CN102898237B - Powdery saline-alkali soil water-retention slow-release fertilizer - Google Patents

Powdery saline-alkali soil water-retention slow-release fertilizer Download PDF

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Publication number
CN102898237B
CN102898237B CN201210400569.8A CN201210400569A CN102898237B CN 102898237 B CN102898237 B CN 102898237B CN 201210400569 A CN201210400569 A CN 201210400569A CN 102898237 B CN102898237 B CN 102898237B
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China
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powdery
fertilizer
water
attapulgite clay
alkali soil
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Expired - Fee Related
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CN201210400569.8A
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CN102898237A (en
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赵怡红
金白云
管永祥
章东林
许庆华
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JIANGSU AGRICULTURAL ENVIRONMENT MONITORING AND PROTECTION STATION
JIANGSU NONGSHENG WASTE RECYCLING CO LTD
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JIANGSU NONGSHENG WASTE RECYCLING Co Ltd
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Abstract

The invention discloses a powdery saline-alkali soil water-retention slow-release fertilizer. The technical scheme of the powdery saline-alkali soil water-retention slow-release fertilizer has the key point that the ingredients of the powdery saline-alkali soil water-retention slow-release fertilizer consist of high-viscosity attapulgite clay powder, acidized attapulgite clay powder, ardealite, ammonia sulfate, calcium superphosphate, potassium sulphate, sulfuric acid, super absorbent resin and microelement mixture, and the ingredients of the powdery saline-alkali soil water-retention slow-release fertilizer are smashed after being stirred and are packed as the finished product of the powdery saline-alkali soil water-retention slow-release fertilizer. The powdery saline-alkali soil water-retention slow-release fertilize is acidic, the alkalinity of soil can be lowered, calcium ions contained in the fertilizer can be used for replacing sodions on a saline alkali soil colloid, so that the content of the soil exchangeable sodions is lowered, and a purpose of improving the saline-alkali soil is achieved. The powdery saline-alkali soil water-retention slow-release fertilizer contains a great quantity of nitrogen, phosphorus and potassium and various trace elements, has the functions on slow release of fertilizer efficiency and water retention and is suitable for topdressing on the saline-alkali soil, and necessary nutritional ingredients for plant growth can be provided.

Description

Powdery saltings the fertilizer of retaining water and releasing nutrients slowly
Technical field
The present invention relates to soil field, be specifically related to a kind of powdery saltings the fertilizer of retaining water and releasing nutrients slowly.
Background technology
The inland saline-alkali soil of China is mainly distributed in the ground such as northeast, North China, northwest, although some area is to build Garden Greenland on the ground in good farmland, with underground salt water, irrigates, and also can cause Soil Secondary saltings.
It is that soil compaction and Soil structure are poor that saline-alkali soil shows the most intuitively, and after irrigating, grogs is easy to automatically disperse and form skinning, and then stops moisture to infiltrate and reduce soil water storage capacity.
Saline land greening engineering is owing to being subject to the restriction of the local conditions such as soil, weather, construction and late maintaining difficulty are very large, improving flower plants and nursery stock surviving rate is the task of top priority, and alkaline water and soil is the major obstacle that causes flower plants and nursery stock death, therefore, need to correctly select applicable water, soil and fertilizer, and the fertilizer composition of supplying on market is more traditional nitrogen-phosphorus-potassium compound fertilizer, can not meet the demand of saline land greening engineering.
Phosphogypsum is the byproduct of sulfuric acid process phosphoric acid extraction production process, 1 ton of phosphoric acid of every production is by the phosphogypsum that produces 4.5~5.5 tons, a large amount of discharges of phosphogypsum not only take a large amount of soils, also, because phosphogypsum is through rainwater long period of soaking, cause the severe contamination to soil, water system and atmosphere.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is provided.
The batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is comprised of the sticky attapulgite clay powder of height, Concavo-convex excellent stone clay after the acidify powder, phosphogypsum, sulfate of ammoniac, calcium superphosphate, potassium sulfate, sulfuric acid, High hydrophilous resin and trace element mixture.The production method of powdery saltings the fertilizer of retaining water and releasing nutrients slowly: the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is stirred to rear pulverizing, be packaged as the finished product of powdery saltings the fertilizer of retaining water and releasing nutrients slowly.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, high sticky attapulgite clay soil property is fine and smooth, water-absorbent is strong, higher viscosity and the plasticity-of tool when wet, be conducive to the bonding between the fertilizer of retaining water and releasing nutrients slowly raw material of powdery saltings, and can be adsorbed on the surface of powdery saltings the fertilizer of retaining water and releasing nutrients slowly raw material, the effective ingredient of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is slowly discharged, keep the nutritive ingredient in the fertilizer of retaining water and releasing nutrients slowly of powdery saltings not run off, the normal growth that is conducive to plant is grown.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250ml through high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into mPasattapulgite clay powder be high sticky attapulgite clay powder, the sticky attapulgite clay powder particles of high fineness≤0.074 millimeter that the present invention selects.
Concavo-convex excellent stone clay after the acidify powder is sulfuric acid to be added in attapulgite clay, to carry out acidification post-treatment be meal, for improving attapulgite clay absorption and cationic exchange capacity.
Phosphogypsum is the byproduct of sulfuric acid process phosphoric acid extraction production process, phosphogypsum main component is calcium sulfate, contain the necessary nutritive element of plant and a certain amount of free acids such as phosphorus, iron simultaneously, both can be used as fertilizer to be used, also can be used as soil improvement agent improvement saline-alkali soil.
Calcium superphosphate is the phosphate fertilizer directly making with sulfuric acid decomposing phosphate rock, in calcium superphosphate, containing effective P2O5:14~20%, uses calcium superphosphate and can reduce surface soil alkalinity.
Ammonium sulfate is physiological acidic fertilizer, and after the ammonium in fertilizer is absorbed by plants, residual sulfate radical can reduce surface soil alkalinity.
Potassium sulfate is conventional potash fertilizer in agricultural, contains potassium oxide: 50%~54% in potassium sulfate.
Sulfuric acid is that to select concentration be 98% industrial sulphuric acid.
The water absorbent rate of High hydrophilous resin can reach hundreds of times even thousands of times of own wt, and the present invention selects particle fineness≤0.149 millimeter of High hydrophilous resin, and water absorbent rate is 100~300 times.
Iron is to form the necessary element of chlorophyll, and during iron deficiency, plant just produces chlorosis, and it is faint yellow that blade is, and is even white, and the present invention selects ferrous sulfate.
Zinc is the component of some enzyme in plant materials, and zinc is also to promote that some metabolic reactions are essential, and zinc generates and forms carbohydrate and is absolutely necessary for chlorophyll, and the present invention selects zinc sulfate.
Copper has the ability that improves plant chlorophyll stability, avoids chlorophyll to wreck too early, is conducive to blade and carries out better photosynthesis, and the present invention selects copper sulfate.
Manganese can promote the metabolism of carbohydrate and the metabolism of nitrogen, has substantial connection with growth and development of plants and output, and the present invention selects manganous sulfate.
Boron can promote the normal operation of carbohydrate, and the position that boron-containing quantity is the highest in plant materials is colored, so boron deficiency often shows as " colored and unreal ", and the present invention selects borax.
The present invention is achieved by following technical proposals:
1, the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~10%, Concavo-convex excellent stone clay after the acidify powder 5~15%, phosphogypsum 10~30%, calcium superphosphate 5~28%, ammonium sulfate 5~25%, potassium sulfate 2~20%, High hydrophilous resin 0.05~5% and trace element mixture 0.01~1%;
The production method of described Concavo-convex excellent stone clay after the acidify powder: (1) the batching of acidification is comprised of following component by weight percentage: attapulgite clay 55~75% and dilute sulphuric acid 25~45%, dilute sulphuric acid is added in attapulgite clay and carries out acidification, and the acidification time is controlled at 24~72 hours; (2) will in the attapulgite clay input rotary dryer after acidification, carry out roasting, temperature is controlled at 280~350 ℃; (3) will in the attapulgite clay input pulverizer after roasting, pulverize as powdery Concavo-convex excellent stone clay after the acidify, Concavo-convex excellent stone clay after the acidify powder particles fineness≤0.25 millimeter, water content≤2%;
The batching of described dilute sulphuric acid is comprised of following component by weight percentage: sulfuric acid 0.5~15% and water 85~99.5%;
Described sulfuric acid is that to select concentration be 98% industrial sulphuric acid, and the per-cent of concentration is weight percentage;
The per-cent of described water content is weight percentage;
The batching of described trace element mixture is comprised of following component by weight percentage: ferrous sulfate 0.01~35%, zinc sulfate 0.01~35%, copper sulfate 0.01~30%, manganous sulfate 0.01~30% and borax 0.01~20%;
The production method of described powdery saltings the fertilizer of retaining water and releasing nutrients slowly: (1) the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is added in the two shaft pugmill mixer having moved, stir the mixture into powdery saltings the fertilizer of retaining water and releasing nutrients slowly; (2) in mixture input pulverizer that will powdery saltings the fertilizer of retaining water and releasing nutrients slowly, pulverize as meal, particle fineness≤0.149 millimeter of meal, is packaged as the finished product of powdery saltings the fertilizer of retaining water and releasing nutrients slowly.
It is acid that powdery saltings the fertilizer of retaining water and releasing nutrients slowly is, can reduce the alkalescence of soil, sodium ion on contained calcium ion replaceable salt affected soil colloid, the content of soil exchangeable sodium ion is reduced, thereby further reduce the sodium basicity of soil, promote the formation of soil aggregate, reach the object in improvement saltings.
In the fertilizer of retaining water and releasing nutrients slowly of powdery saltings, contain a large amount of nitrogen, phosphorus, potassium and various trace elements, there is slow release fertilizer efficiency and water retaining function, can provide plant-growth necessary nutritive ingredient, keep the nutritive ingredient in the fertilizer of retaining water and releasing nutrients slowly of powdery saltings not run off, the normal growth that is conducive to plant is grown, and is that a kind of nutrition is complete, fertilizer efficiency is high, nontoxic, harmless, odorless and long saltings the fertilizer of retaining water and releasing nutrients slowly of water conservation time.
Powdery saltings the fertilizer of retaining water and releasing nutrients slowly is applicable to topdressing of saltings proportion of crop planting and landscape engineering.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is comprised of following component by weight percentage: high sticky attapulgite clay powder 4%, Concavo-convex excellent stone clay after the acidify powder 10%, phosphogypsum 25%, calcium superphosphate 22%, ammonium sulfate 22%, potassium sulfate 16%, High hydrophilous resin 0.8% and trace element mixture 0.2%;
The production method of described Concavo-convex excellent stone clay after the acidify powder: (1) the batching of acidification is comprised of following component by weight percentage: attapulgite clay 64% and dilute sulphuric acid 36%, dilute sulphuric acid is added in attapulgite clay and carries out acidification, and the acidification time is controlled at 48 hours; (2) will in the attapulgite clay input rotary dryer after acidification, carry out roasting, maturing temperature is controlled at 300~320 ℃; (3) will in the attapulgite clay input pulverizer after roasting, pulverize as powdery Concavo-convex excellent stone clay after the acidify, Concavo-convex excellent stone clay after the acidify powder particles fineness≤0.25 millimeter, water content≤1.8%;
The batching of described dilute sulphuric acid is comprised of following component by weight percentage: sulfuric acid 3% and water 97%;
The production method of described powdery saltings the fertilizer of retaining water and releasing nutrients slowly: the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is added in the two shaft pugmill mixer having moved, stir the mixture into powdery saltings the fertilizer of retaining water and releasing nutrients slowly; (2) in mixture input pulverizer that will powdery saltings the fertilizer of retaining water and releasing nutrients slowly, pulverize as meal, particle fineness≤0.149 millimeter of meal, is packaged as the finished product of powdery saltings the fertilizer of retaining water and releasing nutrients slowly;
The batching of described trace element mixture is comprised of following component by weight percentage: ferrous sulfate 26%, zinc sulfate 24%, copper sulfate 22%, manganous sulfate 18% and borax 10%.

Claims (1)

1. a powdery saltings the fertilizer of retaining water and releasing nutrients slowly, it is characterized in that, the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~10%, Concavo-convex excellent stone clay after the acidify powder 5~15%, phosphogypsum 10~30%, calcium superphosphate 5~28%, ammonium sulfate 5~25%, potassium sulfate 2~20%, High hydrophilous resin 0.05~5% and trace element mixture 0.01~1%;
The production method of described Concavo-convex excellent stone clay after the acidify powder: (1) the batching of acidification is comprised of following component by weight percentage: attapulgite clay 55~75% and dilute sulphuric acid 25~45%, dilute sulphuric acid is added in attapulgite clay and carries out acidification, and the acidification time is controlled at 24~72 hours; (2) will in the attapulgite clay input rotary dryer after acidification, carry out roasting, temperature is controlled at 280~350 ℃; (3) will in the attapulgite clay input pulverizer after roasting, pulverize as powdery Concavo-convex excellent stone clay after the acidify, Concavo-convex excellent stone clay after the acidify powder particles fineness≤0.25 millimeter, water content≤2%;
The batching of described dilute sulphuric acid is comprised of following component by weight percentage: sulfuric acid 0.5~15% and water 85~99.5%;
Described sulfuric acid is that to select concentration be 98% industrial sulphuric acid, and the per-cent of concentration is weight percentage;
The per-cent of described water content is weight percentage;
The batching of described trace element mixture is comprised of following component by weight percentage: ferrous sulfate 0.01~35%, zinc sulfate 0.01~35%, copper sulfate 0.01~30%, manganous sulfate 0.01~30% and borax 0.01~20%;
The production method of described powdery saltings the fertilizer of retaining water and releasing nutrients slowly: (1) the batching of powdery saltings the fertilizer of retaining water and releasing nutrients slowly is added in the two shaft pugmill mixer having moved, stir the mixture into powdery saltings the fertilizer of retaining water and releasing nutrients slowly; (2) in mixture input pulverizer that will powdery saltings the fertilizer of retaining water and releasing nutrients slowly, pulverize as meal, particle fineness≤0.149 millimeter of meal, is packaged as the finished product of powdery saltings the fertilizer of retaining water and releasing nutrients slowly;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250mL through high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into mPasattapulgite clay powder be high sticky attapulgite clay powder, the sticky attapulgite clay powder particles of the height of selecting fineness≤0.074 millimeter.
CN201210400569.8A 2012-10-22 2012-10-22 Powdery saline-alkali soil water-retention slow-release fertilizer Expired - Fee Related CN102898237B (en)

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CN105294349A (en) * 2015-11-19 2016-02-03 任珺 Attapulgite-based fertilizer synergist having soil improvement effect
CN105294348A (en) * 2015-11-19 2016-02-03 兰州坤仑环保科技有限公司 Attapulgite-based mineral slow-release fertilizer
CN105294279A (en) * 2015-11-19 2016-02-03 兰州坤仑环保科技有限公司 Attapulgite mixing fertilizer having slow release effect
CN106396867A (en) * 2016-08-29 2017-02-15 山东胜伟园林科技有限公司 Humic acid slow release fertilizer suitable for long-term improvement of secondary salinization land
CN106699449A (en) * 2016-12-14 2017-05-24 张明玉 Double-layer coated slow-release nitrogen fertilizer for improving saline-alkali soil and preparation method thereof
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Patentee before: JIANGSU NONGSHENG WASTE RECYCLING Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140226