CN102831818B - Shipping mark capable of removing information by washing and preparation method of shipping mark - Google Patents
Shipping mark capable of removing information by washing and preparation method of shipping mark Download PDFInfo
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- CN102831818B CN102831818B CN201210332479.XA CN201210332479A CN102831818B CN 102831818 B CN102831818 B CN 102831818B CN 201210332479 A CN201210332479 A CN 201210332479A CN 102831818 B CN102831818 B CN 102831818B
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Abstract
The invention discloses a shipping mark capable of removing information by washing, which comprises a bottom lining and a marking surface, wherein the bottom lining is sprayed and spun by high-polymer resin, and the marking surface is obtained by the method that washing oil ink capable of decoloring is printed on the bottom lining in a silk-screen or flexographic-printing mode. The shipping mark has a peculiar function. After the shipping mark prepared by the preparation method is washed, information printed on the shipping mark can be completely or partially removed according to the client design.
Description
Technical field
The present invention relates to garment accessories field, particularly relate to a kind of washing breath shipping mark and preparation method thereof of can writing to.
Background technology
In garment accessories, shipping mark plays the vital role of transmission of information.Can be divided into BRAND LABEL (claim not only trade mark), size label, CARE LABEL (but also claiming content label) according to the effect of shipping mark.BRAND LABEL is the plate of garment enterprise, is related to the overall image of product and the overall image of enterprise, is the publicity window of clothes production enterprise or garment marketing enterprise.On BRAND LABEL, generally can stamp word or the figurative mark of clothes production enterprise or sale enterprise, it is representing image, fame, technical quality and the market share etc. of clothes production enterprise or sale enterprise to a certain extent, BRAND LABEL generally can be by car the neckline position at clothes.Size label refers to size and applicable people's the bodily form for representing clothes, and size label generally can be by car below BRAND LABEL, also has together with CARE LABEL the side at clothes by car.CARE LABEL is generally used for representing the information such as product specification, properties of product, fibre composition, using method, washing methods, and also have garment enterprise that the production address of oneself or contact method are imprinted on CARE LABEL, CARE LABEL is the side at clothes by car generally.
Along with society constantly develops, organized business activity and social activities are on the increase, the demand of giving clothes of various Shirt with advertisement, frock, community activity dress, large enterprise constantly increases, some organizer wishes only to show within the specific limits quality and clothes production enterprise's information of own clothes, under certain condition, make garment enterprise information disappear, only retain own company information, thereby ensure that the member of oneself has no chance to contact with garment enterprise, ensures the exclusive use of oneself.Also some organizer wishes to increase touch opportunity own and member or client by such " mystery " function, to reaching oneself commercial object or social object.
Summary of the invention
Based on this, the object of this invention is to provide a kind of washing breath shipping mark of can writing to.
Concrete technical scheme is as follows:
A kind of washing breath shipping mark of can writing to, comprises end liner face and mark face, and described end liner face is spun and formed by macromolecule resin spray, and described mark face can be printed on end liner face and be obtained by the mode of silk-screen or flexo by erasable ink by washing.
In some embodiment, described washing can be prepared from by the raw material of following percentage by weight by erasable ink therein: the oligomeric degree polyvinyl alcohol resin of the liquid 70%-80% that viscosity is 800-1200mPas; Aqueous color paste 2%-5%; Distilled water 2%-15%; Ethanol 2%-5%; Salicylic acid 0.01%-0.05%; Defoamer 0.01%-0.05%, the summation of above-mentioned raw materials is 100%.
In some embodiment, the degree of polymerization of the oligomeric degree polyvinyl alcohol resin of described liquid is 1.7-3.5 ten thousand therein, and alcoholysis degree is 88-98%.
Another object of the present invention is to provide can the write to preparation method of breath shipping mark of above-mentioned washing.
Concrete technical scheme is as follows:
Can the write to preparation method of breath shipping mark of above-mentioned washing, comprises the steps:
(1) taking in proportion washing can the each raw material of erasable ink, mixing and obtain washing can erasable ink, and described washing can be prepared from by the raw material of following percentage by weight by erasable ink: the oligomeric degree polyvinyl alcohol resin of the liquid 70%-80% that viscosity is 800-1200mPas; Aqueous color paste 2%-5%; Distilled water 2%-15%; Ethanol 2%-5%; Salicylic acid 0.01%-0.05%; Defoamer 0.01%-0.05%, the summation of above-mentioned raw materials is 100%;
(2) can erasable ink adopt the mode of silk-screen or flexo to be printed on end liner face washing and form mark face, cut and obtain the described washing breath shipping mark of can writing to.
Oligomeric degree polyvinyl alcohol resin can be water-soluble, utilize ink prepared by oligomeric degree polyvinyl alcohol resin to adopt infiltration dry from dry mode, thereby make the ink of drying have the ability that continues to be dissolved in the water, this is the main cause that this ink can be water-washed away.The aqueous color paste that adopts low covering power is excessively strong in order to prevent mill base and clothes fiber binding ability, thereby avoids the ink recontamination clothes of being washed off.End liner face adopts and tears not waste paper, be a kind of adopt tiny macromolecule resin fiber by spray spinning technique be made into, have and can wash not rotten performance, ink has certain permeance property in the above, thereby ensure that this kind of ink does not have good adhesion tearing above waste paper, prevented again that ink from too permeating simultaneously and cause printing figure message fuzzy.By such technical solution, both can ensure to want the information being removed disappearing after more than 15 DEG C washing, can ensure that again printing element exists.
Washing can adopt the oligomeric degree polyvinyl alcohol resin of liquid, auxiliary agent, mill base mixed grinding to be prepared from by erasable ink.
The oligomeric degree polyvinyl alcohol resin of liquid is a kind ofly can't help monomer polymerization and be hydrolyzed the water-soluble polymers obtaining by polyvinyl acetate (PVA), and its physical property is subject to the impact of chemical constitution, alcoholysis degree, the degree of polymerization.In polyvinyl alcohol molecule, exist two kinds of chemical constitutions, i.e. 1,3 and 1,2 ethylene glycol structure, but main structure is 1,3 ethylene glycol structure, i.e. " end to end " structure.The poly degree of polymerization is divided into the superelevation degree of polymerization (molecular weight 25～300,000), high polymerization degree (molecular weight 17-22 ten thousand), the middle degree of polymerization (molecular weight 12～150,000) and low polymerization degree (1.7～3.5 ten thousand).Alcoholysis degree generally has 78%, 88%, 98% 3 kind.Preferably polyethylene alcohol emulsion viscosity of the present invention is 800-1200mpa.s, and the degree of polymerization is 1.7 ~ 3.5 ten thousand, and alcoholysis degree is between 88% ~ 98%
Water-based defoamer has the insoluble mineral oil of water, fatty acid low-carbon-ester, higher alcohol, polysiloxane, higher fatty acid glyceride, remodeling organic siliconresin, organic phosphoric acid three esters, higher fatty acid metallic soap etc., and the present invention is preferably polysiloxane defoamer
The waste paper that tears not as end liner face is to adopt spray spinning technique to prepare by macromolecule resins such as tygon, polypropylene, polystyrene, and the not waste paper that tears forming is spun in preferably polyethylene spray.
Advantage of the present invention is:
(1) there is unique function: shipping mark prepared by the present invention can remove wholly or in part information according to client's design after washing.
(2) environmental protection: in the present invention, the link stuff principal ingredient of ink is the oligomeric degree polyvinyl alcohol resin of liquid; can be water-soluble and ethanol; the auxiliary agent simultaneously using and solvent are all can be water-soluble or itself be water; self-control ink is tasteless nontoxic, is conducive to the healthy of environmental protection and employee and client.
(3) simple to operate: the invention process method is simple, easy operating, without using expensive professional equipment, is all applicable to extensive operation and small-scale operating type;
(4) ink degradable: the ink that the present invention uses is oligomeric degree polyvinyl alcohol (PVA), still can be soluble in water after dry conjunctiva, and for avoiding washing the rear pollution to clothes, this ink does not use inorganic filler except mill base contains a small amount of inorganic filler.
Brief description of the drawings
Fig. 1 the present invention washes the sectional view of the breath shipping mark of can writing to.
Description of reference numerals:
1, mark face (washing can erasable ink); 2, end liner face (tearing not waste paper).
Embodiment
The raw material that the embodiment of the present invention is used is as follows:
Viscosity be the oligomeric degree polyvinyl alcohol resin of the liquid of 800-1200mPas purchased from Guangzhou Qi Sheng Chemical Co., Ltd., the degree of polymerization is 1.7-2.4 ten thousand, alcoholysis degree is 98%;
Aqueous color paste is purchased from loose well pigment chemical industry institute of Japan;
Defoamer is that polysiloxane defoamer is purchased from Foshan Chu Ying Chemical Co., Ltd.;
Tear not waste paper (spy defends by force) purchased from E.I.Du Pont Company as end liner face;
Salicylic acid is purchased from Guangzhou Gui Hua Chemical Co., Ltd..
By specific embodiment, the present invention is further elaborated below.
Embodiment 1
A kind of washing breath shipping mark of can writing to described in the present embodiment, comprise end liner face and mark face, described end liner face, for tearing not waste paper, is to be spun and formed by macromolecule resin (the present embodiment is tygon) spray, and described mark face can be printed on end liner face and be obtained by the mode of silk-screen or flexo by erasable ink by washing.
Described washing can be prepared from by the raw material of following percentage by weight by erasable ink: taking viscosity is the oligomeric degree polyvinyl alcohol resin 80% of liquid of 1000mpa.s; Aqueous black mill base 3%; The blue mill base 0.05% of water-based; Distilled water 11.5%; Ethanol 5%; Salicylic acid 0.05%; Defoamer 0.4%, after above-mentioned raw materials mixes, being evenly also ground to particle diameter with three rod machines by high speed dispersor dispersed with stirring is 15-20 μ m.
Wherein the degree of polymerization of the oligomeric degree polyvinyl alcohol resin of liquid is 1.7-2.4 ten thousand, and alcoholysis degree is 98%.
Can the write to preparation method of breath shipping mark of above-mentioned washing, comprises the steps:
(1) taking in proportion washing can erasable ink raw material, and mixing and obtain washing can erasable ink;
(2) can erasable ink adopt the mode of silk-screen or flexo to be printed on end liner face washing and form mark face, cut and obtain the described washing breath shipping mark of can writing to.
Embodiment 2
Described in the present embodiment, a kind of washing breath shipping mark of can writing to, comprises end liner face and mark face, and described end liner face macromolecule resin spray is spun and formed, and described mark face can be printed on end liner face and be obtained by the mode of silk-screen or flexo by erasable ink by washing.
Described washing can be prepared from by the raw material of following percentage by weight by erasable ink: taking viscosity is the oligomeric degree polyvinyl alcohol resin 80% of liquid of 1000mpa.s; The blue mill base 4% of water-based; Distilled water 10.55%; Ethanol 5%; Salicylic acid 0.05%; Defoamer 0.4%, above-mentioned raw materials stirs with high speed dispersor and is uniformly dispersed, and being ground to particle diameter with three rod machines is 15-20 μ m.
Wherein the degree of polymerization of the oligomeric degree polyvinyl alcohol resin of liquid is 1.7-3.5 ten thousand, and alcoholysis degree is 98%.
Can the write to preparation method of breath shipping mark of above-mentioned washing, comprises the steps:
(1) taking in proportion washing can erasable ink raw material, and mixing and obtain washing can erasable ink;
(2) can erasable ink adopt the mode of silk-screen or flexo to be printed on end liner face washing and form mark face, cut and obtain the described washing breath shipping mark of can writing to.
Of the present invention functional for further illustrating, illustrate below by comparative tests.
Laboratory method and equipment:
1. frictional behaviour test, tests experimental facilities model: TNH06 manufacturer: Dongguan City Dong Ming Instrument Ltd. according to standard A ATCC 116.
2. adhesion performance test, according to standard ISO, 2409-2007 tests, experimental facilities model: A-5123 manufacturer: German BYK company.
3. store test, test experimental facilities model according to standard A ATCC 163: XMTD-8222 manufacturer: the above grand experimental facilities of Nereid company limited.
4. family's washing External Observation examination, tests experimental facilities model: XC7001VIS manufacturer: Whirlpool of the U.S. according to standard A ATCC 135.
Comparative example 1
With embodiment 1, difference is this ink printing on the tatting plain of cotton, carries out printing effect, friction, adhesion, storge quality, family's water-cleaning appearance contrast with embodiment 1 ~ 2, and comparing result is as shown in table 1:
Table 1
* note: AATCC/ISO represents method and the standard of test; 4.5/0 represents the standard of grading, AATCC taking 4.0 grades above as qualified, in ISO taking 0-1 level as qualified.
As can be seen from the above table, use spy to defend while pretending as printing element, utilize washing to brush by erasable ink, ink picture and text after washing disappear completely, defend on strong paper and also exist without ink marks spy; In the time using tatting plain as printing element, printing figure message is not meticulous, and diffusion is serious, although picture and text disappear after wash water, still has ink marks and impression phenomenon on cloth.
Comparative example 2
With embodiment 1, difference is to defend on strong paper and use polyhydroxy polycarboxylic acrylic ester aquosity ink print spy, carries out printing effect, friction, adhesion, storge quality, family's water-cleaning appearance contrast with embodiment 1 ~ 2, and comparing result is as shown in table 2:
Table 2
* note: AATCC/ISO represents method and the standard of test; 4.5/0 represents the standard of grading, AATCC taking 4.0 grades above as qualified, in ISO taking 0-1 level as qualified.
As can be seen from the above table, utilize polyhydroxy polycarboxylic acrylic ester aquosity ink print spy defend effect on strong paper and the present invention's washing can erasable ink brush to defend effect on strong spy suitable, but picture and text are still high-visible after wash water, do not reach the effect that needs to wash the breath of writing to.
Comparative example 3
With embodiment 1, difference is to use water soluble starch and water to be uniformly dispersed and to add in ink formulations according to the oligomeric degree polyvinyl alcohol resin of component replacement liquid of percentage by weight 80% afterwards according to the quality of 60:100, other components are constant, carry out printing effect, friction, adhesion, storge quality, family's water-cleaning appearance contrast with embodiment 1 ~ 2.Find through experiment, while adopting the printing of this kind of potpourri serious, the spy of plug net defend that strong upper inking amount is low, picture and text gross distortion, dry difficult phenomenon.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (3)
1. the washing breath shipping mark of can writing to, is characterized in that, comprises end liner face and mark face, and described end liner face is spun and formed by macromolecule resin spray, and described mark face can be printed on end liner face and be obtained by the mode of silk-screen or flexo by erasable ink by washing; Described washing can be prepared from by the raw material of following percentage by weight by erasable ink: the oligomeric degree polyvinyl alcohol resin 80% of liquid that viscosity is 800-1200mPas; Aqueous color paste 3.05%-4%; Distilled water 10.55%-11.5%; Ethanol 5%; Salicylic acid 0.05%; Defoamer 0.4%, the summation of above-mentioned raw materials is 100%.
2. the washing according to claim 1 breath shipping mark of can writing to, is characterized in that, the degree of polymerization of the oligomeric degree polyvinyl alcohol resin of described liquid is 1.7-3.5 ten thousand, and alcoholysis degree is 98%.
3. the preparation method who washes the breath shipping mark of can writing to described in claim 1-2 any one, is characterized in that, comprises the steps:
(1) taking in proportion washing can the each raw material of erasable ink, and mixing and obtain washing can erasable ink, and described washing can be prepared from by the raw material of following percentage by weight by erasable ink: the oligomeric degree polyvinyl alcohol resin 80% of liquid that viscosity is 800-1200mPas; Aqueous color paste 3.05%-4%; Distilled water 10.55%-11.5%; Ethanol 5%; Salicylic acid 0.05%; Defoamer 0.4%, the summation of above-mentioned raw materials is 100%;
(2) can erasable ink adopt the mode of silk-screen or flexo to be printed on end liner face washing and form mark face, cut and obtain the described washing breath shipping mark of can writing to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210332479.XA CN102831818B (en) | 2012-09-07 | 2012-09-07 | Shipping mark capable of removing information by washing and preparation method of shipping mark |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210332479.XA CN102831818B (en) | 2012-09-07 | 2012-09-07 | Shipping mark capable of removing information by washing and preparation method of shipping mark |
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| Publication Number | Publication Date |
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| CN102831818A CN102831818A (en) | 2012-12-19 |
| CN102831818B true CN102831818B (en) | 2014-07-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210332479.XA Active CN102831818B (en) | 2012-09-07 | 2012-09-07 | Shipping mark capable of removing information by washing and preparation method of shipping mark |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102800245B (en) * | 2012-08-30 | 2014-07-09 | 广东溢达纺织有限公司 | Water-soluble trademark and preparing method thereof |
| CN108877483B (en) * | 2018-07-09 | 2021-04-20 | 庄亚新 | Environment-friendly label for textile products, preparation method and clothes |
| CN115304978B (en) * | 2022-08-17 | 2023-07-25 | 恒昌涂料（惠阳）有限公司 | Paint film water-soluble effect paint and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08211829A (en) * | 1995-02-07 | 1996-08-20 | Toyo Coating Kk | Water-soluble tacky adhesive label |
| US6830782B2 (en) * | 1999-12-28 | 2004-12-14 | Hitoshi Kanazawa | Hydrophilic polymer treatment of an activated polymeric material and use thereof |
| DE602004018679D1 (en) * | 2003-11-14 | 2009-02-05 | 3M Innovative Properties Co | WATER CONTACT INDICATOR |
| CN102428008B (en) * | 2009-05-19 | 2016-04-06 | 宝洁公司 | A kind of method for printing water-soluble film |
| CN102558952A (en) * | 2012-01-06 | 2012-07-11 | 浙江大学 | Irreversible thermally induced decoloring printing ink and preparation method thereof |
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Effective date of registration: 20230310 Address after: No. 38, Mingli Road, Hecheng Street, Gaoming District, Foshan City, Guangdong Province, 528500 (residence application) Patentee after: Guangdong Kangpai Huanchuang Technology Co.,Ltd. Address before: 528500 Guangdong city of Foshan province river export processing zone Patentee before: Guangdong Esquel Textile Co.,Ltd. |