Summary of the invention
In order to solve above-mentioned technical problem, the object of this invention is to provide a kind of preparation method of millboard of high cardboard interfacial bonding strength, the method adopts the paper pulp that beating degree is low, manufactures paper with pulp easy and energy-conservation, and considerably improves the interfacial bonding strength of cardboard.
In order to realize above-mentioned object, present invention employs following technical scheme:
A preparation method for the millboard of high cardboard interfacial bonding strength, the method utilizes beating degree to be 20
osR ~ 35
othe paper pulp of SR after online forms l Water Paper page bonded to each other together before, vaporific binder aqueous solution is sprayed at l Water Paper interlayer, described binder aqueous solution is one in starch, polyacrylamide modifier or its mixture, and binder aqueous solution concentration is 0.5% ~ 6.0%.
As preferably, spray starch selected by described adhesive, and the concentration of binder aqueous solution is 2.0% ~ 5.0%.As preferred again, the concentration of described binder aqueous solution is 3.0% ~ 4.0%.
As preferably, polyacrylamide modifier selected by described adhesive, and the concentration of binder aqueous solution is 0.5% ~ 3.0%.As preferred again, the concentration of binder aqueous solution is 1.5% ~ 2.0%.
As preferably, described adhesive selects spray starch and the mixing of polyacrylamide modifier, and the concentration of binder aqueous solution is 1.0% ~ 6.0%.As preferred again, the concentration of binder aqueous solution is 1.5% ~ 4.0%.
As preferably, described polyacrylamide modifier selects amphiprotic polyacrylamide or anionic polyacrylamide.
As preferred again, described starch concentration 1.5% ~ 3.5%, polyacrylamide modifier concentration 0.3% ~ 0.8%.
As preferably, the nozzle of spray adopts fan nozzle, and injector spacing is at 80mm ~ 130mm, and spray press control is at 0.3Mpa ~ 0.4Mpa.
The present invention, owing to have employed above-mentioned technical scheme, has following feature:
One, manufacture paper with pulp easy and energy-conservation, the paper pulp low because of beating degree is good at papermaking wet end drainage, and dehydration easily, is not easily fallen slurry, bubbled, easily manufacture paper with pulp in the process of manufacturing paper with pulp; Another low beating degree can not need degree of depth defibrination and save a large amount of electric energy;
Two, improve the interfacial bonding strength Be very effective of cardboard, also have certain effect to the retention improving paper pulp and chemical industry auxiliary material.In addition, in paper pulp online forming process, at the composite adhesive of l Water Paper interlayer spray containing polyacrylamide modifier, not only can improve the retention of fiber fines, and greatly can improve the retention of other adhesives such as starch, simultaneously bridge linking effect plays between fiber in the hydroxyl that carries of polyacrylamide modifier itself and modification group, adds and bonding point between paper pulp fiber and bonding force, thus substantially increases the bond strength between ply of board.
Detailed description of the invention
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is made a detailed explanation.
The preparation method of the millboard of a kind of high cardboard interfacial bonding strength as shown in Figure 1, the method utilizes beating degree to be 20
osR ~ 35
oSRpaper pulp after online forms l Water Paper page bonded to each other together before, vaporific binder aqueous solution is sprayed at l Water Paper interlayer, as sprayed vaporific binder aqueous solution at No. 1 net, No. 2 nets respectively after forming l Water Paper page, described binder aqueous solution is one in starch, polyacrylamide modifier or its mixture, and binder aqueous solution concentration is 0.5% ~ 6.0%.And then enter later roller, main pressure roller, pressure roller and fit together, then cylinder dried 1 ovens dry, carry out surface treatment, then enter cylinder dried 2 ovens dry, through calender, then batch, rewind slitting is packed and is put in storage.
Compared by embodiment and comparative example more below, the present invention is further described.
Project |
Speed of a motor vehicle m/min |
Cal(l)iper mm |
Beating degree
oSR
|
Weight in wet base g |
Interlayer sprayed adhesive composition and concentration |
Interlaminar strength ft lb/1000in
2 |
Test situation |
Self-inspection and client feedback |
Before improvement |
35 |
0.90 |
42~45 |
4.8 |
Nothing |
65~75 |
Without exception |
Coating combination is poor, easy layering, and client cannot use |
Embodiment 1 |
35 |
0.90 |
38~42 |
4.8 |
Starch/3.5% aqueous solution |
70~75 |
There are slurry, foaming phenomena in production process |
There is lamination, have customer complaint layering |
Embodiment 2 |
35 |
0.90 |
38~42 |
4.8 |
Amphiprotic polyacrylamide/2.0% aqueous solution |
85~100 |
Without exception |
Occasionally there is lamination, occasionally have layering to complain |
Embodiment 3 |
35 |
0.90 |
30~35 |
4.5 |
(starch/2.0%+ amphiprotic polyacrylamide 0.5%) aqueous solution |
115~130 |
Without exception |
Without layering, customers' responsiveness is good |
Embodiment 4 |
35 |
0.90 |
30~35 |
4.5 |
Starch/4.0% aqueous solution |
110~120 |
Without exception |
Without layering, customers' responsiveness is good |
Embodiment 5 |
35 |
0.90 |
30~35 |
4.5 |
Amphiprotic polyacrylamide/3.0% aqueous solution |
110~120 |
Without exception |
Without layering, customers' responsiveness is good |