CN102368145A - Blue high-temperature resisting ceramic toner and preparation method thereof - Google Patents
Blue high-temperature resisting ceramic toner and preparation method thereof Download PDFInfo
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- CN102368145A CN102368145A CN 201110327960 CN201110327960A CN102368145A CN 102368145 A CN102368145 A CN 102368145A CN 201110327960 CN201110327960 CN 201110327960 CN 201110327960 A CN201110327960 A CN 201110327960A CN 102368145 A CN102368145 A CN 102368145A
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Abstract
The invention discloses a blue high-temperature resisting ceramic toner and a preparation method thereof. According to the invention, a blue inorganic ceramic pigment, styrene-acrylic resin, poly propylene wax, a charge regulator, dimethyl dichlorosilane, hexamethyl disilazane are processed through mixing, performing, rough crushing, jet milling, classifying, sieving, and the like, such that the ceramic toner is obtained. The ceramic toner is high-temperature resisting. The blue high-temperature resisting ceramic toner is used in combination with other high-temperature resisting ceramic toners of three fundamental colors of black, yellow and red. The printed colored patterns and texts are stuck on a ceramic greenware, and the ceramic greenware is fired under a temperature of 800 DEG C. After the processes, fading of the patterns and texts is not occurred, and qualities of ceramic products can be ensured.
Description
Technical field
The present invention relates to a kind of ink powder and preparation method thereof.Specifically, be blue refractory ceramics ink powder of multicolour laser printer dry type one-component and preparation method thereof.
Background technology
As everyone knows, be to improve the aesthetic feeling and the grade of ceramic, common on ceramic have various decorative patterns, literal or a pattern.Decorative pattern wherein, literal or pattern are to adopt manual mode to draw on the greenwave before firing to form.The manual mode render speed is slow, efficient is low but adopt.In order to improve render speed and efficient, there is the people once to attempt to adopt color laser printer earlier decorative pattern, literal or pattern to be printed on the little applique paper, little applique paper wherein is made up of blank sheet of paper and the glued membrane that is compounded in the blank sheet of paper one side.Said decorative pattern, literal or pattern are printed on the glued membrane.Then, there is the little applique paper of decorative pattern, literal or pattern to put into clear water printing and soaks, glued membrane is separated with blank sheet of paper.Afterwards, take the glued membrane that has decorative pattern, literal or pattern and being attached on the greenwave off.The greenwave that will post at last, (having decorative pattern, literal or pattern) glued membrane is put into 800 ℃ kiln and is fired.The pigment composition of the blue ink powder that wherein, uses on the color laser printer is organic pigment.The organic pigment non-refractory is will variable color more than 200 ℃.Therefore, the colored picture and text of printing with this ink powder stick on the greenwave to be fired, and picture and text fade seriously, can't guarantee the quality of ceramic.
Summary of the invention
The problem that the present invention will solve provides a kind of blue refractory ceramics ink powder.This ceramic inkpowder, high temperature resistant.Refractory ceramics ink powder with this blue refractory ceramics ink powder and other black, yellow and red three kinds of Essential colour is used; The colored picture and text of printing stick on the greenwave after firing under 800 ℃ of temperature; Picture and text are colour-fast, can guarantee the quality of ceramic.
Another problem that the present invention will solve provides a kind of method for preparing blue refractory ceramics ink powder.
For addressing the above problem, the present invention takes following technical scheme:
Choose the raw material of following parts by weight earlier:
28 ~ 46 parts of blue inorganic ceramic paints;
42 ~ 65 parts of styrene-acrylic resins;
4 ~ 8 parts of polypropylene waxes;
3 ~ 7 parts of charge adjusting agents;
5 ~ 8 parts of dimethyldichlorosilanes; 9 ~ 13 parts of hexamethyldisilazanes.
Again blue inorganic ceramic paint, styrene-acrylic resin, polypropylene wax and charge adjusting agent are poured in the mixing roll, mixed, process compound.
Afterwards, above-mentioned compound is dropped in the extruding machine, under 150 ~ 200 ℃ temperature, extrude in flakes; Then with sheet compound cooling to 45 ~ 55 ℃ and be ground into fragment.
Afterwards, above-mentioned fragment is ground into the flour that particle diameter is 20 ~ 40 μ m.
Afterwards, with fluidized bed air flow crusher above-mentioned flour is carried out further air-flow and pulverize, and carry out classification, separation, collection successively, obtaining mean grain size is the semi-manufacture particle of 6 ~ 8 μ m.
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 10 ~ 12 minutes, make its flowability greater than 25% with 1200 ~ 1300 rev/mins mixing rolls.
At last, sieve, process blue refractory ceramics ink powder with 200 ~ 250 eye mesh screens.
Adopt above scheme, have the following advantages:
Can find out by such scheme, owing to contain the blue inorganic ceramic paint in the raw material of the high refractory ceramics ink powder of blueness of the present invention, and blue look inorganic ceramic pigment is high temperature resistant, and good with the styrene-acrylic resin intermiscibility.Form four kinds of Essential colour with blue refractory ceramics ink powder of the present invention and other ceramic inkpowder that contains black, redness, yellow inorganic ceramic pigment; To have versicolor decorative pattern, literal or pattern with color laser printer and be printed on the little applique paper, little applique paper wherein is made up of blank sheet of paper and the glued membrane that is compounded in the blank sheet of paper one side.Said decorative pattern, literal or pattern are printed on the glued membrane.Then, there is the little applique paper of decorative pattern, literal or pattern to put into clear water printing and soaks, glued membrane is separated with blank sheet of paper.Afterwards, take the glued membrane that has decorative pattern, literal or pattern and being attached on the greenwave off.At last; To post the sticking on the ceramic base of (having decorative pattern, literal or pattern) glued membrane; Under 800 ℃ of high temperature, fire, colour-fast, and also picture and text are clear more beautiful; Solve on high-quality ceramic the technical barrier of making the picture and text non-refractory, seriously fading, guaranteed the quality of high-quality ceramic.
(4) embodiment
First embodiment
Choose blue inorganic ceramic paint, the styrene-acrylic resin of 50 weight portions, the polypropylene wax of 8 weight portions, the charge adjusting agent of 5 weight portions, the dimethyldichlorosilane of 8 weight portions, the 12 weight portion hexamethyldisilazanes of 40 weight portions.Wherein: said blue inorganic ceramic paint is that peacock blue that pigment company limited produces reined in by Hunan section; Charge adjusting agent is the salicylic acid metal complex that Long-Ting of Hubei Chemical Co produces.
Earlier with blue inorganic ceramic paint, styrene-acrylic resin, polypropylene is cured and charge adjusting agent is poured in the mixing roll.Mix, process compound.
Again above-mentioned compound is dropped in the extruding machine, under 180 ℃ temperature, extrude slabbing.Then, with sheet compound cooling to 50 ℃ and be ground into fragment.
Afterwards, use mechanical crusher that above-mentioned fragment is ground into the flour that particle diameter is 20 μ m.
Afterwards, use pressure to be 7.5kg/m
3Pressurized air in the fluidized bed comminutor, carry out air-flow and pulverize, and carry out classification with 5500 rev/mins grader, separate with cyclone separator, separate, collect with drip catcher, obtaining mean grain size is the semi-manufacture particle of 7 μ m.
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 10 minutes, make its flowability greater than 25% with 1300 rev/mins mixing rolls.
At last, sieve, process blue refractory ceramics ink powder with 200 eye mesh screens.
Second embodiment
Choose the blue inorganic ceramic paint of 46 weight portions, the styrene-acrylic resin of 42 weight portions, the polypropylene wax of 4 weight portions, the charge adjusting agent of 7 weight portions, the dimethyldichlorosilane of 5 weight portions, the hexamethyldisilazane of 13 weight portions.Wherein: said blue inorganic ceramic paint is that peacock blue that pigment company limited produces reined in by Hunan section; Charge adjusting agent is the salicylic acid metal complex that Hubei Dinglong Chemical Co., Ltd produces.
Earlier with blue inorganic ceramic paint, styrene-acrylic resin, polypropylene is cured and charge adjusting agent is poured in the mixing roll.Mix, process compound.
Again above-mentioned compound is dropped in the extruding machine, under 200 ℃ temperature, extrude slabbing.Then, with sheet compound cooling to 45 ℃ and be ground into fragment.
Afterwards, use mechanical crusher that above-mentioned fragment is ground into the flour that particle diameter is 40 μ m.
Afterwards, use pressure to be 8kg/m
3Pressurized air in the fluidized bed comminutor, carry out air-flow and pulverize, and carry out classification with 6000 rev/mins grader, separate with cyclone separator, separate, collect with drip catcher, obtaining mean grain size is the semi-manufacture particle of 8 μ m.
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 12 minutes, make its flowability greater than 25% with 1250 rev/mins mixing rolls.
At last, sieve, process blue refractory ceramics ink powder with 230 eye mesh screens.
The 3rd embodiment
Choose the blue inorganic ceramic paint of 28 weight portions, the styrene-acrylic resin of 65 weight portions, the polypropylene wax of 6 weight portions, the charge adjusting agent of 3 weight portions, the dimethyldichlorosilane of 6 weight portions, the hexamethyldisilazane of 9 weight portions.Wherein: said blue inorganic ceramic paint is that peacock blue that pigment company limited produces reined in by Hunan section; Charge adjusting agent is the salicylic acid metal complex that Hubei Dinglong Chemical Co., Ltd produces.
Earlier with blue inorganic ceramic paint, styrene-acrylic resin, polypropylene is cured and charge adjusting agent is poured in the mixing roll.Mix, process compound.
Again above-mentioned compound is dropped in the extruding machine, under 150 ℃ temperature, extrude slabbing.Then, with sheet compound cooling to 55 ℃ and be ground into fragment.
Afterwards, use mechanical crusher that above-mentioned fragment is ground into the flour that particle diameter is 30 μ m.
Afterwards, use pressure to be 7kg/m
3Pressurized air in the fluidized bed comminutor, carry out air-flow and pulverize, and carry out classification with 5000 rev/mins grader, separate with cyclone separator, separate, collect with drip catcher, obtaining mean grain size is the semi-manufacture particle of 6 μ m.
Again, add dimethyldichlorosilane and hexamethyldisilazane, mixed 11 minutes, make its flowability greater than 25% with 1200 rev/mins mixing rolls.
At last, sieve, process blue refractory ceramics ink powder with 250 eye mesh screens.
Claims (2)
1. blue refractory ceramics ink powder is characterized in that containing the raw material of following parts by weight:
28 ~ 46 parts of blue inorganic ceramic paints;
42 ~ 65 parts of styrene-acrylic resins;
4 ~ 8 parts of polypropylene waxes;
3 ~ 7 parts of charge adjusting agents;
5 ~ 8 parts of dimethyldichlorosilanes;
9 ~ 13 parts of hexamethyldisilazanes.
2. the method for preparing the said blue refractory ceramics ink powder of claim 1 is characterized in that may further comprise the steps successively:
(1) earlier blue inorganic ceramic paint, styrene-acrylic resin, polypropylene wax and charge adjusting agent are poured in the mixing roll, mixed, process compound;
(2) more above-mentioned compound is dropped in the extruding machine, under 150 ~ 200 ℃ temperature, extrude in flakes; Then with sheet compound cooling to 45 ~ 55 ℃ and be ground into fragment;
(3) afterwards, above-mentioned fragment is ground into the flour that particle diameter is 20 ~ 40 μ m;
(4) afterwards, with fluidized bed air flow crusher above-mentioned flour is carried out further air-flow and pulverize, and carry out classification, separation, collection successively, obtaining mean grain size is the semi-manufacture particle of 6 ~ 8 μ m;
(5) again after, add dimethyldichlorosilane and hexamethyldisilazane, with 1200 ~ 1300 rev/mins mixing rolls mixing 10 ~ 12 minutes, make its flowability greater than 25%;
(6) last, sieve with 200 ~ 250 eye mesh screens, process blue refractory ceramics ink powder.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110327960 CN102368145A (en) | 2011-10-26 | 2011-10-26 | Blue high-temperature resisting ceramic toner and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110327960 CN102368145A (en) | 2011-10-26 | 2011-10-26 | Blue high-temperature resisting ceramic toner and preparation method thereof |
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| CN102368145A true CN102368145A (en) | 2012-03-07 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103869643A (en) * | 2012-12-13 | 2014-06-18 | 周拯 | Color ceramic carbon power and preparation method thereof |
| CN104020645A (en) * | 2014-05-06 | 2014-09-03 | 无锡佳腾磁性粉有限公司 | Powdered ink of laser blueprint engineering machine and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068692A (en) * | 1993-10-07 | 2000-05-30 | Zimmer; Michael | Decorated ceramic and glass articles, process for their manufacture and ceramic dye compositions for carrying out the process |
| EP1975728A2 (en) * | 2007-03-26 | 2008-10-01 | Xerox Corporation | Emulsion aggregation toner compositions having ceramic pigments |
| CN101727034A (en) * | 2010-02-02 | 2010-06-09 | 天津市中环天佳电子有限公司 | Black ceramic inkpowder |
| CN101788773A (en) * | 2009-11-13 | 2010-07-28 | 无锡佳腾磁性粉有限公司 | Blue durability anti-counterfeit developer of colored laser printer and preparation method thereof |
-
2011
- 2011-10-26 CN CN 201110327960 patent/CN102368145A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068692A (en) * | 1993-10-07 | 2000-05-30 | Zimmer; Michael | Decorated ceramic and glass articles, process for their manufacture and ceramic dye compositions for carrying out the process |
| EP1975728A2 (en) * | 2007-03-26 | 2008-10-01 | Xerox Corporation | Emulsion aggregation toner compositions having ceramic pigments |
| CN101788773A (en) * | 2009-11-13 | 2010-07-28 | 无锡佳腾磁性粉有限公司 | Blue durability anti-counterfeit developer of colored laser printer and preparation method thereof |
| CN101727034A (en) * | 2010-02-02 | 2010-06-09 | 天津市中环天佳电子有限公司 | Black ceramic inkpowder |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103869643A (en) * | 2012-12-13 | 2014-06-18 | 周拯 | Color ceramic carbon power and preparation method thereof |
| CN103869643B (en) * | 2012-12-13 | 2016-09-28 | 周拯 | The preparation method of chromatic ceramics carbon dust |
| CN104020645A (en) * | 2014-05-06 | 2014-09-03 | 无锡佳腾磁性粉有限公司 | Powdered ink of laser blueprint engineering machine and preparation method thereof |
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Application publication date: 20120307 |