CN102838486B - 紫外光固化聚酯丙烯酸酯及其制备方法 - Google Patents
紫外光固化聚酯丙烯酸酯及其制备方法 Download PDFInfo
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- CN102838486B CN102838486B CN201210362409.9A CN201210362409A CN102838486B CN 102838486 B CN102838486 B CN 102838486B CN 201210362409 A CN201210362409 A CN 201210362409A CN 102838486 B CN102838486 B CN 102838486B
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- acrylic ester
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- ultraviolet curing
- polyester acrylic
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- 229920000728 polyester Polymers 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- -1 acrylic ester Chemical class 0.000 title claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 12
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 11
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 6
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003146 anticoagulant agent Substances 0.000 claims 2
- 229940127219 anticoagulant drug Drugs 0.000 claims 2
- LIQZBCYZGHXLNE-UHFFFAOYSA-N prop-2-enoic acid 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound OC(=O)C=C.CC(COC(C)COC(=O)C=C)OCC(C)OC(=O)C=C LIQZBCYZGHXLNE-UHFFFAOYSA-N 0.000 claims 1
- 238000001723 curing Methods 0.000 abstract description 25
- 239000011347 resin Substances 0.000 abstract description 11
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- 238000003848 UV Light-Curing Methods 0.000 abstract description 2
- 238000004500 asepsis Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000002159 abnormal effect Effects 0.000 description 3
- 230000035943 smell Effects 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- Macromonomer-Based Addition Polymer (AREA)
Abstract
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CN201210362409.9A CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
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CN201210362409.9A CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
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CN102838486A CN102838486A (zh) | 2012-12-26 |
CN102838486B true CN102838486B (zh) | 2016-08-10 |
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CN201210362409.9A Active CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103589306B (zh) * | 2013-10-24 | 2016-08-31 | 惠州市长润发涂料有限公司 | 一种高渗透性uv底漆 |
CN106748765B (zh) * | 2016-12-12 | 2019-08-20 | 华南理工大学 | 一种可uv固化聚酯及其制备方法与应用 |
CN106752752B (zh) * | 2017-01-12 | 2019-06-14 | 广东美涂士建材股份有限公司 | 木门用无溶剂uv手扫涂料及其制备方法与施工工艺 |
CN110684176B (zh) * | 2019-10-17 | 2023-01-03 | 嘉宝莉化工集团股份有限公司 | 聚酯改性环氧丙烯酸酯树脂及其制备方法和应用 |
CN112063275A (zh) * | 2020-08-19 | 2020-12-11 | 广东立邦长润发科技材料有限公司 | 铝卷预涂用紫外光固化底漆及面漆 |
WO2022133680A1 (zh) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | 一种uv固化低粘度聚酯及其制备方法 |
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JPS5430431B2 (zh) * | 1973-03-22 | 1979-10-01 | ||
JPH0749471B2 (ja) * | 1984-11-22 | 1995-05-31 | 東洋インキ製造株式会社 | ポリエステルオリゴマ−の製造方法 |
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Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant after: Beijing Zhanchen Chemical Co.,Ltd. Applicant after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Vision Chemical Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. Applicant before: QINGDAO VISION CHEMICALS CO.,LTD. Applicant before: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. |
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Free format text: CORRECT: APPLICANT; FROM: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO VISION CHEMICAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. TO: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO ZHANCHEN NEW MATERIAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. Free format text: CORRECT: APPLICANT; FROM: SHANGHAI FUCHEN CHEMICAL CO. LTD. TO: SHANGHAI ZHANCHEN PAINT CO., LTD. |
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Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: China Zhanchen New Materials Group Co.,Ltd. Applicant after: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. Applicant before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant before: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. |
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Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: China Zhanchen New Materials Group Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |
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Effective date of registration: 20200720 Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: Zhuhai zhanchen New Material Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |
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TR01 | Transfer of patent right |