CN102838486A - 紫外光固化聚酯丙烯酸酯及其制备方法 - Google Patents
紫外光固化聚酯丙烯酸酯及其制备方法 Download PDFInfo
- Publication number
- CN102838486A CN102838486A CN2012103624099A CN201210362409A CN102838486A CN 102838486 A CN102838486 A CN 102838486A CN 2012103624099 A CN2012103624099 A CN 2012103624099A CN 201210362409 A CN201210362409 A CN 201210362409A CN 102838486 A CN102838486 A CN 102838486A
- Authority
- CN
- China
- Prior art keywords
- reaction
- preparation
- polyester acrylate
- ultraviolet light
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 acrylic ester Chemical class 0.000 claims abstract description 11
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 9
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 12
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 11
- 150000007520 diprotic acids Chemical class 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims 2
- LIQZBCYZGHXLNE-UHFFFAOYSA-N prop-2-enoic acid 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound OC(=O)C=C.CC(COC(C)COC(=O)C=C)OCC(C)OC(=O)C=C LIQZBCYZGHXLNE-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 30
- 239000011347 resin Substances 0.000 abstract description 11
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 20
- 239000004925 Acrylic resin Substances 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210362409.9A CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210362409.9A CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102838486A true CN102838486A (zh) | 2012-12-26 |
CN102838486B CN102838486B (zh) | 2016-08-10 |
Family
ID=47366250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210362409.9A Active CN102838486B (zh) | 2012-09-25 | 2012-09-25 | 紫外光固化聚酯丙烯酸酯及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102838486B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103589306A (zh) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | 一种高渗透性uv底漆 |
CN106748765A (zh) * | 2016-12-12 | 2017-05-31 | 华南理工大学 | 一种可uv固化聚酯及其制备方法与应用 |
CN106752752A (zh) * | 2017-01-12 | 2017-05-31 | 广东美涂士建材股份有限公司 | 木门用无溶剂uv手扫涂料及其制备方法与施工工艺 |
CN110684176A (zh) * | 2019-10-17 | 2020-01-14 | 嘉宝莉化工集团股份有限公司 | 聚酯改性环氧丙烯酸酯树脂及其制备方法和应用 |
CN112063275A (zh) * | 2020-08-19 | 2020-12-11 | 广东立邦长润发科技材料有限公司 | 铝卷预涂用紫外光固化底漆及面漆 |
WO2022133680A1 (zh) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | 一种uv固化低粘度聚酯及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3935173A (en) * | 1973-03-22 | 1976-01-27 | Toagosei Chemical Industrial Co. Ltd. | Curable compositions |
JPS61126128A (ja) * | 1984-11-22 | 1986-06-13 | Toyo Ink Mfg Co Ltd | ポリエステルオリゴマ−の製造方法 |
-
2012
- 2012-09-25 CN CN201210362409.9A patent/CN102838486B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3935173A (en) * | 1973-03-22 | 1976-01-27 | Toagosei Chemical Industrial Co. Ltd. | Curable compositions |
JPS61126128A (ja) * | 1984-11-22 | 1986-06-13 | Toyo Ink Mfg Co Ltd | ポリエステルオリゴマ−の製造方法 |
Non-Patent Citations (3)
Title |
---|
喻兰英等: "聚酯丙烯酸酯预聚物的合成研究", 《弹性体》 * |
张洁: "紫外光固化水性聚酯丙烯酸酯的合成与感光性能", 《苏州大学学报(自然科学)》 * |
苏琳: "UV 固化水性高支化聚酯制备和性能", 《中国优秀硕士学位论文全文数据库(工程科技Ⅰ辑)》 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103589306A (zh) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | 一种高渗透性uv底漆 |
CN103589306B (zh) * | 2013-10-24 | 2016-08-31 | 惠州市长润发涂料有限公司 | 一种高渗透性uv底漆 |
CN106748765A (zh) * | 2016-12-12 | 2017-05-31 | 华南理工大学 | 一种可uv固化聚酯及其制备方法与应用 |
CN106748765B (zh) * | 2016-12-12 | 2019-08-20 | 华南理工大学 | 一种可uv固化聚酯及其制备方法与应用 |
CN106752752A (zh) * | 2017-01-12 | 2017-05-31 | 广东美涂士建材股份有限公司 | 木门用无溶剂uv手扫涂料及其制备方法与施工工艺 |
CN106752752B (zh) * | 2017-01-12 | 2019-06-14 | 广东美涂士建材股份有限公司 | 木门用无溶剂uv手扫涂料及其制备方法与施工工艺 |
CN110684176A (zh) * | 2019-10-17 | 2020-01-14 | 嘉宝莉化工集团股份有限公司 | 聚酯改性环氧丙烯酸酯树脂及其制备方法和应用 |
CN110684176B (zh) * | 2019-10-17 | 2023-01-03 | 嘉宝莉化工集团股份有限公司 | 聚酯改性环氧丙烯酸酯树脂及其制备方法和应用 |
CN112063275A (zh) * | 2020-08-19 | 2020-12-11 | 广东立邦长润发科技材料有限公司 | 铝卷预涂用紫外光固化底漆及面漆 |
WO2022133680A1 (zh) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | 一种uv固化低粘度聚酯及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102838486B (zh) | 2016-08-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101747594B (zh) | 环氧丙烯酸预聚体树脂及其制法和在光固化涂料中的应用 | |
CN102838486A (zh) | 紫外光固化聚酯丙烯酸酯及其制备方法 | |
CN101928508B (zh) | 一种聚乙二醇改性的环氧丙烯酸酯涂料及其制备方法 | |
CN101864204B (zh) | 一种高性能汽车车灯反射镜专用紫外光固化真空镀膜底漆 | |
CN102516326B (zh) | 一种单宁基超支化丙烯酸酯的合成方法 | |
CN105348998A (zh) | 有机硅改性水性光固化环氧-丙烯酸涂料及其制备方法 | |
CN103265871A (zh) | 一种水性环氧丙烯酸uv固化涂料及其制备方法 | |
CN109867760B (zh) | 一种3d打印用腰果酚基光敏树脂及其制备方法 | |
CN108129589B (zh) | 植物油基硫醇自固化树脂及其制备方法与应用 | |
CN112442318A (zh) | 一种生物基自修复光固化涂料及其制备方法和应用 | |
CN104312238A (zh) | 一种高剥离性能的紫外光固化防粘剂 | |
CN107936746A (zh) | 一种有机硅改性阳离子光固化脂环族环氧树脂涂料及其应用 | |
WO2015090076A1 (zh) | 辐射固化于轮胎且自发光的涂料/油墨及制备方法 | |
CN106118320A (zh) | 一种紫外光固化绝缘底漆组合物及其应用 | |
CN104017496A (zh) | 一种利用松香衍生物合成的紫外光固化低聚物及其制备方法 | |
CN113388051A (zh) | 一种苯乙烯-马来酸酐酯化物及制备方法和应用 | |
CN109776347B (zh) | 一种热固性植物油基丙烯酸酯衍生物及其制备方法和应用 | |
CN107828304A (zh) | 一种紫外光固化水性环氧丙烯酸树脂涂料及其制备方法 | |
CN110903769A (zh) | 一种紫外光固化胶黏剂及其制备方法和应用 | |
CN103509162A (zh) | 一种环氧改性聚酯丙烯酸酯及其制备方法 | |
CN101418148A (zh) | 一种紫外光固化涂料的制作方法 | |
CN102993411A (zh) | 一种多元酸改性环氧丙烯酸酯树脂及其制备方法 | |
CN102924987A (zh) | 一种热-紫外光双重固化水性有色涂层组合物 | |
CN104497925A (zh) | 基于光热的uv固化压敏胶制备方法 | |
CN101824137A (zh) | 一种改性双酚a环氧丙烯酸酯及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB02 | Change of applicant information |
Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant after: Beijing Zhanchen Chemical Co.,Ltd. Applicant after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Vision Chemical Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. Applicant before: QINGDAO VISION CHEMICALS CO.,LTD. Applicant before: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. |
|
COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO VISION CHEMICAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. TO: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO ZHANCHEN NEW MATERIAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. Free format text: CORRECT: APPLICANT; FROM: SHANGHAI FUCHEN CHEMICAL CO. LTD. TO: SHANGHAI ZHANCHEN PAINT CO., LTD. |
|
CB02 | Change of applicant information |
Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant after: China Zhanchen New Materials Group Co.,Ltd. Applicant after: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Applicant before: ZHANCHEN PAINT GROUP Co.,Ltd. Applicant before: Beijing Zhanchen Chemical Co.,Ltd. Applicant before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Applicant before: CHENGDU ZHANCHEN CHEMICAL Co.,Ltd. |
|
COR | Change of bibliographic data | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: China Zhanchen New Materials Group Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200720 Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: Zhuhai zhanchen New Material Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |