CN102599177A - Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid - Google Patents
Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid Download PDFInfo
- Publication number
- CN102599177A CN102599177A CN2012100546651A CN201210054665A CN102599177A CN 102599177 A CN102599177 A CN 102599177A CN 2012100546651 A CN2012100546651 A CN 2012100546651A CN 201210054665 A CN201210054665 A CN 201210054665A CN 102599177 A CN102599177 A CN 102599177A
- Authority
- CN
- China
- Prior art keywords
- tea saponin
- apg
- humic acid
- composition
- nereistoxin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000001397 quillaja saponaria molina bark Substances 0.000 title claims abstract description 27
- 229930182490 saponin Natural products 0.000 title claims abstract description 27
- 150000007949 saponins Chemical class 0.000 title claims abstract description 27
- 239000002917 insecticide Substances 0.000 title claims abstract description 24
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 title claims abstract description 18
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229940095100 fulvic acid Drugs 0.000 title claims abstract description 18
- 239000002509 fulvic acid Substances 0.000 title claims abstract description 18
- -1 alkyl glycoside Chemical class 0.000 title claims abstract description 13
- 241001122767 Theaceae Species 0.000 title abstract 4
- 229930182470 glycoside Natural products 0.000 title abstract 4
- 239000000575 pesticide Substances 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 25
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004021 humic acid Substances 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 17
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims abstract description 7
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 claims abstract description 6
- UGTHTQWIQKEDEH-BQBZGAKWSA-N L-alanyl-L-prolylglycine zwitterion Chemical compound C[C@H](N)C(=O)N1CCC[C@H]1C(=O)NCC(O)=O UGTHTQWIQKEDEH-BQBZGAKWSA-N 0.000 claims description 23
- 230000000361 pesticidal effect Effects 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 18
- 241000243812 Arenicola marina Species 0.000 claims description 17
- 239000003053 toxin Substances 0.000 claims description 17
- 231100000765 toxin Toxicity 0.000 claims description 17
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 claims description 11
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 238000013268 sustained release Methods 0.000 claims description 3
- 239000012730 sustained-release form Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 239000003094 microcapsule Substances 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 239000004549 water soluble granule Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 abstract description 5
- 241000500437 Plutella xylostella Species 0.000 description 11
- 239000003905 agrochemical Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 102000015296 acetylcholine-gated cation-selective channel activity proteins Human genes 0.000 description 1
- 108040006409 acetylcholine-gated cation-selective channel activity proteins Proteins 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 150000002632 lipids Chemical group 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000012771 pancakes Nutrition 0.000 description 1
- 150000002966 pentacyclic triterpenoids Chemical class 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000003568 synaptosome Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid, in particular to an insecticidal composition capable of reducing the resistance to nereistoxin pesticide. The insecticidal composition comprises the tea saponin, the alkyl glycoside, humic acid substances and the nereistoxin insecticide, wherein the weight ratio of the tea saponin to the alkyl glycoside to the humic acid substances to the nereistoxin insecticide is (30-50):(5-10):(1-5):(50-100). The insecticidal composition can reduce the resistance to the nereistoxin pesticide, and by application of the insecticidal composition, the problem that the pesticides such as monosultap and bisultap give rise to on agricultural application is solved.
Description
Technical field
The present invention relates to a kind of sandworm toxin insecticide that contains Tea Saponin, APG and fulvic acid, particularly, relate to a kind of sandworm toxin insecticide that improves pesticide efficacy and reduce residue of pesticide.
Background technology
Neires toxin (nereistoxin) insecticide is the bionical insecticide of a kind of novel organic synthesis that the sixties in 20th century, exploitation was risen; Belong to the nAChR inhibitor; Act on the neural synaptosome of insect, make insect nerve impulse be hampered by the cynapse position and final death.Sandworm toxin insecticide has characteristics such as wide spectrum, efficient, low toxicity; And the mode of action is various; Except that having very strong stomach poison function; Tag in addition, food refusal and systemic action, Lepidoptera, coleoptera and dipterous various pests are had the better prevention effect, be widely used in the control of insect on the multiple kinds of crops such as paddy rice, fruit and vegetables at present.
But because a large amount of uses of nereistoxin pesticide, and the frequency of using is too high, causes nereistoxin pesticide on insect, to produce pesticide resistance, can reach there not being the control efficiency of resistant insect after having only a large amount of use nereistoxin pesticides.So the resistance problem of nereistoxin pesticide has limited the long-term use of nereistoxin pesticide.
For solving the problems of the technologies described above, the invention provides a kind of insecticide that can reduce the nereistoxin pesticide resistance.
Summary of the invention
For solving the problems of the technologies described above; The invention provides a kind of Pesticidal combination that can reduce the nereistoxin pesticide resistance; Said composition comprises Tea Saponin, APG, humic acid substance and sandworm toxin insecticide, and wherein the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30-50: 5-10: 1-5: 50-100.
Tea Saponin (Teasaponia) is a kind of pentacyclic triterpenoid that extracts in the tea-seed pancake.It is a kind of natural nonionic surface active agent of function admirable.Tea Saponin is mainly used in wettable powder as fields such as wetting agent, vegetable insecticide and bactericide, plant growth regulations on pesticide industry.
APG (APG) is a kind of green, gentleness, nontoxic new non-ionic surfactants.This product is a base stock with natural fatty alcohol, glucose or starch, and through catalytic reaction, dehydrating condensation forms.The APG excellent performance, surface tension is low, strong detergency, foam is abundant, fine and smooth and stable, and is non-stimulated to human body skin, the ability complete biodegradable, production process is environmentally safe also, has the numerous characteristics of nonionic and anion surfactant concurrently.。
Humic acid substance (HA) is a kind of amorphous big minute subclass polymer; It is by the similar same clan, molecular size difference, the complex mixture that structure is inconsistent, the aromatic condensed ring condensation level different, the different polysubstituted high molecular weight hydroxy aromatic carboxylic acids of substitution value is formed.HA mainly contains the effect of agricultural chemicals: to the sustained-release synergistic effect of agricultural chemicals; Reduce the agricultural chemicals decomposition rate, improve agricultural chemicals stability; Solubilization to agricultural chemicals; Reduce toxicity of pesticide; Suction-operated to agricultural chemicals;
Fulvic acid (fulvic acid) is called for short FA, is that the level that the humic acid substance kind had not only dissolved in acid but also dissolved in the alkaline aqueous solution is divided, and the FA molecular weight is less relatively, lipid structure and to contain the oxygen functional group more.
In the above-mentioned Pesticidal combination, preferred, the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30-40: 8-10: 1-5: 50-90.Especially preferred, the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30: 10: 5: 55, or 35: 10: 5: 90, or 42: 8: 2: 68.
In the above-mentioned Pesticidal combination, preferred, humic acid substance (HA) is ulmic acid, humic acid and/or fulvic acid, and is especially preferred, and humic acid substance is a fulvic acid.
In the above-mentioned Pesticidal combination, preferred, APG is APG class material arbitrarily.
In the above-mentioned Pesticidal combination, sandworm toxin insecticide is one or more in cartap, desinsection peace, dimehypo, monosultap ammonium, thiocyclam, desinsection list, bensultap, the polythiane.
Above-mentioned Pesticidal combination of the present invention can be prepared into wetting powder, sustained release agent, pulvis, micro-capsule suspension, can disperse in dense dose, seed treatment emulsion, aqueous emulsion, big granula, granule, microemulsion, oil-suspending agent, finish, the seed with coated pesticidal, suspension emulsion, water-soluble granule, soluble thick agent, water-dispersible granules any one.
Used Tea Saponin, APG, humic acid substance, sandworm toxin insecticide, especially fulvic acid among the present invention are the conventional substances that can buy on the market, do not have special qualification.
Above-mentioned Pesticidal combination of the present invention is the Pesticidal combination that can reduce the nereistoxin pesticide resistance, uses said composition, has overcome agricultural chemicals such as desinsection list, dimehypo, cartap and on agricultural, has used the problem that produces resistance.
Embodiment
In order to understand the present invention, further specify the present invention with embodiment below, but do not limit the present invention.
Embodiment 1 thiocyclam Pesticidal combination
Get Tea Saponin 30kg, APG 10kg, fulvic acid 5kg, thiocyclam 55kg fully mixes, and gets the thiocyclam Pesticidal combination.Said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, promptly get 30% thiocyclam aqueous emulsion.
Embodiment 2 desinsection list Pesticidal combinations
Get Tea Saponin 35kg, APG 10kg, fulvic acid 5kg, desinsection list 90kg fully mixes, and gets desinsection list Pesticidal combination.Said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, promptly get 25% desinsection list aqueous emulsion
Embodiment 3 cartap Pesticidal combinations
Get Tea Saponin 42kg, APG 8kg, fulvic acid 2kg, cartap 68kg fully mixes, and gets the cartap Pesticidal combination.Said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, promptly get 35% cartap aqueous emulsion
Embodiment 4 Pesticidal combination effect embodiment
30% thiocyclam aqueous emulsion with embodiment 1; The 25% desinsection list aqueous emulsion of embodiment 2; The 35% cartap aqueous emulsion of embodiment 3 respectively with 50% thiocyclam soluble powder (market purchase), the former powder of 90% desinsection list (market purchase), 50% cartap soluble powder (market purchase) experimentizes contrast.Tested object is a diamond-back moth, and diamond-back moth has produced pesticide resistance through the resistance domestication of nereistoxin pesticide to nereistoxin pesticide.The pesticide resistance rank is not confirmed.Measure conventional pesticide kind (as above the kind that obtains is bought in market) and prepare aqueous emulsion through field experiment and compare by component of the present invention; Control efficiency (dead diamond-back moth accounts for the percentage of diamond-back moth total amount) diamond-back moth is the situation more than 90%; The consumption situation of average every mu of used active ingredient is because control efficiency is difficult to accurately regulate through pesticide dosage, according to the control efficiency of expection; The adjustment dosage was measured actual insect killing effect then after 10 days.The condition of field experiment is identical with insecticide-applying way.Be spraying, former powder is prepared into the missible oil spraying.
In this experiment; The dosage of using 50% commercially available thiocyclam soluble powder, the former powder of 90% desinsection list, 50% cartap soluble powder does not have the maximum dosage under the situation of resistance also to improve 15% dosage according to the hypothesis diamond-back moth; Even like this; The control efficiency of its antagonism diamond-back moth still is difficult to reach fully control, and the aqueous emulsion that the Pesticidal combination of embodiment of the invention 1-3 prepares, and has reduced according to the routine administration amount under the situation of about 10% dosage; Still obtained the approaching effect of control fully; The dosage of thiocyclam aqueous emulsion and desinsection list aqueous emulsion still is that some is too high, can also reduce some dosages more fully, also can reach the control efficiency of antagonism diamond-back moth.
The present invention adopts Tea Saponin, APG, fulvic acid to mix the pesticide resistance problem that can solve such agricultural chemicals effectively with sandworm toxin insecticide thus, solves a drug-fast difficult problem, has obtained unexpected effect.
Embodiment 5 other Pesticidal combination effects embodiment
Prepare the aqueous emulsion of desinsection peace, dimehypo, monosultap ammonium, bensultap, polythiane according to the equivalent way of embodiment 1-3; Carry out embodiment 4 described resistance comparative trials then; The conclusion that obtains is; Through the composition pesticide that Tea Saponin, APG, fulvic acid are mixed with desinsection peace, dimehypo, monosultap ammonium, bensultap, polythiane; Antagonistic diamond-back moth can have good control efficiency under the situation that dosage reduces; Concrete condition is that the desinsection peace reduction dosage 12% of the formulation of application implementation example 2, dimehypo reduction dosage 7%, monosultap ammonium reduction dosage 15%, bensultap reduce dosage 6%, polythiane reduces dosage 15%, can reach the effect of conventional pesticide dosage.
Embodiment 6 comparative trials
Because Tea Saponin has insecticidal effect; Therefore the composition of the APG among the embodiment 1-3, fulvic acid is removed; The amount that deducts is added on the Tea Saponin, adds conventional emulsifier then, solvent prepares aqueous emulsion, finds; The mixture of desinsection list, cartap, thiocyclam and Tea Saponin does not reach the good result of preventing and treating the resistance diamond-back moth, and dosage still will increase the control efficiency that can reach expection.So realizing preventing and treating the resistance diamond-back moth is not to have increased other a kind of Tea Saponin with weak sandworm property to realize.Also need Tea Saponin, APG, fulvic acid to prepare composition and can realize good effect with the nereistoxin pesticide proportioning.
Claims (6)
1. Pesticidal combination that can reduce the nereistoxin pesticide resistance; Said composition comprises Tea Saponin, APG, humic acid substance and sandworm toxin insecticide, and wherein the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30-50: 5-10: 1-5: 50-100.
2. according to the said composition of claim 1, wherein the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30-40: 8-10: 1-5: 50-90.
3. composition according to claim 2, wherein the weight ratio of Tea Saponin, APG, humic acid substance and sandworm toxin insecticide is 30: 10: 5: 55, or 35: 10: 5: 90, or 42: 8: 2: 68.
4. according to each described composition of claim 1-4, wherein humic acid substance is ulmic acid, humic acid and/or fulvic acid, is preferably fulvic acid.
5. according to each described composition of claim 1-4, wherein sandworm toxin insecticide is one or more in cartap, desinsection peace, dimehypo, monosultap ammonium, thiocyclam, desinsection list, bensultap, the polythiane.
6. according to each described composition of claim 1-4, said composition can be prepared into wetting powder, sustained release agent, pulvis, micro-capsule suspension, can disperse in dense dose, seed treatment emulsion, aqueous emulsion, big granula, granule, microemulsion, oil-suspending agent, finish, the seed with coated pesticidal, suspension emulsion, water-soluble granule, soluble thick agent, water-dispersible granules any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210054665.1A CN102599177B (en) | 2012-03-05 | 2012-03-05 | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210054665.1A CN102599177B (en) | 2012-03-05 | 2012-03-05 | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102599177A true CN102599177A (en) | 2012-07-25 |
| CN102599177B CN102599177B (en) | 2014-07-23 |
Family
ID=46517255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210054665.1A Active CN102599177B (en) | 2012-03-05 | 2012-03-05 | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102599177B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102960370A (en) * | 2012-10-29 | 2013-03-13 | 广东省农业科学院植物保护研究所 | Agent for controlling flea beetle for soil treatment |
| CN103609558A (en) * | 2013-11-11 | 2014-03-05 | *** | Green and environment-friendly bactericide synergist and preparation method thereof |
| CN103772067A (en) * | 2014-01-07 | 2014-05-07 | 叶长东 | Humic acid-type organic-inorganic insecticide-fertilizer composition containing tea saponin and prepared by using waste of sugar refineries and alcohol plants |
| CN104382940A (en) * | 2014-11-06 | 2015-03-04 | 昆明理工大学 | Compound agent for silkworms and application thereof |
| CN105532664A (en) * | 2015-12-11 | 2016-05-04 | 济南舜昊生物科技有限公司 | Ultralow-volume spraying agent containing bensultap and application thereof |
| CN107494596A (en) * | 2017-08-10 | 2017-12-22 | 黑龙江九穗谷农业科技发展有限公司 | Antimicrobial protection agent is used in one kind plantation |
| CN108651467A (en) * | 2018-04-28 | 2018-10-16 | 江西省农业科学院植物保护研究所 | Efficient pesticide composition containing thiocyclam |
| CN111466386A (en) * | 2020-03-18 | 2020-07-31 | 广西田园生化股份有限公司 | Application of alkyl glycoside compound |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5290557A (en) * | 1992-07-16 | 1994-03-01 | W. Neudorff Gmbh Kg | Saponin containing anti-feedant and molluscicide for terrestrial mollusc control |
| CN1234182A (en) * | 1999-04-23 | 1999-11-10 | 西北农业大学无公害农药研究服务中心 | Pesticide synergist and pesticide composition thereof |
| CN101743982A (en) * | 2009-12-29 | 2010-06-23 | 华南农业大学 | Mixed insecticide of tea saponin and nereistoxin insecticide |
-
2012
- 2012-03-05 CN CN201210054665.1A patent/CN102599177B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5290557A (en) * | 1992-07-16 | 1994-03-01 | W. Neudorff Gmbh Kg | Saponin containing anti-feedant and molluscicide for terrestrial mollusc control |
| CN1234182A (en) * | 1999-04-23 | 1999-11-10 | 西北农业大学无公害农药研究服务中心 | Pesticide synergist and pesticide composition thereof |
| CN101743982A (en) * | 2009-12-29 | 2010-06-23 | 华南农业大学 | Mixed insecticide of tea saponin and nereistoxin insecticide |
Non-Patent Citations (2)
| Title |
|---|
| 王书奇 等: "黄腐酸对几种常用杀虫剂的增效作用", 《第二届全国绿色环保肥料新技术新产品交流会会议交流文集》 * |
| 高楠 等: "绿色表面活性剂在农药加工中的应用", 《中国工程科学》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102960370A (en) * | 2012-10-29 | 2013-03-13 | 广东省农业科学院植物保护研究所 | Agent for controlling flea beetle for soil treatment |
| CN103609558A (en) * | 2013-11-11 | 2014-03-05 | *** | Green and environment-friendly bactericide synergist and preparation method thereof |
| CN103609558B (en) * | 2013-11-11 | 2016-06-08 | *** | A kind of environmental protection bactericide synergist and preparation method thereof |
| CN103772067A (en) * | 2014-01-07 | 2014-05-07 | 叶长东 | Humic acid-type organic-inorganic insecticide-fertilizer composition containing tea saponin and prepared by using waste of sugar refineries and alcohol plants |
| CN103772067B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising tea saponin utilizing sugar refinery, grain distillery's waste |
| CN104382940A (en) * | 2014-11-06 | 2015-03-04 | 昆明理工大学 | Compound agent for silkworms and application thereof |
| CN104382940B (en) * | 2014-11-06 | 2018-03-06 | 昆明理工大学 | A kind of silkworm built agent and purposes |
| CN105532664A (en) * | 2015-12-11 | 2016-05-04 | 济南舜昊生物科技有限公司 | Ultralow-volume spraying agent containing bensultap and application thereof |
| CN105532664B (en) * | 2015-12-11 | 2018-07-20 | 淮安聚友新能源科技有限公司 | A kind of ultra-low volume spray agent containing bensultap and purposes |
| CN107494596A (en) * | 2017-08-10 | 2017-12-22 | 黑龙江九穗谷农业科技发展有限公司 | Antimicrobial protection agent is used in one kind plantation |
| CN108651467A (en) * | 2018-04-28 | 2018-10-16 | 江西省农业科学院植物保护研究所 | Efficient pesticide composition containing thiocyclam |
| CN111466386A (en) * | 2020-03-18 | 2020-07-31 | 广西田园生化股份有限公司 | Application of alkyl glycoside compound |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102599177B (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102599177B (en) | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid | |
| CN102613247B (en) | Organophosphorus herbicide containing tea saponin, alkyl glycoside and fulvic acid | |
| CN103843826A (en) | Fungicidal composition containing alternaria tenuissima-activated protein | |
| CN103598192B (en) | A kind of bactericidal composition containing tetramycin and Zhongshengmycin | |
| CN103858936B (en) | A kind of Multifunctional environment friendly emamectin-benzoate water preparation and preparation method thereof | |
| CN102334493B (en) | Novel fluopicolide-containing antibacterial composition | |
| CN105230640A (en) | Bactericidal composition containing tetramycin and benziothiazolinone | |
| CN103430943A (en) | Synergistic kasugamycin composition containing tea saponin | |
| CN102599151B (en) | Surfactant containing tea saponin, alkyl polyglucoside, and fulvic acid | |
| CN102204529A (en) | Lythidathion microcapsule suspension and preparation method thereof | |
| CN1969626A (en) | Thiazine mixed pesticide | |
| CN105340913A (en) | Sterilization composition containing benziothiazolinone and kasugamycin | |
| CN100594790C (en) | Mixed pesticide preparation of tubatoxin and antibiotic fungicide | |
| CN105052950A (en) | Bactericidal composition containing tetramycin and ethylicin | |
| CN102017969B (en) | Pesticide composition containing Bifenazate and Diafenthiuron | |
| CN103621524B (en) | Pesticide composition | |
| CN105394039A (en) | Bactericidal composition containing oxine-copper and ethylicin | |
| CN102845442B (en) | Bactericidal composition containing polyoxins and iprovalicarb | |
| CN1985590A (en) | Chlorothalonil microemulsion and its preparing process | |
| CN102308796B (en) | Diazinon emulsifiable granules and preparation method thereof | |
| CN104663681A (en) | Abamectin water dispersible nano-composite granule and preparation method thereof | |
| CN106172401B (en) | It is a kind of to eliminate propargite on citrus using the propargite preparation for generating phytotoxicity | |
| CN108576016A (en) | A kind of polynary Herbicidal combinations of rice terrace | |
| CN103651544A (en) | Acaricidal composition of profenofos and etoxazole and formula instance | |
| CN103843798A (en) | Pesticide composition containing aureonucleomycin and strobilurin fungicide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200115 Address after: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee after: Guangxi easy harvest Biotechnology Co., Ltd. Address before: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee before: Ye Changdong |