CN108625204A - A kind of denim stamp black color paste - Google Patents
A kind of denim stamp black color paste Download PDFInfo
- Publication number
- CN108625204A CN108625204A CN201810567728.0A CN201810567728A CN108625204A CN 108625204 A CN108625204 A CN 108625204A CN 201810567728 A CN201810567728 A CN 201810567728A CN 108625204 A CN108625204 A CN 108625204A
- Authority
- CN
- China
- Prior art keywords
- parts
- denim
- alkyl betaines
- epoxy resin
- carbon dust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of denim stamp black color pastes, include the component of following parts by weight：10~15 parts of carbon dust；25~30 parts of cycloaliphatic epoxy resin；20~30 parts of urea；1~3 part of N alkyl betaines, 1 part of auxiliary agent.N alkyl betaines have good wetability, can fully soak carbon dust；The carboxyl anion and cycloaliphatic epoxy resin stable bond contained by N alkyl betaines, cycloaliphatic epoxy resin with the N alkyl betaines on wetting carbon dust surface by being combined, it is equivalent to the surface that cycloaliphatic epoxy resin fully coats carbon dust, improves the bond strength of cycloaliphatic epoxy resin and carbon dust；In addition, N alkyl betaines have lower viscosity, N alkyl betaines to be combined to form dicyandiamide solution with urea, preferable dip dyeing ability is furnished with to cowboy, to improve adhesive force of the dyestuff on denim.
Description
Technical field
The invention belongs to garment industries, and in particular to a kind of denim stamp black color paste.
Background technology
Coating denim is so that fabric is changed outer in the film-forming high-molecular compound of denim surface even spread
See, style or assign various functions, for the hydrophobicity for meeting required by the coating, mostly use polyacrylate PA coating agents and/
Or polyurethane PU coating agent.
Existing frequently-used common denim printing mortar is aqueous printing paste, can be printed on non-coating denim and obtain
Items color fastness well, if but stamp is carried out on coating denim with common denim printing mortar, because of coating cowboy
It deploys troops on garrison duty the presence of aqueous coating, common denim printing mortar can not be bonded with cloth cover fiber, and jeans are by washing, stone mill
Deng processing after stamp rubber cement epithelium can large area fall off, every color fastness is all extremely low.
In conclusion there is an urgent need for a kind of denim stamp black color pastes of strong adhesive force.
Invention content
For overcome the deficiencies in the prior art, the present invention provides a kind of denim stamp black color paste of strong adhesive force.
To solve the above problems, the technical solution adopted in the present invention is as follows：
A kind of denim stamp black color paste, includes the component of following parts by weight：10~15 parts of carbon dust；Alicyclic epoxy
25~30 parts of resin；20~30 parts of urea；1~3 part of N- alkyl betaines, 1 part of auxiliary agent.
Preferably, the auxiliary agent includes thickener, and the thickener is polyurethane thickener.
The molding solid degree of stamp, the molecule hydrophobic side in polyurethane thickener and carbon are improved by polyurethane thickener
Powder, N- alkyl betaines associate to be formed it is solid netted, to improve the wash durability of thickening agent.
Preferably, the cycloaliphatic epoxy resin is 3,4- epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates.
There are two epoxy groups for 3,4- epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates tool, enhance itself and N- alkane
The bond strength of base glycine betaine, to improve the knot of 3,4- epoxycyclohexyl-methyls -3,4- epoxycyclohexylcarboxylate and carbon dust
Close intensity.
Preferably, the denim stamp black color paste includes the component of following parts by weight：13 parts of carbon dust；Aliphatic ring
25 parts of oxygen resin；30 parts of urea；3 parts of N- alkyl betaines, 1 part of auxiliary agent.
The adhesive force of the denim stamp black color paste of the proportioning is most strong.
The beneficial effect of the present invention：N- alkyl betaines have good wetability, can fully soak carbon dust；Pass through N-
Carboxyl anion that alkyl betaine contains and cycloaliphatic epoxy resin stable bond, cycloaliphatic epoxy resin by with wetting carbon
The N- alkyl betaines on powder surface combine, and are equivalent to the surface that cycloaliphatic epoxy resin fully coats carbon dust, improve aliphatic ring
The bond strength of oxygen resin and carbon dust；In addition, N- alkyl betaines have lower viscosity, N- alkyl betaines and urea combination shape
At dicyandiamide solution, preferable dip dyeing ability is furnished with to cowboy, to improve adhesive force of the dyestuff on denim.
Specific implementation mode
Invention is further described in detail With reference to embodiment.
Embodiment 1
Denim stamp black color paste provided in this embodiment includes the component of following parts by weight：13 parts of carbon dust；3,4-
25 parts of epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates；30 parts of urea；3 parts of N- alkyl betaines, polyurethane thickener
1 part.
Sample friction head reciprocating linear friction calculates Rubbing number when dyestuff film layer falls off, and the results are shown in Table 1.
Rub area of bed：Rectangle 19mm × 25mm；Friction head pressure at right angle：9N；Traverse：100mm；Friction velocity：60
Secondary/min；Denim specification：200mm×50mm.
Embodiment 2
Denim stamp black color paste provided in this embodiment includes the component of following parts by weight：10 parts of carbon dust；3,4-
30 parts of epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates；20 parts of urea；1 part of N- alkyl betaines, polyurethane thickener
1 part.
Sample friction head reciprocating linear friction calculates Rubbing number when dyestuff film layer falls off, and the results are shown in Table 1.
Rub area of bed：Rectangle 19mm × 25mm；Friction head pressure at right angle：9N；Traverse：100mm；Friction velocity：60
Secondary/min；Denim specification：200mm×50mm.
Embodiment 3
Denim stamp black color paste provided in this embodiment includes the component of following parts by weight：15 parts of carbon dust；3,4-
25 parts of epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates；25 parts of urea；3 parts of N- alkyl betaines, polyurethane thickener
1 part.
Sample friction head reciprocating linear friction calculates Rubbing number when dyestuff film layer falls off, and the results are shown in Table 1.
Rub area of bed：Rectangle 19mm × 25mm；Friction head pressure at right angle：9N；Traverse：100mm；Friction velocity：60
Secondary/min；Denim specification：200mm×50mm.
Embodiment 4
Denim stamp black color paste provided in this embodiment includes the component of following parts by weight：13 parts of carbon dust；3,4-
25 parts of 3,4- 7-oxa-bicyclo[4.1.0s carboxylate methyl ester；30 parts of urea；3 parts of N- alkyl betaines, 1 part of polyurethane thickener.
Sample friction head reciprocating linear friction calculates Rubbing number when dyestuff film layer falls off, and the results are shown in Table 1.
Rub area of bed：Rectangle 19mm × 25mm；Friction head pressure at right angle：9N；Traverse：100mm；Friction velocity：60
Secondary/min；Denim specification：200mm×50mm.
Comparative example
Denim stamp black color paste provided in this embodiment includes the component of following parts by weight：13 parts of carbon dust；Bisphenol-A
25 parts of epoxy resin；30 parts of urea；3 parts of N- alkyl betaines, 1 part of polyurethane thickener.
Sample friction head reciprocating linear friction calculates Rubbing number when dyestuff film layer falls off, and the results are shown in Table 1.
Rub area of bed：Rectangle 19mm × 25mm；Friction head pressure at right angle：9N；Traverse：100mm；Friction velocity：60
Secondary/min；Denim specification：200mm×50mm.
Table 1
| Project | Rubbing number |
| Embodiment 1 | 674 |
| Embodiment 2 | 381 |
| Embodiment 3 | 378 |
| Embodiment 4 | 266 |
| Comparative example | 173 |
Each technical characteristic of above example can be combined arbitrarily, to keep description succinct, not to above-described embodiment
In each technical characteristic it is all possible combination be all described, as long as however, the combination of these technical characteristics be not present lance
Shield is all considered to be the range of this specification record.
Only several embodiments of the present invention are expressed for above example, the description thereof is more specific and detailed, but can not
Therefore it is construed as limiting the scope of the patent.It should be pointed out that for those of ordinary skill in the art,
Under the premise of not departing from present inventive concept, various modifications and improvements can be made, these are all within the scope of protection of the present invention.
Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (4)
1. a kind of denim stamp black color paste, which is characterized in that include the component of following parts by weight：10~15 parts of carbon dust；
25~30 parts of cycloaliphatic epoxy resin；20~30 parts of urea；1~3 part of N- alkyl betaines, 1 part of auxiliary agent.
2. denim stamp black color paste according to claim 1, which is characterized in that the auxiliary agent includes thickener, institute
It is polyurethane thickener to state thickener.
3. denim stamp black color paste according to claim 1 or 2, which is characterized in that the cycloaliphatic epoxy resin
For 3,4- epoxycyclohexyl-methyl -3,4- epoxycyclohexylcarboxylates.
4. denim stamp black color paste according to claim 1, which is characterized in that the denim stamp black color paste
Include the component of following parts by weight：13 parts of carbon dust；25 parts of cycloaliphatic epoxy resin；30 parts of urea；3 parts of N- alkyl betaines,
1 part of auxiliary agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810567728.0A CN108625204A (en) | 2018-06-05 | 2018-06-05 | A kind of denim stamp black color paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810567728.0A CN108625204A (en) | 2018-06-05 | 2018-06-05 | A kind of denim stamp black color paste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108625204A true CN108625204A (en) | 2018-10-09 |
Family
ID=63691183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810567728.0A Pending CN108625204A (en) | 2018-06-05 | 2018-06-05 | A kind of denim stamp black color paste |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108625204A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605646A (en) * | 2012-02-09 | 2012-07-25 | 东莞市天龙化工实业有限公司 | Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste |
| CN106948191A (en) * | 2017-03-30 | 2017-07-14 | 绍兴市天基印刷材料厂 | The black printed slurries of SM |
| CN107059425A (en) * | 2016-12-23 | 2017-08-18 | 句容市申兔工艺针织厂 | A kind of preparation method and applications of ink-jet printing ink composition suitable for tricot de laine |
-
2018
- 2018-06-05 CN CN201810567728.0A patent/CN108625204A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605646A (en) * | 2012-02-09 | 2012-07-25 | 东莞市天龙化工实业有限公司 | Printing rubber paste for coating denim and screen mesh printing method using printing rubber paste |
| CN107059425A (en) * | 2016-12-23 | 2017-08-18 | 句容市申兔工艺针织厂 | A kind of preparation method and applications of ink-jet printing ink composition suitable for tricot de laine |
| CN106948191A (en) * | 2017-03-30 | 2017-07-14 | 绍兴市天基印刷材料厂 | The black printed slurries of SM |
Non-Patent Citations (1)
| Title |
|---|
| 文水平等: "毛用固色剂HK的合成及应用", 《毛纺科技》 * |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181009 |