CN102465393A - Manufacture method of flexible substrate and solar cell and production method thereof - Google Patents
Manufacture method of flexible substrate and solar cell and production method thereof Download PDFInfo
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- CN102465393A CN102465393A CN2010105409257A CN201010540925A CN102465393A CN 102465393 A CN102465393 A CN 102465393A CN 2010105409257 A CN2010105409257 A CN 2010105409257A CN 201010540925 A CN201010540925 A CN 201010540925A CN 102465393 A CN102465393 A CN 102465393A
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- light absorption
- absorption function
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention provides a manufacture method of a flexible substrate, and a solar cell and a manufacture method thereof. The cloth-shaped or film-shaped flexible substrate is formed by processing composite particles formed by crystal nano powder with a light absorption function and high polymer materials through the steps of spinning, and weaving, rolling or casting by solvents; a back metal electrode and a transparent electrode are respectively formed on the surface of the substrate, and then the solar cell can be produced by packaging; furthermore, light absorption thin layers can be previously formed on two surfaces of the substrate so as to enable the light absorption effect to be continuous; by the acceleration of nucleation and the growth of crystal grains, the process time can be reduced or the process can be performed at a low temperature, the expansion coefficient difference between the flexible substrate and the metal electrode is reduced, and the packaging can be performed by using conventional materials, thus the effects of rapid process and reduced cost are achieved.
Description
Technical field
The present invention relates to the flexible base plate technical field, particularly a kind of preparation method of flexible base plate and solar cell and preparation method thereof.
Background technology
In the prior art; Manufacturing solar cells on flexible base plate, various flexible base plates normally commonly used on the market, and plating light absorbing zone, metal level, contact hole layer etc. above that; Because these layers of plating need high temperature chemical combination and crystal grain-growth; Need as 300 ℃ or higher temperature, at present tolerable temperature surpass 300 ℃ soft usually and the thermal dilation difference between the metal level too big, and be easy to generate slight crack and make the life-span of solar cell lower.
In addition; When the flexible base plate that adopts sheet metal; Therefore shortcoming such as have again that the bending curvature is big inadequately, the then insufficient strength selectivity good, encapsulating material between metal and the encapsulating material is restricted needs a kind of flexible base plate that can improve existing shortcoming.
Summary of the invention
The objective of the invention is to be to provide preparation method and solar cell of a kind of flexible base plate and preparation method thereof.The present invention has the preparation method of flexible base plate of the how rice crystal grain of light absorption function and can and roll and prolong step by feedstock production step, the step of reeling off raw silk from cocoons and weaving step, feedstock production step; Or feedstock production step and solvent casting; The crystallization that will have a light absorption function is ground rice end as CIGS (CIGS) crystallization how ground rice end and macromolecular material institute formation composite micelle of ground rice end or Cu-In-Ga-Se-S (CIGSS) crystallization how how, the flexible base plate of the how meter crystal grain with light absorption function of formation cloth shape or glue sheet.These two surfaces of flexible base plate with how rice crystal grain of light absorption function are formed back-metal electrode and transparency electrode respectively; Form solar cell by encapsulating isolated aqueous vapor and oxygen again; Can respectively form the light absorption thin layer on two surfaces of this flexible base plate with vapor deposition or sputter in advance further, so that the function of light absorption can be even and continuous on whole base plate.
The embodiment of the invention provides a kind of preparation method of flexible base plate of the how rice crystal grain with light absorption function, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function;
One step of reeling off raw silk from cocoons is reeled off raw silk from cocoons said a plurality of composite micelles, and is formed a plurality of composite fibers; And
One weaving step is weaved said a plurality of composite fibers earlier, and forms the flexible base plate that one of cloth shape has the how meter crystal grain of light absorption function.
The embodiment of the invention provides the preparation method of the flexible base plate of second kind of how rice crystal grain with light absorption function, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function; And
One rolls and prolongs step, said a plurality of composite micelles is heated, and roll and prolong, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
The embodiment of the invention provides the preparation method of the flexible base plate of the third how rice crystal grain with light absorption function, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function; And
One solvent casting step; Pour the mixed solution of said a plurality of composite micelles and solvent into a given shape container to form the composite colloid thin plate; After solvent evaporates; The composite colloid thin plate is separated with container, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
In the described method, said a plurality of crystallizations with light absorption function how ground rice end are positioned at the surface of the flexible base plate of this how rice crystal grain with light absorption function.
In the described method, the functional group of said a plurality of macromolecular materials arranges along a preferred orientations order, and said a plurality of crystallization with light absorption function how the ground rice end has same tropism with this preferred orientations.
In the described method, said a plurality of macromolecular materials be polyamide, polyimides, PEI, polyamidoimide and polyaniline at least one of them.
In the described method, said a plurality of crystallizations with light absorption function how ground rice end are CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how.
The embodiment of the invention provides a kind of solar cell, comprises:
One has the flexible base plate of the how rice crystal grain of light absorption function, comprises a plurality of how rice crystal grain with light absorption function, and has the light absorption function;
One back-metal electrode is stacked over a surface of the flexible base plate of this how rice crystal grain with light absorption function, is formed with molybdenum;
One transparency electrode is stacked over another surface of the flexible base plate of this how rice crystal grain with light absorption function, and as a contact hole; And
A plurality of adhesive layers are stacked on this back-metal electrode and this transparency electrode, form with a transparent plastic, with isolated aqueous vapor and oxygen.
This transparency electrode system with cadmium sulfide, zinc sulphide, indium selenide, indium sulfide, zinc oxide, aluminum zinc oxide and alumel at least one of them formed.
Said solar cell; Further comprise two light absorption thin layers; This two light absorption thin layer system is formed at respectively between the flexible base plate and this back-metal electrode of this how rice crystal grain with light absorption function, and this has between the flexible base plate and this transparency electrode of how rice crystal grain of light absorption function.
Said a plurality of crystallization with light absorption function how ground rice end is CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how.
The embodiment of the invention provides the preparation method of solar cell of the flexible base plate of the how rice crystal grain that a kind of application has the light absorption function, comprises:
One substrate preparation process, the crystallization of preparing to have the light absorption function is a flexible base plate at ground rice end how;
One back-metal electrode film forming step; Mode on arbitrary surface of this flexible base plate with vapor deposition or sputter forms a metal film; With as a back-metal electrode, the one-tenth branch of this metal film work function and the crystallization in this flexible base plate with light absorption function how the ground rice end is complementary;
One transparency electrode film forming step, the mode that forms with vapor deposition or sputter on another surface of this flexible base plate forms a nesa coating, with as a transparency electrode;
One encapsulation step forms a clarity plastic layer on the surface of this back-metal electrode and this transparency electrode, to block aqueous vapor and oxygen.
Described method; Further comprise a light absorption thin layer film forming step; Before this back-metal electrode film forming step and this transparency electrode film forming step; Respectively form a light absorption thin layer on the two sides of this flexible base plate with CIGS target or Cu-In-Ga-Se-S target sputter in advance, make this back-metal electrode and this transparency electrode again, be formed at respectively respectively on this light absorption thin layer.
Said a plurality of crystallization with light absorption function how ground rice end is CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how.
The material that forms this transparency electrode be cadmium sulfide, zinc sulphide, indium selenide, indium sulfide, zinc oxide, aluminum zinc oxide and alumel at least one of them.
Characteristics of the present invention are; Can be directly with have as the CIGS crystallization how ground rice end or CIGSS crystallization how ground rice end etc. can absorb attack can crystallization how the ground rice end is directly mixed in the flexible base plate; Make substrate itself just have the composition of light absorption by this mode, can be directly as light absorbing zone, or only need plate the light absorption thin layer; Can be by quickening nucleation or crystal grain-growth; Further reducing the processing procedure time, or can carry out the processing procedure of light absorption thin layer under the lower temperature, further improve lattice interface between flexible base plate and the light absorption thin layer, and the expansion coefficient difference between minimizing and the metal electrode; And can use and commonly use the encapsulating material that blocks water oxygen and encapsulate, with reach processing procedure fast, reduce the effect of cost.
Description of drawings
Fig. 1 is the flow chart of preparation method first embodiment of flexible base plate with how rice crystal grain of light absorption function;
Fig. 2 is the flow chart of preparation method second embodiment of flexible base plate with how rice crystal grain of light absorption function;
Fig. 3 is the flow chart of preparation method the 3rd embodiment of flexible base plate with how rice crystal grain of light absorption function;
Fig. 4 is the structural representation of the solar cell of the flexible base plate of using the how rice crystal grain with light absorption function;
Fig. 5 is the flow chart of the preparation method of the solar cell of the flexible base plate of using the how rice crystal grain with light absorption function.
[primary clustering symbol description]
1 solar cell
10 have the flexible base plate of the how rice crystal grain of light absorption function
20 back-metal electrodes
30 transparency electrodes
40 adhesive layers
50 light absorbing zones
S1 has the preparation method of flexible base plate of the how rice crystal grain of light absorption function
S11 feedstock production step
The S13 step of reeling off raw silk from cocoons
The S15 step of weaving
S2 has the preparation method of flexible base plate of the how rice crystal grain of light absorption function
S21 feedstock production step
S23 rolls and prolongs step
S3 has the preparation method of flexible base plate of the how rice crystal grain of light absorption function
S31 feedstock production step
S33 solvent casting step
S4 uses the preparation method of solar cell of the flexible base plate of the how rice crystal grain with light absorption function
S41 substrate preparation process
S43 back-metal electrode film forming step
S45 transparency electrode film forming step
The S47 encapsulation step
S49 light absorbing zone film forming step
The specific embodiment
Below cooperate graphic and element numbers is done more detailed explanation to embodiment of the present invention, have the knack of this art and after studying this specification carefully, can implement according to this in order to do making.
Fig. 1 is the flow chart of preparation method first embodiment of flexible base plate with how rice crystal grain of light absorption function.As shown in Figure 1; The preparation method S1 of flexible base plate that the present invention has the how rice crystal grain of light absorption function comprises feedstock production step S11, the step of reeling off raw silk from cocoons S13 and weaving step S15; This feedstock production step S11 be have a light absorption function crystallization how ground rice end as CIGS (CIGS) crystallization how ground rice end or Cu-In-Ga-Se-S (CIGSS) crystallization how the ground rice end forms the composite micelle with macromolecular material, the step of reeling off raw silk from cocoons S13 reels off raw silk from cocoons the composite micelle, and the formation composite fiber; Weaving step S13 weaves above-mentioned a plurality of composite fibers; And form the flexible base plate that one of cloth shape has the how rice crystal grain of light absorption function, wherein macromolecular material be polyamide (polyamide, PA), polyimides (polyimide; PI), PEI (polyetherimide; PEI), polyamidoimide (polyamideimide, PAI) and polyaniline (polyaniline, PANI) at least one of them.
Fig. 2 is the flow chart of preparation method second embodiment of flexible base plate with how rice crystal grain of light absorption function.As shown in Figure 2, the preparation method S2 of flexible base plate that the present invention has the how rice crystal grain of light absorption function comprises feedstock production step S21 and rolls and prolong step S23.Feedstock production step S21 is identical with first embodiment, is not giving unnecessary details at this.Prolong step S23 this composite micelle is heated and roll, and roll and prolong, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
Fig. 3 is the flow chart of preparation method the 3rd embodiment of flexible base plate with how rice crystal grain of light absorption function.As shown in Figure 3, the preparation method S2 of flexible base plate that the present invention has the how rice crystal grain of light absorption function comprises feedstock production step S31 and solvent casting step S33.Feedstock production step S31 is identical with first embodiment, is not giving unnecessary details at this.And solvent casting step S33 pours the mixed solution of this composite micelle and solvent into a given shape container to form the composite colloid thin plate; After solvent evaporates; The composite colloid thin plate is separated with container, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
For first embodiment to the, three embodiment; Above-mentioned a plurality of crystallization with light absorption function how ground rice end is positioned at the surface of the flexible base plate of above-mentioned a plurality of how rice crystal grain with light absorption function; And the functional group of above-mentioned a plurality of macromolecular materials arranges along a preferred orientations order, and above-mentioned a plurality of crystallization with light absorption function how the ground rice end has same tropism with this preferred orientations.
Fig. 4 is the structural representation of the solar cell of the flexible base plate of the how rice crystal grain with light absorption function of using first to the 3rd embodiment; As shown in Figure 4; Solar cell 1 comprises flexible base plate 10, back-metal electrode 20, transparency electrode 30, the adhesive layer 40 of the how rice crystal grain with light absorption function; Because having the flexible base plate 10 of the how rice crystal grain of light absorption function comprises owing to have the how rice crystal grain of light absorption function; Therefore can be directly as light absorbing zone, back-metal electrode 20 is formed with molybdenum (Mo), is stacked over a surface of the flexible base plate 10 of this how meter crystal grain with light absorption function; Transparency electrode 30 is stacked over another surface of the flexible base plate 10 of this how rice crystal grain with light absorption function, can be by cadmium sulfide (CdS), zinc sulphide (ZnS), indium selenide (In
2Se
3), indium sulfide (In
2S
3), zinc oxide (ZnO), aluminum zinc oxide (Al:ZnO), other transparent conductive oxide (transparent conductive oxygen), and formation such as alumel, and as a contact hole.Adhesive layer 40 is stacked on this back-metal electrode 20 and the transparency electrode 30, forms with a transparent plastic, with isolated aqueous vapor and oxygen.Further; Solar cell 1 more comprises light absorption thin layer 50; This light absorption thin layer is stacked over two surfaces of the flexible base plate 10 of the how rice crystal grain with light absorption function; Just have between the flexible base plate 10 and back-metal electrode 20 of how rice crystal grain of light absorption function, and have between the flexible base plate 10 and transparency electrode 30 of how rice crystal grain of light absorption function so that the light absorption function on the flexible base plate 10 of whole how rice crystal grain with light absorption function evenly and continuously.
Fig. 5 is the flow chart of the preparation method of the solar cell of the flexible base plate of using the how rice crystal grain with light absorption function.As shown in Figure 5, the preparation method S4 of solar cell that uses the flexible base plate of the how rice crystal grain with light absorption function comprises substrate preparation process S41, back-metal electrode film forming step S43, transparency electrode film forming step S45 and encapsulation step S47.The crystallization that substrate preparation process S41 prepares to have the light absorption function is a flexible base plate at ground rice end how.Back-metal electrode film forming step S43; Arbitrary the mode with vapor deposition or sputter at this flexible base plate forms a metal film; With as the back-metal electrode; The one-tenth branch of this metal film work function (work function) and flexible base plate in have the crystallization of light absorption function how the ground rice end be complementary, the composition of this metal film is generally molybdenum (Mo).Transparency electrode film forming step S45 forms a nesa coating in the mode that another surface of this flexible base plate forms with vapor deposition or sputter, and as a transparency electrode or contact hole, the material of this transparency electrode is cadmium sulfide (CdS), zinc sulphide (ZnS), indium selenide (In
2Se
3), indium sulfide (In
2S
3), zinc oxide (ZnO), aluminum zinc oxide (Al:ZnO), other transparent conductive oxide (transparent conductive oxygen), and alumel etc.Encapsulation step S47 forms a clarity plastic layer on the surface of this back-metal electrode and this transparency electrode, to block aqueous vapor and oxygen.Further; Can comprise a light absorption thin layer film forming step S49; Before back-metal electrode film forming step S43 and transparency electrode film forming step S45, each forms a light absorption thin layer with CIGS target or CIGSS target sputter on the two sides of this flexible base plate in advance so that the function of light absorption can be on whole base plate evenly and continuously; Make back-metal electrode and transparency electrode, be formed at respectively on two light absorption thin layers.
Characteristics of the present invention are; Can be directly with have as the CIGS crystallization how ground rice end or CIGSS crystallization how ground rice end etc. can absorb attack can crystallization how the ground rice end is directly mixed in the flexible base plate; Make substrate itself just have the composition of light absorption by this mode, can be directly as light absorbing zone, or only need plate the light absorption thin layer; Can be by quickening nucleation or crystal grain-growth; Further reducing the processing procedure time, or can carry out the processing procedure of light absorption thin layer under the lower temperature, further improve lattice interface between flexible base plate and the light absorption thin layer, and the expansion coefficient difference between minimizing and the metal electrode; And can use and commonly use the encapsulating material that blocks water oxygen and encapsulate, with reach processing procedure fast, reduce the effect of cost.
The above person is merely in order to explain preferred embodiment of the present invention; Be not that attempt is done any pro forma restriction to this creation according to this; Be with, all have in following any modification or the change of doing relevant this creation of identical spirit, all must be included in the category of this creation intention protection.
Claims (15)
1. the preparation method of the flexible base plate of the how rice crystal grain with light absorption function is characterized in that, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function;
One step of reeling off raw silk from cocoons is reeled off raw silk from cocoons said a plurality of composite micelles, and is formed a plurality of composite fibers; And
One weaving step is weaved said a plurality of composite fibers earlier, and forms the flexible base plate that one of cloth shape has the how meter crystal grain of light absorption function.
2. the preparation method of the flexible base plate of the how rice crystal grain with light absorption function is characterized in that, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function; And
One rolls and prolongs step, said a plurality of composite micelles is heated, and roll and prolong, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
3. the preparation method of the flexible base plate of the how rice crystal grain with light absorption function is characterized in that, comprises:
One feedstock production step, how the ground rice end forms a plurality of composite micelles with a plurality of macromolecular materials with a plurality of crystallizations with light absorption function; And
One solvent casting step; Pour the mixed solution of said a plurality of composite micelles and solvent into a given shape container to form the composite colloid thin plate; After solvent evaporates; The composite colloid thin plate is separated with container, and form the flexible base plate that one of glue sheet has the how rice crystal grain of light absorption function.
4. like each described method in the claim 1 to 3, it is characterized in that said a plurality of crystallizations with light absorption function how ground rice end are positioned at the surface of the flexible base plate of this how rice crystal grain with light absorption function.
5. like each described method in the claim 1 to 3, it is characterized in that the functional group of said a plurality of macromolecular materials arranges along a preferred orientations order, and said a plurality of crystallization with light absorption function how the ground rice end has same tropism with this preferred orientations.
6. like each described method in the claim 1 to 3, it is characterized in that, said a plurality of macromolecular materials be polyamide, polyimides, PEI, polyamidoimide and polyaniline at least one of them.
7. like each described method in the claim 1 to 3, it is characterized in that said a plurality of crystallizations with light absorption function how ground rice end are CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how.
8. a solar cell is characterized in that, comprises:
One has the flexible base plate of the how rice crystal grain of light absorption function, comprises a plurality of how rice crystal grain with light absorption function, and has the light absorption function;
One back-metal electrode is stacked over a surface of the flexible base plate of this how rice crystal grain with light absorption function, is formed with molybdenum;
One transparency electrode is stacked over another surface of the flexible base plate of this how rice crystal grain with light absorption function, and as a contact hole; And
A plurality of adhesive layers are stacked on this back-metal electrode and this transparency electrode, form with a transparent plastic, with isolated aqueous vapor and oxygen.
9. like the said solar cell of claim 8, it is characterized in that, this transparency electrode be with cadmium sulfide, zinc sulphide, indium selenide, indium sulfide, zinc oxide, aluminum zinc oxide and alumel at least one of them formed.
10. like the said solar cell of claim 8; It is characterized in that; Further comprise two light absorption thin layers; This two light absorption thin layer system is formed at respectively between the flexible base plate and this back-metal electrode of this how rice crystal grain with light absorption function, and this has between the flexible base plate and this transparency electrode of how rice crystal grain of light absorption function.
11., it is characterized in that said a plurality of crystallizations with light absorption function how ground rice end are CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how like the said solar cell of claim 8.
12. an application has the preparation method of solar cell of flexible base plate of the how rice crystal grain of light absorption function, it is characterized in that, comprises:
One substrate preparation process, the crystallization of preparing to have the light absorption function is a flexible base plate at ground rice end how;
One back-metal electrode film forming step; Mode on arbitrary surface of this flexible base plate with vapor deposition or sputter forms a metal film; With as a back-metal electrode, the one-tenth branch of this metal film work function and the crystallization in this flexible base plate with light absorption function how the ground rice end is complementary;
One transparency electrode film forming step, the mode that forms with vapor deposition or sputter on another surface of this flexible base plate forms a nesa coating, with as a transparency electrode;
One encapsulation step forms a clarity plastic layer on the surface of this back-metal electrode and this transparency electrode, to block aqueous vapor and oxygen.
13. method as claimed in claim 12; It is characterized in that; Further comprise a light absorption thin layer film forming step, before this back-metal electrode film forming step and this transparency electrode film forming step, respectively form a light absorption thin layer on the two sides of this flexible base plate with CIGS target or Cu-In-Ga-Se-S target sputter in advance; Make this back-metal electrode and this transparency electrode again, be formed at respectively respectively on this light absorption thin layer.
14. method as claimed in claim 12 is characterized in that, said a plurality of crystallizations with light absorption function how ground rice end are CIGS crystallization ground rice end or Cu-In-Ga-Se-S crystallization ground rice end how how.
15. method as claimed in claim 9 is characterized in that, the material that forms this transparency electrode be cadmium sulfide, zinc sulphide, indium selenide, indium sulfide, zinc oxide, aluminum zinc oxide and alumel at least one of them.
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| CN2010105409257A CN102465393A (en) | 2010-11-08 | 2010-11-08 | Manufacture method of flexible substrate and solar cell and production method thereof |
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| CN2010105409257A CN102465393A (en) | 2010-11-08 | 2010-11-08 | Manufacture method of flexible substrate and solar cell and production method thereof |
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| CN102465393A true CN102465393A (en) | 2012-05-23 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107851678A (en) * | 2015-06-30 | 2018-03-27 | 株式会社钟化 | Solar module |
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| CN1851933A (en) * | 2006-05-24 | 2006-10-25 | 武汉科技学院 | Soft-light anode assembly of solar cell and its preparing method |
| CN1925172A (en) * | 2006-09-18 | 2007-03-07 | 邢宪生 | Flexible electrode for optical-voltage battery and its manufacturing method |
| CN101255614A (en) * | 2008-03-28 | 2008-09-03 | 刘燕平 | Inorganic solid-phase combination powder, master batch and manufacture method, fibre and manufacture method |
| CN201178100Y (en) * | 2007-10-16 | 2009-01-07 | 西安海晶光电科技有限公司 | Organic electro-luminescence display screen having organic solar cell |
| US20090071534A1 (en) * | 2007-09-17 | 2009-03-19 | Hsuan-Fu Wang | Photoelectric electrodes capable of absorbing light energy, fabrication methods, and applications thereof |
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| CN1851933A (en) * | 2006-05-24 | 2006-10-25 | 武汉科技学院 | Soft-light anode assembly of solar cell and its preparing method |
| CN1925172A (en) * | 2006-09-18 | 2007-03-07 | 邢宪生 | Flexible electrode for optical-voltage battery and its manufacturing method |
| US20090071534A1 (en) * | 2007-09-17 | 2009-03-19 | Hsuan-Fu Wang | Photoelectric electrodes capable of absorbing light energy, fabrication methods, and applications thereof |
| CN201178100Y (en) * | 2007-10-16 | 2009-01-07 | 西安海晶光电科技有限公司 | Organic electro-luminescence display screen having organic solar cell |
| CN101255614A (en) * | 2008-03-28 | 2008-09-03 | 刘燕平 | Inorganic solid-phase combination powder, master batch and manufacture method, fibre and manufacture method |
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| CN107851678A (en) * | 2015-06-30 | 2018-03-27 | 株式会社钟化 | Solar module |
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Application publication date: 20120523 |