CN102626070B - Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides - Google Patents
Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides Download PDFInfo
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- CN102626070B CN102626070B CN 201210088105 CN201210088105A CN102626070B CN 102626070 B CN102626070 B CN 102626070B CN 201210088105 CN201210088105 CN 201210088105 CN 201210088105 A CN201210088105 A CN 201210088105A CN 102626070 B CN102626070 B CN 102626070B
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Abstract
The invention relates to an ultra-low volume liquid containing cyantraniliprole and insect growth regulator insecticides. The liquid is compounded by cyantraniliprole and an active ingredient II into an active ingredient, and other components are surfactants and solvents; and the active ingredient II is any one of chlorfluazuron, teflubenzuron, triflumuron, flufenoxuron, hexaflumuron, flucycloxuron, penfluron, ehlorfluarizonauron, chlorbenzuron, diflubenzuron, diafenthiuron, food suppressing hydrazine, buprofezin, fenoxycarb or tebufenozide. The ultra-low volume liquid has the advantages of convenience in processing, long duration, high work efficiency, low possibility of generatingresistance to pesticides by a target, low environmental contamination, economy of drug and water, and improvement in pesticide utilization rate; and through ultra-low volume spraying, low volume spraying or ultra-low volume static spraying, a variety of pests of rice, wheat, corn, vegetables, tobacco, tea trees, fruit trees and sugarcanes can be prevented and treated.
Description
Technical field
The present invention relates to pesticide field, is the ultra low volume liquids that contains cyanogen insect amide and insect growth regulator, IGR insecticides specifically, mainly by ultra low volume spraying, low-gallonage spraying or the realization of the ultra low volume electrostatic spray effective control to crop pest.
Background technology
At present for the control of insect that easily produces resistance on the agricultural, main way is that exploitation and existing kind do not have composite between the new composition of cross resistance or the existing pesticide species, the former since required development cost height, cycle long, and at present development rate far away less than the speed of pest resistance to insecticide generation.Therefore, being mixed for the different existing pesticide species of the mechanism of action is a kind of selection of the best.If reasonable mixture ratio then can produce significant synergistic effect, make field control effect significantly be better than the effect of each single agent.Usually there is certain defective in the insecticide that contains the single-activity composition on agricultural insect pests control, continuous several times is used and is not only made insect be easy to generate pesticide resistance, and easily cause pollution, can overcome above shortcoming by rationally being mixed between the pesticide active ingredient to food and environment.The reasonably composite simultaneously synergistic effect that active ingredient is produced, can improve preventive effect, reduce the effective ingredient consumption, save cost, delay the drug-fast generation of insect, closely can alleviate even avoid the pollution of agricultural chemicals food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops out, not only the target drug effect is significantly strengthened, and very low to the influence of people, crop, non-target and environment.
The cyanogen insect amide English name is Cyantraniliprole, trade name is CyazypyrTM, test code number is DPX-HGW86, chemical name is 3-bromo-N-(4-cyano group-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides, be the novel O-formammidotiazol-benzamide insecticide that du pont company develops, its chemical structural formula is
Cyanogen insect amide belongs to insect ryania acceptor inhibitor, mainly calcium ion discharges to show and tags and stomach poison function in striated muscle by inducing insect ryania receptor modulators and the smooth muscle cell, can be used for the control of various crop insects such as paddy rice, vegetables, cotton, beet, especially the control to various lepidoptera pests and sucking pest has special efficacy, its control efficiency is remarkable in other commercialization insecticide varieties that use in the current production, and there is not cross resistance in other insecticides.Therefore, cyanogen insect amide is described as efficient pesticides of new generation in the world.
Insect growth regulator, IGR is to change the class specific compound that insect growth is grown, and with regard to the possibility and validity of insect growth control, belongs to non-direct insecticide, promptly controls the growth course of insect with artificial method, thereby reaches the purpose of Pest Control.This compounds has unique mode of action, selectivity height, using dosage be little, to human, natural enemy and Environmental security, be difficult for to produce resistance, therefore more and more be subjected to people's favor, the chemical name of the related insect growth regulator, IGR insecticides of active component II is as follows among the present invention:
The chemical name of UC 62644 is 1-[3,5-two chloro-4-(3-chloro-5-trifluoromethyl-2-pyridine oxygen base) phenyl]-3-(2, the 6-difluoro benzoyl) urea;
The chemical name of Teflubenzuron is 1-(3,5-two chloro-2,4-difluorophenyl)-3-(2, the 6-difluoro benzoyl) urea;
The grand chemical name of desinsection is 1-(2-chlorobenzene formacyl)-3-(4-Trifluoromethoxyphen-l) urea;
The chemical name of flufenoxuron is 1-(4-(A-three chloro-are to toloxyl for 2-chloro-A, A)-2-fluorophenyl)-3-(2,6-two fluorobenzoyl) urea;
The chemical name of fluorine bell urea is 1-[3,5-two chloro-4-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-(2, the 6-difluoro benzoyl) urea;
The chemical name of flucycloxuron is 1-(α-(4-chloro-α-cyclopropyl benzal amino oxygen)-right-tolyl)-3-(2-difluoro benzoyl) urea;
The chemical name of penfluron is 1-(4-trifluoromethyl)-3-(2, the 6-difluoro benzoyl) urea;
The chemical name of fluorine pyridine urea is 1-[3,5-two chloro-4-(3-chloro-5-trifluoromethyl-2-pyridine oxygen base) phenyl]-3-(2, the 6-difluoro benzoyl) urea;
The chemical name of young urea of going out is 1-(2-chlorobenzene formacyl)-3-(4-chlorphenyl) urea;
The chemical name of diflubenzuron is 1-(4-chlorphenyl)-3-(2, the 6-difluoro benzoyl) urea;
The chemical name that presses down the food hydrazine is 2`-benzoyl-1`-tert-butyl benzene formylhydrazine;
The chemical name of Buprofezin is 2-tertbutylimido-3-isopropyl-5-phenyl-1,3,5-thiadiazine-4-ketone;
The chemical name of ABG-6215 is 2-(4-phenoxy group phenoxy group) ethyl carbamic acid ethyl ester;
The chemical name of butyl ether urea is 1-tertiary butyl-3-(2,6-diisopropyl-4-Phenoxyphenyl) thiocarbamide;
The chemical name of worm hydrazides is N-tertiary butyl-N '-(4-ethylamino benzonitrile acyl group)-3,5-dimethyl benzene hydrazides.
Ultra low volume liquids is low by the screening volatility, flash-point is high, to former medicine dissolubility is good, low to chemical injury of crops, viscosity is low solvent, do not convert water during dispenser, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is not owing to contain the high volatile volatile composition in the droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, reduced volatilization with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Because need not to convert water uses, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large tracts of land takes place and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
The ultra low volume spraying technology has the following advantages:
1. spouting liquid is few, only is hundreds of/one of conventional spraying.
2. droplet is little, and ultra low volume electrostatic spray fogdrop diameter is that 30～60 μ m, ultra low volume ground spraying droplet diameter are 30～80 μ m, aerial ultra low volume spraying fogdrop diameter 30～60 μ m, and conventional spraying droplet diameter is many more than 200～600 μ m.
3. spray pattern is the spraying of drift accumulation property, and conventional spraying is the specific aim spraying, promptly facing to the crop spraying.
What 4. ultra low volume sprayed is to be the finish of carrier with oil, and concentration is generally a few percent to percent tens; And the conventional water diluent agent concentration that sprays is very low, is generally some thousandths of to ten thousand/several.
5. the work efficiency height is prevented and treated in time.Hand-held ultra low volume spraying machine improves 20～30 times of work efficiency than manual compression sprayer, because of its work efficiency height, can timely and effectively prevent and treat the fulminant insect, as plant hopper, mythimna separata, locust etc.
6. save agricultural chemicals.Save agricultural chemicals more than 30% with general than conventional spraying.
7. water not.Saved water intaking, made up a prescription and heavy physical labor such as negative water operation, the hilly and mountainous land of especially short of rain in arid, manpower shortage and water intaking difficulty is used, and is more convenient.
8. good drug efficacy is held and is imitated length.The oil agricultural chemicals is easy to penetrate ester dissolubility insect body surface and enters in the pest body, show as desinsection rapidly, good drug efficacy; The high boiling point auxiliary agent that occupies larger proportion in the finish can play protective effects such as anti-hydrolysis, anti-oxidant, anti-photodissociation to pesticide active ingredient, show as hold imitate long.
9. to crop safety.Ultra low volume spraying be difficult for to produce poisoning to crop safety, does not have obviously residually, can improve crop quality.
10. expenses for prevention and control is low.Since ultra low volume spraying have province's medicine, laborsaving, not water, good drug efficacy, hold and imitate advantages such as long, so expenses for prevention and control is lower than conventional spraying.
Summary of the invention
The purpose of this invention is to provide a kind of ultra low volume liquids preparation that contains cyanogen insect amide and insect growth regulator, IGR insecticides, and the preparation method of described ultra low volume liquids is provided.
The ultra low volume liquids formulation that the present invention makes, it be composite with cyanogen insect amide and active component II be active component, all the other supply 100% with surfactant and solvent; Active component II is that UC 62644, Teflubenzuron, desinsection are grand, flufenoxuron, fluorine bell urea, flucycloxuron, penfluron, fluorine pyridine urea, the young urea that goes out, diflubenzuron, butyl ether urea, press down any one of food hydrazine, Buprofezin, ABG-6215 or worm hydrazides.
This ultra low volume liquids is composite with cyanogen insect amide and active component II to be active component, the weight content of its total amount is 0.2%～70%, the weight content of cyanogen insect amide is 0.1%～20%, the weight content of active component II is 0.1%～50%, the weight content of auxiliary agent is 1%～10%, and solvent complements to 100%.
Suitable surfactant is selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, the phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, OPEO, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, or one or more the combination in the calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, alkylphenol polyoxyethylene, the phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, or calcium dodecyl benzene sulfonate etc.
The solvent that is fit to is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene or two wires oil; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, corn oil, turpentine oil, methyl oleate or ethyl oleate; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, N,N-dimethylacetamide, n-hexyl alcohol, n-octyl alcohol or terpineol.
The preparation method of ultra low volume liquids of the present invention is, earlier with partial solvent with the active component stirring and dissolving after, add surfactant and remaining solvent again, fully mix, promptly get the ultra low volume liquids that contains cyanogen insect amide and insect growth regulator, IGR insecticides; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
The target crop that is fit to is cereal crops such as paddy rice, wheat, economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is fit to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resembles the star stinkbug, green rice bug resembles, red must fleahopper, rice is negative mixes worm, rice tube water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, secondly is low-gallonage spraying and ultra low volume electrostatic spray, and a situation arises determines suitable dosage according to controlling object, and formulation rate is 75～150g a.i./hm usually
2.
The inventor is by studies have shown that, cyanogen insect amide and UC 62644, Teflubenzuron, desinsection are grand, flufenoxuron, fluorine bell urea, flucycloxuron, penfluron, fluorine pyridine urea, the young urea that goes out, diflubenzuron, butyl ether urea, press down the ultra low volume liquids that the arbitrary pesticide active ingredient in food hydrazine, Buprofezin, ABG-6215, the worm hydrazides is re-dubbed target pest is had extremely strong synergistic effect.
Ultra low volume liquids of the present invention is easy to process, with low cost, good drug efficacy, hold imitate long, coordinate the synergy height, save water; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
The present invention is further described below in conjunction with embodiment, but do not limit the scope of the invention.
Embodiment 1
Prepare 5.0% cyanogen insect amide UC 62644 ultra low volume liquids
Preparation technology: earlier with partial solvent with active component cyanogen insect amide and UC 62644 stirring and dissolving after, add surfactant and remaining solvent again, fully mix, promptly get 5% cyanogen insect amide UC 62644 ultra low volume liquids; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
Step of preparation process according to identical with embodiment 1 can prepare following examples.
Embodiment 2
Prepare 20.1% cyanogen insect amide UC 62644 ultra low volume liquids
Embodiment 3
Prepare 21% cyanogen insect amide Teflubenzuron ultra low volume liquids
Embodiment 4
Prepare 55% cyanogen insect amide Teflubenzuron ultra low volume liquids
Embodiment 5
Prepare the grand cyanogen insect amide ultra low volume liquids of 26% desinsection
Embodiment 6
Prepare the grand cyanogen insect amide ultra low volume liquids of 52% desinsection
Embodiment 7
Prepare 7% cyanogen insect amide flufenoxuron ultra low volume liquids
Embodiment 8
Prepare 20.1% cyanogen insect amide flufenoxuron ultra low volume liquids
Embodiment 9
Prepare 23% cyanogen insect amide fluorine bell urea ultra low volume liquids
Embodiment 10
Prepare 25% cyanogen insect amide fluorine bell urea ultra low volume liquids
Embodiment 11
Prepare 15% cyanogen insect amide flucycloxuron ultra low volume liquids
Embodiment 12
Prepare 20.1% cyanogen insect amide flucycloxuron ultra low volume liquids
Embodiment 13
Prepare 5% cyanogen insect amide penfluron ultra low volume liquids
Embodiment 14
Prepare 50.1% cyanogen insect amide penfluron ultra low volume liquids
Embodiment 15
Prepare 6% cyanogen insect amide fluorine pyridine urea ultra low volume liquids
Embodiment 16
Prepare 25% cyanogen insect amide fluorine pyridine urea ultra low volume liquids
Embodiment 17
The preparation 5% young urea cyanogen insect amide ultra low volume liquids of going out
Embodiment 18
The preparation 20.1% young urea cyanogen insect amide ultra low volume liquids of going out
Embodiment 19
Prepare 8% diflubenzuron cyanogen insect amide ultra low volume liquids
Embodiment 20
Prepare 50.1% diflubenzuron cyanogen insect amide ultra low volume liquids
Embodiment 21
Prepare 9% butyl ether urea cyanogen insect amide ultra low volume liquids
Embodiment 22
Prepare 50.1% butyl ether urea cyanogen insect amide ultra low volume liquids
Embodiment 23
Preparation 11% presses down food hydrazine cyanogen insect amide ultra low volume liquids
Embodiment 24
Preparation 51% presses down food hydrazine cyanogen insect amide ultra low volume liquids
Embodiment 25
Prepare 5% cyanogen insect amide Buprofezin ultra low volume liquids
Embodiment 26
Prepare 20.1% cyanogen insect amide Buprofezin ultra low volume liquids
Embodiment 27
Prepare 11% cyanogen insect amide ABG-6215 ultra low volume liquids
Embodiment 28
Prepare 50.1% cyanogen insect amide ABG-6215 ultra low volume liquids
Embodiment 29
Prepare 7% cyanogen insect amide worm hydrazides ultra low volume liquids
Embodiment 30
Prepare 53% cyanogen insect amide worm hydrazides ultra low volume liquids
The prepared ultra low volume liquids outward appearance that contains cyanogen insect amide and insect growth regulator, IGR insecticides is the homogeneous oily liquids; Low temperature compatibility is good, and under-5 ℃ of conditions, refrigeration 7d does not separate out crystallization and suspension; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, no poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10
-6～1 * 10
-10In the s/cm scope.
Below again in conjunction with using the furthermore bright beneficial effect of the present invention of field efficacy measurement result that the embodiment of the invention is carried out.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80＜CTC＜120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field control effectiveness test again.
Application Example
Controlling object: cabbage caterpillar
Experiment place: vegetables field, three pool, Nanning City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2.
The contrast medicament: 1.8% Avermectin EC, preparation mu consumption 200ml is diluted with water to the conventional spraying of 30L
Table 1: control cabbage pieris test of pesticide effectiveness result
As can be seen from Table 1: ultra low volume liquids employing ultra low volume spraying method control cabbage pieris of the present invention comparison is sprayed according to the medicament routine, and quick-acting is strong, control efficiency good, the lasting period is longer.
Claims (2)
1. contain the ultra low volume liquids of cyanogen insect amide and insect growth regulator, IGR insecticides, it is characterized in that: it be composite with cyanogen insect amide and active component II be active component, all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II is that UC 62644, Teflubenzuron, desinsection are grand, flufenoxuron, fluorine bell urea, flucycloxuron, penfluron, fluorine pyridine urea, the young urea that goes out, diflubenzuron, butyl ether urea, press down any one of food hydrazine, Buprofezin, ABG-6215, worm hydrazides;
Cyanogen insect amide and active component II are composite to be active component, the weight content of its total amount is 0.2%～70%, and the weight content of cyanogen insect amide is 0.1%～20%, and the weight content of active component II is 0.1%～50%, the weight content of auxiliary agent is 1%～10%, and solvent complements to 100%;
Described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent is selected from butylbenzene, methyl naphthalene, two wires oil; The plant oil solvent is selected from turpentine oil, methyl oleate, ethyl oleate; Polar solvent is selected from N-Methyl pyrrolidone, N, dinethylformamide, N,N-dimethylacetamide, n-hexyl alcohol, n-octyl alcohol, terpineol;
Described surfactant is one or more the combination in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the calcium dodecyl benzene sulfonate.
2. the preparation method of ultra low volume liquids as claimed in claim 1 is: earlier with partial solvent with the active component stirring and dissolving after, add surfactant and remaining solvent again, fully mix, promptly get the ultra low volume liquids that contains cyanogen insect amide and insect growth regulator, IGR insecticides; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105994330A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and chlorfluazuron and application thereof |
| CN106070247A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof |
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| CN103651537B (en) * | 2013-12-13 | 2016-06-29 | 广西田园生化股份有限公司 | The ultra low volume liquids of fluorine silicon chrysanthemum ester and insect growth regulator, IGR insecticides |
| CN104920412B (en) * | 2015-06-24 | 2017-08-08 | 浙江省化工研究院有限公司 | A kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide |
| CN105028443A (en) * | 2015-08-24 | 2015-11-11 | 江阴苏利化学股份有限公司 | Insecticidal composition containing diflubenzuron and cyantraniliprole and application thereof |
| CN106070278A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof |
| CN105994288A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and tebufenozide and application thereof |
| CN108184884A (en) * | 2018-02-28 | 2018-06-22 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing bromine cyanogen insect amide and flubenzuron |
| CN112998020A (en) * | 2019-12-20 | 2021-06-22 | 江苏功成生物科技有限公司 | Insecticidal composition containing second-generation ryanodine receptor inhibitor and application thereof |
| CN115211425B (en) * | 2022-07-31 | 2023-03-31 | 中国农业科学院植物保护研究所 | Food attractant for preventing and treating rice leaf rollers and application |
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| CN102626070A (en) | 2012-08-08 |
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