslinking agent 5 weight portions, the mixing of promoter 1 weight portion is placed on high speed dispersor, 1000～1500r/min stirs 5～10min, filters with 100 order screen packs, collects stand-by;
(3) end backing layer processing: rubber 100 weight portions, aluminium hydroxide or magnesium hydroxide 5 weight portions, reinforcing filler 140 weight portions, sulphur 5 weight portions, zinc oxide 2 weight portions, stearic acid 1.5 weight portions, promoter 1 weight portion, age resistor 1 weight portion, antimonous oxide 5 weight portions, phosphorus flame retardant 10 weight portions, molybdenum compound 0.5 weight portion, borate 2 weight portions and pigment 2 weight portions are produced rubber coiled material at four-roll calender and vulcanizer;
(4) applying processing: preheating is being arranged, the gluing group, the production line of applying group is made the adhesive that obtains with step (2) and is coated on step (1) the gained woven pattern surface layer then preheating, fit with end backing layer, produce terylene reinforced yarn woven patterns rubber coiled material semi-finished product;
(5) UV surface treatment: with the half-finished upper surface coating of step (4) gained polyurethane, by the photochemical processing of UV ultraviolet ray, be solidificated in surface of semi-finished, namely get product.
PVC paste formula described in the step (1) comprises following component and weight portion content: PVC paste resin 100, and 100, No. 200 solvent naphthas 12 of dioctyl phthalate, calcium carbonate 20, look sticks with paste 3, stabilizing agent 3.
Described look stick with paste comprise that heat-resisting purplish red, carbon black, You Ji perylene are red, permanent yellow, phthalein viridescent or phthalocyanine blue; Described stabilizing agent is Ca/Zn composite thermal stabilizer or Ba/Zn composite thermal stabilizer.
Crosslinking agent described in the step (2) is cumyl peroxide, benzoyl peroxide, di-tert-butyl peroxide or di-isopropylbenzene hydroperoxide; Described promoter is 2-benzothiazolyl mercaptan, zine dimethyldithiocarbamate or N-cyclohexyl-2-benzothiazole sulfonamide.
Reinforcing filler described in the step (3) is calcium carbonate, white carbon, cellulose or mica; Promoter is 2-benzothiazolyl mercaptan, zine dimethyldithiocarbamate or N-cyclohexyl-2-benzothiazole sulfonamide; Age resistor is 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, N-phenyl-α-aniline or N-Phenyl beta naphthylamine; The molybdenum compound is molybdenum dioxide or molybdenum chloride; Borate is Boratex; Pigment is titanium dioxide, former orchid, heat-resisting purplish red, rose-red, medium chrome yellow, phthalein viridescent or phthalocyanine blue.
Compared with prior art, the present invention has the following advantages:
(1) surperficial UV processes, and is wear-resisting, and resistant is easy to clean;
(2) pattern is abundant, and safety non-toxic does not produce formaldehyde;
(3) good stability of the dimension is beneficial to and mats formation;
(4) flexible, comfortable foot feeling, effectively anti-skidding;
(5) rubber layer excellent sound absorbing, noiselessness;
(6) weather resisteant is good, durable in use especially.
Description of drawings
Fig. 1 is process chart of the present invention.
The specific embodiment
The present invention is described in detail below in conjunction with the drawings and specific embodiments.
Embodiment 1
A kind of manufacture method of terylene reinforced yarn woven patterns rubber-sole coiled material may further comprise the steps:
(1) high tenacity polyester filament is processed to form multiply monomer 500D by warping, and then the PVC thickener is crossed and moulded, and filling a prescription is: PVC paste resin 100, and 100, No. 200 solvent naphthas 12 of dioctyl phthalate, calcium carbonate 20, look is stuck with paste an amount of, stabilizing agent 3.Enter again the oven dry of 24M IR bake, plasticizing.(temperature 170,190,170 ℃) cross the chilled water cooling, and coolant-temperature gage is collected warping by macro-axis again less than 18 ℃, is divided into warp-wise, broadwise.Then be formed by weaving at gripper machine, can produce different patterns, the woven pattern of different density degree.
(2) make binder: vinyl chloride-vinyl acetate resin 100, dioctyl phthalate 70, coupling agent 5, promoter 1 is poured high speed dispersor into, and 1400r/min stirred 7 minutes, filtered with 100 order screen packs, collected stand-by.
(3) end backing layer: raw material is mainly by rubber 100kg, aluminium hydroxide 5kg, reinforcing filler 140kg, sulphur 5kg, zinc oxide 2kg, stearic acid 1.5kg, promoter 1kg, age resistor 1kg, antimonous oxide 5kg, phosphorus flame retardant 10kg, molybdenum dioxide 0.5kg, the compositions such as Boratex 2kg and titanium white powder pigment 2kg, at four-roll calender, produce the rubber coiled material semi-finished product on the tympanum vulcanizer, wherein, the reinforcing filler that uses is calcium carbonate, promoter is the 2-benzothiazolyl mercaptan, age resistor is 6-ethyoxyl-2,2,4-trimethyl-1, the 2-dihyaroquinoline.
(4) applying foaming processing: preheating is being arranged, the gluing group, the production line of applying group will be appealed semi-finished product by preheating, the surface layer gluing, the technical process such as MULTILAYER COMPOSITE are produced terylene reinforced yarn woven patterns rubber coiled material product.
(5) UV surface treatment: product surface coating high strength polyurethane by the photochemical processor of UV ultraviolet ray, is solidificated in product surface.
Embodiment 2
A kind of manufacture method of terylene reinforced yarn woven patterns rubber-sole coiled material may further comprise the steps:
(1) surface layer processing: inside is processed to form the multiply monomer by high tenacity polyester filament by warping, outside coating PVC thickener is crossed and is moulded, enter the 24M IR bake, at 170 ℃, oven dry, plasticizing, then cooling is formed by weaving at gripper machine, obtains different patterns, the woven pattern surface layer of different density degree, wherein, the PVC paste formula comprises following component and content: PVC paste resin 100kg, dioctyl phthalate 100kg, No. 200 solvent naphtha 12kg, calcium carbonate 20, look are stuck with paste heat-resisting purplish red 3kg, Ca/Zn composite thermal stabilizer 3kg;
(2) make binder: with vinyl chloride-vinyl acetate resin 100kg, dioctyl phthalate 70kg, crosslinking agent cumyl peroxide 5kg, promoter 2-benzothiazolyl mercaptan 1kg mixing is placed on high speed dispersor, 1000r/min stirred 10 minutes, filtered with 100 order screen packs, collected stand-by;
(3) end backing layer processing: rubber 100kg, aluminium hydroxide 5kg, reinforcing filler 140kg, sulphur 5kg, zinc oxide 2kg, stearic acid 1.5kg, promoter 1kg, age resistor 1kg, antimonous oxide 5kg, phosphorus flame retardant 10kg, molybdenum chloride 0.5kg, Boratex 2kg and former blue pigment 2kg are produced rubber coiled material at four-roll calender and vulcanizer, wherein, the reinforcing filler that uses is cellulose, promoter is zine dimethyldithiocarbamate, and age resistor is N-phenyl-α-aniline;
(4) applying processing: preheating is being arranged, the gluing group, the production line of applying group is made the adhesive that obtains with step (2) and is coated on step (1) the gained woven pattern surface layer then preheating, fit with end backing layer, produce terylene reinforced yarn woven patterns rubber coiled material semi-finished product;
(5) UV surface treatment: with the half-finished upper surface coating of step (4) gained polyurethane, by the photochemical processing of UV ultraviolet ray, be solidificated in surface of semi-finished, namely get product.
Embodiment 3
A kind of manufacture method of terylene reinforced yarn woven patterns rubber-sole coiled material may further comprise the steps:
(1) surface layer processing: inside is processed to form the multiply monomer by high tenacity polyester filament by warping, outside coating PVC thickener is crossed and is moulded, enter the 24M IR bake, at 190 ℃, oven dry, plasticizing, then cooling is formed by weaving at gripper machine, obtains different patterns, the woven pattern surface layer of different density degree, wherein, the PVC paste formula comprises following component and content: PVC paste resin 100kg, dioctyl phthalate 100kg, No. 200 solvent naphtha 12kg, calcium carbonate 20, look is stuck with paste the red 3kg of You Ji perylene, Ba/Zn composite thermal stabilizer 3kg;
(2) make binder: with vinyl chloride-vinyl acetate resin 100kg, dioctyl phthalate 70kg, crosslinking agent di-isopropylbenzene hydroperoxide 5kg, accelerant N-cyclohexyl-2-benzothiazole sulfonamide 1kg mixing is placed on high speed dispersor, 1500r/min stirred 5 minutes, filter with 100 order screen packs, collect stand-by;
(3) end backing layer processing: rubber 100kg, magnesium hydroxide 5kg, reinforcing filler 140kg, sulphur 5kg, zinc oxide 2kg, stearic acid 1.5kg, promoter 1kg, age resistor 1kg, antimonous oxide 5kg, phosphorus flame retardant 10kg, molybdenum dioxide 0.5kg, Boratex 2kg and heat-resisting maroon pigment 2kg are produced rubber coiled material at four-roll calender and vulcanizer, wherein, the reinforcing filler that uses is mica, promoter is the N-cyclohexyl-2-benzothiazole sulfonamide, and age resistor is the N-Phenyl beta naphthylamine;
(4) applying processing: preheating is being arranged, the gluing group, the production line of applying group is made the adhesive that obtains with step (2) and is coated on step (1) the gained woven pattern surface layer then preheating, fit with end backing layer, produce terylene reinforced yarn woven patterns rubber coiled material semi-finished product;
(5) UV surface treatment: with the half-finished upper surface coating of step (4) gained polyurethane, by the photochemical processing of UV ultraviolet ray, be solidificated in surface of semi-finished, namely get product.
Claims (5)
1. the manufacture method of a terylene reinforced yarn woven patterns rubber-sole coiled material is characterized in that, the method may further comprise the steps:
(1) surface layer processing: inside is processed to form the multiply monomer by high tenacity polyester filament by warping, outside coating PVC thickener is crossed and is moulded, enter the 24M IR bake, at 170 ℃～190 ℃, oven dry, plasticizing, then cooling is formed by weaving at gripper machine, obtain different patterns, the woven pattern surface layer of different density degree;
(2) make binder: with vinyl chloride-vinyl acetate resin 100 weight portions, dioctyl phthalate 70 weight portions, crosslinking agent 5 weight portions, the mixing of promoter 1 weight portion is placed on high speed dispersor, 1000～1500r/min stirs 5～10min, filters with 100 order screen packs, collects stand-by;
(3) end backing layer processing: rubber 100 weight portions, aluminium hydroxide or magnesium hydroxide 5 weight portions, reinforcing filler 140 weight portions, sulphur 5 weight portions, zinc oxide 2 weight portions, stearic acid 1.5 weight portions, promoter 1 weight portion, age resistor 1 weight portion, antimonous oxide 5 weight portions, phosphorus flame retardant 10 weight portions, molybdenum compound 0.5 weight portion, borate 2 weight portions and pigment 2 weight portions are produced rubber coiled material at four-roll calender and vulcanizer;
(4) applying processing: preheating is being arranged, the gluing group, the production line of applying group is made the adhesive that obtains with step (2) and is coated on step (1) the gained woven pattern surface layer then preheating, fit with end backing layer, produce terylene reinforced yarn woven patterns rubber coiled material semi-finished product;
(5) UV surface treatment: with the half-finished upper surface coating of step (4) gained polyurethane, by the photochemical processing of UV ultraviolet ray, be solidificated in surface of semi-finished, namely get product.
2. the manufacture method of a kind of terylene reinforced yarn woven patterns rubber-sole coiled material according to claim 1, it is characterized in that, PVC paste formula described in the step (1) comprises following component and weight portion content: PVC paste resin 100, dioctyl phthalate 100, No. 200 solvent naphthas 12, calcium carbonate 20, look sticks with paste 3, stabilizing agent 3.
3. the manufacture method of a kind of terylene reinforced yarn woven patterns rubber-sole coiled material according to claim 2 is characterized in that, described look stick with paste comprise that heat-resisting purplish red, carbon black, You Ji perylene are red, permanent yellow, phthalein viridescent or phthalocyanine blue; Described stabilizing agent is Ca/Zn composite thermal stabilizer or Ba/Zn composite thermal stabilizer.
4. the manufacture method of a kind of terylene reinforced yarn woven patterns rubber-sole coiled material according to claim 1, it is characterized in that, the crosslinking agent described in the step (2) is cumyl peroxide, benzoyl peroxide, di-tert-butyl peroxide or di-isopropylbenzene hydroperoxide; Described promoter is 2-benzothiazolyl mercaptan, zine dimethyldithiocarbamate or N-cyclohexyl-2-benzothiazole sulfonamide.
5. the manufacture method of a kind of terylene reinforced yarn woven patterns rubber-sole coiled material according to claim 1 is characterized in that, the reinforcing filler described in the step (3) is calcium carbonate, white carbon, cellulose or mica; Promoter is 2-benzothiazolyl mercaptan, zine dimethyldithiocarbamate or N-cyclohexyl-2-benzothiazole sulfonamide; Age resistor is 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline, N-phenyl-α-aniline or N-Phenyl beta naphthylamine; The molybdenum compound is molybdenum dioxide or molybdenum chloride; Borate is Boratex; Pigment is titanium dioxide, former orchid, heat-resisting purplish red, rose-red, medium chrome yellow, phthalein viridescent or phthalocyanine blue.
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| CN201110217491.1A CN102899913B (en) | 2011-07-29 | 2011-07-29 | Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material |
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| CN201110217491.1A CN102899913B (en) | 2011-07-29 | 2011-07-29 | Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material |
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| CN103289351A (en) * | 2013-05-21 | 2013-09-11 | 中国船舶重工集团公司第七二五研究所 | Preparation method of wide-temperature and wideband piezoelectric synergic damping material formed by vinyl |
| CN105442299A (en) * | 2016-01-08 | 2016-03-30 | 盐城工学院 | Flame-retardant environment-friendly textile and preparation method thereof |
| CN105525506A (en) * | 2015-12-29 | 2016-04-27 | 苏州宇希新材料科技有限公司 | Preparation method of textile heat insulation coating |
| CN105525503A (en) * | 2015-12-29 | 2016-04-27 | 苏州宇希新材料科技有限公司 | Fabric back lining heat insulation coating |
| CN109098214A (en) * | 2018-08-17 | 2018-12-28 | 庐江荣睿建设工程有限公司 | A kind of building basement concrete water-proof construction method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289351A (en) * | 2013-05-21 | 2013-09-11 | 中国船舶重工集团公司第七二五研究所 | Preparation method of wide-temperature and wideband piezoelectric synergic damping material formed by vinyl |
| CN103289351B (en) * | 2013-05-21 | 2015-06-03 | 中国船舶重工集团公司第七二五研究所 | Preparation method of wide-temperature and wideband piezoelectric synergic damping material formed by vinyl |
| CN105525506A (en) * | 2015-12-29 | 2016-04-27 | 苏州宇希新材料科技有限公司 | Preparation method of textile heat insulation coating |
| CN105525503A (en) * | 2015-12-29 | 2016-04-27 | 苏州宇希新材料科技有限公司 | Fabric back lining heat insulation coating |
| CN105442299A (en) * | 2016-01-08 | 2016-03-30 | 盐城工学院 | Flame-retardant environment-friendly textile and preparation method thereof |
| CN109098214A (en) * | 2018-08-17 | 2018-12-28 | 庐江荣睿建设工程有限公司 | A kind of building basement concrete water-proof construction method |
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| CN102899913B (en) | 2014-11-19 |
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