CN102382381A - High water resistance degaussing cable sheath material and preparation method thereof - Google Patents

High water resistance degaussing cable sheath material and preparation method thereof Download PDF

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Publication number
CN102382381A
CN102382381A CN2011103598831A CN201110359883A CN102382381A CN 102382381 A CN102382381 A CN 102382381A CN 2011103598831 A CN2011103598831 A CN 2011103598831A CN 201110359883 A CN201110359883 A CN 201110359883A CN 102382381 A CN102382381 A CN 102382381A
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China
Prior art keywords
cable sheath
sheath material
agent
parts
degaussing cable
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CN2011103598831A
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Chinese (zh)
Inventor
李海全
张漫
张小健
解向前
李嵘
陈培
沈晶晶
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ZHONGTIAN TECHNOLOGY EQUIPMENT CABLE Co Ltd
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ZHONGTIAN TECHNOLOGY EQUIPMENT CABLE Co Ltd
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Priority to CN2011103598831A priority Critical patent/CN102382381A/en
Publication of CN102382381A publication Critical patent/CN102382381A/en
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Abstract

The invention discloses a high water resistance degaussing cable sheath material, which comprises the following components in part by weight: 100 parts of chlorinated polyethylene, 5 to 50 parts of reinforcing filler, 25 to 70 parts of filling agent, 3 to 5 parts of promoter, 5 to 10 parts of coloring agent, 1 to 3 parts of anti-ageing agent, 7 to 30 parts of plasticizer, 3 to 6 parts of co-curing agent, 6 to 10 parts of fire retardant, 2 to 4 parts of curing agent and 1 to 3 parts of processing aid. The invention also discloses a method for preparing the high water resistance degaussing cable sheath material. The rubber chlorinated polyethylene is added with aids in certain ratios to form the degaussing cable sheath material for ships, and the degaussing cable sheath material has high water resistance, tensile strength, breaking elongation, seawater corrosion resistance, radial watertightness, and oxygen index, and a degaussing cable sheath made of the material has excellent water resistance.

Description

A kind of high resistant water-based degaussing cable sheath material and preparation method thereof
Technical field
The present invention relates to a kind of sheath material of cable, be specifically related to the preparation method of a kind of high resistant water-based naval vessel with the degaussing cable sheath material.
Background technology
Along with the mankind deepen continuously to what magnetic field was familiar with, the basic distribution character of earth magnetism, periodically changed rule and correlation theory are perfect gradually, and people can be used as a kind of characteristic and from environmental magnetic field, come out by discrimination.Boundless marine greatly, except light, sound, radar wave, thermal signal, the detecting on naval vessel a kind of more hidden means have been increased again.The magnetic source on naval vessel is from iron and steel, and Modern Ships takes shape in iron and steel more, because steel itself have " firmly " magnetic and " soft " magnetic, the naval vessel also correspondingly has fixed magnetic and inducedmagnetism.Hull structure by this ferromagnetic material of steel is constituted is built and is navigated by water in the terrestrial magnetic field, thereby has received the latter's magnetization, has produced ship's magnetism at the hull surrounding space.Invisible magneticline of force from all directions with hull around wherein, their extend around the naval vessel place of tens meters even hundreds of rice, are attracting magneticinduction submarine mine nearby constantly.Torpedo and magnetic are visited the sense of smell of appearance sensitive.So, very important to the demagnetization on naval vessel.On the naval vessel, pressing certain orientation winding temporary cable formation coil winding degaussing cable can demagnetization.In addition, the cable arrangements of demagnetization is flexible, can adjust according to the fixing needs of winding, and fixedly the winding demagnetization then can change by the stochastic control ship's magnetism during ship navigation.Owing to reasons such as ship type restrictions, small sweeper and submarine can only adopt interim coil demagnetization method, and the Controlled Mine Countermeasures naval vessel mostly adopts non magnetic outer panel material, therefore mostly only adopt fixedly winding demagnetization.
With respect to the fixing randomness of demagnetization, interim coil demagnetization roughly need be experienced following technological process: except that power unit, the specific equipment of demagnetizing ship also has: major and minor demagnetization power supply, erasing current opertaing device, degaussing cable and magnetic field detection equipment etc.Demagnetization power supply and switchboard are arranged in special cabin, set up the demagnetization watch-keeping cubicle in the superstructure, keep watch on and the whole demagnetization operation of remote control.Degaussing cable is equipped with the rubber insulation high flexible cable of 2-3 kind specifications according to various demagnetization technologies, and every kind of cable storage reaches thousands of rice, on being placed on cable hoist and place in the cable storage cabin, can manually or electronic emit during use, so handled easily at ordinary times.Therefore, particularly important as the degaussing cable sheath with the research and development of material.
Development along with cable industry; Requirement to cable material also improves year by year; When satisfying general sheath material; Various materials with property such as environmental protection, high flame retardant, high water resistant, seawater corrosion resistance, anti-mud, grease-proof materials demand are also very urgent, and the degaussing cable sheath material of using as the naval vessel requires to have very high seawater corrosion resistance, the high resistant water-based.
Chlorinatedpolyethylene (CPE) is a kind of type material that is applied to electric wire and cable jacket in recent years, and it has good weathering resistance, anti-ozone, chemicals-resistant and heat aging property, has good oil-proofness, flame retardant resistance and tinctorial property.Common chlorinatedpolyethylene CABLE MATERIALS resistance to corrosion seawater is poor, water preventing ability is poor, and is unstable in the process of in the naval vessel, using, and occurs such-and-such problem easily, has a strong impact on ship security.Therefore, it is necessary with chlorinated polyethylene sheath glue that research has the degaussing cable of high water resistant performance, sea water corrosion resistant.
Summary of the invention
Goal of the invention: the present invention provides a kind of high resistant water-based naval vessel of excellent performance to use the degaussing cable sheath material in order to solve the deficiency of prior art.
Another object of the present invention provides the preparation method of this high resistant water-based naval vessel with the degaussing cable sheath material.
Technical field: a kind of high resistant water-based degaussing cable sheath material, it is formed and mass fraction is: the rubber matrix is 100 parts, reinforced filling 5-50 part, weighting agent 25-70 part, promotor 3-5 part, tinting material 5-10 part, anti-aging agent 1-3 part, softening agent 7-30 part, cocuring agent 3-6 part, fire retardant 6-10 part, vulcanizing agent 2-4 part, processing aid 1-3 part.
As optimization, said rubber matrix is a chlorinatedpolyethylene, and said reinforced filling is one or both mixtures in WHITE CARBON BLACK, the potter's clay.
As optimization, said weighting agent is a talcum powder.
As optimization, said promotor is triallyl isonitrile urea acid fat (TAIC).
As optimization, said tinting material is a carbon black.
As optimization, said anti-aging agent is one or both mixtures in calcium-zinc composite stabilizing agent or the paraffin.
As optimization, said softening agent is one or both mixtures in adjacent this dioctyl phthalate dibutyl ester or the clorafin.
As optimization, said cocuring agent is a yellow lead oxide.
As optimization, said fire retardant is an Antimony Trioxide: 99.5Min.
As optimization, said vulcanizing agent is a Di Cumyl Peroxide 99.
As optimization, said processing aid is a lead stearate.
A kind of preparation method of above-mentioned high resistant water-based degaussing cable sheath material may further comprise the steps:
1, in torque rheometer, carry out mixing; Controlled temperature is 65-75 ℃; In torque rheometer, add the rubber matrix; The reinforced filling, weighting agent, secondary accelerator, softening agent, anti-aging agent, fire retardant, tinting material, vulcanization accelerator, secondary accelerator, the processing aid that add above-mentioned mass fraction more successively, with said components is mixing evenly obtain mixing colloid after, it is mixing more evenly to add vulcanizing agent.
2, adopt mill to carry out the compressing tablet film-making.
3, record mixing colloidal curing parameter t with no rotor vulkameter 90Be characteristic parameter.
4, get parametric t 90Adding 1~2min is sulfurizing time, and pressure is 12-16Mpa, and temperature is 175-185 ℃, on vulcanizing press, produces test piece, and sample carries out each item performance detection after leaving standstill 14-18h.
5, the requirement that the performance that records said sample meets high resistant water-based degaussing cable sheath material gets final product.
The performance of this high resistant water-based degaussing cable sheath material is: have fabulous block-water performance, heat-resisting extension property, seawater corrosion resistance, good mechanical strength and flame retardant properties.Tensile strength>=13Mpa, elongation at break>=400%, hygroscopicity value≤8mg/ml, oxygen index>=35%, after the hot air aging, stretch breaking strength, elongation at break velocity of variation≤± 20%, anti-IRM902 oil tensile strength velocity of variation≤± 20%.
Beneficial effect: the present invention adopts the rubber chlorinatedpolyethylene; Adding certain proportion of auxiliary agent prepares and is applicable to the sheath material of naval vessel with degaussing cable; Have high resistant water-based, tensile strength, elongation at break, seawater corrosion resistance, radially watertightness, oxygen index; Use this material to make degaussing cable and use sheath material, block-water performance is very excellent.
Embodiment
Embodiment 1
A kind of high resistant water-based degaussing cable sheath material, it is formed with mass fraction and is: chlorinatedpolyethylene is 100 parts, 5 parts of WHITE CARBON BLACKs, 70 parts of talcum powder, 4 parts in the sour fat of triallyl isonitrile urea, 5 parts of carbon blacks, 2.5 parts of calcium-zinc composite stabilizing agents, 2.5 parts in paraffin, 3 parts of o-phthalic acid dibutyl esters, 4 parts of clorafins, 3 parts of yellow lead oxides, 6 parts of Antimony Trioxide: 99.5Mins, 2 parts of Di Cumyl Peroxide 99s, 1 part of lead stearate.
A kind of preparation method of high resistant water-based degaussing cable sheath material may further comprise the steps:
1, in torque rheometer, carry out mixing; Controlled temperature is 65 ℃; At first in torque rheometer, add the rubber matrix; The reinforced filling, weighting agent, secondary accelerator, softening agent, anti-aging agent, fire retardant, tinting material, vulcanization accelerator, secondary accelerator, the processing aid that add above-mentioned mass fraction more successively, with said components is mixing evenly obtain mixing colloid after, it is mixing more evenly to add vulcanizing agent.
2, adopt mill to carry out the compressing tablet film-making.
3, record mixing colloidal curing parameter t with no rotor vulkameter 90Characteristic parameter.
4, get parametric t 90Adding 1min is sulfurizing time, and pressure is 12Mpa, and temperature is 175 ℃, on vulcanizing press, produces test piece, and sample carries out each item performance detection after leaving standstill 14h.
5, the requirement that the performance that records above-mentioned style meets high resistant water-based degaussing cable sheath material gets final product.
Embodiment 2
A kind of high resistant water-based degaussing cable sheath material, it is formed with mass fraction and is: chlorinatedpolyethylene is 100 parts, 35 parts of WHITE CARBON BLACKs, 45 parts in potter's clay, 25 parts of talcum powder, 5 parts in the sour fat of triallyl isonitrile urea, 6 parts of carbon blacks, 0.5 part of calcium-zinc composite stabilizing agent, 0.5 part in paraffin, 8 parts of o-phthalic acid dibutyl esters, 20 parts of clorafins, 5 parts of yellow lead oxides, 8 parts of Antimony Trioxide: 99.5Mins, 3 parts of Di Cumyl Peroxide 99s, 2 parts of lead stearates.
A kind of preparation method of high resistant water-based degaussing cable sheath material may further comprise the steps:
1, in torque rheometer, carry out mixing; Controlled temperature is 70 ℃; At first in torque rheometer, add the rubber matrix; The reinforced filling, weighting agent, secondary accelerator, softening agent, anti-aging agent, fire retardant, tinting material, vulcanization accelerator, secondary accelerator, the processing aid that add above-mentioned mass fraction more successively, with said components is mixing evenly obtain mixing colloid after, it is mixing more evenly to add vulcanizing agent.
2, adopt mill to carry out the compressing tablet film-making.
3, record mixing colloidal curing parameter t with no rotor vulkameter 90Be characteristic parameter.
4, get parametric t 90Adding 1.5min is sulfurizing time, and pressure is 14Mpa, and temperature is 180 ℃, on vulcanizing press, produces test piece, and sample carries out each item performance detection after leaving standstill 16h.
5, the requirement that the performance that records above-mentioned style meets high resistant water-based degaussing cable sheath material gets final product.
Embodiment 3
A kind of high resistant water-based degaussing cable sheath material, it is formed with mass fraction and is: chlorinatedpolyethylene is 100 parts, 35 parts of WHITE CARBON BLACKs, 50 parts in potter's clay, 30 parts of talcum powder, 3 parts in the sour fat of triallyl isonitrile urea, 10 parts of carbon blacks, 2.5 parts of calcium-zinc composite stabilizing agents, 5 parts in paraffin, 8 parts of o-phthalic acid dibutyl esters, 22 parts of clorafins, 6 parts of yellow lead oxides, 10 parts of Antimony Trioxide: 99.5Mins, 4 parts of Di Cumyl Peroxide 99s, 3 parts of lead stearates.
A kind of preparation method of high resistant water-based degaussing cable sheath material may further comprise the steps:
1, in torque rheometer, carry out mixing; Controlled temperature is 75 ℃; At first in torque rheometer, add the rubber matrix; The reinforced filling, weighting agent, secondary accelerator, softening agent, anti-aging agent, fire retardant, tinting material, vulcanization accelerator, secondary accelerator, the processing aid that add above-mentioned mass fraction more successively, with said components is mixing evenly obtain mixing colloid after, it is mixing more evenly to add vulcanizing agent.
2, adopt mill to carry out the compressing tablet film-making.
3, record mixing colloidal curing parameter t with no rotor vulkameter 90Be characteristic parameter.
4, get parametric t 90Adding 2min is sulfurizing time, and pressure is 16Mpa, and temperature is 185 ℃, on vulcanizing press, produces test piece, and sample carries out each item performance detection after leaving standstill 18h.
5, the requirement that the performance that records above-mentioned style meets high resistant water-based degaussing cable sheath material gets final product.
More than three embodiment performance of recording high resistant water-based degaussing cable sheath material be:
Performance perameter Target value Embodiment 1 Embodiment 2 Embodiment 3
Tensile strength (MPa) before aging >;= 12 13.0 13.5 13.2
Elongation at break (%) before the presbyopic >;= 300 415 485 453
Aging back draft change rate of strength (%)<= ±30 -3 -2 -6
Aging back elongation at break velocity of variation (%)<= ±30 -11 -8 -10
Heat extension load elongation (%)<= 175 3 2 3
Oxygen index (%) >;= 35 37 38 39
Ozone resistance test There is not cracking There is not cracking There is not cracking There is not cracking
Hygroscopicity value (mg/cm 2)≤ 15 14.8 10.2 7.3
Above embodiment is under with a kind of test conditions, changes three groups of tests that the proportioning in prescription of paraffin and linking agent is carried out, and can find out from test-results, tests time for three groups, and all performances can both satisfy the performance index requirement.Change the paraffin umber, thereby utilize a paraffin ejection material surface formation skim and improve cross-linking density reduction water-absorbent through the consumption that increases linking agent.From test-results, when the paraffin consumption is that 5 parts, crosslink agent DCP consumption are 4 parts, when Antimony Trioxide: 99.5Min was 10 parts, the over-all properties of material was better.Therefore, we select this a kind of proportioning mode to remove to study other auxiliary agents to effect of material performance, thereby draw an optimum formula, so that the production reference to be provided.

Claims (10)

1. high resistant water-based degaussing cable sheath material is characterized in that: it is formed and mass fraction is: the rubber matrix is 100 parts, reinforced filling 5-50 part, weighting agent 25-70 part, promotor 3-5 part, tinting material 5-10 part, anti-aging agent 1-3 part, softening agent 7-30 part, cocuring agent 3-6 part, fire retardant 6-10 part, vulcanizing agent 2-4 part, processing aid 1-3 part.
2. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said rubber matrix is a chlorinatedpolyethylene, and said reinforced filling is one or both mixtures in WHITE CARBON BLACK, the potter's clay.
3. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said weighting agent is a talcum powder, and said promotor is triallyl isonitrile urea acid fat (TAIC).
4. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said tinting material is a carbon black.
5. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said anti-aging agent is one or both mixtures in calcium-zinc composite stabilizing agent or the paraffin.
6. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said softening agent is one or both mixtures in adjacent this dioctyl phthalate dibutyl ester or the clorafin.
7. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said cocuring agent is a yellow lead oxide, and said fire retardant is an Antimony Trioxide: 99.5Min.
8. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said vulcanizing agent is a Di Cumyl Peroxide 99.
9. according to the said high resistant water-based of claim 1 degaussing cable sheath material, it is characterized in that: said processing aid is a lead stearate.
10. preparation method of high resistant water-based degaussing cable sheath material according to claim 1 is characterized in that: may further comprise the steps:
(1) in torque rheometer, carry out mixing; Controlled temperature is 65-75 ℃; In torque rheometer, add the rubber matrix; The reinforced filling, weighting agent, secondary accelerator, softening agent, anti-aging agent, fire retardant, tinting material, vulcanization accelerator, secondary accelerator, vulcanizing agent, the processing aid that add above-mentioned mass fraction more successively evenly obtain mixing colloid with said components is mixing;
(2) adopt mill to carry out the compressing tablet film-making;
(3) record mixing colloidal curing parameter t with no rotor vulkameter 90Be characteristic parameter;
(4) get parametric t 90Adding 1~2min is sulfurizing time, and pressure is 12-16Mpa, and temperature is 175-185 ℃, on vulcanizing press, produces test piece, and sample carries out each item performance detection after leaving standstill 14-18h;
(5) requirement that the performance that records said sample meets high resistant water-based degaussing cable sheath material gets final product.
CN2011103598831A 2011-11-15 2011-11-15 High water resistance degaussing cable sheath material and preparation method thereof Pending CN102382381A (en)

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Publication number Priority date Publication date Assignee Title
CN103509283A (en) * 2013-09-06 2014-01-15 安徽华通电缆集团有限公司 Blended easy-tearing wire cable material
CN103724846A (en) * 2013-12-27 2014-04-16 福州亚舟线缆有限公司 Cable sheath and preparation method thereof
CN103897271A (en) * 2014-03-01 2014-07-02 安徽省定兴电缆有限公司 Environment-friendly ageing-resistant cable sheath material
CN104927215A (en) * 2015-02-06 2015-09-23 青岛科技大学 Wear-resistant and flame-retardant plastic track
CN106751065A (en) * 2016-12-16 2017-05-31 安徽极光照明工程有限公司 A kind of formula of industrial light light fixture electricity consumption line crust
CN106751066A (en) * 2016-12-16 2017-05-31 安徽极光照明工程有限公司 A kind of formula of outdoor illuminating lamp electricity consumption wire-coated material
CN106916386A (en) * 2017-04-26 2017-07-04 天津金山电线电缆股份有限公司 A kind of water proof rubber flexible cable sheath material and preparation method thereof
CN107216557A (en) * 2017-07-20 2017-09-29 合肥安力电力工程有限公司 A kind of cable material with ageing-resistant performance and preparation method thereof
CN108034097A (en) * 2017-12-01 2018-05-15 安徽渡江电缆集团有限公司 A kind of cable jacket material
CN108666014A (en) * 2018-06-20 2018-10-16 沈阳天荣电缆材料有限公司 A kind of sea water resistance semiconductive sealing binding strap and preparation method thereof
CN108676265A (en) * 2018-04-12 2018-10-19 天津大学 High heat conduction degaussing cable sheath material and preparation method
CN110504053A (en) * 2019-08-28 2019-11-26 江苏亨通电力电缆有限公司 Wind power generating set presses antitorque power cable in
CN110828033A (en) * 2019-11-08 2020-02-21 中国船舶重工集团公司第七0四研究所 Scrape-abrasion-resistant seawater corrosion-resistant degaussing cable and processing technology thereof
CN116814012A (en) * 2023-05-31 2023-09-29 吉林盛大电缆有限公司 Low-temperature-resistant chlorinated polyethylene cable protective sleeve material and preparation method thereof
US12034148B2 (en) 2017-10-27 2024-07-09 Lg Energy Solution, Ltd. Negative electrode active material for lithium secondary battery and lithium secondary battery comprising the same

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509283A (en) * 2013-09-06 2014-01-15 安徽华通电缆集团有限公司 Blended easy-tearing wire cable material
CN103509283B (en) * 2013-09-06 2016-01-20 安徽华通电缆集团有限公司 One is blended easily tears wire cable material
CN103724846A (en) * 2013-12-27 2014-04-16 福州亚舟线缆有限公司 Cable sheath and preparation method thereof
CN103724846B (en) * 2013-12-27 2016-01-06 福州亚舟线缆有限公司 A kind of cable sheath and preparation method thereof
CN103897271A (en) * 2014-03-01 2014-07-02 安徽省定兴电缆有限公司 Environment-friendly ageing-resistant cable sheath material
CN104927215A (en) * 2015-02-06 2015-09-23 青岛科技大学 Wear-resistant and flame-retardant plastic track
CN106751065A (en) * 2016-12-16 2017-05-31 安徽极光照明工程有限公司 A kind of formula of industrial light light fixture electricity consumption line crust
CN106751066A (en) * 2016-12-16 2017-05-31 安徽极光照明工程有限公司 A kind of formula of outdoor illuminating lamp electricity consumption wire-coated material
CN106916386A (en) * 2017-04-26 2017-07-04 天津金山电线电缆股份有限公司 A kind of water proof rubber flexible cable sheath material and preparation method thereof
CN107216557A (en) * 2017-07-20 2017-09-29 合肥安力电力工程有限公司 A kind of cable material with ageing-resistant performance and preparation method thereof
US12034148B2 (en) 2017-10-27 2024-07-09 Lg Energy Solution, Ltd. Negative electrode active material for lithium secondary battery and lithium secondary battery comprising the same
CN108034097A (en) * 2017-12-01 2018-05-15 安徽渡江电缆集团有限公司 A kind of cable jacket material
CN108676265A (en) * 2018-04-12 2018-10-19 天津大学 High heat conduction degaussing cable sheath material and preparation method
CN108666014A (en) * 2018-06-20 2018-10-16 沈阳天荣电缆材料有限公司 A kind of sea water resistance semiconductive sealing binding strap and preparation method thereof
CN110504053A (en) * 2019-08-28 2019-11-26 江苏亨通电力电缆有限公司 Wind power generating set presses antitorque power cable in
CN110828033A (en) * 2019-11-08 2020-02-21 中国船舶重工集团公司第七0四研究所 Scrape-abrasion-resistant seawater corrosion-resistant degaussing cable and processing technology thereof
CN116814012A (en) * 2023-05-31 2023-09-29 吉林盛大电缆有限公司 Low-temperature-resistant chlorinated polyethylene cable protective sleeve material and preparation method thereof
CN116814012B (en) * 2023-05-31 2024-02-06 吉林盛大电缆有限公司 Low-temperature-resistant chlorinated polyethylene cable protective sleeve material and preparation method thereof

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Application publication date: 20120321