CN102719089A - Bisphenol A-type phosphate ester modified nylon alloy material - Google Patents
Bisphenol A-type phosphate ester modified nylon alloy material Download PDFInfo
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- CN102719089A CN102719089A CN2012101988550A CN201210198855A CN102719089A CN 102719089 A CN102719089 A CN 102719089A CN 2012101988550 A CN2012101988550 A CN 2012101988550A CN 201210198855 A CN201210198855 A CN 201210198855A CN 102719089 A CN102719089 A CN 102719089A
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- modified nylon
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Abstract
The invention relates to a bisphenol A-type phosphate ester modified nylon alloy material and belongs to the technical field of high polymer materials. The bisphenol A-type phosphate ester modified nylon alloy material is made of, by weight, 40-47 parts of nylon 11 resin, 16-24 parts of polyethylene resin, 0.4-0.9 part of coupling agent, 15-21 parts of filler, 9-16 parts of phosphate ester, 0.2-0.7 part of antioxidant, 20-26 parts of glass fibers and 0.4-0.7 part of surface modifier. The bisphenol A-type phosphate ester modified nylon alloy material has the advantages that the tensile strength is larger than 150MPa, the bending strength is larger than 220MPa, the cantilever notched impact strength is larger than 24kj/m<2>, the melt index is larger than 26g/min, and flame retardance reaches V-0(UL-94-3mm), and environment protection and safety are embodied as the material contains no halogen.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to the phosphate modified nylon alloy material of a kind of bisphenol A-type.
Background technology
At present; Electronic apparatus, household electrical appliance, material of construction are all required to have flame retardant effect; Common way is in material, to add the halogen fire retardant, and forms toxic smog easily during the burning of halogen fire retardant, loses the anxiety that environmental protection and existence undermine HUMAN HEALTH.And that SULPHOSUCCINIC ACID ESTER is acknowledged as is safe and fire-retardant material modified, reflects this, and modification has positive effect to nylon material to utilize SULPHOSUCCINIC ACID ESTER, and the technical scheme that will introduce below produces under this background.
Summary of the invention
Task of the present invention is to provide a kind of and does not contain halogen and use and embody Environmental Safety and the phosphate modified nylon alloy material of bisphenol A-type that helps to ensure ideal intensity.
Task of the present invention is accomplished like this, the nylon alloy material that a kind of bisphenol A-type is phosphate modified, and its raw material by following parts by weight is formed:
In one embodiment of the invention, described Ni Long11 resin is a fusing point at 200 ℃ resin.
In another embodiment of the present invention, described polyvinyl resin is a medium-density polyethylene.
In yet another embodiment of the present invention, described coupling agent is a silane coupling agent.
In another embodiment of the present invention, described filler is surface treated Marinco H.
Also have among the embodiment of the present invention, described SULPHOSUCCINIC ACID ESTER is the dihydroxyphenyl propane tetraphenyldiphosphate.
more of the present invention and among embodiment, described oxidation inhibitor is 2,2-methylene-bis (4-methyl-6-tert butyl phenol).
In of the present invention and then embodiment, described spun glass is the alkali-free short glass fiber of length 3mm.
Of the present invention again more and among embodiment, described surface-modifying agent is two stearic amides.
The tensile strength of the nylon alloy material that bisphenol A-type provided by the invention is phosphate modified is greater than 150MPa, and flexural strength is greater than 220MPa, and the socle girder notched Izod impact strength is greater than 24kj/m
2, melting index is greater than 26g/10min, the fire-retardant V-0 (UL-94-3mm) that reaches; Owing to do not contain halogen, thereby can embody environmental protection and safety.
Embodiment
Embodiment 1:
By weight, fusing point is 45 parts of Ni Long11 resins at 200 ℃ resin, 16 parts of medium-density polyethylene resins; Coupling agent is 0.4 part of a silane coupling agent, and filler is 21 parts of surface treated Marinco Hs, and SULPHOSUCCINIC ACID ESTER is 9 parts of dihydroxyphenyl propane tetraphenyldiphosphates; Oxidation inhibitor is 2; 0.4 part of 2-methylene-bis (4-methyl-6-tert butyl phenol), length are 20 parts of the alkali-free short glass fibers of 3mm, 0.4 part of the promptly two stearic amide of surface-modifying agent.
Embodiment 2:
By weight, fusing point is 40 parts of Ni Long11 resins at 200 ℃ resin, 19 parts of medium-density polyethylene resins; Coupling agent is 0.6 part of a silane coupling agent, and filler is 15 parts of surface treated Marinco Hs, and SULPHOSUCCINIC ACID ESTER is 11 parts of dihydroxyphenyl propane tetraphenyldiphosphates; Oxidation inhibitor is 2; 0.5 part of 2-methylene-bis (4-methyl-6-tert butyl phenol), length are 22 parts of the alkali-free short glass fibers of 3mm, 0.7 part of the promptly two stearic amide of surface-modifying agent.
Embodiment 3:
By weight, fusing point is 47 parts of Ni Long11 resins at 200 ℃ resin, 21 parts of medium-density polyethylene resins; Coupling agent is 0.9 part of a silane coupling agent, and filler is 18 parts of surface treated Marinco Hs, and SULPHOSUCCINIC ACID ESTER is 14 parts of dihydroxyphenyl propane tetraphenyldiphosphates; Oxidation inhibitor is 2; 0.7 part of 2-methylene-bis (4-methyl-6-tert butyl phenol), length are 36 parts of the alkali-free short glass fibers of 3mm, 0.6 part of the promptly two stearic amide of surface-modifying agent.
Embodiment 4:
By weight, fusing point is 42 parts of Ni Long11 resins at 200 ℃ resin, 24 parts of medium-density polyethylene resins; Coupling agent is 0.7 part of a silane coupling agent, and filler is 20 parts of surface treated Marinco Hs, and SULPHOSUCCINIC ACID ESTER is 16 parts of dihydroxyphenyl propane tetraphenyldiphosphates; Oxidation inhibitor is 2; 0.6 part of 2-methylene-bis (4-methyl-6-tert butyl phenol), length are 24 parts of the alkali-free short glass fibers of 3mm, 0.5 part of the promptly two stearic amide of surface-modifying agent.
The phosphate modified nylon alloy material of bisphenol A-type that is obtained by the foregoing description 1 to 4 has the technique effect shown in the following table through test:
Claims (9)
1.
The nylon alloy material that a kind of bisphenol A-type is phosphate modified is characterized in that its raw material by following parts by weight forms:
40～47 parts of
Ni Long11 resins; 16～24 parts of polyvinyl resins; 0.4～0.9 part of coupling agent; 15～21 parts of fillers; SULPHOSUCCINIC ACID ESTER 9～16; 0.2～0.7 part in oxidation inhibitor; 20～26 parts in spun glass; 0.4～0.7 part of surface-modifying agent.
2.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described Ni Long11 resin is a fusing point at 200 ℃ resin.
3.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described polyvinyl resin is a medium-density polyethylene.
4.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described coupling agent is a silane coupling agent.
5.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described filler is surface treated Marinco H.
6.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described SULPHOSUCCINIC ACID ESTER is the dihydroxyphenyl propane tetraphenyldiphosphate.
7.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described oxidation inhibitor is 2,2-methylene-bis (4-methyl-6-tert butyl phenol).
8.
phosphate modified nylon alloy material of bisphenol A-type according to claim 1 is characterized in that described spun glass is the alkali-free short glass fiber of length 3mm.
9.
The nylon alloy material that bisphenol A-type according to claim 1 is phosphate modified is characterized in that described surface-modifying agent is two stearic amides
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101988550A CN102719089A (en) | 2012-06-15 | 2012-06-15 | Bisphenol A-type phosphate ester modified nylon alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101988550A CN102719089A (en) | 2012-06-15 | 2012-06-15 | Bisphenol A-type phosphate ester modified nylon alloy material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102719089A true CN102719089A (en) | 2012-10-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101988550A Pending CN102719089A (en) | 2012-06-15 | 2012-06-15 | Bisphenol A-type phosphate ester modified nylon alloy material |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1140588C (en) * | 1995-06-07 | 2004-03-03 | 通用电气公司 | Phosphate flame retardant polymer |
| CN1950451A (en) * | 2004-03-31 | 2007-04-18 | 通用电气公司 | Method of making poly(arylene ether) compositions |
| CN101608063A (en) * | 2009-07-06 | 2009-12-23 | 株洲时代工程塑料制品有限责任公司 | Line for Passenger Transportation fastener system nylon part low temperature resistant proprietary material and preparation method thereof |
| CN101724258A (en) * | 2008-10-31 | 2010-06-09 | 比亚迪股份有限公司 | Nylon composition, method for preparing same and application thereof |
-
2012
- 2012-06-15 CN CN2012101988550A patent/CN102719089A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1140588C (en) * | 1995-06-07 | 2004-03-03 | 通用电气公司 | Phosphate flame retardant polymer |
| CN1950451A (en) * | 2004-03-31 | 2007-04-18 | 通用电气公司 | Method of making poly(arylene ether) compositions |
| CN101724258A (en) * | 2008-10-31 | 2010-06-09 | 比亚迪股份有限公司 | Nylon composition, method for preparing same and application thereof |
| CN101608063A (en) * | 2009-07-06 | 2009-12-23 | 株洲时代工程塑料制品有限责任公司 | Line for Passenger Transportation fastener system nylon part low temperature resistant proprietary material and preparation method thereof |
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Application publication date: 20121010 |