CN102605646B - Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste - Google Patents
Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste Download PDFInfo
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- CN102605646B CN102605646B CN201210027902.5A CN201210027902A CN102605646B CN 102605646 B CN102605646 B CN 102605646B CN 201210027902 A CN201210027902 A CN 201210027902A CN 102605646 B CN102605646 B CN 102605646B
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Abstract
The invention discloses a printing rubber paste for coating denim and a screen mesh printing method using the printing rubber paste. The printing rubber paste for coating denim comprises, by weight, a component A, a component B and a component C, the component A comprises 15-20 parts of an acrylate adhesive, 5-10 parts of a polyurethane adhesive, 0.5-0.8 parts of an emulsifier, 0.5-2 parts of a thickener, 0.3-0.8 parts of sodium methylene bis-naphthalene sulfonate and 0.5-1 part of a softener, the component B is a crosslinking agent with the weight parts of 0.5-3, and the component C is an assistant with the weight parts of 2-4, wherein the component C can destroy the water proof coating of the coating denim, the component A can be combined with the cloth cover fiber of the denim through the self-crosslinking of the component A, and the component B has an effect on the promotion of the bonding crosslinking of the component A to form a stable reticular structure. The printing rubber paste of the invention can be directly used to print the coating denim, and the good color fastness can be still obtained after washing and stone processing.
Description
Technical field
The present invention relates to textile industry printing technology, be specifically related to the printing and dyeing of denim, relate in particular to a kind of coating denim printing mortar, and the screen printing method of using this printing mortar to carry out coating denim.
Background technology
Coating denim is to be coated with film-forming macromolecular compound at denim surface uniform, make fabric change outward appearance, style or give various functions, for meeting the desired hydrophobicity of this coating, adopt polyacrylate PA coating agent and/or polyurethane PU coating agent more.
Conventional common denim printing mortar is water-based printing paste now, can be printed on and on non-coating denim, obtain good every COLOR FASTNESS, if but carry out stamp with common denim printing mortar on coating denim, because the existence of coating denim water proofing property coating, common denim printing mortar cannot be bonding with cloth cover fiber, the rubber cement epithelium of jeans stamp after the processing such as washing, stone mill can large area come off, and every COLOR FASTNESS is all extremely low.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide a kind of and can directly on coating denim, carry out stamp, and after processing, still can obtain the coating denim printing mortar of good every COLOR FASTNESS through washing, stone mill.
Another object of the present invention is to provide utilizes above-mentioned coating denim with printing mortar, coating denim to be carried out the screen printing method of stamp.
Above-mentioned purpose of the present invention is achieved by following scheme:
A denim printing mortar, its formula is meter by weight, these three components of component A, B component and component C, consists of, specific as follows:
(1) 15～20 parts of component A acrylic ester adhesives, 5～10 parts of polyurethane binder, 0.5～0.8 part of emulsifying agent, 0.5～2 part of thickener, 0.3～0.8 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate and softener are 0.5～1 part;
(2) B component crosslinking agent is 0.5～3 part;
(3) component C dimethyl sulfoxide (DMSO) is 2～4 parts.
The adhesive that can be used for textile printing can be divided into acrylate adhesive, butadiene type adhesive, vinylacetate class adhesive and polyurethane binding by its chemical constitution, selects acrylic ester adhesive and polyurethane binder in said components A; Described acrylate adhesive is methyl acrylate, methyl methacrylate, methylol methyl acrylate, hexyl acrylate or n-BMA etc., described polyurethane binding is PACESTTER LU-551, URA301G or UN20 etc., and described PACESTTER LU-551, URA301G or UN20 are commercially available trade name; In component A of the present invention, for the adhesive of COAT PRINTING, be mainly acrylic ester type, inventor can improve the feel of fabric by collocation polyurethane-type, makes it more soft comfortable.
In said components A, emulsifying agent adopts emulsifier op-10, emulsifying agent TX-10, emulsifying agent SOPE series or Emulsifier MOA series etc.
In said components A, thickener adopts thickener TLC-1, thickener 601A, thickener 701A, thickener BE903, thickener PT-669 or thickening agent PTF etc.
In said components A, softener adopts softener SF8800, softener HD-80, softener DL-AR, softener A D-HUP908 or softener sg etc.
In said components A, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate has been peptizaiton, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate be otherwise known as dispersant NNO or sodium metnylene bis-naphthalene sulfonate.
In said components B, crosslinking agent adopts crosslinking aid S aC-100, crosslinking agent K-106 or crosslinking agent LCA-DA etc.
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso, and this auxiliary agent can destroy in stamp process needs the coating denim at stamp position water proofing property coating, makes adhesive and the bonding film forming of denim cloth cover fiber, increases fastness.
Above-mentioned coating denim is by joining in ball mill after each material mixing in component A, obtaining component A after fully grinding and stirring and evenly mixing by the preparation method of component A in printing mortar, standby.
When above-mentioned coating denim is used with printing mortar, after being mixed, the component A preparing, B component and component C directly on coating denim, carry out stamp.
The inventor also provides a kind of screen printing method of using above-mentioned printing mortar to carry out coating denim, and this screen printing method is based on existing screen printing method, to half tone, scraper, scrape condition and color fixing condition is optimized as follows:
1. half tone
(1) adopt the T-shaped silk screen of monofilament polyester plain weave, its mesh is 80～100 order/inches;
(2) the net tension force that stretches tight is 20N/cm;
(3) adopt water-resistant type photoresists coating meshi fabric to form light sensitivity film, film thickness is 20 μ m;
2. scraper
Adopt polyurethane scraper, blade thickness is that 12mm, hardness are that 60 °, cutting edge are right angle;
3. scrape condition
The angle of scraper is that 75 °, pressure are 1.7kg/cm
2, the speed of service is 0.6m/s, scrape twice;
4 color fixing conditions
Stamp post-drying or air dry, dry 150 ℃ * 2min fixation through guide belt infrared drier heat.
Compared with prior art, the present invention has following beneficial effect:
1. coating denim of the present invention is comprised of component A, B component and tri-components of component C jointly with printing mortar, component C can destroy the coating that coating denim has water proofing property, then component A generation self-crosslinking is combined with denim cloth cover fiber, then B component plays and impels component A that the crosslinked action of better bonding occurs, form stable network structure, further improve its every COLOR FASTNESS.To needing the position of stamp to dissolve in advance waterproof coating, then row stamp form new waterproof coating.
2. coating denim of the present invention can directly carry out stamp with printing mortar on coating denim, and after processing, still can obtain good every COLOR FASTNESS through washing, stone mill.
The specific embodiment
Basic embodiment of the present invention is to provide a kind of coating denim printing mortar, and its formula is meter by weight, these three components of component A, B component and component C, consists of, specific as follows:
(1) 15～20 parts of component A acrylic ester adhesives, 5～10 parts of polyurethane binder, 0.5～0.8 part of emulsifying agent, 0.5～2 part of thickener, 0.3～0.8 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate and softener are 0.5～1 part;
(2) B component crosslinking agent is 0.5～3 part;
(3) component C dimethyl sulfoxide (DMSO) is 2～4 parts.
The adhesive that can be used for textile printing can be divided into acrylate adhesive, butadiene type adhesive, vinylacetate class adhesive and polyurethane binding by its chemical constitution, selects acrylic ester adhesive and polyurethane binder in said components A; Described acrylate adhesive is methyl acrylate, methyl methacrylate, methylol methyl acrylate, hexyl acrylate or n-BMA etc., described polyurethane binding is PACESTTER LU-551, URA301G or UN20 etc., and described PACESTTER LU-551, URA301G or UN20 are commercially available trade name; In component A of the present invention, for the adhesive of COAT PRINTING, be mainly acrylic ester type, inventor can improve the feel of fabric by collocation polyurethane-type, makes it more soft comfortable.
In said components A, emulsifying agent adopts emulsifier op-10, emulsifying agent TX-10, emulsifying agent SOPE series or Emulsifier MOA series etc.
In said components A, thickener adopts thickener TLC-1, thickener 601A, thickener 701A, thickener BE903, thickener PT-669 or thickening agent PTF etc.
In said components A, softener adopts softener SF8800, softener HD-80, softener DL-AR, softener A D-HUP908 or softener sg etc.
In said components A, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate has been peptizaiton, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate be otherwise known as dispersant NNO or sodium metnylene bis-naphthalene sulfonate.
In said components B, crosslinking agent adopts crosslinking aid S aC-100, crosslinking agent K-106 or crosslinking agent LCA-DA etc.
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso, and this auxiliary agent can destroy in stamp process needs the coating denim at stamp position water proofing property coating, makes adhesive and the bonding film forming of denim cloth cover fiber, increases fastness.
Below in conjunction with specific embodiment, the present invention is done further and described, but specific embodiment is not done any restriction to the present invention.
embodiment 1
The present embodiment coating denim printing mortar, its formula by weight meter, by these three components of component A, B component and component C, formed, specific as follows shown in:
(1) component A
15 parts of acrylic ester adhesives;
10 parts of polyurethane binder;
0.5 part of emulsifying agent;
2 parts of thickeners;
0.3 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate;
1 part of softener;
(2) B component
3 parts of crosslinking agents;
(3) component C
4 parts of dimethyl sulfoxide (DMSO) Dmso.
In said components A, acrylate adhesive adopts methyl acrylate;
In said components A, polyurethane binding adopts PACESTTER LU-551;
In said components A, emulsifying agent adopts emulsifier op-10;
In said components A, thickener adopts thickener 601A;
In said components A, softener adopts softener SF8800;
In said components B, crosslinking agent adopts crosslinking aid S aC-100;
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso.
No matter above-mentioned, be adhesive or emulsifying agent, thickener, softener, crosslinking agent etc., all can adopt two or more mixture, or a kind of single material.Generally, can not use two or more, to prevent the impact of compatible and chemical reaction.
Above-mentioned coating denim is by joining in ball mill after each material mixing in component A, obtaining component A after fully grinding and stirring and evenly mixing by the preparation method of component A in printing mortar, standby.
When the present embodiment coating denim is used with printing mortar, after being mixed, the component A preparing, B component and component C directly on coating denim, carry out stamp.
embodiment 2
The present embodiment coating denim printing mortar, its formula by weight meter, by these three components of component A, B component and component C, formed, specific as follows shown in:
(1) component A
20 parts of acrylic ester adhesives;
5 parts of polyurethane binder;
0.8 part of emulsifying agent;
0.5 part of thickener;
0.8 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate;
1 part of softener;
(2) B component
0.5 part of crosslinking agent;
(3) component C
3 parts of dimethyl sulfoxide (DMSO) Dmso.
In said components A, acrylate adhesive adopts methyl methacrylate and hexyl acrylate;
In said components A, polyurethane binding adopts PACESTTER LU-551;
In said components A, emulsifying agent adopts emulsifying agent TX-10;
In said components A, thickener adopts thickener TLC-1;
In said components A, softener adopts softener DL-AR;
In said components B, crosslinking agent adopts crosslinking aid S aC-100;
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso.
Above-mentioned coating denim is by joining in ball mill after each material mixing in component A, obtaining component A after fully grinding and stirring and evenly mixing by the preparation method of component A in printing mortar, standby.
When the present embodiment coating denim is used with printing mortar, after being mixed, the component A preparing, B component and component C directly on coating denim, carry out stamp.
embodiment 3
The present embodiment coating denim printing mortar, its formula by weight meter, by these three components of component A, B component and component C, formed, specific as follows shown in:
(1) component A
18 parts of acrylic ester adhesives;
6 parts of polyurethane binder;
0.7 part of emulsifying agent;
0.5 part of thickener;
0.5 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate;
0.5 part of softener;
(2) B component
2.5 parts of crosslinking agents;
(3) component C
2 parts of dimethyl sulfoxide (DMSO) Dmso.
In said components A, acrylate adhesive adopts n-BMA;
In said components A, polyurethane binding adopts UN20 and URA301G;
In said components A, emulsifying agent adopts emulsifier op-10 and emulsifying agent TX-10;
In said components A, thickener adopts thickener BE903 and thickener PT-669;
In said components A, softener adopts softener sg;
In said components B, crosslinking agent adopts crosslinking aid S aC-100 and crosslinking agent K-106;
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso.
Above-mentioned coating denim is by joining in ball mill after each material mixing in component A, obtaining component A after fully grinding and stirring and evenly mixing by the preparation method of component A in printing mortar, standby.
When the present embodiment coating denim is used with printing mortar, after being mixed, the component A preparing, B component and component C directly on coating denim, carry out stamp.
embodiment 4
The present embodiment coating denim printing mortar, its formula by weight meter, by these three components of component A, B component and component C, formed, specific as follows shown in:
(1) component A
16 parts of acrylic ester adhesives;
9 parts of polyurethane binder;
0.7 part of emulsifying agent;
1 part of thickener;
0.5 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate;
0.8 part of softener;
(2) B component
1.5 parts of crosslinking agents;
(3) component C
3.5 parts of dimethyl sulfoxide (DMSO) Dmso.
In said components A, acrylate adhesive adopts the mixture of methylol methyl acrylate, methyl acrylate and n-BMA;
In said components A, polyurethane binding adopts UN20;
In said components A, emulsifying agent adopts emulsifier op-10;
In said components A, thickener adopts thickening agent PTF;
In said components A, softener adopts softener A D-HUP908;
In said components B, crosslinking agent adopts crosslinking aid S aC-100;
In said components C, auxiliary agent is dimethyl sulfoxide (DMSO) Dmso.
Above-mentioned coating denim is by joining in ball mill after each material mixing in component A, obtaining component A after fully grinding and stirring and evenly mixing by the preparation method of component A in printing mortar, standby.
When the present embodiment coating denim is used with printing mortar, after being mixed, the component A preparing, B component and component C directly on coating denim, carry out stamp.
embodiment 5
With printing mortar, adopt identical screen printing method respectively coating denim to be carried out to stamp processing the coating denim of embodiment 1～4, described screen printing method is based on existing screen printing method, to half tone, scraper, scrape condition and color fixing condition is optimized as follows:
1. half tone
(1) adopt the T-shaped silk screen of monofilament polyester plain weave, its mesh is 80～100 order/inches;
(2) the net tension force that stretches tight is 20N/cm;
(3) adopt water-resistant type photoresists coating meshi fabric to form light sensitivity film, film thickness is 20 μ m;
2. scraper
Adopt polyurethane scraper, blade thickness is that 12mm, hardness are that 60 °, cutting edge are right angle;
3. scrape condition
The angle of scraper is that 75 °, pressure are 1.7kg/cm
2, the speed of service is 0.6m/s, scrape twice;
4 color fixing conditions
Stamp post-drying or air dry, dry 150 ℃ * 2min fixation through guide belt infrared drier heat.
After screen printing finishes, carry out performance test, result is as follows:
The coating denim of embodiment 1～4 all can directly carry out stamp with printing mortar on coating denim, and after washing, stone mill are processed, the rubber cement epithelium of stamp there will not be obscission, still can obtain good every COLOR FASTNESS.
Claims (3)
1. a coating denim printing mortar, this coating denim is counted by weight with the formula of printing mortar, three large component A, B and C, consists of, specific as follows:
(1) component A
15～20 parts of acrylic ester adhesives;
5～10 parts of polyurethane binder;
0.5～0.8 part of emulsifying agent;
0.5～2 part of thickener;
0.3～0.8 part of dispersant;
0.5～1 part of softener;
(2) B component
0.5～3 part of crosslinking agent;
(3) component C
2～4 parts of dimethyl sulfoxide (DMSO)s;
Wherein, in described A component, acrylic ester adhesive is methyl acrylate, methyl methacrylate, methylol methyl acrylate, hexyl acrylate or n-BMA;
Described polyurethane binder is PACESTTER LU-551, URA301G or UN20;
Described emulsifying agent is emulsifier op-10, emulsifying agent TX-10, emulsifying agent SOPE series or Emulsifier MOA series;
Described thickener is thickener 601A, thickener 701A, thickener BE903, thickener PT-669 or thickening agent PTF;
Described dispersant is dispersant NNO, MS, NUOSPERSE FA196, LBD-1;
Described softener is softener SF8800, softener HD-80, softener DL-AR, softener A D-HUP908 or softener sg, and described crosslinking agent is crosslinking aid S aC-100, crosslinking agent K-106 or crosslinking agent LCA-DA.
2. a screen printing method, is characterized in that this screen printing method is to adopt printing mortar described in claim 1 to carry out screen printing to coating denim.
3. a kind of screen printing method according to claim 2, is characterized in that each parameter of described screen printing is as follows:
(1) half tone adopts the T-shaped silk screen of monofilament polyester plain weave, and its mesh is 80～100 order/inches;
(2) the net tension force that stretches tight is 20N/cm;
(3) adopt water-resistant type photoresists coating meshi fabric to form light sensitivity film, film thickness is 20 μ m;
(4) adopt polyurethane scraper, blade thickness is that 12mm, hardness are that 60 °, cutting edge are right angle;
(5) angle of scraper is that 75 °, pressure are 1.7kg/cm
2, the speed of service is 0.6m/s, scrape twice;
(6) stamp post-drying or air dry, dry 150 ℃ * 2min fixation through guide belt infrared drier heat.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210027902.5A CN102605646B (en) | 2012-02-09 | 2012-02-09 | Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210027902.5A CN102605646B (en) | 2012-02-09 | 2012-02-09 | Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste |
Publications (2)
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| CN102605646A CN102605646A (en) | 2012-07-25 |
| CN102605646B true CN102605646B (en) | 2014-01-15 |
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| CN103082537B (en) * | 2013-01-31 | 2016-01-20 | 青岛海森林进出口有限公司 | A kind of method of impressing pattern on wig |
| CN104060484B (en) * | 2014-06-11 | 2016-01-20 | 周文叶 | A kind of color-fixing agent for nylon carpet digit printing and application thereof |
| CN104532609B (en) * | 2014-12-11 | 2017-01-25 | 江门市宝发纺织服饰制造有限公司 | Printing paste for locking jeans elasticity and preventing bleaching and application thereof |
| CN108642928A (en) * | 2018-05-14 | 2018-10-12 | 广州市创兴服装集团有限公司 | A kind of technique that jeans wear away quality |
| CN108625204A (en) * | 2018-06-05 | 2018-10-09 | 吴文广 | A kind of denim stamp black color paste |
| CN109440500B (en) * | 2018-10-31 | 2020-12-29 | 潢川县圣宇服饰科技有限公司 | High-definition screen printing process and application thereof in composite fabric printing |
| CN112144305A (en) * | 2019-09-16 | 2020-12-29 | 滨州亚光家纺有限公司 | Carving three-dimensional printing method for towel |
| CN110699981A (en) * | 2019-10-22 | 2020-01-17 | 徐州双辰服饰有限公司 | Printing adhesive cement for coating of jeans |
| CN113897802A (en) * | 2021-10-15 | 2022-01-07 | 泗县恒星烫画机械股份有限公司 | Water-based printing adhesive cement and preparation method thereof |
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Effective date of registration: 20151016 Address after: 523000 third industrial zone, Hongmei Town, Guangdong, Dongguan Patentee after: DONGGUAN TONGLING NEW NANOMETER MATERIAL TECHNOLOGY CO., LTD. Address before: 523045 Guangdong province Dongguan City Wanjiang Xian Yong community Haikou Road No. 62 Patentee before: Dongguan Tianlong Chemical Industry Co., Ltd. |
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Address after: 523000 Guangdong city of Dongguan Province Hong Mei Town Industrial Zone Third Patentee after: DONGGUAN TONGLING NEW NANOMETER MATERIAL TECHNOLOGY CO., LTD. Address before: 523000 third industrial zone, Hongmei Town, Guangdong, Dongguan Patentee before: DONGGUAN TONGLING NEW NANOMETER MATERIAL TECHNOLOGY CO., LTD. |
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