CN102613198B - Chitosan oligosaccharide agricultural composition for improving coloration of plants and application thereof and method by utilizing same to improve coloration of plants - Google Patents
Chitosan oligosaccharide agricultural composition for improving coloration of plants and application thereof and method by utilizing same to improve coloration of plants Download PDFInfo
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- CN102613198B CN102613198B CN201210058562.2A CN201210058562A CN102613198B CN 102613198 B CN102613198 B CN 102613198B CN 201210058562 A CN201210058562 A CN 201210058562A CN 102613198 B CN102613198 B CN 102613198B
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- chitosan oligosaccharide
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- 239000000203 mixture Substances 0.000 title claims abstract description 68
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 33
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 claims abstract description 12
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 12
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004471 Glycine Substances 0.000 claims abstract description 6
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims abstract description 6
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 claims abstract description 6
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims abstract description 6
- 235000006539 genistein Nutrition 0.000 claims abstract description 6
- 229940045109 genistein Drugs 0.000 claims abstract description 6
- TZBJGXHYKVUXJN-UHFFFAOYSA-N genistein Natural products C1=CC(O)=CC=C1C1=COC2=CC(O)=CC(O)=C2C1=O TZBJGXHYKVUXJN-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZCOLJUOHXJRHDI-CMWLGVBASA-N genistein 7-O-beta-D-glucoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC(O)=C2C(=O)C(C=3C=CC(O)=CC=3)=COC2=C1 ZCOLJUOHXJRHDI-CMWLGVBASA-N 0.000 claims abstract description 6
- 235000013922 glutamic acid Nutrition 0.000 claims abstract description 6
- 229960002989 glutamic acid Drugs 0.000 claims abstract description 6
- 239000004220 glutamic acid Substances 0.000 claims abstract description 6
- 229960002449 glycine Drugs 0.000 claims abstract description 6
- 229940040102 levulinic acid Drugs 0.000 claims abstract description 6
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960005190 phenylalanine Drugs 0.000 claims abstract description 6
- BSYNRYMUTXBXSQ-FOQJRBATSA-N 59096-14-9 Chemical compound CC(=O)OC1=CC=CC=C1[14C](O)=O BSYNRYMUTXBXSQ-FOQJRBATSA-N 0.000 claims abstract description 5
- 235000008729 phenylalanine Nutrition 0.000 claims description 5
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 claims description 5
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 abstract description 5
- 239000001110 calcium chloride Substances 0.000 abstract description 5
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 abstract description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004327 boric acid Substances 0.000 abstract description 4
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract description 4
- 229910000160 potassium phosphate Inorganic materials 0.000 abstract description 4
- 235000011009 potassium phosphates Nutrition 0.000 abstract description 4
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract description 4
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract description 4
- 239000001120 potassium sulphate Substances 0.000 abstract description 4
- 235000011151 potassium sulphates Nutrition 0.000 abstract description 4
- 238000011156 evaluation Methods 0.000 abstract description 2
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 abstract 1
- 235000010338 boric acid Nutrition 0.000 abstract 1
- 235000011148 calcium chloride Nutrition 0.000 abstract 1
- 235000019797 dipotassium phosphate Nutrition 0.000 abstract 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 abstract 1
- 238000003306 harvesting Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229940111688 monobasic potassium phosphate Drugs 0.000 abstract 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 abstract 1
- 229940093916 potassium phosphate Drugs 0.000 abstract 1
- 229960004441 tyrosine Drugs 0.000 abstract 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 238000009472 formulation Methods 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 6
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- 210000000056 organ Anatomy 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
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- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 3
- 244000141359 Malus pumila Species 0.000 description 3
- 235000011430 Malus pumila Nutrition 0.000 description 3
- 235000015103 Malus silvestris Nutrition 0.000 description 3
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 3
- 229960002442 glucosamine Drugs 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 3
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- JLIDBLDQVAYHNE-YKALOCIXSA-N (+)-Abscisic acid Chemical compound OC(=O)/C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-YKALOCIXSA-N 0.000 description 2
- 241000167854 Bourreria succulenta Species 0.000 description 2
- 235000004936 Bromus mango Nutrition 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 235000016623 Fragaria vesca Nutrition 0.000 description 2
- 240000009088 Fragaria x ananassa Species 0.000 description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 2
- 240000004550 Hesperantha coccinea Species 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 240000007228 Mangifera indica Species 0.000 description 2
- 235000014826 Mangifera indica Nutrition 0.000 description 2
- 241000233855 Orchidaceae Species 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 235000009184 Spondias indica Nutrition 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 229930014669 anthocyanidin Natural products 0.000 description 2
- 150000001453 anthocyanidins Chemical class 0.000 description 2
- 235000008758 anthocyanidins Nutrition 0.000 description 2
- 238000002144 chemical decomposition reaction Methods 0.000 description 2
- 235000019693 cherries Nutrition 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 235000005489 dwarf bean Nutrition 0.000 description 2
- 125000003147 glycosyl group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- 229960001138 acetylsalicylic acid Drugs 0.000 description 1
- 235000010208 anthocyanin Nutrition 0.000 description 1
- 229930002877 anthocyanin Natural products 0.000 description 1
- 239000004410 anthocyanin Substances 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 230000002605 anti-dotal effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000006196 deacetylation Effects 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- FCRACOPGPMPSHN-UHFFFAOYSA-N desoxyabscisic acid Natural products OC(=O)C=C(C)C=CC1C(C)=CC(=O)CC1(C)C FCRACOPGPMPSHN-UHFFFAOYSA-N 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000008376 long-term health Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- YGGXZTQSGNFKPJ-UHFFFAOYSA-N methyl 2-naphthalen-1-ylacetate Chemical compound C1=CC=C2C(CC(=O)OC)=CC=CC2=C1 YGGXZTQSGNFKPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 150000002482 oligosaccharides Polymers 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
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- 230000037452 priming Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000024053 secondary metabolic process Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
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Claims (7)
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CN201210058562.2A CN102613198B (en) | 2012-03-07 | 2012-03-07 | Chitosan oligosaccharide agricultural composition for improving coloration of plants and application thereof and method by utilizing same to improve coloration of plants |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104649807A (en) * | 2013-11-21 | 2015-05-27 | 中国科学院大连化学物理研究所 | Chitosan oligosaccharide compound and application of chitosan oligosaccharide compound in relieving albino seedling of graminaceous crops |
CN105432343B (en) * | 2015-11-11 | 2018-03-23 | 长江大学 | A kind of application for the method and Genistein for improving ginkgo biloba flavonoid content |
CN105985179A (en) * | 2015-12-29 | 2016-10-05 | 芜湖市创源新材料有限公司 | Coloring promotion type special fertilizer for grapes |
CN107739250A (en) * | 2017-11-16 | 2018-02-27 | 潍坊友容实业有限公司 | Saline and alkaline region orchard functional form liquid fertilizer and preparation method thereof |
CN111018600A (en) * | 2019-12-15 | 2020-04-17 | 惠州学院 | Foliar fertilizer for improving anthocyanin content of litchi peels and preparation and use methods thereof |
CN111559937A (en) * | 2020-05-21 | 2020-08-21 | 潍坊真维农生物工程有限公司 | Biological activator for promoting fruit coloring and preparation method and application thereof |
CN114437250B (en) * | 2022-03-15 | 2023-07-04 | 内蒙古农业大学 | Chitosan oligosaccharide amino hydroxy propionamide derivative and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101305738A (en) * | 2007-05-18 | 2008-11-19 | 叶青 | Agricultural mixed formulation constituted by chitosan oligosaccharide or the like |
CN101462896A (en) * | 2008-11-06 | 2009-06-24 | 常大勇 | Leaf surface calcareous fertilizer |
CN102057906A (en) * | 2010-12-10 | 2011-05-18 | 常大勇 | Fruit coloring adjunct and method for promoting fruit coloring with same |
CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
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2012
- 2012-03-07 CN CN201210058562.2A patent/CN102613198B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101305738A (en) * | 2007-05-18 | 2008-11-19 | 叶青 | Agricultural mixed formulation constituted by chitosan oligosaccharide or the like |
CN101462896A (en) * | 2008-11-06 | 2009-06-24 | 常大勇 | Leaf surface calcareous fertilizer |
CN102057906A (en) * | 2010-12-10 | 2011-05-18 | 常大勇 | Fruit coloring adjunct and method for promoting fruit coloring with same |
CN102144637A (en) * | 2010-12-23 | 2011-08-10 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composite with cold-resistant function and application of composite |
Non-Patent Citations (4)
Title |
---|
具有农业生物活性壳寡糖的研究进展;刘幸海等;《农药学学报》;20060330;第8卷(第01期);1-7 * |
刘幸海等.具有农业生物活性壳寡糖的研究进展.《农药学学报》.2006,第8卷(第01期),1-7. |
花青素的生物合成和成色机理及提高其稳定性的途径;顾林等;《食品工业科技》;20071125;第28卷(第11期);240-243 * |
顾林等.花青素的生物合成和成色机理及提高其稳定性的途径.《食品工业科技》.2007,第28卷(第11期),240-243. |
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Denomination of invention: A chitooligosaccharide agricultural composition for improving plant coloring and its use and method Effective date of registration: 20201026 Granted publication date: 20140115 Pledgee: Qiongshan branch of Agricultural Development Bank of Haikou city China Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: Y2020980007201 |
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Denomination of invention: A chitosan oligosaccharide agricultural composition for improving plant coloring and its use and method Effective date of registration: 20231020 Granted publication date: 20140115 Pledgee: Industrial Bank Co.,Ltd. Haikou Branch Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: Y2023980062064 |
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