CN102720320B - A kind of heat insulating decorative board and preparation method thereof - Google Patents
A kind of heat insulating decorative board and preparation method thereof Download PDFInfo
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- CN102720320B CN102720320B CN201210241763.6A CN201210241763A CN102720320B CN 102720320 B CN102720320 B CN 102720320B CN 201210241763 A CN201210241763 A CN 201210241763A CN 102720320 B CN102720320 B CN 102720320B
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Abstract
The present invention relates to a kind of heat insulating decorative board, described heat insulating decorative board comprises foamed material layer and is arranged on the face material layer that described foamed material layer can make described foamed material layer penetrate into, on described face material layer, coating arranges solid sand material layer, is solidified with the decoration sand for the formation of decorative pattern in described solid sand material layer.The present invention also comprises a kind of preparation method of above-mentioned warming plate, and the expanded material in described foamed material layer enters when foaming in described face material layer to be also bonded together with described face material layer and forms described heat insulating decorative board.The heat-insulation layer of the heat insulating decorative board using above-mentioned preparation method to prepare is more firm with the combination of solid sand material layer, not easily layering.
Description
Technical field
The present invention is specifically related to a kind of heat insulating decorative board and preparation method thereof, belongs to building material field.
Background technology
Along with the raising of people's living standard, for daily necessities and also more and more higher to the requirement of the relevant product of life, not only require functional, also requirement simultaneously has certain ornamental; Such as heat insulating decorative board, except needs possess certain heat-insulating property, also needs to possess certain decorate properties, thus directly can be used as external wall, plays the effect of insulation and decoration simultaneously.
Because the topmost effect of heat insulating decorative board one is insulation effect, another is decoration function, all has the structure realizing above two kinds of effects in therefore general heat insulating decorative board.In prior art, Chinese patent literature CN201981726U discloses a kind of external insulation board of thin-plastered, the agent structure of described warming plate is foundation wall body, foundation wall body is provided with tack coat, heat-insulation layer, overcoat and finish coat successively, and foundation wall body is connected by connector with between tack coat, heat-insulation layer.Wherein, tack coat is binding agent, adopts adhesive mortar and/or cement-bonded mortar; Heat-insulation layer adopts phenolic resin foamed board to make; Overcoat is that thin-coat plaster strengthens overcoat, adopts finishing mucilage compound alkali-proof glass fiber mesh to make; Finish coat adopts water-based exterior wall paint, cement decorative plate, PVC wood plastic plate, ceramic tile; The warming plate with said structure and material has possessed insulation and decoration function simultaneously.In addition, the preparation method of this warming plate is also disclosed in this patent document, it coats adhesive mortar on foundation wall body, stick phenolic board, then on phenolic board, finishing mucilage is spread, and imbed alkali-proof glass fiber mesh, and then according to the concrete purposes of warming plate, determine the material of finish coat and make and form finish coat.
In warming plate in the above-described techniques, heat-insulation layer plays insulation effect, finish coat plays decoration function, agent structure due to heat-insulation layer is phenolic resin foamed board, the agent structure of finish coat is coating, cement or PVC, in order to realize the combination of heat-insulation layer and finish coat, in the above-described techniques by arranging described overcoat to realize; Wherein, overcoat adopts finishing mucilage compound alkali-proof glass fiber mesh to make, it utilizes rubber cement to achieve bonding to heat-insulation layer and finish coat, but when utilizing rubber cement to bond heat-insulation layer phenolic resin foamed board, it is only the interfacial adhesion utilized between rubber cement and cystosepiment, so adhesive fastness is inadequate, easily there is the phenomenon of heat-insulation layer and finish coat layering.
Summary of the invention
In order to the heat-insulation layer and finish coat adhesive fastness that solve heat insulating decorative board of the prior art are inadequate, easily there is the problem of layering, the invention provides the heat insulating decorative board containing foamed material layer, described foamed material layer has part to enter face material layer, there is insulation and cementation simultaneously, and then a kind of preparation method of above-mentioned heat insulating decorative board is also provided.
Technical scheme provided by the present invention is as follows:
A kind of heat insulating decorative board, comprise foamed material layer and be arranged on the face material layer that described foamed material layer can make described foamed material layer penetrate into, on described face material layer, coating arranges solid sand material layer, is solidified with the decoration sand for the formation of decorative pattern in described solid sand material layer;
Described expanded material is Foamex or foam cement, and described Foamex is one or more in phenolic resins, polyurethane, polyvinyl chloride;
Described solid sand material layer is PVC, and is added with the curing agent that mass percent is 1% ~ 30% in described solid sand material layer, or
Described solid sand material layer is fireproof coating or cement, and is added with the curing agent that mass percent is 0 ~ 30% in described solid sand material layer.
Above-mentioned heat insulating decorative board, described face material layer is nonwoven layer or glass layer of cloth.
Above-mentioned heat insulating decorative board, is provided with the fortifying fibre layer of disordered state distribution in described foamed material layer.
Above-mentioned heat insulating decorative board, the mass percent that the fortifying fibre layer that described disordered state distributes accounts for described foamed material layer is 5% ~ 40%.
Above-mentioned heat insulating decorative board, described fortifying fibre layer is glass layer.
Above-mentioned heat insulating decorative board, described foamed material layer also comprise in blowing agent, surfactant, modifier, fire retardant one or more.
Above-mentioned heat insulating decorative board, described foamed material layer also comprise in blowing agent, surfactant, modifier, fire retardant one or more, in described foamed material layer, the mass percent of expanded material, blowing agent, surfactant, modifier is respectively 50% ~ 70%, 1% ~ 3%, 2% ~ 5%, 2% ~ 7%.
Above-mentioned heat insulating decorative board, is added with ultra-violet absorber in described solid sand material layer, and the mass percent that described ultra-violet absorber accounts for described solid sand material layer is 0.5% ~ 3%.
Above-mentioned heat insulating decorative board, the mass percent of the curing agent in described solid sand material layer is 10% ~ 25%.
The present invention still further provides a kind of preparation method of above-mentioned heat insulating decorative board, and it comprises the following steps:
(1) solid for liquid state sand material or one or both the liquid state be added with in curing agent, ultra-violet absorber are consolidated sand Material coating on the surface of face material, and on described solid sand material, insert decoration sand formation decorative pattern, be cured at 60 ~ 210 DEG C, obtain the face material layer that a lower surface is hair side, upper surface is solidified with solid sand material;
(2) expanded material or one or more the expanded material be added with in blowing agent, surfactant, modifier, fire retardant are coated on described hair side, foam at 60 ~ 80 DEG C, obtain described foamed material layer;
Expanded material in described foamed material layer enters when foaming in described face material layer to be also bonded together with described face material layer and forms described heat insulating decorative board.
The preparation method of above-mentioned heat insulating decorative board, step (2) comprises:
1) described face material layer hair side is layered on the surface of the fortifying fibre layer of disordered state distribution downwards;
2) spray into expanded material or be added with one or more the expanded material in blowing agent, surfactant, modifier, fire retardant in the fortifying fibre layer distributed to described disordered state, to fortifying fibre layer described in complete submergence, be depressed into described fortifying fibre layer without after air, foam at 60 ~ 80 DEG C, expanded material foaming forms foaming body, and enter the hair side of face material layer, make foaming body and face material bonding, obtain described heat insulating decorative board.
The present invention is as follows relative to the beneficial effect of prior art:
(1) heat insulating decorative board provided by the invention, it comprises foamed material layer and is arranged on the face material layer on described foamed material layer, on described face material layer, coating arranges solid sand material layer, is solidified with the decoration sand for the formation of decorative pattern in described solid sand material layer; And to arrange foamed material layer be further Foamex or foam cement, and Foamex or foam cement have certain expansion, permeance property in its foaming process, thus Foamex and foam cement can be penetrated in face material layer fully, achieve the strong bonded of foamed material layer and face material layer; Meanwhile, Gu the material of sand material layer also can combine with face material layer fully when solidifying, so just achieving foamed material layer, combining closely between face material layer and solid sand material layer, avoiding lamination.
In addition, on described face material layer, coating arranges solid sand material layer, the decoration sand for the formation of decorative pattern is solidified with in described solid sand material layer, thus utilize solid sand material to form pattern with the strong cohesive force of decoration sand, decorative pattern can be made to be combined with described heat insulating decorative board comparatively firm, difficult drop-off, avoids having influence on decorative effect.
(2) heat insulating decorative board provided by the invention, is provided with the fortifying fibre layer of disordered state distribution in described foamed material layer, the mass percent that the fortifying fibre layer that described disordered state distributes accounts for described foamed material layer is 5% ~ 40%.The present invention makes the bulk strength of this heat insulating decorative board be strengthened by adding fortifying fibre in foamed material layer.
(3) preparation method of above-mentioned heat insulating decorative board provided by the invention, comprise and solid for liquid state sand material or one or both the liquid state be added with in curing agent, ultra-violet absorber are consolidated sand Material coating on the surface of face material, and on described solid sand material, insert decoration sand formation decorative pattern, be cured at 60 ~ 210 DEG C, obtain the face material layer that a lower surface is hair side, upper surface is solidified with solid sand material.In the process preparing foamed material layer, the production method that the surface that the present invention adopts the expanded material in foamed material layer to enter described face material layer when foaming also is bonded together with described face material layer, be layered on the surface of the fortifying fibre layer of disordered state distribution downwards by first just described face material layer hair side, in the fortifying fibre layer that described disordered state distributes, spray into expanded material or be added with blowing agent, surfactant, modifier, one or more expanded material in fire retardant, to fortifying fibre layer described in complete submergence, be depressed into described fortifying fibre layer without after air, foam at 60 ~ 80 DEG C, expanded material foaming forms foaming body, and enter the hair side of face material layer, make foaming body and face material bonding, obtain described heat insulating decorative board.The present invention adopts the one side solid sand material being coated on face material, thus form the method that foaming body enters the hair side of face material, overcome solid sand material and the poor shortcoming of expanded material adhesion, the reinforcement decorative layer that foaming body and face material, expanded material are formed can combine, avoid the phenomenon of layering more firmly.
(4) preparation method of above-mentioned heat insulating decorative board provided by the invention, adding in described solid sand material has that to account for described solid sand material layer mass percent be the curing agent of 0 ~ 30%, the present invention by adding curing agent in described solid sand material, described solid sand material is more easily solidified, and the mass percent of preferred consolidation agent of the present invention is 10% ~ 25%.
(5) preparation method of above-mentioned heat insulating decorative board provided by the invention, add in the solid sand material of described liquid state and have ultra-violet absorber, the mass percent that described ultra-violet absorber accounts for described solid sand material layer is 0.5% ~ 3%.The present invention, by adding ultra-violet absorber in described liquid PVC or fireproof coating or cement, adds the service life of described heat insulating decorative board.
(6) preparation method of above-mentioned heat insulating decorative board provided by the invention, is also added with blowing agent, surfactant, modifier, fire retardant in described expanded material.The present invention, by adding blowing agent, improves the uniformity of the foamed material layer of described heat insulating decorative board, makes the surface more smooth of described heat insulating decorative board, density more homogeneous; By adding surfactant, improve bubbling efficiency, shortening foamed time; By adding fire retardant in described expanded material, improve the fire resistance of described heat insulating decorative board, the addition of fire retardant is determined according to the fire-protection rating needed.
Accompanying drawing explanation
The structural representation that Fig. 1 is heat insulating decorative board described in embodiments of the invention;
Reference numeral in figure is expressed as follows:
1-decoration sand, the solid sand material layer of 2-, 3-face material layer, 4-foamed material layer, 5-enter the expanded material of face material layer.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, technical scheme of the present invention and beneficial effect are described further.
Embodiment 1
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described expanded material is phenolic resins, and described face material is glass-fiber-fabric, and except containing except PVC in described solid sand material layer 2, be also the curing agent of 1% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is hexamethylenetetramine.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the hexamethylenetetramine of 1% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: phenolic resins is coated on described hair side, foam 4min at 60 ~ 80 DEG C, obtains described novolac resin layer; Phenolic resins in described novolac resin layer enters when foaming in described glass layer of cloth to be also bonded together with described glass layer of cloth and forms described heat insulating decorative board.
Embodiment 2
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be 1% blowing agent and the mass percent that accounts for described foamed material layer 4 be the glass fibre of 4%, described blowing agent is liquid CO
2; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 30% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 30% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and liquid CO in the glass fibre of described unordered shape
2mixture, described phenolic resins, methylolurea and CO
2liquefied mixture, glass fibre mass ratio be 95:1:4, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 3
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be 2% surfactant and the mass percent that accounts for described foamed material layer 4 be the glass fibre of 4%, described surfactant is fatty alcohol polyether siloxane; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 10% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 10% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and fatty alcohol polyether siloxane in the glass fibre of described unordered shape, the mass ratio of described glass fibre and phenolic resins, fatty alcohol polyether siloxane is 4:94:2, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 4
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be 2% modifier and the mass percent that accounts for described foamed material layer 4 be the glass fibre of 4%, described modifier is toluene di-isocyanate(TDI); Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 10% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 10% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and toluene di-isocyanate(TDI) in the glass fibre of described unordered shape, the mass ratio of described glass fibre and phenolic resins, toluene di-isocyanate(TDI) is 4:94:2, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 5
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be 2% fire retardant and the mass percent that accounts for described foamed material layer 4 be the glass fibre of 4%, described fire retardant is boric acid; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 10% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 10% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and boric acid in the glass fibre of described unordered shape, the mass ratio of described glass fibre and phenolic resins, boric acid is 4:94:2, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 6
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 3%, the modifier of 7% and the mass percent that accounts for described foamed material layer 4 be the glass fibre of 20%, described blowing agent is carrene, and described modifier is toluene di-isocyanate(TDI); Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 10% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 10% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, toluene di-isocyanate(TDI) in the glass fibre of described unordered shape, the mass ratio of described glass fibre and phenolic resins, carrene, toluene di-isocyanate(TDI) is 20:70:3:7, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 7
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, the blowing agent, the surfactant of 5%, the fire retardant of 2% and the mass percent that accounts for described foamed material layer 4 that are also 3% containing the mass percent accounting for described foamed material layer 4 are the glass fibre of 20%, described blowing agent is carrene, described surfactant is polyether siloxane, and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, be also the curing agent of 10% containing accounting for the described mass percent consolidating sand material layer 2, described curing agent is p-methyl benzenesulfonic acid.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: be that the liquid PVC of the p-methyl benzenesulfonic acid of 10% is coated on the upper surface of glass-fiber-fabric by being added with mass fraction, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polyether siloxane, antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and phenolic resins, carrene, polyether siloxane, antimony oxide is 20:70:3:5:2, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 8
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 6%, surfactant, the modifier of 1%, the fire retardant of 7% and the mass percent that accounts for described foamed material layer 4 of 1% be the glass fibre of 45%, described blowing agent is carrene, described surfactant is alkyl phenol polyether siloxane, described modifier is toluene di-isocyanate(TDI), and described fire retardant is urea; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, also containing the mass percent accounting for described solid sand material layer 2 be 10% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 0.5%, described curing agent is p-methyl benzenesulfonic acid, and ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid PVC being added with p-methyl benzenesulfonic acid and BTA is coated on the upper surface of glass-fiber-fabric, the mass percent that described p-methyl benzenesulfonic acid and described BTA account for described solid sand material layer 2 is respectively 10% and 0.5%, and insert on described PVC decoration sand 1 form decorative pattern, at 60 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene in the glass fibre of described unordered shape, alkyl phenol polyether siloxane, toluene di-isocyanate(TDI), urea, described glass fibre and phenolic resins, carrene, alkyl phenol polyether siloxane, toluene di-isocyanate(TDI), the mass ratio of urea is 45:40:6:1: 1:7, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 80 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 9
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except polyurethane, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 3%, surfactant, the modifier of 1%, the fire retardant of 1% and the mass percent that accounts for described foamed material layer 4 of 5% be the glass fibre of 40%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, also containing the mass percent accounting for described solid sand material layer 2 be 10% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 0.5%, described curing agent is hexamethylenetetramine, and ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid PVC being added with hexamethylenetetramine and BTA is coated on the upper surface of glass-fiber-fabric, the mass percent that described hexamethylenetetramine and described BTA account for described solid sand material layer 2 is respectively 10% and 0.5%, and insert on described PVC decoration sand 1 form decorative pattern, at 80 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into polyurethane and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 40:50:3:5:1:1, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 60 DEG C, polyurethane foam forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the polyurethane of part enters glass layer of cloth, thus makes polyurethane be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 10
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except polyvinyl chloride, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 1%, surfactant, the modifier of 7%, the fire retardant of 15% and the mass percent that accounts for described foamed material layer 4 of 2% be the glass fibre of 5%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Except containing except PVC in described solid sand material layer 2, also containing the mass percent accounting for described solid sand material layer 2 be 25% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 3%, described curing agent is p-methyl benzenesulfonic acid, and ultra-violet absorber is hindered amine as light stabilizer (HALS).
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid PVC being added with p-methyl benzenesulfonic acid and hindered amine as light stabilizer (HALS) is coated on the upper surface of glass-fiber-fabric, the mass percent that described p-methyl benzenesulfonic acid and hindered amine as light stabilizer (HALS) account for described solid sand material layer 2 is respectively 25% and 3%, and insert on described PVC decoration sand 1 form decorative pattern, at 70 DEG C, solidify 20min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into polyvinyl chloride and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 5:70:1:2:7:15, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 20min at 70 DEG C, foam polyvinyl chloride forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the polyvinyl chloride of part enters glass layer of cloth, thus makes polyvinyl chloride be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 11
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 3%, surfactant, the modifier of 1%, the fire retardant of 1% and the mass percent that accounts for described foamed material layer 4 of 5% be the glass fibre of 30%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material is fireproof coating.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: liquid fireproof coating is coated on the upper surface of glass-fiber-fabric, and insert on described fireproof coating decoration sand 1 form decorative pattern, at 80 DEG C, solidify 10min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with fireproof coating;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 30:60:3:5:1:1, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 10min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 12
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 3%, surfactant, the modifier of 1%, the fire retardant of 1% and the mass percent that accounts for described foamed material layer 4 of 5% be the glass fibre of 30%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material layer 2 is except containing except fireproof coating, and be also the ultra-violet absorber of 2% containing accounting for the described mass percent consolidating sand material layer 2, described ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid fireproof coating of the BTA being added with 2% is coated on the upper surface of glass-fiber-fabric, and insert on described fireproof coating decoration sand 1 form decorative pattern, at 80 DEG C, solidify 10min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with fireproof coating;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 30:60:3:5:1:1, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 10min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 13
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 3%, surfactant, the modifier of 1%, the fire retardant of 1% and the mass percent that accounts for described foamed material layer 4 of 5% be the glass fibre of 30%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material layer 2 is except containing except fireproof coating, also containing the mass percent accounting for described solid sand material layer 2 be 10% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 2%, described curing agent is hexamethylenetetramine, and ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid fireproof coating being added with hexamethylenetetramine and BTA is coated on the upper surface of glass-fiber-fabric, the mass percent that described hexamethylenetetramine and described BTA account for described solid sand material layer 2 is respectively 10% and 2%, and insert on described fireproof coating decoration sand 1 form decorative pattern, at 80 DEG C, solidify 10min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with fireproof coating;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 30:60:3:5:1:1, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 10min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 14
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 1%, surfactant, the modifier of 2%, the fire retardant of 5% and the mass percent that accounts for described foamed material layer 4 of 2% be the glass fibre of 10%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material is cement.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: aqueous water mud is coated on the upper surface of glass-fiber-fabric, and insert on described cement decoration sand 1 form decorative pattern, at 210 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with cement;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 10:80:1:2:2:5, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 15
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 1%, surfactant, the modifier of 2%, the fire retardant of 5% and the mass percent that accounts for described foamed material layer 4 of 2% be the glass fibre of 10%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material layer 2 is except containing except cement, and be also the ultra-violet absorber of 1% containing accounting for the described mass percent consolidating sand material layer 2, described ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the aqueous water mud of the BTA being added with 1% is coated on the upper surface of glass-fiber-fabric, and insert on described cement decoration sand 1 form decorative pattern, at 210 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with cement;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 10:80:1:2:2:5, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 16
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 is except containing except phenolic resins, also containing the mass percent accounting for described foamed material layer 4 be the blowing agent of 1%, surfactant, the modifier of 2%, the fire retardant of 5% and the mass percent that accounts for described foamed material layer 4 of 2% be the glass fibre of 30%, described blowing agent is carrene, described surfactant is polysiloxanes, described modifier is toluene di-isocyanate(TDI), and described fire retardant is antimony oxide; Described face material is glass-fiber-fabric; Described solid sand material layer 2 is except containing except cement, also containing the mass percent accounting for described solid sand material layer 2 be 30% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 1%, described curing agent is hexamethylenetetramine, and ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the aqueous water mud being added with hexamethylenetetramine and BTA is coated on the upper surface of glass-fiber-fabric, the mass percent that described hexamethylenetetramine and described BTA account for described solid sand material layer 2 is respectively 30% and 1%, and insert on described cement decoration sand 1 form decorative pattern, at 210 DEG C, solidify 4min, obtain the glass layer of cloth that a lower surface is hair side, upper surface is solidified with cement;
Second step: described glass layer of cloth hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into phenolic resins and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide in the glass fibre of described unordered shape, the mass ratio of described glass fibre and carrene, polysiloxanes, toluene di-isocyanate(TDI), antimony oxide is 10:80:1:2:2:5, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 4min at 60 DEG C, Foaming of phenolic resin forms foaming body, and enter the hair side of glass-fiber-fabric layer, make foaming body and glass-fiber-fabric bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the phenolic resins of part enters glass layer of cloth, thus makes phenolic resins be combined tightr with glass-fiber-fabric, thus makes described heat insulating decorative board more firm.
Embodiment 17
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 except containing except foam cement, is also the glass fibre of 96% containing the mass percent accounting for described foamed material layer 4; Described face material is non-woven fabrics; Described solid sand material layer 2 is except containing except refractory material, and be also the ultra-violet absorber of 1% containing accounting for the described mass percent consolidating sand material layer 2, described ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid fireproof coating of the BTA being added with 1% is coated on the upper surface of non-woven fabrics, and insert on described fireproof coating decoration sand 1 form decorative pattern, at 150 DEG C, solidify 20min, obtain the nonwoven layer that a lower surface is hair side, upper surface is solidified with fireproof coating;
Second step: described nonwoven layer hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into foam cement in the glass fibre of described unordered shape, the mass ratio of described glass fibre and foam cement is 96:4, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 20min at 60 DEG C, foam cement foaming forms foaming body, and enter the hair side of nonwoven layer, make foaming body and non-woven fabrics bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the foam cement of part enters nonwoven layer, thus makes foam cement be combined tightr with non-woven fabrics, thus makes described heat insulating decorative board more firm.
Embodiment 18
Heat insulating decorative board of the present invention, as shown in Figure 1, its structure comprises foamed material layer 4 and is arranged on the face material layer 3 that described foamed material layer 4 can make described foamed material layer 4 penetrate into, on described face material layer 3, coating arranges solid sand material layer 2, is solidified with the decoration sand 1 for the formation of decorative pattern in described solid sand material layer 2.
Described foamed material layer 4 except containing except foam cement, is also the glass fibre of 96% containing the mass percent accounting for described foamed material layer 4; Described face material is non-woven fabrics; Described solid sand material layer 2 is except containing except PVC, also containing the mass percent accounting for described solid sand material layer 2 be 10% curing agent and the mass percent that accounts for described solid sand material layer 2 be the ultra-violet absorber of 1%, described curing agent is hexamethylenetetramine, and ultra-violet absorber is BTA.
The making of above-mentioned heat insulating decorative board comprises the following steps:
The first step: the liquid PVC being added with hexamethylenetetramine and BTA is coated on the upper surface of non-woven fabrics, the mass percent that described hexamethylenetetramine and described BTA account for described solid sand material layer 2 is respectively 10% and 1%, and insert on described PVC decoration sand 1 form decorative pattern, at 150 DEG C, solidify 20min, obtain the nonwoven layer that a lower surface is hair side, upper surface is solidified with PVC;
Second step: described nonwoven layer hair side is layered on the surface in the glass layer of unordered shape downwards;
3rd step: spray into foam cement in the glass fibre of described unordered shape, the mass ratio of described glass fibre and foam cement is 96:4, to glass layer described in complete submergence, be depressed into described glass layer without after air, described glass fibre foams 20min at 60 DEG C, foam cement foaming forms foaming body, and enter the hair side of nonwoven layer, make foaming body and non-woven fabrics bonding, obtain described heat insulating decorative board.As can be seen from Figure 1, the foam cement of part enters nonwoven layer, thus makes foam cement be combined tightr with non-woven fabrics, thus makes described heat insulating decorative board more firm.
In the above-described embodiments, in the making step of described heat insulating decorative board, the solid hardening time of sand material layer 2 or the foamed time of expanded material are 4min, 10min, 20min, as selectable embodiment, described hardening time or foamed time can be arbitrary numerical value between 4min ~ 20min.
Obviously, above-described embodiment is only for clearly example being described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here without the need to also cannot give all embodiments exhaustive and thus the apparent change of extending out or variation be still among protection scope of the present invention.
Claims (10)
1. a heat insulating decorative board, it is characterized in that, comprise foamed material layer and be arranged on the face material layer that described foamed material layer can make described foamed material layer penetrate into, on described face material layer, coating arranges solid sand material layer, is solidified with the decoration sand for the formation of decorative pattern in described solid sand material layer; Described expanded material is Foamex or foam cement, and described Foamex is one or more in phenolic resins, polyurethane, polyvinyl chloride; Described solid sand material layer is PVC, and the curing agent that mass percent is 1% ~ 30% is added with in described solid sand material layer, or described solid sand material layer is fireproof coating or cement, and the curing agent that mass percent is 0 ~ 30% is added with in described solid sand material layer, the preparation method of described heat insulating decorative board, comprises the following steps:
(1) solid for liquid state sand material or one or both the liquid state be added with in curing agent, ultra-violet absorber are consolidated sand Material coating on the surface of face material, and on described solid sand material, insert decoration sand formation decorative pattern, be cured at 60 ~ 210 DEG C, obtain the face material layer that a lower surface is hair side, upper surface is solidified with solid sand material;
(2) expanded material or one or more the expanded material be added with in blowing agent, surfactant, modifier, fire retardant are coated on described hair side, foam at 60 ~ 80 DEG C, obtain described foamed material layer;
Expanded material in described foamed material layer enters when foaming in described face material layer to be also bonded together with described face material layer and forms described heat insulating decorative board.
2. heat insulating decorative board according to claim 1, is characterized in that, described face material layer is nonwoven layer or glass layer of cloth.
3. heat insulating decorative board according to claim 2, is characterized in that, is provided with the fortifying fibre layer of disordered state distribution in described foamed material layer.
4. heat insulating decorative board according to claim 3, is characterized in that, the mass percent that the fortifying fibre layer that described disordered state distributes accounts for described foamed material layer is 5% ~ 40%.
5. heat insulating decorative board according to claim 4, is characterized in that, described fortifying fibre layer is glass layer.
6. heat insulating decorative board according to claim 5, it is characterized in that, described foamed material layer also comprise in blowing agent, surfactant, modifier, fire retardant one or more, in described foamed material layer, the mass percent of expanded material, blowing agent, surfactant, modifier is respectively 50% ~ 70%, 1% ~ 3%, 2% ~ 5%, 2% ~ 7%.
7. heat insulating decorative board according to claim 6, is characterized in that, in described solid sand material layer, be added with ultra-violet absorber, and the mass percent that described ultra-violet absorber accounts for described solid sand material layer is 0.5% ~ 3%.
8. heat insulating decorative board according to claim 7, is characterized in that, the mass percent of the curing agent in described solid sand material layer is 10% ~ 25%.
9. a preparation method for the arbitrary described heat insulating decorative board of claim 1 to 8, comprises the following steps:
(1) solid for liquid state sand material or one or both the liquid state be added with in curing agent, ultra-violet absorber are consolidated sand Material coating on the surface of face material, and on described solid sand material, insert decoration sand formation decorative pattern, be cured at 60 ~ 210 DEG C, obtain the face material layer that a lower surface is hair side, upper surface is solidified with solid sand material;
(2) expanded material or one or more the expanded material be added with in blowing agent, surfactant, modifier, fire retardant are coated on described hair side, foam at 60 ~ 80 DEG C, obtain described foamed material layer;
Expanded material in described foamed material layer enters when foaming in described face material layer to be also bonded together with described face material layer and forms described heat insulating decorative board.
10. the preparation method of heat insulating decorative board according to claim 9, is characterized in that, step (2) comprises:
1) described face material layer hair side is layered on the surface of the fortifying fibre layer of disordered state distribution downwards;
2) spray into expanded material or be added with one or more the expanded material in blowing agent, surfactant, modifier, fire retardant in the fortifying fibre layer distributed to described disordered state, to fortifying fibre layer described in complete submergence, be depressed into described fortifying fibre layer without after air, foam at 60 ~ 80 DEG C, expanded material foaming forms foaming body, and enter the hair side of face material layer, make foaming body and face material bonding, obtain described heat insulating decorative board.
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| CN103195222A (en) * | 2013-04-01 | 2013-07-10 | 新乡职业技术学院 | Insulation wall panel |
| CN104457125B (en) * | 2014-12-09 | 2017-01-04 | 常熟市久昇电器有限公司 | The glass interlayer board that a kind of refrigerator is special |
| CN110171177A (en) * | 2019-03-29 | 2019-08-27 | 浙江汇锋智造科技有限公司 | A kind of Insulating board that coating type is novel and its processing technology |
| CN110154479A (en) * | 2019-03-29 | 2019-08-23 | 浙江汇锋智造科技有限公司 | A kind of attaching type insulation board and its processing technology |
| CN112521104B (en) * | 2020-12-24 | 2021-12-03 | 陕西省建筑科学研究院有限公司 | Cement mortar for geogrid reinforced masonry structure |
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| CN102720320A (en) | 2012-10-10 |
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