CN102433058A - 可带锈施工的环氧酯底漆及其制备方法 - Google Patents
可带锈施工的环氧酯底漆及其制备方法 Download PDFInfo
- Publication number
- CN102433058A CN102433058A CN2011102593065A CN201110259306A CN102433058A CN 102433058 A CN102433058 A CN 102433058A CN 2011102593065 A CN2011102593065 A CN 2011102593065A CN 201110259306 A CN201110259306 A CN 201110259306A CN 102433058 A CN102433058 A CN 102433058A
- Authority
- CN
- China
- Prior art keywords
- epoxy ester
- rust
- undercoat
- percent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004593 Epoxy Substances 0.000 title claims abstract description 76
- 150000002148 esters Chemical class 0.000 title claims abstract description 74
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000010276 construction Methods 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 15
- 238000007865 diluting Methods 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 48
- 229910052742 iron Inorganic materials 0.000 claims description 24
- 239000003822 epoxy resin Substances 0.000 claims description 15
- 229920000647 polyepoxide Polymers 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000012466 permeate Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229920003987 resole Polymers 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- WETINTNJFLGREW-UHFFFAOYSA-N calcium;iron;tetrahydrate Chemical compound O.O.O.O.[Ca].[Fe].[Fe] WETINTNJFLGREW-UHFFFAOYSA-N 0.000 claims description 8
- 239000002383 tung oil Substances 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 7
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 claims description 7
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 7
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000001739 pinus spp. Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 229940036248 turpentine Drugs 0.000 claims description 3
- 229910000859 α-Fe Inorganic materials 0.000 claims description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- 229910001308 Zinc ferrite Inorganic materials 0.000 claims description 2
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 claims description 2
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 14
- 238000000576 coating method Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000000149 penetrating effect Effects 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 17
- 230000007797 corrosion Effects 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 10
- 230000032050 esterification Effects 0.000 description 7
- 238000005886 esterification reaction Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 238000002161 passivation Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 230000008261 resistance mechanism Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- -1 siccative Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
实施例 | 环氧树脂 | 亚麻油 | 桐油 | 酚醛树脂 |
实施例1 | 30%(E-51) | 40% | 20% | 10% |
实施例2 | 33%(E-44) | 44% | 18% | 5% |
实施例3 | 26%(E-44) | 44% | 20% | 10% |
组份 | 实施例1 | 实施例2 | 实施例3 |
环氧酯 | 20% | 30% | 29.6% |
稀释溶剂 | 30% | 20% | 29.6% |
填料 | 25% | 21.5% | 19.7% |
铁锈稳定剂 | 23.6% | 25% | 19.7% |
活性防锈颜料 | 1% | 3% | 1.2% |
催干剂 | 0.3% | 0.2% | 0.05% |
渗透剂 | 0.1% | 0.3% | 0.15% |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110259306 CN102433058B (zh) | 2011-09-05 | 2011-09-05 | 可带锈施工的环氧酯底漆及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110259306 CN102433058B (zh) | 2011-09-05 | 2011-09-05 | 可带锈施工的环氧酯底漆及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102433058A true CN102433058A (zh) | 2012-05-02 |
CN102433058B CN102433058B (zh) | 2013-09-11 |
Family
ID=45981409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110259306 Active CN102433058B (zh) | 2011-09-05 | 2011-09-05 | 可带锈施工的环氧酯底漆及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102433058B (zh) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102977743A (zh) * | 2012-12-24 | 2013-03-20 | 青岛宣威涂层材料有限公司 | 一种带水带锈施工的涂层材料及其制备方法 |
CN103013283A (zh) * | 2012-12-24 | 2013-04-03 | 青岛宣威涂层材料有限公司 | 一种水下固化施工的防腐涂层材料及其制备方法 |
CN103992722A (zh) * | 2014-05-07 | 2014-08-20 | 河海大学 | 一种多羧基环氧树脂铁锈稳定剂 |
CN106047069A (zh) * | 2016-07-11 | 2016-10-26 | 湖南中汉高分子材料科技有限公司 | 一种工程机械用防锈涂料 |
CN106752665A (zh) * | 2015-11-25 | 2017-05-31 | 湖南开磷雁峰塔涂料有限公司 | 一种环氧脂底漆及其制作方法 |
CN107936781A (zh) * | 2017-12-11 | 2018-04-20 | 湖南太子化工涂料有限公司 | 一种环氧酯底漆及其制备方法与应用 |
CN108753093A (zh) * | 2018-06-21 | 2018-11-06 | 天津市津海特种涂料装饰有限公司 | 一种水性超防腐改性环氧底漆 |
CN109385175A (zh) * | 2017-08-02 | 2019-02-26 | Kcc公司 | 重防腐涂料用油漆套装 |
CN112920687A (zh) * | 2021-03-01 | 2021-06-08 | 西北永新涂料有限公司 | 单组份鳞片型环氧富锌防锈底漆及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1488689A (zh) * | 2003-09-02 | 2004-04-14 | 杨冠星 | 化锈防锈变色底漆 |
CN1763138A (zh) * | 2005-11-07 | 2006-04-26 | 广州珠江化工集团有限公司 | 一种高效低成本环保型纳米复合防锈涂料及其制备方法 |
CN101457116A (zh) * | 2007-12-12 | 2009-06-17 | 上海海悦涂料有限公司 | 长效低表面处理环氧涂装底漆 |
CN101864240A (zh) * | 2010-06-13 | 2010-10-20 | 徐友志 | 适用于海洋环境的自释型船舶防污漆及其制备与用法 |
-
2011
- 2011-09-05 CN CN 201110259306 patent/CN102433058B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1488689A (zh) * | 2003-09-02 | 2004-04-14 | 杨冠星 | 化锈防锈变色底漆 |
CN1763138A (zh) * | 2005-11-07 | 2006-04-26 | 广州珠江化工集团有限公司 | 一种高效低成本环保型纳米复合防锈涂料及其制备方法 |
CN101457116A (zh) * | 2007-12-12 | 2009-06-17 | 上海海悦涂料有限公司 | 长效低表面处理环氧涂装底漆 |
CN101864240A (zh) * | 2010-06-13 | 2010-10-20 | 徐友志 | 适用于海洋环境的自释型船舶防污漆及其制备与用法 |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103013283A (zh) * | 2012-12-24 | 2013-04-03 | 青岛宣威涂层材料有限公司 | 一种水下固化施工的防腐涂层材料及其制备方法 |
CN102977743B (zh) * | 2012-12-24 | 2016-01-20 | 青岛宣威涂层材料有限公司 | 一种带水带锈施工的涂层材料及其制备方法 |
CN103013283B (zh) * | 2012-12-24 | 2016-01-20 | 青岛宣威涂层材料有限公司 | 一种水下固化施工的防腐涂层材料及其制备方法 |
CN102977743A (zh) * | 2012-12-24 | 2013-03-20 | 青岛宣威涂层材料有限公司 | 一种带水带锈施工的涂层材料及其制备方法 |
CN103992722A (zh) * | 2014-05-07 | 2014-08-20 | 河海大学 | 一种多羧基环氧树脂铁锈稳定剂 |
CN103992722B (zh) * | 2014-05-07 | 2016-04-13 | 河海大学 | 一种多羧基环氧树脂铁锈稳定剂 |
CN106752665A (zh) * | 2015-11-25 | 2017-05-31 | 湖南开磷雁峰塔涂料有限公司 | 一种环氧脂底漆及其制作方法 |
CN106047069A (zh) * | 2016-07-11 | 2016-10-26 | 湖南中汉高分子材料科技有限公司 | 一种工程机械用防锈涂料 |
CN109385175A (zh) * | 2017-08-02 | 2019-02-26 | Kcc公司 | 重防腐涂料用油漆套装 |
CN107936781A (zh) * | 2017-12-11 | 2018-04-20 | 湖南太子化工涂料有限公司 | 一种环氧酯底漆及其制备方法与应用 |
CN108753093A (zh) * | 2018-06-21 | 2018-11-06 | 天津市津海特种涂料装饰有限公司 | 一种水性超防腐改性环氧底漆 |
CN112920687A (zh) * | 2021-03-01 | 2021-06-08 | 西北永新涂料有限公司 | 单组份鳞片型环氧富锌防锈底漆及其制备方法 |
CN112920687B (zh) * | 2021-03-01 | 2022-06-10 | 西北永新涂料有限公司 | 单组份鳞片型环氧富锌防锈底漆及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102433058B (zh) | 2013-09-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102433058B (zh) | 可带锈施工的环氧酯底漆及其制备方法 | |
CN105038424B (zh) | 水性重防腐单组份带锈底漆及其制备方法与应用 | |
CN102382540B (zh) | 一种高光泽工程机械底盘水性防腐涂料及其制备方法 | |
KR101986487B1 (ko) | 도료 및 피복 강재 | |
JP5600992B2 (ja) | 耐候性に優れた表面処理耐食性鋼材 | |
CN104525458A (zh) | 一种船舶防腐方法 | |
JP6242318B2 (ja) | Snイオンを利用した弱溶剤形高耐食性塗料組成物 | |
CN105017884A (zh) | 一种水性自转锈钢铁表面处理液及其制备方法 | |
CN106675363A (zh) | 一种石墨烯功能性金属表面长效处理材料及其制备方法 | |
CN106349866A (zh) | 太阳能支架防腐涂料、其制备方法及应用 | |
CN109852163A (zh) | 一种可带锈涂装的水性防锈涂料及其制备方法 | |
CN104341924A (zh) | 一种沥青船底水性防锈除锈涂料及其制备方法 | |
JP6252400B2 (ja) | 補修用下地塗料組成物 | |
CN106811040A (zh) | 水性重防腐单组分底漆及其制备方法和应用 | |
JP4895533B2 (ja) | 塗料組成物 | |
CN104449391A (zh) | 一种铁红防腐涂料及其制备方法 | |
JP5993799B2 (ja) | Snイオンを利用した高耐食性塗料組成物 | |
CN113667376A (zh) | 一种带湿带锈条件下涂料的配方 | |
CN107858079A (zh) | 一种水性单组可带锈施工钢结构底漆及其制备方法和应用 | |
JP2018066055A (ja) | 鉄錆還元防錆処理剤の製造方法 | |
JP2004148163A (ja) | 鉄鋼材料の補修塗装方法 | |
CN103509416A (zh) | 水性丙烯酸带锈除锈防锈漆 | |
JP5712625B2 (ja) | 防錆用塗料および塗装鋼材 | |
CN104789104B (zh) | 高机械性能含羟基聚氨酯共聚丙烯酸水性工业漆 | |
JP5396693B2 (ja) | 表面処理耐候性鋼材 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20120502 Assignee: ZHEJIANG HAIFU MARINE BIOTECHNOLOGY Co.,Ltd. Assignor: ZHEJIANG MARINE DEVELOPMENT Research Institute Contract record no.: X2022330000405 Denomination of invention: Epoxy ester primer that can be applied with rust and preparation method thereof Granted publication date: 20130911 License type: Common License Record date: 20220811 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20120502 Assignee: Ningbo Rongjue New Materials Co.,Ltd. Assignor: ZHEJIANG MARINE DEVELOPMENT Research Institute Contract record no.: X2023980044358 Denomination of invention: Epoxy ester primer capable of carrying rust and its preparation method Granted publication date: 20130911 License type: Common License Record date: 20231025 |
|
EE01 | Entry into force of recordation of patent licensing contract |