CN102382363A - Modified polypropylene material and preparation method thereof - Google Patents
Modified polypropylene material and preparation method thereof Download PDFInfo
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- CN102382363A CN102382363A CN2010106071623A CN201010607162A CN102382363A CN 102382363 A CN102382363 A CN 102382363A CN 2010106071623 A CN2010106071623 A CN 2010106071623A CN 201010607162 A CN201010607162 A CN 201010607162A CN 102382363 A CN102382363 A CN 102382363A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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Abstract
The invention discloses a modified polypropylene material, which is characterized by being prepared from the following raw materials in percentage by weight: 60-90 percent of polypropylene, 0-35 percent of talc powder, 1-10 percent of ordered mesoporous material, 1-10 percent of toughening agent, 0.1-1.0 percent of heat stabilizer and 0.1-2.0 percent of antioxidant. The modified polypropylene material has low smell (the smell level is lower than 3), and can be used for improving the internal air quality of an automobile when applied to an automotive interior; the modified polypropylene material has excellent physical and mechanical properties (the tensile strength is over 25 MPa, and the bending strength is over 36 MPa), and the application requirements of automotive interiors are met; and by adopting the modified polypropylene material, the material quality of an automotive interior is improved, and industrial application of the ordered mesoporous material to the field of low-smell materials special for automobiles is facilitated. A preparation method of the modified polypropylene material has the advantages of easiness for operating, low carbon, environmental friendliness and economic efficiency.
Description
Technical field
The present invention relates to a kind of modified polypropylene material and preparation method thereof, relate in particular to a kind of modified polypropylene material that is applied to the low smell of automotive upholstery and preparation method thereof.
Background technology
In recent years; The smell problem of automotive upholstery has caused that world car is manufacturing and has shown great attention to; All contain a certain amount of volatile organic compounds in most of inner-decoration components; They mainly are the materials of alkane, alkene, aromatic hydrocarbons, acetaldehyde or ketone, and the boiling point of these materials is usually within 50～260 ℃ scope.When temperature reach a certain height, these volatile matter will discharge, and some can form the fog pass and condense on the front windshield, thereby influenced officer's sight line; Some then generation make us uncomfortable smell, even cause uncomfortable reaction such as headache, dry cough and allergy, thereby occupant's health damaged.Reducing the volatility of automotive upholstery material, improve the Air quality of automotive interior, is one of common target of pursuing of automaker and automotive material manufacturers.From the automotive plastic kind, Vestolen PP 7052 (being called for short PP) material accounts for more than 40% of automotive plastic, and wherein car interior trim consumption accounts for more than 2/3, so polypropylene material is one of main source of smell in the automobile.So, must take effective way to prepare low smell even scentless polypropylene material.
Usually, the smell of polypropylene material is owing to the following aspects causes.At first, the catalyst system that in acrylic resin matrix building-up process, uses contains the compound that some have the pungency peculiar smell, like ester compound or alkane derivative.This compounds can not be removed after resin polymerization is accomplished fully, and they remain in the middle of the acrylic resin, thereby make polypropylene material have irritating smell.Secondly, carry out in the process of modification processing at the acrylic resin matrix, acrylic resin more or less can produce the low molecular compound of some degraded under the fused state, like ketone, aldehyde compound.These material parts rest in the middle of the material after the modification, in the use of product, progressively give out irritating smell.Once more, some filler components that added in the modified polypropylene material, like talcum powder, they can have some irritating smell equally.At last, some stablizer that is added in the modified polypropylene material also has certain irritating smell.
The PP composite material and the complete processing that are used as the low odor dispersion level of automotive upholstery at present both at home and abroad mainly contain following 3 kinds of modes:
(1) devolatilization
This method mainly is to utilize the devolatilization equipment and technology of specialty in the Vestolen PP 7052 polymerization process, to carry out devolatilization.Fukui etc. adopt the method for high temperature extruding pelletization in U.S. Pat P 5109056; And in the middle of the process of extruding, adopt the mode that vacuumizes; At last the particle of making is being carried out flint dry, removing the residue of the alkane derivative that produces smell with this.Research shows, devolatilization in polymerization process, and efficient is higher, but because the limitation of its Processes and apparatus, and cost is higher, is difficult for widespread use.
(2) physisorphtion
This method mainly is to add sorbent materials such as mineral soil, zeolite molecular sieve such as gac, silica gel, attapulgite at Vestolen PP 7052, then through screw extrusion press extruding pelletization under certain process conditions.Can also plastics be placed among the odor adsorption agent such as gac and high surface area silicate, the vacuum-treat environment can be accelerated desorption process.The Chinese patent CN1730534A and the Shanghai Jinfa Technology Development Co., Ltd of Pulite Composite Material Co., Ltd., Shanghai's application all adopt zeolite molecular sieve material as physical absorbent in Chinese patent CN1840576A.Research shows, in polymkeric substance, fills a spot of zeolite molecular sieve material, can play the effect of removing the material smell.Zeolite has a large amount of crystallization cavities, and those gas molecules with smell can be caught in these cavities.The smell of gained material obviously reduces, and each item mechanical property of material is relatively good.
(3) chemical reaction method
This method is meant and in the middle of material prescription, adds the additive that can discharge the small molecules reaction of smell with these; Through the reaction between these additives and the small molecules produce molecular weight big, use under the thermal environment normal; As less than 100 ℃; Can from material, not evaporate the another kind of compound that produces peculiar smell, thereby reach the effect of eliminating peculiar smell.Yui etc. adopt alkyl 3 in U.S. Pat 4080359, the smell problem that some stablizers brought that the method for 5-two-Te-butyl-4-hydroxyl-carboxylation styracin and dialkyl group thiodipropionate acetate mixture solves in the modified polypropylene material to be added.Rifi etc. adopt a kind of esterification glyceride type compound, a kind of epoxy compounds, a kind of monohydroxy-alcohol or multicomponent alcoholics compound, a kind of fatty acid ester compound or the mixture of above-mentioned several kinds of compounds in U.S. Pat 4851499; Through above-claimed cpd and acrylic resin are melt extruded; In the middle of the process of extruding, make these compounds and the ester class residue that has peculiar smell carry out transesterification reaction; Form other macromolecular compounds and be fixed in the middle of the resin, thereby reach the purpose of removing this smell.Result of study shows that chemical reaction method can be controlled other performances that do not influence material in theory, but the related reaction of this method is extremely complicated, not easy to operate.
Above-mentioned research method about the automotive upholstery odor eliminating on some angle, all has solution in various degree to the smell problem of polypropylene material.Yet, as the polypropylene material that the automotive upholstery product uses, its in modifying process the relevant smell factor that will consider be not only certain discrete factor wherein.At first, the fundamental starting point that solves this type modified polypropylene material smell must consider that certainly acrylic resin matrix self some in the middle of polymerization process have the residue problem of pungency peculiar smell; Secondly, therefore this type modified polypropylene material all must will consider the thermo-cracking small molecules problem in the extruding pelletization process through melt extruding granulation; Once more, the thermo-oxidative ageing of this type polypropylene material requires also very high, therefore must add corresponding stabiliser system, and this must consider some the smell problem that possibly bring in the stabilizer component.And above-mentioned the whole bag of tricks all is that modification is carried out in certain aspect wherein, can not solve the problem that all respects produce smells.
Physical adsorption can be adsorbed the small molecules of any generation smell or other fugitive constituents in theory, therefore an ideal effect might all be arranged to all respects that produce this problem.And along with the physical absorbent industrial expansion, the multiple physical absorbent system that grown up at present comprises mineral soil body system, molecular sieve system etc. such as gac system, silica gel system, attapulgite.Based on adsorption effect, when above-mentioned serial sorbent systems was distributed in resin matrix with a definite form, they all can adsorb the small molecules that produces smell or other fugitive constituent in the resin material.Yet in the middle of the application of reality, they have deficiency separately again.For example, adopt traditional gac as sorbent material, before use by special sorbent material activating apparatus with its activation, the micropore through gac plays adsorption to the small molecules that discharges smell in the macromolecular material.The problem that this method produces is: the micropore size size distribution in the gac is uneven; Difference is very big; Maximum aperture reaches about 100nm; Therefore often the additive of other intermediate molecular weight of adding is simultaneously adsorbed together, this has greatly influenced mechanical property and the thermo-oxidative stability etc. of material.Therefore, gac using value in this regard is little.And when adopting mineral soil body system such as attapulgite to remove system as smell, it is uneven to be faced with sorbent material micropore size size distribution equally, and difference is very big, thereby causes problem that other intermediate molecular weight additives that add are adsorbed together.The general aperture of widely used now zeolite molecular sieve material＜1.5 nm; Because its aperture is less, the major diameter molecule gets into the duct difficulty, and diffusional resistance is bigger simultaneously; The accumulative gas molecule can not be overflowed fast in its vestibule, thereby has limited its application in adsorbing domain.
Summary of the invention
The object of the present invention is to provide a kind of modified polypropylene material that satisfies the low smell of automotive upholstery application requiring.
Another object of the present invention is to provide a kind of preparation method of above-mentioned modified polypropylene material.
The present invention seeks to realize like this; A kind of modified polypropylene material is characterized in that: it is made by following materials of weight proportions: Vestolen PP 7052 60 ~ 90%, talcum powder 0～35%, ordered mesoporous material 1～10%, toughner 1～10%, thermo-stabilizer 0.1～1.0% and oxidation inhibitor 0.1～2.0%.
Ordered mesoporous material is that a kind of novel high-ratio surface (can be up to 2000 m
2/ g), the aperture size homogeneous is adjustable (2 ~ 50nm), arrange the material of long-range order, be applied to chemical catalysis field at present more, protein adsorption is separated, enzyme biological field such as fix.Compare with the normal physical absorbent molecular screen material that adopts in the prior art, the ordered mesoporous material pore diameter range is big, good stability, duct shape various (cylindrical, sphere or tabular), good characteristics such as modified surface.The present invention makes full use of these character of ordered mesoporous material, organically combines the volatile matter in the adsorption vehicle inside gadget polypropylene material (for example amine, phenol, mercaptan, superoxide, benzene, aldehyde, ketone etc.) with Vestolen PP 7052.
In order to make in the modified polypropylene material of the present invention the ordered mesoporous material adsorption effect better; The preferred meso pore silicon oxide material of above-mentioned ordered mesoporous material; Further preferred MCM-41 mesoporous material or SBA-15 mesoporous material; Said MCM-41 mesoporous material belongs to the one-dimensional channels system structure, has aperture evenly (mean pore size is at 3.5nm), high-specific surface area (800～1000m
2/ g) with big loading capacity (0.8～1cm
3/ g) characteristics more help the rapid diffusion of gas molecule than traditional molecular screen materials such as zeolite and aluminophosphates; To account for the per-cent of raw material gross weight, the preferred 3-5% of above-mentioned ordered mesoporous material, further preferred 3%.
In order to make modified polypropylene material excellent combination property of the present invention; Preferred homo-polypropylene of above-mentioned Vestolen PP 7052 and/or block copolymerization propylene; Like the PP HP500N homo-polypropylene that the Basel produces, PP BJ350 homo-polypropylene and PP BJ750 block copolymerization propylene that Korea S's Samsung is produced, the PP 1304E1 homo-polypropylene that Exxon Mobil Corporation produces; The K8303 block copolymerization propylene that Yanshan Petrochemical is produced, the PP T30S block copolymerization propylene that Daqing petrochemical is produced etc.
In order to make modified polypropylene material of the present invention have better toughness, above-mentioned toughner optimal ethylene-octene copolymer (being called for short POE) or terpolymer EP rubber (being called for short EPDM); POE is a kind of ethylene-octene copolymer; Octene content is between 20%-30%; Density is 0.88～0.90g/cm3; Melting index is 1～50g/10min, and its distinctive molecular structure has determined its excellent comprehensive performance, its elasticity brilliance, good fluidity, mechanical property height, erosion resistance, the lower temperature resistance that ventilation property is good, electrical property is excellent and outstanding, heat-resisting, anti-ozone, UV resistant and water tolerance; In order to give more excellent comprehensive performance of modified polypropylene material of the present invention; Reduce little like modulus in flexure and tensile strength; And higher toughness, high transparent, high-performance/price compares etc., and above-mentioned toughner further is preferably ethylene-octene copolymer (POE).
In order to make modified polypropylene material excellent combination property of the present invention, preferred 0.5～10 micron of above-mentioned talcous particle size range.
In order to make modified polypropylene material excellent combination property of the present invention, above-mentioned thermo-stabilizer preferably contains the thioesters type thermal stabilizing agent, like Tyox B (being called for short DLTP) or thio-2 acid stearic acid (being called for short DSTP); Further preferred DSTP, the trade names of producing like Britain ICE company are Negonxo DSTP, the fusing point that toxicity is low is 41 ℃ white crystalline powder DSTP.
In order to make modified polypropylene material excellent combination property of the present invention; Above-mentioned oxidation inhibitor preferably adopts Hinered phenols antioxidant or/and phosphite ester kind antioxidant; Like antioxidant 1010 or the oxidation inhibitor 168 that Ciba company produces, the anti-oxidant Irganox 1076 that Liaoyang Organic Chemical Plant produces etc.; The compound antioxidant of further preferred antioxidant 1010 and oxidation inhibitor 168; The trade names of producing like Ciba company are the antioxidant 1010 of Irganox 1010; Its chemical name is four (β-(3; The 5-di-tert-butyl-hydroxy phenyl) pentaerythritol ester propionic acid), oxidation inhibitor 168 is produced for Ciba company, and trade names are Irgafos 168; Chemical name is three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester.
The preparation method of above-mentioned modified polypropylene material is characterized in that: it comprises the steps: that elder generation with said ratio raw material thorough mixing, adds in the twin screw extruder again, and through melt extruding, granulation gets product; Said thorough mixing can add raw material and carries out thorough mixing in the super mixer.
For modified polypropylene material over-all properties that preparation method of the present invention is made is more superior, above-mentioned twin screw extruder length-to-diameter ratio is 40:1, and screw speed is at 100～500 rev/mins; It is 130～250 ℃ that its twin screw is extruded working temperature one district, and two districts are 140～260 ℃, and three districts are 150～270 ℃; Four districts are 160～280 ℃, and five districts are 160～280 ℃, and six districts are 160～280 ℃; Seven districts are 160～280 ℃, and 1～2 minute residence time, pressure is 12～18Mpa.
The beneficial effect that the present invention has
The present invention adopts the sorbent material of ordered mesoporous material as modified polypropylene material; Organically combine with other raw material; Not only active adsorption the smell that produces in the modified polypropylene material production process; Make modified polypropylene material have the characteristic of low smell; When being applied to automotive upholstery, improved the Air quality of automotive interior, having overcome in the background technology influences pilot's line of vision and causes the shortcoming that uncomfortable reaction pair occupant healths such as people's headache, dry cough and allergy damage because of what the automotive upholstery material caused; But also make that each item physical and mechanical property of modified polypropylene material is excellent, and satisfy the automotive upholstery application requiring, when having promoted the automotive upholstery material quality, also promoted the industrial applications of ordered mesoporous material in low smell automobile special material field.
The oder levels of modified polypropylene material of the present invention is lower than 3, and the organic cpds volatility is lower than 0.25%; And add the polypropylene material of non-mesoporous material as sorbent material, and its oder levels is generally greater than 3, and the organic cpds volatility is more than 0.25%.
The mechanical property of modified polypropylene material of the present invention (like tensile strength and flexural strength) is significantly improved, and wherein tensile strength is more than 25Mpa, and flexural strength is more than 36Mpa; And added the polypropylene material of non-mesoporous material as sorbent material, because the amplitude that its mechanical property of adding sorbent material generally can decrease or improve is little.
When preparation modified polypropylene material of the present invention; Because of modified polypropylene material of the present invention adopts ordered mesoporous material as sorbent material; Need not special sorbent material activating apparatus, the finished product of preparation just can adsorb smell rapidly, and the preparation method who makes modified polypropylene material of the present invention is low-carbon environment-friendly both; Simply, easy to operate, also have favorable economic benefit.
Embodiment
Through embodiment the present invention is carried out concrete description below; Be necessary to be pointed out that at this following examples only are used for the present invention is further specified; Can not be interpreted as the restriction to protection domain of the present invention, those skilled in the art can make some nonessential improvement and adjustment to the present invention according to the invention described above content.
Embodiment 1A kind of modified polypropylene material; Make like this; By weight ratio, the Vestolen PP 7052 with 60.15%, 29.6% talcum powder, 5% MCM-41 mesoporous material, 4% toughner POE, 0.8% thermo-stabilizer DSTP, 0.35% antioxidant 1010,0.1% oxidation inhibitor 168 thorough mixing add in the twin screw extruder through melt extruding again; Granulation gets product.
The length-to-diameter ratio of this routine twin screw extruder is 40:1, and screw speed is 200 rev/mins, and forcing machine working temperature one district is 170 ℃; Two districts are 200 ℃, and three districts are 210 ℃, and four districts are 205 ℃; Five districts are 200 ℃, and six districts are 210 ℃, and seven districts are 200 ℃; 1～2 minute residence time, pressure is 12～18Mpa.
Modified polypropylene material to the present embodiment preparation carries out comprehensive mechanical property, smell and the test of organism volatility:
Material pre-treatment---the modified polypropene particulate material that will make as stated above in 90～100 ℃ convection oven dry 2～3 hours carries out the injection molding sample preparation with it again on injection moulding machine;
Comprehensive mechanical performance is estimated through the numerical value of test tensile strength and shock strength; The tensile property test is undertaken by ISO527～2, and specimen size is 150 * 10 * 4mm, and draw speed is 50mm/min; The bending property test is undertaken by ISO178, and specimen size is 80 * 10 * 4mm, and rate of bending is 2mm/min, and span is 64mm;
The odor property of material is tested by the PV3900 of Volkswagen, and sample mass is 40～60g, and the vessel content size is 1 liter; The odor property of material is divided into according to standard code: 1 grade: odorlessness, 2 grades: scent of, but non interference smell; 3 grades: obvious smell is arranged, but the non interference smell, 4 grades: the interference smell is arranged; 5 grades: strong interference smell is arranged, 6 grades: insupportable smell is arranged;
The sample of certain mass was got in the test of the organism volatility of material, 100 ℃ of held 10 hours; The volatile calculating of material organism is calculated according to self-defined formula: volatility %=(quality of material initial mass-material after the standard code held)/material initial mass * 100%; Calculate; The high more expression material of the numerical value organic cpds volatility of calculating gained is big more, otherwise then more little.
Modified polypropylene material tensile strength through the preparation of test present embodiment is 37.65Mpa, and flexural strength is 54.3Mpa, oder levels 2.3, and the organic cpds volatility is 0.14%.
Embodiment 2A kind of modified polypropylene material; Make like this; By weight ratio, be 0.1% thorough mixing with Vestolen PP 7052 60.95%, talcum powder 29.8%, MCM-41 mesoporous material 4%, toughner POE 4%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.35%, oxidation inhibitor 168, add again in the twin screw extruder through melt extruding; Granulation gets product; Wherein the length-to-diameter ratio of twin screw extruder is 40:1, and screw speed is 200 rev/mins, and the forcing machine working temperature is 170 ℃ in a district, 200 ℃ in two districts; 210 ℃ in three districts, 205 ℃ in four districts, 200 ℃ in five districts, 210 ℃ in six districts; 200 ℃ in seven districts, 1～2 minute residence time, pressure is 12～18Mpa.The tensile strength of present embodiment modified polypropylene material is 36.5Mpa; Flexural strength is 54.1Mpa; Oder levels 2.3, organic cpds volatility are 0.16% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 3A kind of modified polypropylene material; Make like this; By weight ratio, be 0.1% thorough mixing with Vestolen PP 7052 62.8%, talcum powder 29%, MCM-41 mesoporous material 3%, toughner POE 4%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.3%, oxidation inhibitor 168; Add in the twin screw extruder through melt extruding, granulation gets product again; Wherein the length-to-diameter ratio of twin screw extruder is 40:1, and screw speed is 200 rev/mins, and the forcing machine working temperature is 170 ℃ in a district, 200 ℃ in two districts; 210 ℃ in three districts, 205 ℃ in four districts, 200 ℃ in five districts, 210 ℃ in six districts; 200 ℃ in seven districts, 1～2 minute residence time, pressure is 12～18Mpa.Present embodiment modified polypropylene material tensile strength is 35.8Mpa; Flexural strength is 54Mpa; Oder levels 2.4, organic cpds volatility are 0.18% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 4A kind of modified polypropylene material; Make like this; By weight ratio, be 0.1% thorough mixing with Vestolen PP 7052 62.75%, talcum powder 30%, MCM-41 mesoporous material 2%, toughner POE 4%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.35%, oxidation inhibitor 168; Add in the twin screw extruder through melt extruding, granulation gets product again; Wherein the length-to-diameter ratio of twin screw extruder is 40:1, and screw speed is 200 rev/mins, and the forcing machine working temperature is 170 ℃ in a district, 200 ℃ in two districts; 210 ℃ in three districts, 205 ℃ in four districts, 200 ℃ in five districts, 210 ℃ in six districts; 200 ℃ in seven districts, 1～2 minute residence time, pressure is 12～18Mpa.Present embodiment modified polypropylene material tensile strength is 35.2Mpa; Flexural strength is 53.9Mpa; Oder levels 2.5, organic cpds volatility are 0.20% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 5A kind of modified polypropylene material; Make like this; By weight ratio, be 0.1% thorough mixing with Vestolen PP 7052 63.75%, talcum powder 30%, MCM-41 mesoporous material 1%, toughner POE 4%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.35%, oxidation inhibitor 168; Add in the twin screw extruder through melt extruding, granulation gets product again; Wherein the length-to-diameter ratio of twin screw extruder is 40:1, and screw speed is 200 rev/mins, and the forcing machine working temperature is 170 ℃ in a district, 200 ℃ in two districts; 210 ℃ in three districts, 205 ℃ in four districts, 200 ℃ in five districts, 210 ℃ in six districts; 200 ℃ in seven districts, 1～2 minute residence time, pressure is 12～18Mpa.Present embodiment modified polypropylene material 34.95Mpa, flexural strength is 52.8Mpa, oder levels 2.8, the organic cpds volatility is 0.23% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard is with embodiment 1).
Embodiment 6A kind of modified polypropylene material makes like this, by weight ratio, is 0.35% thorough mixing with Vestolen PP 7052 90 %, MCM-41 mesoporous material 3.5%, toughner POE 5%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.35%, oxidation inhibitor 168; Add in the twin screw extruder through melt extruding, granulation gets product again; Wherein the length-to-diameter ratio of twin screw extruder is 40:1, and screw speed is 200 rev/mins, and the forcing machine working temperature is 170 ℃ in a district, 200 ℃ in two districts; 210 ℃ in three districts, 205 ℃ in four districts, 200 ℃ in five districts, 210 ℃ in six districts; 200 ℃ in seven districts, 1～2 minute residence time, pressure is 12～18Mpa.Present embodiment modified polypropylene material tensile strength is 25.95 Mpa; Flexural strength is 36.72 Mpa; Oder levels 2.3, organic cpds volatility are 0.20% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 7A kind of modified polypropylene material; Make like this; By weight ratio; With the PP HP500N homo-polypropylene 60% of Basel's production, talcum powder 35%, MCM-41 mesoporous material 3%, toughner terpolymer EP rubber (being called for short EPDM) 1%, thermo-stabilizer DSTP 0.8%, antioxidant 1010 0.1%, the oxidation inhibitor 168 that particle diameter is 0.5 micron is 0.1% adding super mixer, thorough mixing; Add in the twin screw extruder through melt extruding, granulation gets product again.Present embodiment modified polypropylene material tensile strength is higher than 25 Mpa; Flexural strength is higher than 36 Mpa; Oder levels is lower than 3, and the organic cpds volatility is lower than 0.25% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 8A kind of modified polypropylene material; Make like this; By weight ratio; With PP BJ350 homo-polypropylene 40% and PP BJ750 block copolymerization propylene 50% that Korea S's Samsung is produced, MCM-48 mesoporous material 6%, toughner POE 1%, thermo-stabilizer DSTP 1%, antioxidant 1010 1%, oxidation inhibitor 168 are 1% thorough mixing; Add in the twin screw extruder through melt extruding, granulation gets product again.Present embodiment modified polypropylene material tensile strength is higher than 25 Mpa; Flexural strength is higher than 36 Mpa; Oder levels is lower than 3, and the organic cpds volatility is lower than 0.25% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 9A kind of modified polypropylene material; Make like this; By weight ratio, the K8303 block copolymerization propylene of Yanshan Petrochemical being produced 72%, the talcum powder 7.8% that particle diameter is 10 microns, SBA-15 mesoporous material 10%, toughner POE 10%, thermo-stabilizer Tyox B (being called for short DLTP) 0.1%, antioxidant 1010 0.1% thorough mixing; Add in the twin screw extruder through melt extruding, granulation gets product again.
This routine twin screw extruder length-to-diameter ratio is 40:1, and screw speed is at 500 rev/mins; It is 250 ℃ that its twin screw is extruded working temperature one district, and two districts are 140 ℃, and three districts are 150 ℃, and four districts are 1280 ℃, and five districts are 280 ℃, and six districts are 280 ℃, and seven districts are 160 ℃, and 1～2 minute residence time, pressure is 12～18Mpa.
Present embodiment modified polypropylene material tensile strength is higher than 25 Mpa; Flexural strength is higher than 36 Mpa; Oder levels is lower than 3, and the organic cpds volatility is lower than 0.25% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Embodiment 10A kind of modified polypropylene material; Make like this; By weight ratio, anti-oxidant Irganox 1,076 0.1% thorough mixing that the K8303 block copolymerization propylene of Yanshan Petrochemical being produced 70%, the talcum powder 9.8% that particle diameter is 5 microns, SBA-16 mesoporous material 10%, toughner POE 10%, thermo-stabilizer DSTP 0.1%, Liaoyang Organic Chemical Plant produce; Add in the twin screw extruder through melt extruding, granulation gets product again.
This routine twin screw extruder length-to-diameter ratio is 40:1, and screw speed is at 100 rev/mins; It is 130 ℃ that its twin screw is extruded working temperature one district, and two districts are 260 ℃, and three districts are 270 ℃, and four districts are 160 ℃, and five districts are 160 ℃, and six districts are 160 ℃, and seven districts are 280 ℃, and 1～2 minute residence time, pressure is 12～18Mpa.
Present embodiment modified polypropylene material tensile strength is higher than 25 Mpa; Flexural strength is higher than 36 Mpa; Oder levels is lower than 3, and the organic cpds volatility is lower than 0.25% (evaluation method of material comprehensive mechanical property, smell and the test of organism volatility and implementation standard are with embodiment 1).
Claims (10)
1. modified polypropylene material, it is characterized in that: it is made by following materials of weight proportions: Vestolen PP 7052 60 ~ 90%, talcum powder 0～35%, ordered mesoporous material 1～10%, toughner 1～10%, thermo-stabilizer 0.1～1.0% and oxidation inhibitor 0.1～2.0%.
2. modified polypropylene material as claimed in claim 1 is characterized in that: said ordered mesoporous material is a meso pore silicon oxide material.
3. according to claim 1 or claim 2 modified polypropylene material, it is characterized in that: said meso pore silicon oxide material is MCM-41 mesoporous material or SBA-15 mesoporous material.
4. according to claim 1 or claim 2 modified polypropylene material, it is characterized in that: to account for the per-cent of raw material gross weight, said ordered mesoporous material is 3～5%.
5. modified polypropylene material as claimed in claim 3 is characterized in that: to account for the per-cent of raw material gross weight, said ordered mesoporous material is 3～5%.
6. like the arbitrary described modified polypropylene material of claim 1～5, it is characterized in that: said Vestolen PP 7052 is homo-polypropylene and/or block copolymerization propylene.
7. modified polypropylene material as claimed in claim 6 is characterized in that: said talcous particle diameter is 0.5～10 micron.
8. like claim 6 or 7 described modified polypropylene materials, it is characterized in that: said toughner is ethylene-octene copolymer or terpolymer EP rubber.
9. like the preparation method of the arbitrary described modified polypropylene material of claim 1～8, it is characterized in that: it comprises the steps: that elder generation with said ratio raw material thorough mixing, adds in the twin screw extruder again, and through melt extruding, granulation gets product.
10. the preparation method of modified polypropylene material as claimed in claim 9, it is characterized in that: said twin screw extruder length-to-diameter ratio is 40:1, and screw speed is at 100～500 rev/mins; It is 130～250 ℃ that its twin screw is extruded working temperature one district, and two districts are 140～260 ℃, and three districts are 150～270 ℃; Four districts are 160～280 ℃, and five districts are 160～280 ℃, and six districts are 160～280 ℃; Seven districts are 160～280 ℃, and 1～2 minute residence time, pressure is 12～18Mpa.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690466A (en) * | 2012-05-29 | 2012-09-26 | 上海瀚氏模具成型有限公司 | Anti-aging polypropylene material and preparation method thereof |
| CN103242463A (en) * | 2013-05-10 | 2013-08-14 | 长沙精智塑化新材料有限公司 | Method for preparing polypropylene with high melt index |
| CN103897565A (en) * | 2013-11-15 | 2014-07-02 | 东南大学 | Low-odor resin coating |
| EP2851394A1 (en) | 2013-09-19 | 2015-03-25 | Lanxess Elastomers B.V. | Vulcanizable rubber composition for low fogging articles |
| CN105754212A (en) * | 2016-03-07 | 2016-07-13 | 北京聚菱燕塑料有限公司 | Low VOC blend material and preparation method thereof |
| CN105996123A (en) * | 2016-05-27 | 2016-10-12 | 阜阳卷烟材料厂 | Cigarette filter stick for reducing release quantity of crotonaldehyde in smoke gas |
| CN106243487A (en) * | 2016-07-29 | 2016-12-21 | 苏州润佳工程塑料股份有限公司 | Anti-Budgerigar stricture of vagina, nonshrink wall, low warpage PP composite material |
| CN106700379A (en) * | 2016-12-25 | 2017-05-24 | 合肥会通新材料有限公司 | Highly filled low-density polypropylene composite material and preparation method thereof |
| CN107189196A (en) * | 2017-05-19 | 2017-09-22 | 浙江帝恒实业有限公司 | A kind of polypropylene material of low smell environment-friendly type and preparation method thereof |
| CN108485066A (en) * | 2018-04-08 | 2018-09-04 | 成都工业学院 | A kind of automobile-used PP composite material of environmental protection type, less smell and preparation method thereof |
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| CN111057306A (en) * | 2019-12-25 | 2020-04-24 | 会通新材料(上海)有限公司 | TPV composition and preparation method thereof |
| CN111393749A (en) * | 2020-04-30 | 2020-07-10 | 宁夏大学 | Polypropylene composite material and preparation method thereof |
| CN112574499A (en) * | 2020-12-14 | 2021-03-30 | 天津金发新材料有限公司 | High-performance, low-odor and low-VOC polypropylene whisker modified material and preparation method thereof |
| CN114456411A (en) * | 2020-10-21 | 2022-05-10 | 中国石油化工股份有限公司 | Polypropylene resin with low VOC content and preparation method thereof |
| CN115418048A (en) * | 2022-09-01 | 2022-12-02 | 浙江利帆家具有限公司 | Anti-shrinkage polypropylene furniture board composite material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1840576A (en) * | 2005-04-01 | 2006-10-04 | 上海金发科技发展有限公司 | High-performance low-odour polypropylene dedicated for automobile dashboard and method for preparing same |
-
2010
- 2010-12-27 CN CN2010106071623A patent/CN102382363A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1840576A (en) * | 2005-04-01 | 2006-10-04 | 上海金发科技发展有限公司 | High-performance low-odour polypropylene dedicated for automobile dashboard and method for preparing same |
Non-Patent Citations (1)
| Title |
|---|
| 王娜等: "纳米介孔 MCM-41 填充物对聚丙烯基复合材料性能的影响", 《材料工程》 * |
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| CN103242463A (en) * | 2013-05-10 | 2013-08-14 | 长沙精智塑化新材料有限公司 | Method for preparing polypropylene with high melt index |
| EP2851394A1 (en) | 2013-09-19 | 2015-03-25 | Lanxess Elastomers B.V. | Vulcanizable rubber composition for low fogging articles |
| US9944781B2 (en) | 2013-09-19 | 2018-04-17 | Lanxess Deutschland Gmbh | Vulcanizable rubber composition for low fogging articles |
| CN103897565A (en) * | 2013-11-15 | 2014-07-02 | 东南大学 | Low-odor resin coating |
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| CN108485066A (en) * | 2018-04-08 | 2018-09-04 | 成都工业学院 | A kind of automobile-used PP composite material of environmental protection type, less smell and preparation method thereof |
| CN108485066B (en) * | 2018-04-08 | 2021-03-16 | 成都工业学院 | Environment-friendly low-odor polypropylene composite material for vehicles and preparation method thereof |
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