CN102603950A - 一种低分子高活性聚异丁烯制备方法 - Google Patents
一种低分子高活性聚异丁烯制备方法 Download PDFInfo
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- CN102603950A CN102603950A CN201210057388XA CN201210057388A CN102603950A CN 102603950 A CN102603950 A CN 102603950A CN 201210057388X A CN201210057388X A CN 201210057388XA CN 201210057388 A CN201210057388 A CN 201210057388A CN 102603950 A CN102603950 A CN 102603950A
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- catalyst
- iso
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- raw material
- butylene
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- 229920002367 Polyisobutene Polymers 0.000 title claims abstract description 35
- 230000000694 effects Effects 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003054 catalyst Substances 0.000 claims abstract description 35
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 35
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000002861 polymer material Substances 0.000 claims abstract description 10
- 239000011552 falling film Substances 0.000 claims abstract description 4
- 239000010408 film Substances 0.000 claims abstract description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 30
- 229910015900 BF3 Inorganic materials 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 150000001993 dienes Chemical class 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000004523 catalytic cracking Methods 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- -1 alkyl diol Chemical class 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 238000005336 cracking Methods 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000012442 inert solvent Substances 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 6
- 238000005292 vacuum distillation Methods 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000000379 polymerizing effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000012805 post-processing Methods 0.000 description 7
- 239000008139 complexing agent Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (7)
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CN 201210057388 CN102603950B (zh) | 2012-03-07 | 2012-03-07 | 一种低分子高活性聚异丁烯制备方法 |
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CN 201210057388 CN102603950B (zh) | 2012-03-07 | 2012-03-07 | 一种低分子高活性聚异丁烯制备方法 |
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CN102603950A true CN102603950A (zh) | 2012-07-25 |
CN102603950B CN102603950B (zh) | 2013-11-06 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105324399A (zh) * | 2013-06-05 | 2016-02-10 | 大林产业株式会社 | 制备具有多种分子量的聚丁烯的装置和方法 |
CN108368197A (zh) * | 2015-12-17 | 2018-08-03 | Jxtg能源株式会社 | 丁烯聚合物的制造方法 |
CN114369180A (zh) * | 2021-12-23 | 2022-04-19 | 浙江信汇新材料股份有限公司 | 一种制备高品质聚异丁烯的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1353122A (zh) * | 2000-11-03 | 2002-06-12 | 中国石油天然气股份有限公司 | 高反应活性聚异丁烯的制备方法 |
CN1412210A (zh) * | 2001-10-12 | 2003-04-23 | 中国石油天然气股份有限公司 | 低分子量、高活性聚异丁烯的制备方法 |
CN101921352A (zh) * | 2010-09-28 | 2010-12-22 | 潍坊滨海石油化工有限公司 | 一种低分子量高活性聚异丁烯的生产方法 |
-
2012
- 2012-03-07 CN CN 201210057388 patent/CN102603950B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1353122A (zh) * | 2000-11-03 | 2002-06-12 | 中国石油天然气股份有限公司 | 高反应活性聚异丁烯的制备方法 |
CN1412210A (zh) * | 2001-10-12 | 2003-04-23 | 中国石油天然气股份有限公司 | 低分子量、高活性聚异丁烯的制备方法 |
CN101921352A (zh) * | 2010-09-28 | 2010-12-22 | 潍坊滨海石油化工有限公司 | 一种低分子量高活性聚异丁烯的生产方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105324399A (zh) * | 2013-06-05 | 2016-02-10 | 大林产业株式会社 | 制备具有多种分子量的聚丁烯的装置和方法 |
JP2016526091A (ja) * | 2013-06-05 | 2016-09-01 | テリム インダストリアル カンパニー リミテッド | 多様な分子量を有するポリブテンの製造装置および方法 |
CN105324399B (zh) * | 2013-06-05 | 2017-09-08 | 大林产业株式会社 | 制备具有多种分子量的聚丁烯的装置和方法 |
US9862784B2 (en) | 2013-06-05 | 2018-01-09 | Daelim Industrial Co., Ltd. | Apparatus and method for preparing polybutene having various molecular weights |
CN108368197A (zh) * | 2015-12-17 | 2018-08-03 | Jxtg能源株式会社 | 丁烯聚合物的制造方法 |
CN108368197B (zh) * | 2015-12-17 | 2020-09-22 | Jxtg能源株式会社 | 丁烯聚合物的制造方法 |
US11008409B2 (en) | 2015-12-17 | 2021-05-18 | Eneos Corporation | Method for producing butene polymer |
CN114369180A (zh) * | 2021-12-23 | 2022-04-19 | 浙江信汇新材料股份有限公司 | 一种制备高品质聚异丁烯的方法 |
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CN102603950B (zh) | 2013-11-06 |
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Address after: 250400 No. 6, Nanyuan street, Pingyin Industrial Park, Pingyin County, Ji'nan, Shandong Patentee after: SHANDONG HONGRUI NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 250400 Shandong Pingyin Industrial Park, Pingyin County, Ji'nan, Shandong Patentee before: Shandong Hongrui Petroleum Chemical Co.,Ltd. |
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