CN102643682A - Preparation method for high-energy organic fuel replacing diesel oil - Google Patents
Preparation method for high-energy organic fuel replacing diesel oil Download PDFInfo
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- CN102643682A CN102643682A CN2012101195239A CN201210119523A CN102643682A CN 102643682 A CN102643682 A CN 102643682A CN 2012101195239 A CN2012101195239 A CN 2012101195239A CN 201210119523 A CN201210119523 A CN 201210119523A CN 102643682 A CN102643682 A CN 102643682A
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Abstract
The invention relates to a preparation method for a high-energy organic fuel replacing diesel oil. At the rapid development era of science and technology in nowadays, as the shortage of global stone resources and the environmental pollution caused by diesel oil are increasingly more serious, people hope that a novel fuel which can be used for replacing the diesel oil and solving the shortage of resources and is safe and environmentally friendly is disclosed. The invention aims to develop a preparation method for the high-energy organic fuel completely replacing the diesel oil. The high-energy organic fuel is formed by combining low-carbon alcohol methyl tertiary butyl ether, heavy aromatics, naphtha, dimethylbenzene, ethanolamine and an anti-swelling agent. The preparation method comprises the following steps: fully mixing the above components in a reaction kettle, repeatedly pumping out and pumping in the mixture by a high shear emulsification pump and carrying out high shear circulation emulsification to obtain the high-energy organic fuel replacing the diesel oil. The high-energy organic fuel is significant in social and economic benefits and obvious in environmental protection benefit, benefits the nation and people and benefits survival and development of descendants.
Description
Technical field
The invention belongs to the organic-fuel technical field of new forms of energy, be specifically related to a kind of method for formulating of high energy organic-fuel of alternative diesel oil.
Background technology
As everyone knows, because the pollution that the global shortage of petroleum resources and automobile use diesel oil to cause increasingly sharpens, countries in the world are all attempting utilizing other chemistry, physics and bioenergy to substitute diesel oil.The Oil Safety and the environmental issue of China are on the rise, and pay attention to more to substitute wholly or in part diesel oil with new forms of energy.In dropping into the various solutions of research, methyl alcohol substitutes diesel oil becomes first-selection.This is prone to fully burning not only because the methyl alcohol octane value is high, and is cheap, and the coal resources that can make full use of China's abundant are to carry out mass production.But the trial of adopting methyl alcohol to substitute diesel oil is fully never succeedd, and its subject matter is: the one, and the low heat value of methyl alcohol (having only 21000KJ/Kg), low-calorie half the less than diesel oil, dynamic property is relatively poor during use, and has the problem of cold start-up difficulty; The 2nd, methyl alcohol is prone to make rubber and the plastics swelling on the diesel vehicle component, thereby causes the swelling thing to stop up oil circuit; The 3rd, methyl alcohol produces formaldehyde and formic acid when imperfect combustion, and the latter possibly cause corrosion to automobile component.In promoting the use of the process of methyl alcohol, avoid the generation of the problems referred to above; The solution of taking both at home and abroad mainly is that thereby part is added a certain proportion of methyl alcohol acquisition methanol diesel-oil emulsion fuel or microemulsion fuel in diesel oil; But the methanol content in the fuel of these emulsifications and microemulsified is lower; Standing storage lower leaf problem does not solve fully, thereby all fails to obtain production and apply.From prior art, occur at present fully without diesel oil on the domestic and international market as yet and can substitute the organic-fuel of diesel oil fully, there is not this type of organic-fuel of pertinent literature public reported yet.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art; And provide that a kind of calorific value is high, cold starting property is good, swelling property is little, cost is low, erosion resistance is strong, leave standstill the high energy organic-fuel that can substitute diesel oil fully of good stability, and corresponding a kind of aforementioned method for formulating that can substitute the high energy organic-fuel of diesel oil fully is provided.
The technical scheme that the present invention proposes is achieved in that it is a kind of method for formulating of high energy organic-fuel of alternative diesel oil, and said high energy organic-fuel is mainly formulated by the composition of following massfraction:
Low-carbon alcohol 50%~65%;
MTBE 5%~10%;
Heavy aromatics 10%~20%;
Petroleum naphtha 9%~16%;
YLENE 8%~12%;
Thanomin 0.2~1%;
Anti-swelling agent 0.2~1%.
The method for formulating of the high energy organic-fuel of above-mentioned a kind of alternative diesel oil, said low-carbon alcohol preferentially comprise at least a in methyl alcohol, the ethanol.
The method for formulating of the high energy organic-fuel of above-mentioned a kind of alternative diesel oil can not contain diesel oil in the said high energy organic-fuel especially.
The high energy organic-fuel method for formulating of above-mentioned a kind of alternative diesel oil, the heavy aromatics in the said high energy organic-fuel are the BTX aromatics of molecular weight greater than YLENE, mainly are carbon 9 and carbon 10 aromatic hydrocarbons.
The method for formulating of the high energy organic-fuel of above-mentioned a kind of alternative diesel oil, the anti-swelling agent in the said high energy organic-fuel is the mixture of isopropylcarbinol and petroleum sodium sulfonate, ratio is 3: 1.
As a total technical conceive; The present invention also provides a kind of above-mentioned method for formulating that can substitute the high energy organic-fuel of diesel oil fully; May further comprise the steps: at first prepare each feed composition by the requirement of said massfraction; In reaction kettle, add said low-carbon alcohol and MTBE then earlier, add heavy aromatics, petroleum naphtha and YLENE after mixing again, behind the thorough mixing; In mixture, add thanomin and anti-swelling agent again; Start high speed dispersor then and carry out mixed at high speed from solution at reaction kettle, adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil various groups.
As a total technical conceive, the present invention also provides a kind of can substitute the application of the high energy organic-fuel of diesel oil as gasoline engine fuel fully, and the low heat value of said high energy organic-fuel reaches more than the 38000KJ/Kg.High energy organic-fuel of the present invention can replace diesel oil to be used for various types of vehicles such as automobile, steamer fully.
Compared with prior art, the invention has the advantages that:
(1) high energy organic-fuel product of the present invention can not contain diesel oil fully, but can substitute the product of diesel oil, as a kind of novel high energy organic-fuel; Because the raw material of mainly using in the product of the present invention is low-carbon alcohol such as methyl alcohol; This type raw material can extract through coal; And China is a coal resources big country; Therefore product of the present invention makes full use of the superior resources of this country for the situation of the oil shortage of alleviating China, has crucial meaning.
(2) low heat value of high energy organic-fuel product of the present invention reaches more than the 38000KJ/Kg, is equivalent to low-calorie 1.8 times of methyl alcohol, has considerable thermo-efficiency, can not influence the use properties of its Application Areas and combustion powered equipment.
(3) through on petrol engine, using high energy organic-fuel product of the present invention, mover is not only worked and is worked well, and good dynamic property, does not have the problem of cold starting property difference, and result of use is suitable with 93# gasoline.
(4) use high energy organic-fuel product of the present invention, pollutent such as carbon monoxide, hydrocarbon polymer, nitrogen oxidation are closed, the quantity discharged of particle (PM) and flue gas all reduces more than 2/3.Has tangible environmental benefit.
(5) high energy organic-fuel product swelling property of the present invention is little, uses the motor vehicle of product of the present invention the problem that rubber-like is stopped up oil circuit not occur.
(6) high energy organic-fuel product erosion resistance of the present invention is strong, uses the motor vehicle of product of the present invention not find the component etching problem, and is little to existing petrolic negative impact.
(7) the most outstanding advantage of product of the present invention is that economy is obvious, compares similar gasoline products, and the present invention not only raw material sources is extensive, and fuel cost can reduce more than 10%.
Description of drawings
Fig. 1 is the technological process block-diagram of method for formulating of the present invention.
Embodiment
Embodiment 1:
The method for formulating of the high energy organic-fuel of alternative diesel oil of the present invention, this high energy organic-fuel can formulated by the composition of following massfraction (not containing the gasoline series products):
Low-carbon alcohol 50%;
MTBE 7%;
Heavy aromatics 16%;
Petroleum naphtha 15%;
YLENE 11%;
Thanomin 0.5%;
Anti-swelling agent 0.5%.
The method for formulating of the high energy organic-fuel of the alternative diesel oil of present embodiment; May further comprise the steps: at first the requirement by above-mentioned massfraction is equipped with each feed composition; In reaction kettle, add mass ratio then and be 50: 7 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 16: 15: 11: 50; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 50, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
Embodiment 2:
The method for formulating of the high energy organic-fuel of alternative gasoline of the present invention, this high energy organic-fuel also can formulated by the composition of following massfraction (not containing the gasoline series products):
Low-carbon alcohol 57%;
MTBE 5%;
Heavy aromatics 15%;
Petroleum naphtha 13%;
YLENE 9%;
Thanomin 0.5%;
Anti-swelling agent 0.5%.
The method for formulating that can substitute the high energy organic-fuel of diesel oil fully of present embodiment; May further comprise the steps: at first the requirement by above-mentioned massfraction is equipped with each feed composition; In reaction kettle, add mass ratio then and be 57: 5 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 15: 13: 9: 57; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 57, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
Embodiment 3:
The high energy organic-fuel that can substitute diesel oil fully of the present invention, this high energy organic-fuel can also formulated by the composition of following massfraction (not containing diesel oil):
Low-carbon alcohol 65%;
MTBE 5%;
Heavy aromatics 10%;
Petroleum naphtha 10%;
YLENE 9%;
Thanomin 0.5%;
Anti-swelling agent 0.5%.
The method for formulating of the high energy organic-fuel of a kind of alternative diesel oil of present embodiment; May further comprise the steps: at first prepare each feed composition by the requirement of above-mentioned massfraction; In reaction kettle, add mass ratio then and be 65: 5 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 10: 10: 9: 65; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 65, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
Through detecting, its low heat value of the product of above-mentioned each embodiment reaches more than the 38000KJ/Kg, is equivalent to low-calorie 1.8 times of methyl alcohol.
Application implementation example 4:
1. oil property engine rig test.
The product of above-mentioned present embodiment 1 is delivered to Hunan Province oil engine quality supervision and test granting station carry out diesel motor bench testing comparison detection (the comparison object of reference is a 0# diesel oil), detected result is following:
Experimental prototype uses this product to compare with using commercially available No. 0 diesel oil: its peak power high pulling torque early slightly descends; The declared working condition specific fuel oil consumption is basic identical.
2. smoke intensity simultaneous test.
It is as shown in table 2 below by Hunan Province's automobile and motorcycle product quality supervision and inspection power station the diesel oil that uses present embodiment 1 product freely to be quickened smoke intensity comparison test detected result.Visible by table 2, use high energy organic-fuel of the present invention, with 0
#Diesel oil is compared, and smoke intensity can reduce more than 65%.
Table 1: freely quicken smoke intensity simultaneous test table
0# diesel oil | This product | |
Freely quicken smoke intensity (m -1) | 0.78 | 0.26 |
3. oil circuit detected result.
Through to using the tracing observation of the vehicles such as automobile of high energy organic-fuel product of the present invention more than 6 months, use the motor vehicle of product of the present invention the problem that rubber-like swelling thing stops up oil circuit not occur.
4. oil circuit detected result.
Through to using the tracing observation of the vehicles such as automobile of high energy organic-fuel product of the present invention more than 6 months, use the motor vehicle of product of the present invention not find the component etching problem.
5. economy detects contrast.
Hunan Province automobile and motorcycle product quality supervision inspection center is to the economy detected result detected result as shown in table 2 of the embodiment of the invention 1 product: this product and 0
#Diesel oil is compared, and actual road(wear)test per 100 km oil consumption (60km/h) reduces by 4%.And the price of this product is lower than the 0# diesel-fuel price, and economy is more obvious.
Table 2. fuel consumption per hundred kilometers economic analysis
Claims (9)
1. the high energy organic-fuel method for formulating of an alternative diesel oil is characterized in that said high energy organic-fuel is mainly formulated by the composition of following massfraction: (by weight percentage)
Low-carbon alcohol 50%~65%;
MTBE 5%~10%;
Heavy hydrocarbon 10%~20%;
Petroleum naphtha 9%~16%;
YLENE 8%~12%;
Thanomin 0.2-1%;
Anti-swelling agent 0.2%~1%;
The present invention a kind of method for formulating of high energy organic-fuel of alternative diesel oil; May further comprise the steps: at first the requirement by said massfraction is equipped with each feed composition; In reaction kettle, add said low-carbon alcohol and MTBE then earlier, add heavy aromatics, petroleum naphtha and YLENE after mixing again, behind the thorough mixing; In mixture, add thanomin and the anti-swelling agent of 1# again; Start high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle, adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, obtain to substitute fully the high energy organic-fuel of diesel oil.
2. the method for formulating of the high energy organic-fuel of a kind of alternative diesel oil according to claim 1, its characteristic: pressing embodiment 1 this high energy organic-fuel can be formulated by the composition of following massfraction:
Low-carbon alcohol 50%;
MTBE 7%;
Heavy aromatics 16%;
Petroleum naphtha 15%;
YLENE 11%;
Thanomin 0.5%;
Anti-swelling agent 0.5%;
The method for formulating of the high energy organic-fuel of the alternative diesel oil of present embodiment; May further comprise the steps: at first the requirement by above-mentioned massfraction is equipped with each feed composition; In reaction kettle, add mass ratio then and be 50: 7 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 16: 15: 11: 50; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 50, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
3. the method for formulating of the high energy organic-fuel of a kind of alternative gasoline according to claim 1, its characteristic: pressing embodiment 2 these high energy organic-fuels also can be formulated by the composition of following massfraction:
Low-carbon alcohol 57%;
MTBE 5%;
Heavy aromatics 15%;
Petroleum naphtha 13%;
YLENE 9%;
Thanomin 0.5%;
Anti-swelling agent 0.5%:
The method for formulating that can substitute the high energy organic-fuel of diesel oil fully of present embodiment; May further comprise the steps: at first the requirement by above-mentioned massfraction is equipped with each feed composition; In reaction kettle, add mass ratio then and be 57: 5 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 15: 13: 9: 57; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 57, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
4. the high energy organic-fuel of a kind of alternative diesel oil according to claim 1, its characteristic: pressing embodiment 3 these high energy organic-fuels can also be formulated by the composition of following massfraction:
Low-carbon alcohol 65%;
MTBE 5%;
Heavy aromatics 10%;
Petroleum naphtha 10%;
YLENE 9%;
Thanomin 0.5%;
Anti-swelling agent 0.5%;
The method for formulating of the high energy organic-fuel of a kind of alternative diesel oil of present embodiment; May further comprise the steps: at first prepare each feed composition by the requirement of above-mentioned massfraction; In reaction kettle, add mass ratio then and be 65: 5 methyl alcohol and MTBE, add heavy aromatics, petroleum naphtha and YLENE after mixing respectively, the mass ratio of heavy aromatics, petroleum naphtha and YLENE and methyl alcohol is 10: 10: 9: 65; Behind thorough mixing; In mixture, add thanomin and anti-swelling agent again, the mass ratio of thanomin, anti-swelling agent and methyl alcohol is controlled to be 0.5: 0.5: 65, starts high speed dispersor then various component solution are carried out mixed at high speed at reaction kettle; Adopt the high-shear emulsifying pump that mixture is pumped to pump into repeatedly again and carry out the high-shear circulating emulsion, promptly obtain to substitute fully the high energy organic-fuel of diesel oil.
5. the method for formulating of the high energy organic-fuel of a kind of alternative diesel oil according to claim 1 is characterized in that said low-carbon alcohol comprises at least a in methyl alcohol, the ethanol.
6. the method for formulating of the high energy organic-fuel of a kind of alternative diesel oil according to claim 1 is characterized in that said anti-swelling agent is the mixture of isopropylcarbinol and petroleum sodium sulfonate, and ratio is 3: 1.
7. a kind of method for formulating that substitutes the high energy organic-fuel of diesel oil fully according to claim 1 is characterized in that not containing diesel oil in the said high energy organic-fuel.
8. the method for formulating of the high energy organic-fuel of a kind of alternative diesel oil according to claim 1, it is characterized in that heavy aromatics in the high energy organic-fuel be molecular weight greater than the YLENE BTX aromatics, mainly be carbon 9 and carbon 10 aromatic hydrocarbons.
9. the method for formulating of the high energy organic-fuel of alternative diesel oil according to claim 1, the low heat value of said high energy organic-fuel reaches more than the 38000KJ/KG.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104560234A (en) * | 2015-01-20 | 2015-04-29 | 刘敏 | New energy fuel and production technique thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1746271A (en) * | 2004-09-09 | 2006-03-15 | 马春宇 | Energy-saving clean fuel substituting diesel oil and production thereof |
CN1931970A (en) * | 2006-09-29 | 2007-03-21 | 刘连强 | Additive for gasoline and diesel oil and its prepn process |
CN102391897A (en) * | 2011-10-09 | 2012-03-28 | 谢虎 | Methanol gasoline for vehicles |
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- 2012-04-23 CN CN2012101195239A patent/CN102643682A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1746271A (en) * | 2004-09-09 | 2006-03-15 | 马春宇 | Energy-saving clean fuel substituting diesel oil and production thereof |
CN1931970A (en) * | 2006-09-29 | 2007-03-21 | 刘连强 | Additive for gasoline and diesel oil and its prepn process |
CN102391897A (en) * | 2011-10-09 | 2012-03-28 | 谢虎 | Methanol gasoline for vehicles |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104560234A (en) * | 2015-01-20 | 2015-04-29 | 刘敏 | New energy fuel and production technique thereof |
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Application publication date: 20120822 |