CN102731947A - Antistatic floor wax composition - Google Patents
Antistatic floor wax composition Download PDFInfo
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- CN102731947A CN102731947A CN201210199995XA CN201210199995A CN102731947A CN 102731947 A CN102731947 A CN 102731947A CN 201210199995X A CN201210199995X A CN 201210199995XA CN 201210199995 A CN201210199995 A CN 201210199995A CN 102731947 A CN102731947 A CN 102731947A
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Abstract
The invention discloses an antistatic floor wax composition which comprises the following components: 22 to 55 wt% of acrylic polymer emulsion, with solid content being in a range of 8 to 30 wt%; 10 to 50 wt% of PEDOT dispersion liquid, with solid content being in a range of 0.5 to 5 wt%; 2 to 15 wt% of polypropylene wax emulsion, with solid content being in a range of 1 to 4 wt%; 2 to 15 wt% of a film forming agent; 0.001 to 4 wt% of polysiloxane emulsion, with solid content being in a range of 1 to 8 wt%; 0.001 to 3 wt% of a non-fluorinated lubricant; 0. 1 to 0.2 wt% of an antiseptic; and the balance being water. PEDOT is a conductive polymer, and the technology of using a conductive polymer in floor wax liquid enables a lasting and highly efficient electrostatic dissipation function to be obtained, accumulation of static to be eliminated, surface static to be released, function degeneration, failure or scraping of electronic components used under electrostatic discharge environment to be reduced and a beautiful, clean, transparent and shiny appearance effect to be maintained.
Description
Technical field
The present invention relates to floor wax water field, be specifically related to a kind of floor wax water composition with electrostatic-proof function.
Background technology
Along with the development of international trade and the research and development and the production of hard-core technology product, increasing precise electronic industry becomes our national mainstream and mainstay industry.Because the influence of many factors such as geographical environment, transportation environment, climatope, the production base that great majority are produced precise electronic apparatus and semiconductor product concentrates on Pearl River Delta and Yangtze River Delta Area more than 80%.Mostly the factory of this type precise electronic is dustless cleaning shop; Must build according to international standard; Whole cleaning shop is from ground to the wall; The equipment that is equipped with, findings such as the tool using that comprises the inside, workshop and personnel's clothes, feel, touch, used slight part from big to small all requires the purification rank.And because product precision is very high, environment must anti-electrostatic, just will eliminate static, and reason is exactly that static can damage product.
Ground is the highest part of requirement in the dust-free workshop, and the material of being selected for use is also very special.What application was the widest at present is PVC plastic cement conductive flooring and epoxy resin conductive flooring.Yet any ground does not have loss, and the personnel of the every day reasons such as long-time friction with Trolley of walking about in the dust-free workshop all can have influence on the electrostatic-proof function and the duration of service on ground.
For the electrostatic-proof function and the work-ing life that prolongs ground on permanent stable this type of ground of maintenance, a kind of special conductive flooring skin care products-antistatic floor wax water just arises at the historic moment.Antistatic floor wax is applicable to zones such as microelectronics factory, telecommunication apparatus district, electronically controlled chamber, responsive medical diagnosis equipment chamber.The electrostatic dissipation function of persistent high efficiency can be provided, can effectively eliminate electrostatic accumulation, help release surface static, reduce electronic devices and components under the static discharge environment functional deterioration, lost efficacy or scrapped, and keep cleaning attractive in appearance, transparent glossy appearance.
Summary of the invention
Goal of the invention of the present invention provides a kind of employing conductive polymers technology, and the antistatic floor wax water composition of the electrostatic dissipation function of persistent high efficiency is provided.
In order to realize the foregoing invention purpose, the technical solution adopted for the present invention to solve the technical problems is: a kind of antistatic floor Wax composition is provided, comprises:
1) acrylic polymer emulsions of 22-55wt%, its range of solid content are 8-30wt%;
2) the PEDOT dispersion liquid of 10-50wt%, its range of solid content is 0.5-5wt%;
3) the polypropylene-base wax emulsion of 2-15wt%, its range of solid content is 1-4wt%;
4) the film binder of 2-15wt%;
5) polysiloxane emulsion of 0.001-4wt%, its range of solid content are 1-8wt%;
6) the fluorine-free lubricant of 0.001-3wt%;
7) 0.1-0.2wt% sanitas;
8) all the other are water;
The total solid content of said antistatic floor Wax composition is 15-40wt%, and wherein all content and solid content are 100wt% in the gross weight of compsn all,
Said PEDOT dispersion liquid is the PEDOT:PSS aqueous liquid dispersion.
Wherein, the content of said acrylic polymer emulsions in compsn is 30-40wt%, and the content of said polypropylene-base wax emulsion in compsn is 5-10wt%.
The present invention solves another technical scheme that its technical problem adopts: a kind of antistatic floor Wax composition is provided, comprises:
1) the styrene acrylic copolymerized polymer emulsion of 22-55wt%, its range of solid content is 8-30wt%;
2) the PEDOT dispersion liquid of 10-50wt%, its range of solid content is 0.5-5wt%;
3) the polyethylene kind wax emulsion of 2-15wt%, its range of solid content is 1-4wt%;
4) the film binder of 2-15wt%;
5) polysiloxane emulsion of 0.001-4wt%, its range of solid content are 1-8wt%;
6) the fluorine-free lubricant of 0.001-3wt%;
7) sanitas of 0.1-0.2wt%;
8) all the other are water;
The total solid content of said antistatic floor Wax composition is 15-40wt%, and wherein all content and solid content are 100wt% in the gross weight of compsn all,
Said PEDOT dispersion liquid is the PEDOT:PSS aqueous liquid dispersion.
Wherein, the content of said styrene acrylic copolymerized polymer emulsion in compsn is 30-40wt%, and the content of said polyethylene kind wax emulsion in compsn is 5-10wt%.
Wherein, the content of said film binder in compsn is 5-10wt%, and the film binder comprises and helps film, softening agent and skimmer.
In order to make cere have good removeability, the present invention further comprises the alkali soluble resins emulsion of 0-12wt%, and its range of solid content is 0-3wt%.
Wherein, the content of said alkali soluble resins emulsion in compsn is 3-8wt%.
The invention has the beneficial effects as follows; PEDOT is a conductive polymers, in floor wax water, adopts the conductive polymers technology, and the electrostatic dissipation function of persistent high efficiency is provided; Can effectively eliminate electrostatic accumulation; Help release surface static, reduce electronic devices and components under the static discharge environment functional deterioration, lost efficacy or scrapped, and keep cleaning attractive in appearance, transparent glossy appearance.Have been found that; Antistatic floor Wax composition of the present invention has not only kept the fundamental property of traditional cooperation floor wax; And according to excellent anti-pollution characteristic and antistatic performance are arranged; Antistatic floor wax water is applicable to has zones such as microelectronics factory that control requires, telecommunication apparatus district, electronically controlled chamber, responsive medical diagnosis equipment chamber to static, and the composition proportion that the present invention is unique makes it under any humidity environment, all to have good antistatic performance.
Embodiment
By specifying technology contents of the present invention, structural attitude, realized purpose and effect, give explanation below in conjunction with embodiment is detailed.
To make a more detailed description the various necessary component that adopts in the floor polish composition of the present invention and the kind and the content of optional components below.
PEDOT is the polymkeric substance of EDOT (3,4-enedioxy thiophene monomer), and EDOT is the monomer material of PEDOT, can prepare the PEDOT film through the method for electrochemical polymerization.EDOT electronic industry in modern times is widely used for the compositing conducting polymkeric substance.PEDOT is the verivate of conductive polymers Polythiophene, and PEDOT has characteristics such as molecular structure is simple, energy gap is little, specific conductivity height.The PEDOT dispersion liquid that the present invention adopts is the PEDOT:PSS aqueous liquid dispersion, and wherein the ratio of PEDOT and PSS is 1:2.5.
The film binder comprises at least and helps film, softening agent and optional but preferably contain skimmer.The used film that helps includes but not limited to: dipropylene glycol methyl ether, diethylene glycol dimethyl ether, diethylene glycol ether, Diethylene Glycol butyl ether etc., its consumption is preferably 5-8wt%.Used softening agent includes but not limited to: face butyl phthalate, three butoxy butyl phosphates, benzoates and tetramethyleneimine etc., its consumption is preferably 0.5-1.5wt%.
Wetting agent is the fluorine-free wetting agent, preferably includes a kind of or mixture in hydrocarbon type of wetting agent of silicon wetting agent or alkyne diol base.
Polysiloxane emulsion is hydroxy-end capped dimethione emulsion.
Embodiment 1
Embodiment 2
Embodiment 3
Embodiment 4
Embodiment 5
Embodiment 6
Comparative example 1 (conventional formulation)
Method of use of the present invention is:
Remove original wax layer, clean and dry, drag with clean wax this product evenly is applied on the floor, wait 30-60 minute, treat that the wax layer thoroughly parches, smear second layer wax again, can be coated with 3-5 layer wax as required.
The abrasive blasting polishing: available 5 parts of water are converted 1 part of antistatic floor wax, high speed polishing.
Regularly mend wax: available 1 part of water is converted 1 part of antistatic floor wax, drags to be coated with ground.
Method according to the front is described is tested the various performances of the floor polish composition of Comparative Examples, and the result is as shown in the table:
Can be known by last table: it is low that the present invention has surface resistivity, the advantage that the electrostatic attenuation time is short.Adopt technology provided by the invention; The electrostatic dissipation function of persistent high efficiency can be provided, can effectively eliminate electrostatic accumulation, help release surface static; Reduce electronic devices and components under the static discharge environment functional deterioration, lost efficacy or scrapped, and keep cleaning attractive in appearance, transparent glossy appearance.
The above is merely embodiments of the invention; Be not so limit claim of the present invention; Every equivalent structure or equivalent flow process conversion that utilizes description of the present invention to do; Or directly or indirectly be used in other relevant technical fields, all in like manner be included in the scope of patent protection of the present invention.
Claims (7)
1. an antistatic floor Wax composition is characterized in that, comprises:
1) acrylic polymer emulsions of 22-55wt%, its range of solid content are 8-30wt%;
2) the PEDOT dispersion liquid of 10-50wt%, its range of solid content is 0.5-5wt%;
3) the polypropylene-base wax emulsion of 2-15wt%, its range of solid content is 1-4wt%;
4) the film binder of 2-15wt%;
5) polysiloxane emulsion of 0.001-4wt%, its range of solid content are 1-8wt%;
6) the fluorine-free lubricant of 0.001-3wt%;
7) 0.1-0.2wt% sanitas;
8) all the other are water;
The total solid content of said antistatic floor Wax composition is 15-40wt%, and wherein all content and solid content are 100wt% in the gross weight of compsn all,
Said PEDOT dispersion liquid is the PEDOT:PSS aqueous liquid dispersion.
2. antistatic floor Wax composition according to claim 1 is characterized in that, the content of said acrylic polymer emulsions in compsn is 30-40wt%, and the content of said polypropylene-base wax emulsion in compsn is 5-10wt%.
3. an antistatic floor Wax composition is characterized in that, comprises:
1) the styrene acrylic copolymerized polymer emulsion of 22-55wt%, its range of solid content is 8-30wt%;
2) the PEDOT dispersion liquid of 10-50wt%, its range of solid content is 0.5-5wt%;
3) the polyethylene kind wax emulsion of 2-15wt%, its range of solid content is 1-4wt%;
4) the film binder of 2-15wt%;
5) polysiloxane emulsion of 0.001-4wt%, its range of solid content are 1-8wt%;
6) the fluorine-free lubricant of 0.001-3wt%;
7) sanitas of 0.1-0.2wt%;
8) all the other are water;
The total solid content of said antistatic floor Wax composition is 15-40wt%, and wherein all content and solid content are 100wt% in the gross weight of compsn all,
Said PEDOT dispersion liquid is the PEDOT:PSS aqueous liquid dispersion.
4. antistatic floor Wax composition according to claim 3 is characterized in that, the content of said styrene acrylic copolymerized polymer emulsion in compsn is 30-40wt%, and the content of said polyethylene kind wax emulsion in compsn is 5-10wt%.
5. according to claim 1 or 3 described antistatic floor Wax compositions, it is characterized in that the content of said film binder in compsn is 5-10wt%, the film binder comprises and helps film, softening agent and skimmer.
6. according to claim 1 or 3 described antistatic floor Wax compositions, it is characterized in that further comprise the alkali soluble resins emulsion of 0-12wt%, its range of solid content is 0-3wt%.
7. antistatic floor Wax composition according to claim 6 is characterized in that, the content of said alkali soluble resins emulsion in compsn is 3-8wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210199995XA CN102731947A (en) | 2012-06-18 | 2012-06-18 | Antistatic floor wax composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210199995XA CN102731947A (en) | 2012-06-18 | 2012-06-18 | Antistatic floor wax composition |
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| CN102731947A true CN102731947A (en) | 2012-10-17 |
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| CN201210199995XA Pending CN102731947A (en) | 2012-06-18 | 2012-06-18 | Antistatic floor wax composition |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293009A (en) * | 2013-07-18 | 2015-01-21 | 株式会社大河曼泰克 | Electroconductive coating composition, manufacturing method of the composition and electroconductive coatings |
| CN105567036A (en) * | 2016-03-21 | 2016-05-11 | 深圳市纳路特科技有限公司 | Washable antistatic floor wax |
| CN107286826A (en) * | 2017-05-11 | 2017-10-24 | 3M创新有限公司 | Antistatic floor wax and preparation method thereof, conductive flooring coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101293999A (en) * | 2007-04-29 | 2008-10-29 | 3M创新有限公司 | Watersoluble floor polish composition |
| CN101314692A (en) * | 2007-05-30 | 2008-12-03 | 3M创新有限公司 | Aqueous coating compositions |
| CN101873994A (en) * | 2007-11-30 | 2010-10-27 | 东丽株式会社 | Carbon nanotube assembly and process for producing the same |
| CN102051011A (en) * | 2009-11-06 | 2011-05-11 | 3M创新有限公司 | Water-based floor wax composition |
-
2012
- 2012-06-18 CN CN201210199995XA patent/CN102731947A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101293999A (en) * | 2007-04-29 | 2008-10-29 | 3M创新有限公司 | Watersoluble floor polish composition |
| CN101314692A (en) * | 2007-05-30 | 2008-12-03 | 3M创新有限公司 | Aqueous coating compositions |
| CN101873994A (en) * | 2007-11-30 | 2010-10-27 | 东丽株式会社 | Carbon nanotube assembly and process for producing the same |
| CN102051011A (en) * | 2009-11-06 | 2011-05-11 | 3M创新有限公司 | Water-based floor wax composition |
Non-Patent Citations (1)
| Title |
|---|
| 孙东成 等: "PEDOT/PSS的合成及在抗静电涂料中的应用", 《高分子材料科学与工程》, vol. 25, no. 7, 15 July 2009 (2009-07-15) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293009A (en) * | 2013-07-18 | 2015-01-21 | 株式会社大河曼泰克 | Electroconductive coating composition, manufacturing method of the composition and electroconductive coatings |
| CN104293009B (en) * | 2013-07-18 | 2017-04-12 | 株式会社大河曼泰克 | Manufacturing method of conductive coating solution composition capable of shielding electromagnetic interference |
| CN105567036A (en) * | 2016-03-21 | 2016-05-11 | 深圳市纳路特科技有限公司 | Washable antistatic floor wax |
| CN107286826A (en) * | 2017-05-11 | 2017-10-24 | 3M创新有限公司 | Antistatic floor wax and preparation method thereof, conductive flooring coating |
| CN107286826B (en) * | 2017-05-11 | 2020-04-14 | 3M中国有限公司 | Anti-static floor wax, preparation method thereof and anti-static floor coating |
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Address after: 518000 Guangdong province Shenzhen City Pingshan sand Tang with rich industrial area Applicant after: Shenzhen Xinyubang Science and Technology Co., Ltd. Address before: Longgang District of Shenzhen city in Guangdong province 518000 Ping Sha Pok with rich industrial area Applicant before: Shenzhen Xinyubang Science and Technology Co., Ltd. |
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Application publication date: 20121017 |