CN102656234B - 热固化性树脂组合物、树脂组合物清漆的制造方法、预浸料及层叠板 - Google Patents
热固化性树脂组合物、树脂组合物清漆的制造方法、预浸料及层叠板 Download PDFInfo
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Abstract
Description
实施例1 | 实施例2 | 实施例3 | 比较例1 | 比较例2 | 比较例3 | |
使用量(质量份) | ||||||
A:具有酸性取代基的不饱和马来酰亚胺化合物 | ||||||
A-1(制造例1) | 65 | 65 | 65 | 65 | ||
A-2(制造例2) | 50 | |||||
B:热固化性树脂 | ||||||
B-1(联苯芳烷基型环氧树脂) | 35 | 35 | 35 | 35 | ||
B-2(苯酚/酚醛清漆型环氧树脂) | 50 | 61 | ||||
B-3(甲酚/酚醛清漆型环氧树脂) | 39 | |||||
固化促进剂:2-乙基-4-甲基咪唑 | 0.5 | 0.25 | 0.5 | 0.5 | 0.15 | 0.5 |
C:无机填充材料 | ||||||
C-1(熔融球状二氧化硅浆料:SC2050-KC) | 199 | 124 | 81 | 199 | 124 | |
C-2(氢氧化铝:CL-310) | 34 | 34 | ||||
C-3(烧成滑石:ST-100) | 48 | 54 | ||||
D:钼化合物 | ||||||
D-1(钼酸锌) | 86 | 154 | ||||
D-2(钼酸锌负载滑石10%负载) | 6.0 | 6.0 | ||||
D-3(钼酸钙) | 5.6 | |||||
组成(体积%) | ||||||
A+B:不饱和马来酰亚胺化合物+热固化性树脂 | 50 | 60 | 79 | 50 | 60 | 70 |
C:无机填充材料 | 38 | 38.5 | 20 | 38 | 38.5 | |
D:钼化合物 | 12 | 1.5 | 1.0 | 12 | 1.5 | 30 |
测定·评价 | ||||||
(1)钻孔加工性 | ||||||
钻头刀刃磨损量(μm) | 11 | 9 | 7 | 31 | 8 | 5 |
孔位置精度(μm) | 31 | 30 | 28 | 48 | 29 | 25 |
(2)热膨胀率(10-6/℃) | 10.8 | 11.4 | 11.7 | 10.7 | 14.1 | 14.5 |
(3)耐热性(玻璃转化温度:℃) | 210 | 220 | 215 | 212 | 175 | 199 |
Claims (9)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009296058A JP5682110B2 (ja) | 2009-12-25 | 2009-12-25 | 熱硬化性樹脂組成物並びにこれを用いたプリプレグ及び積層板 |
JP2009-296058 | 2009-12-25 | ||
JP2010-160979 | 2010-07-15 | ||
JP2010160979A JP5556466B2 (ja) | 2010-07-15 | 2010-07-15 | 配線板用積層板 |
JP2010165556A JP5593915B2 (ja) | 2010-07-23 | 2010-07-23 | 樹脂組成物ワニスの製造方法、プリプレグ、積層板 |
JP2010-165556 | 2010-07-23 | ||
PCT/JP2010/073376 WO2011078339A1 (ja) | 2009-12-25 | 2010-12-24 | 熱硬化性樹脂組成物、樹脂組成物ワニスの製造方法、プリプレグ及び積層板 |
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CN102656234A CN102656234A (zh) | 2012-09-05 |
CN102656234B true CN102656234B (zh) | 2015-06-17 |
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US (4) | US20120276392A1 (zh) |
EP (1) | EP2518115B1 (zh) |
KR (2) | KR20120123031A (zh) |
CN (1) | CN102656234B (zh) |
HK (1) | HK1171777A1 (zh) |
TW (4) | TWI555733B (zh) |
WO (1) | WO2011078339A1 (zh) |
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US20120276392A1 (en) * | 2009-12-25 | 2012-11-01 | Hitachi Chemical Company, Ltd. | Thermosetting resin composition, method for producing resin composition varnish, prepreg and laminate |
WO2011111847A1 (ja) * | 2010-03-08 | 2011-09-15 | 味の素株式会社 | 樹脂組成物 |
KR20140063710A (ko) * | 2011-09-22 | 2014-05-27 | 히타치가세이가부시끼가이샤 | 적층체, 적층판, 다층 적층판, 프린트 배선판 및 적층판의 제조 방법 |
SG11201406174PA (en) * | 2012-03-30 | 2014-10-30 | Mitsubishi Gas Chemical Co | Resin composition, prepreg, and laminate |
ITMI20130452A1 (it) | 2013-03-26 | 2014-09-27 | Riem Service S R L | Processo per la rigenerazione del gruppo pompante di un compressore volumetrico a vite del tipo "oil-free". |
SG11201600586XA (en) * | 2013-09-09 | 2016-02-26 | Mitsubishi Gas Chemical Co | Prepreg, metal foil-clad laminate, and printed wiring board |
KR101677736B1 (ko) | 2013-09-30 | 2016-11-18 | 주식회사 엘지화학 | 반도체 패키지용 열경화성 수지 조성물과 이를 이용한 프리프레그 및 금속박 적층판 |
TWI499627B (zh) * | 2013-10-11 | 2015-09-11 | Nanya Plastics Corp | A surface-coated inorganic filler molybdenum compound and use thereof |
US10208188B2 (en) | 2013-10-11 | 2019-02-19 | Shengyi Technology Co., Ltd. | Thermosetting resin composition and uses thereof |
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WO2011078339A1 (ja) | 2011-06-30 |
TW201531510A (zh) | 2015-08-16 |
HK1171777A1 (zh) | 2013-04-05 |
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TW201132625A (en) | 2011-10-01 |
TWI560223B (en) | 2016-12-01 |
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US10414943B2 (en) | 2019-09-17 |
TWI555733B (zh) | 2016-11-01 |
US20160230037A1 (en) | 2016-08-11 |
KR102143743B1 (ko) | 2020-08-28 |
US20120276392A1 (en) | 2012-11-01 |
KR20120123031A (ko) | 2012-11-07 |
EP2518115B1 (en) | 2017-10-18 |
CN102656234A (zh) | 2012-09-05 |
EP2518115A4 (en) | 2014-04-16 |
US20180094162A1 (en) | 2018-04-05 |
TWI531610B (zh) | 2016-05-01 |
EP2518115A1 (en) | 2012-10-31 |
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