CN102899015B - A kind of low-density ceramic proppant utilizing coal ash for manufacturing standby and preparation method thereof - Google Patents
A kind of low-density ceramic proppant utilizing coal ash for manufacturing standby and preparation method thereof Download PDFInfo
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- CN102899015B CN102899015B CN201210353045.8A CN201210353045A CN102899015B CN 102899015 B CN102899015 B CN 102899015B CN 201210353045 A CN201210353045 A CN 201210353045A CN 102899015 B CN102899015 B CN 102899015B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a kind of low-density ceramic proppant utilizing coal ash for manufacturing standby and preparation method thereof, weight percentage, this propping agent comprises following feed composition: bauxitic clay 60% ~ 80%, flyash 10% ~ 30% and manganese powder 5% ~ 10%.The main component of flyash is Al
2o
3, SiO
2, and Al
2o
3and SiO
2content higher than coal gangue, purity is also high than coal gangue, can not affect the quality of haydite, and the density of flyash is lower, is suitable for the raw material as preparing low-density ceramsite.Powdered coal ash widely distributed, can utilize coal ash instead high-al clay resource less and less, saves Nonrenewable resources.Adopt flyash significantly can reduce the percentage of damage of low-density ceramic proppant as low-density ceramic proppant prepared by raw material compared with coal gangue, reduce volume density and the turbidity of ceramsite propping agent, improve the quality product of ceramsite propping agent, reduce costs, solve flyash and discharge the environmental pollution brought.
Description
Technical field
The invention belongs to inorganic non-metallic ceramics Material Field, be specifically related to a kind of low-density ceramic proppant utilizing coal ash for manufacturing standby and preparation method thereof.
Background technology
Petroleum fracturing propping agent (ceramsite sand) is a kind of ceramic particle product, has very high fracturing strengh, is mainly used in oil field well and supports, and to increase the output of oil and gas, belongs to environmentfriendly products.This product is the substitute of the Medium and low intensity propping agents such as natural siliceous sand, glass sphere, Metal Ball, has good result to stimulating oil Sweet natural gas.
During oil and gas deep mining, high locking pressure deposits of low permeability, after fracture treatment, makes Oil gas-containing rock layer split, and oil gas collects from the passage of cracking initiation.Enter Filling with petroleum fracturing propping agent in rock crack in company with high-pressure solution, play and support crack not stress release and closed effect, thus keep high flow conductivity, make oil gas unimpeded, increase yield.Facts have proved, use the oil well of petroleum fracturing propping agent pressure break to improve output 30-50%, can also extend the Oil/gas Well length of service, is the critical material of oil, the exploitation of Sweet natural gas low-permeability oil gas well, construction.Product application is when deep well fracturing is constructed, fill it in the rock crack in hyposmosis mineral deposit, carry out the closed fracture treatment of height, Oil gas-containing rock layer is split, play support crack not stress release and close, thus keep the high flow conductivity of oil gas, not only can increase oil and gas production, and more can extend the Oil/gas Well length of service.
Propping agent density is divided into three kinds by usual people custom: low density, Midst density and high-density, is generally 1.65 g/cm respectively with volume density and volume density
3below and 3.0g/cm
3hereinafter referred to as low-density propping agent; 1.65 g/cm
3~ 1.80 g/cm
3with 3.00 g/cm
3~ 3.35g/cm
3for Midst density propping agent; 1.80g/cm
3above with 3.35 g/cm
3it is more than high density proppants.
Coal gangue is the solid waste discharged in coal mining process and coal washing process, is a kind of black gray expandable rock lower, harder than coal with a kind of carbon content of coal seam association in coalification course.Its main component of coal gangue is Al
2o
3, SiO
2, also contain the Fe that quantity does not wait in addition
2o
3, CaO, MgO, Na
2o, K
2o, P
2o
5, SO
3with micro-rare elements (gallium, vanadium, titanium, cobalt).Number of patent application is that the patent application document of 200910023599.X discloses a kind of petroleum fracturing propping agent being added with coal gangue.But the harmful element in coal gangue, the content as sulphur, potassium, sodium etc. is higher, can affect the quality of petroleum fracturing propping agent, product strength is declined when the consumption of coal gangue is higher, and percentage of damage rises; And due to the content of the sulphur of coal gangue higher, can the obnoxious flavour of exhaust emission environment during production, as sulfurous gas etc.; The particle diameter of coal gangue is general comparatively large, during use, needs now to be milled to qualified granularity.
Flyash, be receive to catch the thin ash got off from the flue gas after coal combustion, flyash is the primary solids refuse that coal-burning power plant discharges.The main oxides of power plants flyash consists of: SiO
2, Al
2o
3, FeO, Fe
2o
3, CaO, TiO
2deng.Flyash is one of industrial residue that the current discharge capacity of China is larger, and along with the development of power industry, the flyash quantity discharged of coal-burning power plant increases year by year.A large amount of flyash does not add process, will produce airborne dust, atmosphere pollution; River can be caused to silt up if enter water system, and toxic chemical substance wherein also can work the mischief to human body and biology.China is again the limited country of a per capita resource reserve, the comprehensive utilization of flyash, turn waste into wealth, turn bane into boon, to become in China's economic construction an important techno-economic policy, solve China's electrical production environmental pollution, the important means of contradiction between resource shortage, be also electrical production one of the task of facing solution.
Summary of the invention
The object of the present invention is to provide a kind of low-density ceramic proppant utilizing coal ash for manufacturing standby and preparation method thereof.
Another object of the present invention is to the preparation method that a kind of low-density ceramic proppant utilizing coal ash for manufacturing standby is provided.
Object of the present invention can be achieved through the following technical solutions:
Utilize the low-density ceramic proppant that coal ash for manufacturing is standby, weight percentage, this propping agent comprises following feed composition: bauxitic clay 60% ~ 80%, flyash 10% ~ 30% and manganese powder 5% ~ 10%.Each feed composition sum is 100%.
Particle diameter≤300 order (0.045mm) of described bauxitic clay, is preferably 300 ~ 600 orders; Particle diameter≤300 order (0.045mm) of described manganese powder, is preferably 300 ~ 600 orders.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.。
The above-mentioned low-density ceramic proppant utilizing coal ash for manufacturing standby, it adopts following methods to prepare:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate; Use spray method adds water, and amount of water is 10% ~ 20% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 2 ~ 4 hours at 1280 ~ 1360 DEG C, obtains low-density ceramic proppant.
The preparation method of the above-mentioned low-density ceramic proppant utilizing coal ash for manufacturing standby, comprises the following steps:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate; Use spray method adds water, and amount of water is 10% ~ 20% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 2 ~ 4 hours at 1280 ~ 1360 DEG C, obtains low-density ceramic proppant.
Beneficial effect of the present invention:
The main component of flyash is Al
2o
3, SiO
2, and Al
2o
3and SiO
2content higher than coal gangue, purity is also high than coal gangue, can not affect the quality of haydite, and the density of flyash is lower, is suitable for the raw material as preparing low-density ceramsite.Powdered coal ash widely distributed, can utilize coal ash instead high-al clay resource less and less, saves Nonrenewable resources.
Adopt flyash significantly can reduce the percentage of damage of low-density ceramic proppant as low-density ceramic proppant prepared by raw material compared with coal gangue, reduce the volume density of ceramsite propping agent, improve the quality product of ceramsite propping agent, reduce costs.
The comprehensive Utilization Ways of development powder coal ash, turns waste into wealth, turns bane into boon, and solves flyash and discharges the environmental pollution brought.
Embodiment
Embodiment 1
This propping agent comprises following feed composition: bauxitic clay 70%, flyash 25% and manganese powder 5%.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; The particle diameter of described bauxitic clay is 320 orders; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.The particle diameter of described manganese powder is 320 orders.
Preparation process:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate (shaping particle diameter is 0.5-1.0mm); Use spray method adds water, and amount of water is 15% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 3 hours at 1300 DEG C, obtains low-density ceramic proppant.
Embodiment 2
This propping agent comprises following feed composition: bauxitic clay 65%, flyash 30% and manganese powder 5%.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; The particle diameter of described bauxitic clay is 320 orders; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.The particle diameter of described manganese powder is 320 orders.
Preparation process:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate (shaping particle diameter is 0.5-1.0mm); Use spray method adds water, and amount of water is 15% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 3 hours at 1300 DEG C, obtains low-density ceramic proppant.
Embodiment 3
This propping agent comprises following feed composition: bauxitic clay 80%, flyash 14% and manganese powder 6%.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; The particle diameter of described bauxitic clay is 320 orders; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.The particle diameter of described manganese powder is 320 orders.
Preparation process:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate (shaping particle diameter is 0.5-1.0mm); Use spray method adds water, and amount of water is 15% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 3 hours at 1300 DEG C, obtains low-density ceramic proppant.
Embodiment 4
This propping agent comprises following feed composition: bauxitic clay 63%, flyash 30% and manganese powder 7%.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; The particle diameter of described bauxitic clay is 320 orders; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.The particle diameter of described manganese powder is 320 orders.
Preparation process:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate (shaping particle diameter is 0.5-1.0mm); Use spray method adds water, and amount of water is 15% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 3 hours at 1300 DEG C, obtains low-density ceramic proppant.
Comparative example 1
This propping agent comprises following feed composition: bauxitic clay 70%, coal gangue 25% and manganese powder 5%.
In described bauxitic clay, the weight percentage of main chemical compositions is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; The particle diameter of described bauxitic clay is 320 orders; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.The particle diameter of described manganese powder is 320 orders.
Preparation process:
(1) pulverized coal gangue into 320 object fine powders, and then mixed with bauxitic clay and manganese powder in proportion and obtain mixture;
(2) mixture is put in tablets press granulate, obtain haydite base substrate (shaping particle diameter is 0.5-1.0mm); Use spray method adds water, and amount of water is 15% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 3 hours at 1300 DEG C, obtains low-density ceramic proppant.
Table 1 is the quality product detected result of embodiment 1-4 and comparative example 1
Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 |
Volume density g/cm 3 | 1.58 | 1.45 | 1.59 | 1.46 | 1.64 |
52MPa percentage of damage | 5.91 | 5.90 | 6.04 | 5.90 | 7.23 |
Circularity | >0.9 | >0.9 | >0.9 | >0.9 | >0.9 |
Sphericity | >0.9 | >0.9 | >0.9 | >0.9 | >0.9 |
Turbidity NTV | 36 | 35 | 36 | 35 | 46.2 |
Acid-soluble degree % | 6.37 | 6.36 | 6.37 | 6.36 | 6.36 |
Volume density g/cm 3 | 2.81 | 2.68 | 2.82 | 2.69 | 2.95 |
Compared with the quality measurements of product in comparative example, the detected result of the volume density of the product of embodiment 1-4, percentage of damage, turbidity and volume density is all obviously better than comparative example.
Claims (4)
1. utilize the low-density ceramic proppant that coal ash for manufacturing is standby, it is characterized in that weight percentage, this propping agent is made up of following raw material: bauxitic clay 60% ~ 80%, flyash 10% ~ 30% and manganese powder 5% ~ 10%;
Prepared by employing following methods:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate; Use spray method adds water, and amount of water is 10% ~ 20% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 2 ~ 4 hours at 1280 ~ 1360 DEG C, obtains low-density ceramic proppant.
2. the low-density ceramic proppant utilizing coal ash for manufacturing standby according to claim 1, is characterized in that particle diameter≤300 order of described bauxitic clay; Particle diameter≤300 order of described manganese powder.
3. the low-density ceramic proppant utilizing coal ash for manufacturing standby according to claim 1, is characterized in that the weight percentage of main chemical compositions in described bauxitic clay is: Al
2content 65% ~ 78%, Si content 4%-12%, Fe content 1% ~ 7%, Ti content 2% ~ 4%; In described manganese powder, the weight percentage of main chemical compositions is: Fe content 55% ~ 65%, Si content 25% ~ 35%.
4. the preparation method of the low-density ceramic proppant utilizing coal ash for manufacturing standby according to claim 1, is characterized in that comprising the following steps:
(1) bauxitic clay, flyash and manganese powder are mixed obtain mixture in proportion;
(2) mixture is put in tablets press granulate, obtain haydite base substrate; Use spray method adds water, and amount of water is 10% ~ 20% of mixture weight;
(3) by haydite base substrate screening post-drying, then sintering soak 2 ~ 4 hours at 1280 ~ 1360 DEG C, obtains low-density ceramic proppant.
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